Universid

Actividad de a
niversidad Autónoma de Yucatán
Facultad de Ingenieria Química

INGENIERÍA DE REACTORES 1
Dr. Alejandro Estrella Gutiérrez.

Actividad de aprendizaje 3. Cinética de las reacciones químicas.

Equipo:

Edwin Josué Martín Martín

Alfredo Enrique Azcorra Ventura
Evelyn Obdulia Segovia Piste
 CINETICA
SEGUNDO OR
t(s)
CA0 0.1 0
CB0 0.1 230
465
720
1040
1440
1920
2370

CINÉTICA DE SEGUNDO
30

f(x) = 0.00749353504585757 x + 10.023343537603

25 R² = 0.999983452943762

20
T1/[C5H5N]

15

10

5
 20

T1/[C5H5N]
15

10

0
0 500 1000 150
t(s)
 CINETICA
SEGUNDO ORDEN
[I] (mol/dm-3) [C5H5N](mol/L) 1/[C5H5N]
0 0.1 10
0.015 0.085 11.7647058824
0.026 0.074 13.5135135135
0.035 0.065 15.3846153846
0.044 0.056 17.8571428571
0.052 0.048 20.8333333333
0.059 0.041 24.3902439024
0.064 0.036 27.7777777778

CINÉTICA DE SEGUNDO ORDEN

30

f(x) = 0.00749353504585757 x + 10.0233435376038

25 R² = 0.999983452943762

20

15

10

5
20

15

10

0
0 500 1000 1500 2000 2500
t(s)

k 0.0075
t1/2(s) P0(torr) In(t1/2) In(P0)
634 86.5 6.4520489544 4.4601444139
393 164 5.9738096119 5.0998664278
255 290 5.5412635452 5.669880923
212 360 5.3565862747 5.8861040315

Pendiente -0.7642
Orden (n) 1.7642
 Tiempo de Vida Media
7

6 f(x) = − 0.764232265432391 x + 9.86530842258053

R² = 0.999654159712201
5

4
Log(t1/2)

0
4.2 4.4 4.6 4.8 5 5.2 5.4 5.6 5.8 6
Log(CA0)
5.8 6
 [H2O2]
Tiempo (s) (mol/L) CA/CA0 -Ln(CA/CA0 )

0 7.50E-06 1.99E+00 -0.690484063

2 6.23E-06 1.66E+00 -0.504957375
4 4.84E-06 1.29E+00 -0.252495763
6 3.76E-06 1.00E+00 0
8 3.20E-06 8.51E-01 0.1612681476
10 2.60E-06 6.91E-01 0.3689075124
12 2.16E-06 5.74E-01 0.5543107357
14 1.85E-06 4.92E-01 0.7092333183
16 1.49E-06 3.96E-01 0.9256428374
18 1.27E-06 3.38E-01 1.0854020569
20 1.01E-06 2.69E-01 1.3144686265
 Cineti ca de Primer Orden
1.5
f(x) = 0.0987823918400327 x − 0.654069733577836
1 R² = 0.997258361655733
-Ln(CA/CA0 )

0.5

0
0 5 10 15 20 25

-0.5

-1

tiemo (s)

k 0.988
20 25
 t(min) C(M) In(C)
0 0.32 -1.13943428318836
5 0.3175 -1.14727746064939
8 0.3159 -1.1523295711741
10 0.3149 -1.15550015087516
13 0.3133 -1.16059408102399
16 0.3118 -1.16539332235846

Cinetica de Primer Orden (Grafi ca 1)

-1.125
0 2 4 6 8 10 12 14 16 18
-1.13
-1.135
-1.14
-1.145
ln(c)

-1.15
-1.155
-1.16
-1.165
-1.17
t(min)

Column D Column E
t(min) C(M) C/C0 In(C/C0)
0 0.32 1 0
5 0.3175 0.9921875 0.0078431774610259
8 0.3159 0.9871875 0.0128952879857327
10 0.3149 0.9840625 0.0160658676867932
13 0.3133 0.9790625 0.0211597978356261
16 0.3118 0.974375 0.025959039170096

Cinetica de Primer Orden (Grafica 2)

Column M Linear (Column M) Column N
0.03
0.025
f(x) = 0.00162933505369321 x − 0.000133708775462175
0.02 R² = 0.999841685556765
-Ln(C/C0)

0.015
0.01

0.005
0
0 2 4 6 8 10 12 14 16 18
t(min)

k 0.0016
T1/2 (S) PT, mmHg In(T1/2 (S)) In(PT, mmHg)
265 200 5.579729825986 5.29831736654804
186 240 5.225746673713 5.48063892334199
115 280 4.744932128363 5.63478960316925
104 320 4.644390899141 5.76832099579377
67 360 4.204692619391 5.88610403145016

