T (min) A [M] Ln A 1/A

0 1.5 0.4054651081 0.66666667 Orden 2

10 0.385 -0.954511945 2.5974026 25
20 0.221 -1.509592577 4.52488688
20
30 0.155 -1.864330162 6.4516129 f(x) = 0.193887935015179 x + 0.646
R² = 0.999945110947835
40 0.119 -2.128631786 8.40336134 15
50 0.097 -2.3330443 10.3092784
10
60 0.082 -2.501036032 12.195122
70 0.07 -2.659260037 14.2857143 5
80 0.062 -2.780620894 16.1290323 0
90 0.055 -2.900422094 18.1818182 0 20 40 60 80
100 0.05 -2.995732274 20

Constante de velocidad 0.19388794 1/ M minutos

Tiempo de vida media 3.43841233 minutos
Tiempo de la rxn a 0.066 M 74.7073225 minutos
 Orden 2

0.193887935015179 x + 0.646048287149489
0.999945110947835

20 40 60 80 100 120
 Tiempo (Seg) B [M] Ln B[M] 1/ B
Orden 1
0 0.5 -0.69314718 2
20 0.263 -1.33560125 3.80228137 0
0 50 100 150
40 0.138 -1.98050159 7.24637681 -1 f(x) = − 0.031050946781281 x − 0.74636
-2 R² = 0.99912681820896
60 0.073 -2.61729584 13.6986301
80 0.038 -3.27016912 26.3157895 -3
100 0.02 -3.91202301 50 -4
120 0.011 -4.50986001 90.9090909 -5
140 0.006 -5.11599581 166.666667 -6
160 0.003 -5.80914299 333.333333 -7
180 0.002 -6.2146081 500 -8
200 0.001 -6.90775528 1000

Constante de velocidad 0.03105095 1/minutos

Tiempo de vida media 22.3229 segundos
Tiempo de la rxn a 0.066 M 65.2139006 segundos
 Orden 1
50 100 150 200 250
− 0.031050946781281 x − 0.746368973450363
99912681820896
 Orden 0.
Orden 0 Orden 1 Orden 2 0.8
Tiempo [A] Ln [B] 1/[B] 0.7 f(x) = − 0.0148 x + 0.75
0 0.75 -0.28768207 1.33333333 0.6 R² = 1
10 0.602 -0.50749783 1.66112957 0.5
20 0.454 -0.78965808 2.20264317 0.4
30 0.306 -1.18417018 3.26797386 0.3
40 0.158 -1.84516025 6.32911392 0.2
50 0.01 -4.60517019 100 0.1
0
0 10 20 30 40

Constate de velocidad 0.0148 M/minutos

Tiempo de vida medio 25.3378378 minutos
Tiempo a 0.182 M 38.3783784 minutos
 Orden 0.

− 0.0148 x + 0.75

10 20 30 40 50 60
 Orden 0 Orden 1 Orden 2
Tiempo [A] Ln [B] 1/[B] Orden 2
0 1.24 0.21511138 0.80645161 3.5
1 0.96 -0.04082199 1.04166667 3 f(x) = 0.241973043558237 x + 0.8031818103484
2 0.775 -0.25489225 1.29032258 R² = 0.999865741033036
2.5
3 0.655 -0.42312004 1.52671756
2
4 0.56 -0.5798185 1.78571429
5 0.502 -0.68915516 1.99203187 1.5
6 0.442 -0.8164454 2.26244344 1
7 0.402 -0.91130319 2.48756219 0.5
8 0.365 -1.00785793 2.73972603
0
9 0.335 -1.09362475 2.98507463 0 2 4 6 8 1
10 0.31 -1.17118298 3.22580645

Constate de velocidad 0.24197304 1/M hora

Tiempo de vida medio 3.33281592 horas
Tiempo a 0.380 M 7.54268867 horas
 Orden 2

41973043558237 x + 0.803181810348432
9865741033036

4 6 8 10 12
 Tiempo (Seg) nitrilo [M] ln NITRILO 1/ nitrilo
0 1.1 0.09531018 0.90909091
Orden 1
2000 0.86 -0.15082289 1.1627907 0.2
4000 0.67 -0.40047757 1.49253731 0 f(x) = − 0.000123449231470837 x + 0.0939463
0 2000 4000 6000 8000 10000 1
-0.2 R² = 0.999961884007434
6000 0.52 -0.65392647 1.92307692
-0.4
8000 0.41 -0.89159812 2.43902439
-0.6
10000 0.32 -1.13943428 3.125
-0.8
12000 0.25 -1.38629436 4 -1
-1.2
Constate de velocidad 0.00012345 -1.4
-1.6
 Orden 1

