Se estudió la cinética de esta degradación a las temperaturas de 0 oC 10oC, 25oC, 30oC, 40oC

y 50oC, siguiendo la formación del producto paranitrofenol, registrando los valores de la

absorbancia a l = 400 nm en función del tiempo, los resultados experimentales se
presentan en el siguiente Cuadro:
t (min) A a 0 oC ao/at ln ao/at
0 0.14143 1 0
10 0.16977 0.83306827 -0.18263968
20 0.19213 0.73611617 -0.30636733
30 0.21127 0.66942775 -0.40133204
40 0.23176 0.61024336 -0.49389746
50 0.24949 0.56687643 -0.56761394
60 0.26887 0.52601629 -0.6424231
90 0.31897 0.44339593 -0.81329216
120 0.35325 0.40036801 -0.91537113
130 0.36021 0.39263208 -0.9348823
140 0.36421 0.38831993 -0.94592573
160 0.36656 0.38583042 -0.95235732
180 0.36786 0.38446692 -0.95589754
k -0.0103 t -67.2958428
-0.8

-0.7
y = -0.0103x - 0.0615
R² = 0.9724
-0.6

-0.5

-0.4

-0.3

-0.2

-0.1
0 10 20 30 40 50 60 70
0
 t (min) A a 25oC ao/at lnao/at
0 0.14143 1 0
10 0.17321 0.8165233 -0.20269984
20 0.20213 0.69969821 -0.35710616
30 0.23127 0.6115363 -0.49178096
40 0.25876 0.54656825 -0.6040961
50 0.28549 0.49539388 -0.70240211
60 0.30987 0.45641721 -0.78434796
90 0.36997 0.38227424 -0.96161703
120 0.40325 0.35072536 -1.04775182
130 0.41021 0.34477463 -1.06486433
140 0.41423 0.34142867 -1.07461648
160 0.41656 0.33951892 -1.08022561
180 0.41786 0.33846264 -1.08334155
k -0.015 t -46.209812
-0.7
y = -0.015x - 0.0317
-0.6 R² = 0.987

-0.5

-0.4

-0.3

-0.2

-0.1
0 5 10 15 20 25 30 35 40 45
0
 t (min) A a 40oC ao/at lnao/at
0 0.14143 1 0
10 0.21321 0.66333662 -0.4104727
20 0.27813 0.50850322 -0.67628374
30 0.33527 0.42183911 -0.86313128
40 0.37576 0.37638386 -0.97714575
50 0.41549 0.34039327 -1.07765365
60 0.44987 0.31437971 -1.15715376
90 0.50897 0.27787492 -1.28058418
120 0.53325 0.26522269 -1.32718546
130 0.53621 0.2637586 -1.33272098
140 0.53923 0.2622814 -1.3383373
160 0.54556 0.25923821 -1.3500079
180 0.55106 0.25665082 -1.3600388
k -0.0286 t -24.2359154
-1

-0.9
y = -0.0286x - 0.0592
-0.8
R² = 0.9697
-0.7

-0.6

-0.5

-0.4

-0.3

-0.2

-0.1
0 5 10 15 20 25 30 35
0
Temperatura k T 1/T lnk 0.7
0 0.0103 273.15 0.00366099 -4.57561138
10 0.0133 283.15 0.0035317 -4.31999124 0.6
25 0.015 298.15 0.00335402 -4.19970508
30 0.0229 303.15 0.0032987 -3.77661837 0.5

40 0.0286 313.15 0.00319336 -3.55434856

0.4
50 0.0333 323.15 0.00309454 -3.40219788
0.3
m=Ea/R
Ea=mR 0.2
17710.4828 j/mol
0.1
-5

-4.5

-4

-3.5 y = -2130.2x + 3.1767

R² = 0.9375
-3

-2.5

-2

-1.5

-1

-0.5
0.003 0.0031 0.0032 0.0033 0.0034 0.0035 0.0036 0.0037
0
 t (min) A a 10oC ao/at lnao/at
0 0.14143 1 0
10 0.16921
0.83582531 -0.17933565
20 0.19213 0.73611617 -0.30636733
30 0.21782 0.64929759 -0.43186414
40 0.24276 0.58259186 -0.54026841
50 0.26549 0.5327131 -0.62977228
60 0.28987 0.48790837 -0.71762765
90 0.34011 0.41583605 -0.8774642
120 0.37325 0.37891494 -0.97044354
130 0.38021 0.37197864 -0.98891884
140 0.38421 0.36810598 -0.99938438
160 0.38656 0.36586817 -1.0054822
180 0.38786 0.36464188 -1.00883955
k -0.0133 t -52.1163294
-0.6

-0.5
y = -0.0133x - 0.025
R² = 0.9908
-0.4

-0.3

-0.2

-0.1

0 5 10 15 20 25 30 35 40 45
0
 t (min) A a 30oC ao/at ln ao/at
0 0.14143 1 0
10 0.19321 0.73200145 -0.31197279
20 0.24213 0.58410771 -0.53766988
30 0.28127 0.50282647 -0.68751017
40 0.31676 0.44648946 -0.80633949
50 0.34549 0.40936062 -0.8931588
60 0.36987 0.38237759 -0.9613467
90 0.42897 0.32969672 -1.10958209
120 0.45325 0.3120353 -1.16463895
130 0.46021 0.30731623 -1.17987801
140 0.46423 0.30465502 -1.18857522
160 0.46656 0.30313357 -1.19358173
180 0.46806 0.30216212 -1.1967916
k -0.0229 t -30.2684358
-0.8
y = -0.0229x - 0.0411
-0.7 R² = 0.9755

-0.6

-0.5

-0.4

-0.3

-0.2

-0.1
0 5 10 15 20 25 30 35
0
 t (min) A a 50oC Ao/at lnAo/At
0 0.14143 1 0
10 0.24321 0.58151392 -0.54212037
20 0.32213 0.43904635 -0.8231503
30 0.39127 0.36146395 -1.01759296
40 0.44876 0.31515732 -1.15468333
50 0.49549 0.28543462 -1.25374228
60 0.529879 0.26690999 -1.32084378
90 0.57897 0.24427863 -1.40944577
120 0.60225 0.23483603 -1.44886775
130 0.60721 0.23291777 -1.4570698
140 0.60923 0.2321455 -1.46039097
160 0.61656 0.22938562 -1.47235075
180 0.61806 0.22882892 -1.47478065
k -0.0333 t -20.8152306
-1.2

y = -0.0333x - 0.0956
-1 R² = 0.946

-0.8

-0.6

-0.4

-0.2

0 5 10 15 20 25 30 35
0
0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 20 40 60 80 100 120 140 160 180 200

A a 0oC A a 10oC A a 25oC A a 30oC A a 40oC A a 50oC

1.2

0.8

0.6

0.4

0.2

0
0 5 10 15 20 25 30 35 40 45

Ao/At (0°C) Ao/At (10°C) Ao/At (25°C)

Ao/At (30°C) Ao/At (40°C) Ao/At (50°C)