𝑚=1−𝑛
𝑚−1=−𝑛
−𝑚+1=𝑛

n (orden) 1.4302
 Tiempo de Vida Media
6
5.9
f(x) = − 0.43015051466432 x + 7.71272500494182
5.8 R² = 0.976882431138152
5.7
5.6
ln(pt,mmhg)

5.5
5.4
5.3
5.2
5.1
5
4 4.2 4.4 4.6 4.8 5 5.2 5.4 5.6 5.8
ln(T 1/2)
 CAO 0.1823 mol/L T,min CA, mol/L CA-CAe
CRO 0 mol/L 0 0.1823 0.1329
CSO 55 mol/L 36 0.1453 0.0959
65 0.1216 0.0722
CAe 0.0494 mol/L 100 0.1025 0.0531
𝑋_𝐴=(𝑁_𝐴𝑂−𝑁_𝐴𝑒)/𝑁_𝐴𝑂 160 0.0795 0.0301

XAe 0.729018102 mol/L Reversible de Pseudo

CAO-CAe 0.1329 mol/L 1.6
1.4 f(x) = 0.00927745052829472 x − 0.002043
R² = 0.99984866117442
1.2
1
0.8
--lN

0.6
0.4
0.2
0
0 20 40 60 80
T,MIN
 (CA-CAe)/(CAO-CAE) -LN((CA-CAe)/(CAO-CAe))
1 0 𝑚=(𝑀−1)/(𝑀−𝑋_𝐴𝑒 )
0.721595184349135 0.326290983829807
0.54326561324304 0.610156919820419
𝑀=𝐶_𝑅𝑂/𝐶_𝐴𝑂 =0/0,1823=0
0.399548532731377 0.917420037471307
0.226486079759217 1.48507179396437
0,0093=𝐾_1 1/0,1290

ible de Pseudo Primer Orden 𝐾_1=(0,0093)(0,7290)=6,78𝑥10^(−3

27745052829472 x − 0.00204398112569848
4866117442
𝐾=(𝑀+𝑋_𝐴𝑒)/(1−𝑋_𝐴𝑒 )=0,7290/(1−0,7290

𝐾=𝑘_1/𝑘_(−1)

𝑘_1=𝑘_1/𝐾=(6,78𝑥10^(−3))/2,69=2,52𝑥10^(

40 60 80 100 120 140 160 180

T,MIN
=(𝑀−1)/(𝑀−𝑋_𝐴𝑒 )

_𝑅𝑂/𝐶_𝐴𝑂 =0/0,1823=0

0093=𝐾_1 1/0,1290

93)(0,7290)=6,78𝑥10^(−3)

−𝑋_𝐴𝑒 )=0,7290/(1−0,7290)=2,69

𝐾=𝑘_1/𝑘_(−1)

6,78𝑥10^(−3))/2,69=2,52𝑥10^(−3)
 XAe 0.527272727

CAe 2.6
CAO-CAe 2.9

𝐶_2 𝐻_5 𝑆𝑂_4 𝐻=2𝜉

𝜉=(𝐶_2 𝐻_5 𝑆𝑂_4 𝐻)/2

𝐻_2 𝑆𝑂_4=5.5−𝜉

Reaccion Reversible de Segundo Orden

3

f(x) = 0.00671044143892006 x − 0.0275963628105305

2.5 R² = 0.998805749754826
[XAe-XA(2XAe-1)]/ [XAe-XA]

1.5

1
 ln[XAe-XA(2XAe-1)]/ [XA
0
0.5
1
1.5
2

Ttiempo, min
 Reacción Reversible de la forma A+B↔2R
Tiempo, C2H5SO4H, (C2H5)2SO4 XA XA(2XAe-1) XAe-XA
min mol/L
0 0 5.5 0 0 0.527272727
41 1.18 4.91 0.107272727 0.00585124 0.42
48 1.38 4.81 0.125454545 0.006842975 0.401818182
55 1.63 4.685 0.148181818 0.008082645 0.379090909
75 2.24 4.38 0.203636364 0.011107438 0.323636364
_5 𝑆𝑂_4 𝐻=2𝜉
96 2.75 4.125 0.25 0.013636364 0.277272727
𝐻_5 𝑆𝑂_4 𝐻)/2 127 3.31 3.845 0.300909091 0.016413223 0.226363636
146 3.76 3.62 0.341818182 0.018644628 0.185454545
𝑆𝑂_4=5.5−𝜉 162 3.81 3.595 0.346363636 0.018892562 0.180909091
180 4.11 3.445 0.373636364 0.020380165 0.153636364
194 4.31 3.345 0.391818182 0.021371901 0.135454545
212 4.45 3.275 0.404545455 0.022066116 0.122727273
267 4.86 3.07 0.441818182 0.024099174 0.085454545
318 5.15 2.925 0.468181818 0.02553719 0.059090909
368 5.32 2.84 0.483636364 0.026380165 0.043636364
379 5.35 2.825 0.486363636 0.026528926 0.040909091
410 5.42 2.79 0.492727273 0.026876033 0.034545455
5.8 2.6 0.527272727 0.028760331 0

ble de Segundo Orden A+B↔2R 𝑚=2𝑘_1 (1/𝑋_𝐴𝑒 −1) 𝐶_𝐴𝑂

𝑘_1=(𝑚𝑋_𝐴𝑒)/(2𝐶_𝐴𝑂 (1−𝑋_𝐴𝑒))
275963628105305

𝑘_1=(0,0067(0,5272))/(2(5,5)(1−0,5272))=6,79172

𝐾=𝑋_𝐴𝑒/(1−𝑋_𝐴𝑒 )=0,5272/(1−0,5272)=1,1
 𝐾=𝑋_𝐴𝑒/(1−𝑋_𝐴𝑒 )=0,5272/(1−0,5272)=1,1

𝐾=𝑘_1/𝑘_(−1)

𝑘_(−1)=𝑘_1/𝐾=(6,79172435𝑥10^(−4))/1,115059222=6,09

Ttiempo, min
a A+B↔2R

XAe-XA(2XAe-1) [XAe-XA(2XAe-1)]/ ln[XAe-XA(2XAe-

[XAe-XA] 1)]/ [XAe-XA]
0.52727272727 1 0
0.5214214876 1.241479732389 0.2163040007332
0.52042975207 1.2951871657754 0.2586552142644
0.51919008264 1.36956616525 0.3144940219892
0.51616528926 1.594892747702 0.4668064911557
0.51363636364 1.852459016393 0.616513954539
0.51085950413 2.256809054399 0.8139518927498
0.50862809917 2.742602495544 1.0089072855021
0.50838016529 2.810141617177 1.0332348796476
0.50689256198 3.2993006993007 1.1937105367137
0.50590082645 3.734838316046 1.3177045287713
0.50520661157 4.116498316498 1.4150028787919
0.50317355372 5.888201160542 1.7729505453371
0.50173553719 8.4909090909091 2.1389960724364
0.50089256198 11.47878787879 2.4405007998455
0.50074380165 12.240404040404 2.5047422863763
0.50039669421 14.48516746411 2.6731251923637
0.49851239669 #DIV/0! #DIV/0!

𝑚=2𝑘_1 (1/𝑋_𝐴𝑒 −1) 𝐶_𝐴𝑂

=(𝑚𝑋_𝐴𝑒)/(2𝐶_𝐴𝑂 (1−𝑋_𝐴𝑒))

2))/(2(5,5)(1−0,5272))=6,79172435𝑥10^(−4)

𝑋_𝐴𝑒 )=0,5272/(1−0,5272)=1,115059222
𝑋_𝐴𝑒 )=0,5272/(1−0,5272)=1,115059222

𝐾=𝑘_1/𝑘_(−1)

2435𝑥10^(−4))/1,115059222=6,090909091𝑥10^(−4)
T(min) P (atm) a 100°C 𝒅𝑷_𝑨/𝒅𝒕 (𝑷_𝑨 ) ̅ ln(𝒅𝑷_𝑨/𝒅𝒕) ln( )
(𝑷_𝑨 ) ̅
0 1.251677852
1 1.531677852 0.2800000 1.391677852 -1.27296568 0.330510107
2 1.331677852 0.2000000 1.431677852 -1.60943791 0.35884708
3 1.215677852 0.1160000 1.273677852 -2.15416509 0.241908662 -0.4
4 1.131677852 0.0840000 1.173677852 -2.47693848 0.160142282
5 1.061677852 0.0700000 1.096677852 -2.65926004 0.092285476
6 0.991677852 0.0700000 1.026677852 -2.65926004 0.026328203
7 0.951677852 0.0400000 0.971677852 -3.21887582 -0.02873096
8 0.915677852 0.0360000 0.933677852 -3.32423634 -0.06862381
9 0.881677852 0.0340000 0.898677852 -3.38139475 -0.10683065
ln(dpa/dt)

10 0.851677852 0.0300000 0.866677852 -3.5065579 -0.14308794

15 0.759677852 0.0184000 0.805677852 -3.99540461 -0.2160713
20 0.707677852 0.0104000 0.733677852 -4.56594947 -0.30968524

ln(kp)= -3.0526
kp= 0.047235951
kc= 0.001542616
 𝑷_𝑨𝟎 1.251677852349
a 2
Δn -1

P parcial(atm) a
T(min)
25°C
0 1
1 1.14
2 1.04
3 0.982
4 0.94
5 0.905
6 0.87
7 0.85
8 0.832
9 0.815
10 0.8
15 0.754
20 0.728
P (atm) a 100°C 1/P
1.25167785234899 0.79892761394
1.53167785234899 0.65287880116
1.33167785234899 0.75093236569
1.21567785234899 0.82258634396
1.13167785234899 0.88364369588
1.06167785234899 0.94190530375
0.99167785234899 1.00839198701
0.95167785234899 1.05077574048
0.91567785234899 1.09208713243
0.88167785234899 1.13420111136
0.85167785234899 1.17415287628
0.75967785234899 1.31634744505
0.70767785234899 1.41307234172

Pendiente = Kp= 0.0393

Kc= 0.00128344597

Segundo metodo
0
-0.4 -0.3 -0.2 -0.1 0 0.1 0.2 0.3 0.4
-0.5

-1

-1.5
f(x) = 4.15240720037662 x − 3.05258141373249
R² = 0.973164795674282 -2
ln(dpa/dt)

-2.5

-3

-3.5

-4

-4.5

-5
ln(pa)
 Primer metodo
1.6

1.4 f(x) = 0.0392769155848894 x + 0.725504395177204

R² = 0.929071701834166
1.2

0.8
1/p

0.6

0.4

0.2

0
0 5 10 15 20 25
T(min)

0.3 0.4
 𝒕/
𝑪_𝑨 𝑪_𝑨𝟎/𝑪_𝑨 𝐥𝐧⁡(𝑪_𝑨𝟎/𝑪_𝑨 ) 𝐥𝐧⁡(𝑪_𝑨
t(h) 𝑪_𝑨𝟎−𝑪_𝑨
𝟎/𝑪_𝑨 )
(mmol/L)
0.84 1 1.1904762 0.174353387 0.16 5.7354779
0.68 2 1.4705882 0.385662481 0.32 5.1858817
0.53 3 1.8867925 0.634878272 0.47 4.7253153
0.38 4 2.6315789 0.967584026 0.62 4.1340079
0.27 5 3.7037037 1.30933332 0.73 3.8187373
0.16 6 6.2500000 1.832581464 0.84 3.2740700
0.09 7 11.1111111 2.407945609 0.91 2.9070424
0.04 8 25.0000000 3.218875825 0.96 2.4853397
0.018 9 55.5555556 4.017383521 0.982 2.2402641
0.006 10 166.6666667 5.11599581 0.994 1.9546537
0.0025 11 400.0000000 5.991464547 0.9975 1.8359451

𝑪_𝑨𝟎 (mmol/L) 1
𝑪_𝑬𝟎 (mmol/L) 0.01

Ejercicio 9
1.0000000

0.9000000 f(x) = 0.195710940420846 x − 0.188120276234529

R² = 0.998850293469977
0.8000000

0.7000000
(CA0-CA)/LN(CA0/CA)

0.6000000

0.5000000

0.4000000

0.3000000

0.2000000

0.1000000
 0.5000000

(CA0-CA)/LN(
0.4000000

0.3000000

0.2000000

0.1000000

0.0000000
1.5000000 2.0000000 2.5000000 3.0000000 3.5000000 4.0000000 4.5000000 5.0000000 5.5000000
T/LN/CA0/CA)
 Paso previo a resolver el ejericicio
Tenemos que ajustar la ecuacion cinetica del tipo de
Michaelis-Menten, haciendo nos hacer unos ajustes,
que son los siguentes:

(𝑑𝐶_𝐴)/𝑑𝑡=(𝑘_3 𝐶_𝐴 𝐶_𝐸0)/(𝐶_𝐴+𝑀)

〖 (𝐶 〗 _𝐴+𝑀)∙𝑑𝐶_𝐴= (𝑘_3
𝐶_𝐴 𝐶_𝐸0)∙𝑑𝑡
Dividimos a toda la expresion entre 𝐶_𝐴
dando como resultado la siguente expresion:
((𝐶_𝐴+𝑀)/𝐶_𝐴 )∙𝑑𝐶_𝐴= (𝑘_3
𝐶_𝐸0)∙𝑑𝑡
Integramos la ecuacion
(𝑪_𝑨𝟎−𝑪_ ∫_(𝐶_𝐴0)^(𝐶_𝐴)▒ 〖 (𝐶_𝐴+𝑀)/𝐶_𝐴 ∙𝑑𝑐𝐴=𝑘_3∙𝐶_𝐸0∙∫_0^𝑡▒𝑑𝑡 〗
𝑨)/
𝐥𝐧⁡(𝑪_𝑨𝟎/
𝑪_𝑨 )
0.9176765
0.8297411 ∫_(𝐶_𝐴0)^(𝐶_𝐴)▒ 〖 (𝐶_𝐴+𝑀)/𝐶_𝐴 ∙𝑑𝑐𝐴=𝑘_3∙𝐶_𝐸0∙∫_0^𝑡▒𝑑𝑡 〗
0.7402994
0.6407712
0.5575356 ∫_(𝐶_𝐴0)^(𝐶_𝐴)▒ 〖 (1+𝑀/
0.4583698 𝐶_𝐴 )∙𝑑𝑐𝐴=𝑘_3∙𝐶_𝐸0∙∫_0^𝑡▒𝑑𝑡 〗
0.3779155
0.2982408 Me da como resultado:
0.2444377
(𝐶_𝐴0−𝐶_𝐴 )+𝑀∙ln⁡(𝐶_𝐴0/𝐶_𝐴 )=𝑘_3∙𝐶_𝐸0∙𝑡
0.1942926
0.1664868
ln⁡(𝐶_𝐴0/𝐶_𝐴 )
Dividimos entre

toda la ecuacion, dando como resultado:

(𝐶_𝐴0−𝐶_𝐴)/ln⁡(𝐶_𝐴0/𝐶_𝐴 ) =−𝑀+[𝑘_3∙𝐶_𝐸0∙𝑡/ln⁡(𝐶_𝐴0/𝐶_𝐴 ) ]

Una vez buscada la ecuacion sabemos que la M es la

ordnada y que 𝒌_𝟑∙𝑪_𝑬𝟎es la pendiente
Para M, al estar en la ecuacion negativa y en la recta
nos dio un numero negativo, solo se multiplica negativo
con negativo, entonces M nos queda:
Para en contar a K3 tenemos que que hacer una
pequeña ecuacion, la cual es la siguente:
0.1957=𝑘_3∙𝐶_𝐸0
𝑀=𝟎.𝟏𝟖𝟖𝟏
 0.1957=𝑘_3∙𝐶_𝐸0
𝑀=𝟎.𝟏𝟖𝟖𝟏
Como sasabemos el valor de 𝐶_𝐸0

𝑘_3= 19.57
4.5000000 5.0000000 5.5000000 6.0000000
𝑷_𝟎(Torr) 𝒕_(𝟏/𝟐)
(s) ln(𝑷_𝟎) 𝒕_(𝟏/𝟐)
ln( )
86.5 634 4.460144414 6.452048954 Pendiente -0.7642
164 393 5.099866428 5.973809612 Orden 1.7642
290 255 5.669880923 5.541263545
360 212 5.886104031 5.356586275

Ejercicio 10
7

6 f(x) = − 0.764232265432391 x + 9.86530842258053

R² = 0.999654159712201
5

4
ln(t1/2)

0
4 4.2 4.4 4.6 4.8 5 5.2

ln(Po)
10

530842258053

5.2 5.4 5.6 5.8 6

)
 T(°C) T(K)
𝒌/ 〖 𝟏𝟎 〗 ^(−𝟓) 𝒔^(−𝟏)k 1/T ln(k)
493 766.15 8.4 0.000084 0.001305227 -9.38469376
509 782.15 24.1 0.000241 0.001278527 -8.33071362
514 787.15 24.2 0.000242 0.001270406 -8.32657283
522 795.15 38.1 0.000381 0.001257624 -7.87271118
541 814.15 90.2 0.000902 0.001228275 -7.01089604
546 819.15 140 0.0014 0.001220778 -6.57128304
555 828.15 172 0.00172 0.001207511 -6.36543099

Ejercicio 11
0
0.0012 0.00122 0.00124 0.00126 0.00128 0.0013 0.00132

-1

-2

-3

-4
ln(k)

-5

-6
f(x) = − 30976.5509232381 x + 31.1072683666862
-7 R² = 0.990705764265019
-8

-9

-10

1/t
 Una vez conseguida la grafica, podemos encontrar los parametros de
Arrhenius, Ea y A

ln⁡〖𝑘 = 〗−𝐸 _𝑎/𝑅 (1/𝑇)+ln⁡𝐴

donde la pendiente es
𝑚=−𝐸_𝑎/𝑅

despejamos a Ea y sustituimos los valores encontrados gracias a la

grafica
𝐸_𝑎=−𝑚∙𝑅
𝐸_𝑎=−(−30977)∙(8.314)
13 0.00132

𝐸_𝑎= 257542.778 J

Para calcular a A, sabemos que ln A es la ordena por lo quetenemos que

hacer lo siguente:
ln⁡𝐴=31.107

𝐴=𝑒^31.107=3.232946E+13
T(°C) 𝒌/ 〖 𝟏𝟎
T(K) 𝒌 〗〖〖𝒅𝒎〗 ^𝟑/𝒎𝒐𝒍 〗
〗 ^(−𝟐) 〖〖𝒅𝒎〗 ^𝟑 𝒎𝒐𝒍 ^(−𝟏) 𝒔^(−𝟏) 𝒌 ^𝟏
〖𝒎𝒔^𝟏
^𝟑/𝒎𝒐𝒍 〗 ^𝟏 𝒔^𝟏
20.07 293.22 1.8 0.018 0.000018
36.87 310.02 13.1 0.131 0.000131
50.03 323.18 43 0.43 0.00043

Ejercicio 12
0
0.00305 0.0031 0.00315 0.0032 0.00325 0.0033 0.00335

-2

-4
ln(k)

-6

-8
f(x) = − 10083.2870404655 x + 23.4986016546034
R² = 0.997835666913341
-10

-12
1/T
 Una vez conseguida la grafica, podemos encontrar los parametros d
Arrhenius, Ea y A

ln⁡〖𝑘 = 〗−𝐸 _𝑎/𝑅 (1/𝑇)+ln⁡𝐴

donde la pendiente es
𝑚=−𝐸_𝑎/𝑅

despejamos a Ea y sustituimos los valores encontrados gracias a la

grafica
𝐸_𝑎=−𝑚∙𝑅

1/T ln(k) 𝐸_𝑎=−(−10083)∙(8.314)

𝒎𝒐𝒍 〗 ^𝟏 𝒔^𝟏
0.003410409 -10.9251388
0.003225598 -8.94031323 𝐸_𝑎= 83830.062 J
0.003094251 -7.75172535
Para calcular a A, sabemos que ln A es la ordena por lo quetenemos
que hacer lo siguente:
ln⁡𝐴=23.499

.0033 0.00335 0.0034 0.00345 1.6050E+10

𝐴=𝑒^31.107=
ontrar los parametros de

encontrados gracias a la

dena por lo quetenemos

e:
 T (°C) k(seg^-1) T(K) 1/T ln(k)
0 7.87E-07 273.15 3.660992E-03 -14.055038
25 3.46E-05 298.15 3.354016E-03 -10.271657
35 1.35E-04 308.15 3.245173E-03 -8.9102358
45 4.98E-04 318.15 3.143171E-03 -7.6049105
55 1.50E-03 328.15 3.047387E-03 -6.5022902
65 4.87E-03 338.15 2.957267E-03 -5.3246613

Ejercicio 13
0
2.900000E-03 3.000000E-03 3.100000E-03 3.200000E-03 3.300000E-03 3.400000E-03 3.500000E-03 3.600000E-03

-2

-4

-6 f(x) = − 12388.08305717 x + 31.2932021129154

R² = 0.999916134790693
ln(k)

-8

-10

-12

-14

-16
1/T
 Por lo pedido en el ejercicio, debemos encontrar lo
Arrhenius, Ea y A

ln⁡〖𝑘 = 〗−𝐸 _𝑎/𝑅 (1/𝑇)+ln⁡𝐴

donde la pendiente es
𝑚=−𝐸_𝑎/𝑅

despejamos a Ea y sustituimos los valores encontrados

𝐸_𝑎=−𝑚∙𝑅
𝐸_𝑎=−(−12388)∙(8.314)

𝐸_𝑎=

Para calcular a A, sabemos que ln A es la ordena por lo

hacer lo siguente:

𝐴=𝑒^31.107=
03 3.500000E-03 3.600000E-03 3.700000E-03
Procdemos a colocarlo en la siguente ecuacion, para p
50°C, que es igual a 323.15 K

ln⁡〖𝑘 = 〗− 102993.832/8.314 (1/323.1

ln⁡〖𝑘 = 〗
𝑘=
 en el ejercicio, debemos encontrar los parametros de
Arrhenius, Ea y A

ln⁡〖𝑘 = 〗−𝐸 _𝑎/𝑅 (1/𝑇)+ln⁡𝐴

donde la pendiente es
𝑚=−𝐸_𝑎/𝑅

y sustituimos los valores encontrados gracias a la grafica

𝐸_𝑎=−𝑚∙𝑅
𝐸_𝑎=−(−12388)∙(8.314)

𝐸_𝑎= 102993.832 J

A, sabemos que ln A es la ordena por lo quetenemos que

hacer lo siguente:
ln⁡𝐴=31.293

𝐴=𝑒^31.107= 3.8938E+13

ocarlo en la siguente ecuacion, para poder encontrarlo a

50°C, que es igual a 323.15 K

𝑘 = 〗− 102993.832/8.314 (1/323.15)+31.293

ln⁡〖𝑘 =-7.04213848058
〗
𝑘= 8.74255E-04
 P r(HBr) ln(P) ln(r(HBr))
4.7 0.98 1.5476 -0.0202
11 2.35 2.3979 0.8544
15.3 3.16 2.7279 1.1506
20.3 3.96 3.0106 1.3762
26.1 5.56 3.2619 1.7156
34.1 6.77 3.5293 1.9125

Velocidad HBr con P constante 10 Torr de NO2

2.5000

2.0000
f(x) = 0.97875616436784 x − 1.52267344092095
1.5000 R² = 0.997592494815757
ln(r(HBr))

1.0000

0.5000

0.0000
1.0000 1.5000 2.0000 2.5000 3.0000 3.5000 4.0000
-0.5000
ln(P) Hr
 P -r(HBr) ln(P) ln(-r(HBr))
5 1.27 1.6094 0.2390
10.2 2.37 2.3224 0.8629
15.4 3.64 2.7344 1.2920
20.3 4.94 3.0106 1.5974
25.7 6.19 3.2465 1.8229

Velocidad NO2 con P constante 10 Torr de HBr

2.0000
1.8000
f(x)==0.997754800682802
R² 0.975433341282615 x − 1.3583263282002
1.6000
1.4000
In (-r(HBr))

1.2000
1.0000
0.8000
0.6000
0.4000
0.2000
0.0000
1.4000 1.6000 1.8000 2.0000 2.2000 2.4000 2.6000 2.8000 3.0000 3.2000 3.4000

In(p) NO2
3.4000
 T,k Kf Kr 1/T ln(Kf) ln(Kr)
400 0.161 0.000159 0.002500 -1.826351 -8.746606
410 0.279 0.000327 0.002439 -1.276543 -8.025550
420 0.47 0.000649 0.002381 -0.755023 -7.340078
430 0.775 0.00125 0.002326 -0.254892 -6.684612
440 1.249 0.002323 0.002273 0.222343 -6.064896

Directa
0.500000

0.000000 f(x) = − 9012.40316421296 x + 20.704385478194

0.002250 R² = 0.999999012048419
0.002300 0.002350 0.002400 0.002450 0.002500 0.002550

-0.500000
In(Kf)

-1.000000

-1.500000

-2.000000
1/T

Reacción Directa
A -9012.4
R 8.314
Ae 74929.0936
 Ecuación de Arrhenius
Ecuación Expresada Ecuación Integrada

Inversa
0.000000
0.002250 0.002300 0.002350 0.002400 0.002450 0.002500 0.002550
-1.000000
0.002550 -2.000000
-3.000000
-4.000000
-5.000000
-6.000000
f(x) = − 11804.0651075018 x + 20.7644950316058
-7.000000 R² = 0.99999780351449
-8.000000
-9.000000
-10.000000

Reacción Inversa
A -11804
R 8.314
Ae 98138.456
rrhenius
Ecuación Integrada
 SE SUPONE QUE DEBE SER DE PRIMER ORDEN LA REACCIÓN
t, min In(T = 25 °C) In(T=30 °C) In(T=35 °C) In(T=40 °C)
0 -0.288 -0.288 -0.288 -0.288
15 -0.434 -0.475 -0.528 -0.587
30 -0.576 -0.635 -0.713 -0.821
45 -0.666 -0.761 -0.892 -1.008
60 -0.777 -0.892 -1.008 -1.155
75 -0.882 -0.973 -1.155 -1.291
90 -0.955 -1.091 -1.238 -1.415

T(°C) k(A) 1/T

25 -0.0074 0.003354
30 -0.0087 0.003299
35 -0.0105 0.003245
40 -0.0122 0.003193
45 -0.014 0.003143
 t, min T = 25 °C T=30 °C T=35 °C T=40 °C T=45 °C
0 0.750 0.750 0.750 0.750 0.750
15 0.648 0.622 0.590 0.556 0.520
30 0.562 0.530 0.490 0.440 0.400
45 0.514 0.467 0.410 0.365 0.324
60 0.460 0.410 0.365 0.315 0.270
75 0.414 0.378 0.315 0.275 0.235
90 0.385 0.336 0.290 0.243 0.205

In(T) 25~45 °C
0.000
0 10 20 30 40 50 60 70 80 90
LA REACCIÓN -0.200
In(T=45 °C)
-0.400 f(x)
f(x) == −− 0.00737336767188616 x − 0.321950188629013
-0.288 f(x)
f(x) −− 0.00871832804949632
=====0.989682987064498
0.0104766302007618
0.0121981708829146 xx x−−−0.360148461430457
0.338233076931125
R²
R²
f(x) 0.985390909132245
− 0.0139826639646383
R² == 0.97272061865123
0.978532040034925 x − 0.388849194806911
0.417517181532402
-0.654 R²
R² = 0.967224551156846
-0.600
-0.916
-1.127 -0.800
-1.309
In(T)

-1.448 -1.000
-1.585
-1.200

-1.400

-1.600

-1.800
T,min

In(K)
-3.800000
In(K) 0.003100 0.003150 0.003200 0.003250 0.003300 0.003350 0.003400
-4.906275 -4.000000
-4.744432
-4.200000
f(x) = − 3062.56815513697 x + 5.36737983812521
-4.400000 R² = 0.998293950356405
 -3.800000
0.003100 0.003150 0.003200 0.003250 0.003300 0.003350 0.003400

-4.000000

-4.556380 -4.200000
-4.406319 f(x) = − 3062.56815513697 x + 5.36737983812521
-4.400000 R² = 0.998293950356405
-4.268698

-4.600000

-4.800000

-5.000000
 Ecuación de Arrhenius
Ecuación Expresada Ecuación Integrada

5~45 °C
70 80 90 100

In(T=25°C)
Linear
(In(T=25°C))
In(T=30°C)
Linear
(In(T=30°C))
In(T=35°C)
Linear
(In(T=35°C))
In(T=40°C)
Linear
(In(T=40°C))
In(T=45°C)
Linear
(In(T=45°C))

Reacción Directa
A -3062.6
R 8.314
Ae 25462.4564
Ecuación Integrada Datos
cA0 0.5 mol/L
cR0 0 mol/L
xA 0.333 %
xAe 0.667 %
t 8 min
 k1+ (k-1) 0.086456132 k 2.003003003

k1=2*(k-1) 0.028818711 k1 0.057637421

 Planteando la ecuación de la reacción
−𝑟𝐴=−𝑑𝑐𝐴/𝑑𝑡 −𝑑𝑐𝐴/𝑑𝑡=3∗𝐶_𝐴^0.5 𝑚𝑜𝑙/(𝑙∗ℎ)

Sustituyendo Datos
𝑐𝐴^(1−𝑛)=𝑘∗(𝑛−1)∗𝑡+𝑐𝐴0^((1−𝑛))
√𝑐𝐴0−√𝑐𝐴=1.5𝑡

Buscamos el Tiempo donde la conveción es 100 %

√1−√0=1.5𝑡
t=0.6667 ℎ𝑟𝑠
t=1/1.5=0.6667
 Ecuación de Cinetica

Sustituyendo valores

T=1 (0.25)^(1−𝑛)− 〖 (1) 〗 ^(1−𝑛)=𝑘∗(𝑛−1)∗𝑡

T=2 (0)^(1−𝑛)− 〖 (1) 〗 ^(1−𝑛)=𝑘∗(𝑛−1)∗𝑡

 Suponemos inicialmente
n=0.8 y k=0.8

Datos T Concentración (cA)

n 0.50126424975 0 1
K supuesta 0.8 1 0.25
2 0

Dividiendo ec.1 entre ec.2

0.499 "=" 0.5 -rA = 1
Diferencia
-0.000877079518398105

Usando busqueda por objetivo en la celda

diferencia donde debe ser "0" cambiando los
valores de "n" en la tabla de datos. Se pudo
obtener el valor real de n donde K es igual a 1
Conversión (xA)
0
0.75
1

*cA^ 0.5
 t Presión Parcial A PpA-PpAe (PpA-PpAe)/(PpA0-PpAe)
0 760 610 1
2 600 450 0.737704918032787
4 475 325 0.532786885245902
6 390 240 0.39344262295082
8 320 170 0.278688524590164
10 275 125 0.204918032786885
12 240 90 0.147540983606557
14 215 65 0.10655737704918
eq 150

-ln((PpA-PpAe)/(PpA0-PpAe))
2.5

f(x) = 0.160309917824087 x − 0.0118954376239899

2 R² = 0.99986338285586

1.5

0.5

0
0 2 4 6 8 10 12 14 16
 #NAME?
0
0.304211374402991
0.629633774837619
0.932820033825366
1.2776605201171
1.58514521986506
1.91364928683709
2.23907168727172

xAe 0.802631579
M 0
Ae 0.1603
k 4.066666667
K1 0.128661842
k-1 0.031638158

14 16