− 0.000123449231470837 x + 0.0939463163212948
00 4000 6000 8000 10000 12000 14000
999961884007434
 Tiempo (min) [x] ln x 1/x
0 0.5 -0.69314718056 2
10 0.443 -0.814185508937 2.257336343115
20 0.395 -0.928869514081 2.53164556962
30 0.348 -1.055552799208 2.8735632183908
40 0.31 -1.171182981503 3.2258064516129
50 0.274 -1.294627172594 3.649635036496
60 0.24 -1.42711635564 4.166666666667
70 0.212 -1.55116900431 4.716981132075
80 0.19 -1.660731206822 5.263157894737
90 0.171 -1.766091722479 5.847953216374
100 0.164 -1.807888851158 6.09756097561

Constate de velocidad 0.011658258245 1/minutos

Tiempo de vida medio 59.45546632964 minutos
Tiempo a 0.330 M 35.64129694353 minutos
 Orden 1
0
-0.2 0 20 40 60 80 100 120
-0.4
-0.6
-0.8 f(x) = − 0.0116582582452035 x − 0.705320023857275
-1 R² = 0.995752678807024
-1.2
-1.4
-1.6
-1.8
-2
 Tiempo Na2S2O3 CH3I ln(Bo*[A]/[Ao][B]
Ord
0 35.35 18.25 0
4.75 30.5 13.4 0.1613386643424 2
1.8
10 27 9.9 0.3421687965497 f(x) = 0.033757506529612
1.6 R² = 0.999988222141369
20 23.2 6.1 0.6747301951789 1.4
1.2
35 20.3 3.2 1.186336763928 1
55 18.6 1.5 1.8565631602969 0.8
0.6
0.4
0.2
0
0 10 20

Constate de velocidad 0.03375751 1/ M unidad de tiempo

Tiempo de vida medio 0.83799267 Na2S2O3 1.6231803287923 CH3I
 Orden 2
2
1.8
f(x) = 0.0337575065296125 x + 0.0016481067877947
1.6 R² = 0.999988222141369
1.4
1.2
1
0.8
0.6
0.4
0.2
0
0 10 20 30 40 50 60
 T(min) A [M] Ln( A) 1/A
0 1.250 0.2231 0.8000 Orden 0
5 1.175 0.1613 0.8511 1.400
10 1.105 0.0998 0.9050 1.200
15 1.039 0.0383 0.9625 1.000 f(x) = − 0.00490113831089351 x +
20 0.918 -0.0856 1.0893 0.800 R² = 0.882734250366386
50 0.674 -0.3945 1.4837 0.600
75 0.495 -0.7032 2.0202 0.400
100 0.364 -1.0106 2.7473 0.200
150 0.196 -1.6296 5.1020 0.000
0 50 100 150 2
200 0.106 -2.2443 9.4340
250 0.057 -2.8647 17.5439

A) Orden de Reacción Orden 2

B) Constante de Velocidad 0.0123 1/minutos
C) Tiempo de vida medio 56.3651 minutos
D) Tiempo de reacción A=0.525 M 70.5432 minutos
0.525
 Orden 1 Orden
Orden 0
20.0000
1.400 0.5000 18.0000
1.200 0.0000 f(x) = − 0.012297442651993 x + 0.213657751502854 16.0000
0 50 100 150 200 250 300 14.0000
1.000 f(x) = − 0.00490113831089351 x + 1.06068145654835 -0.5000 R² = 0.999706215017758
12.0000 f(x) = 0.0561771203963
0.800 R² = 0.882734250366386 -1.0000 R² = 0.85755099844267
10.0000
-1.5000 8.0000
0.600
-2.0000 6.0000
0.400 4.0000
-2.5000
0.200 2.0000
-3.0000 0.0000
0.000 0 50 100 15
0 50 100 150 200 250 300 -3.5000
 Orden 2
20.0000
18.0000
16.0000
14.0000
12.0000 f(x) = 0.056177120396302 x − 0.565104872072179
10.0000 R² = 0.857550998442671
8.0000
6.0000
4.0000
2.0000
0.0000
0 50 100 150 200 250 300
 T(min) A [M] Ln( A) 1/A
0 1.000 0.0000 1.0000 Orden 0
1 0.901 -0.1043 1.1099 1.200
2 0.803 -0.2194 1.2453
1.000
3 0.704 -0.3510 1.4205 f(x) = − 0.0987 x + 1.00004545454
0.800 R² = 0.999999227992745
4 0.605 -0.5025 1.6529
5 0.507 -0.6792 1.9724 0.600
6 0.408 -0.8965 2.4510
0.400
7 0.309 -1.1744 3.2362
8 0.210 -1.5606 4.7619 0.200
9 0.112 -2.1893 8.9286 0.000
10 0.013 -4.3428 76.9231 0 2 4 6

A) Orden de Reacción Orden 0

B) Constante de Velocidad 0.0987 M/minutos
C) Tiempo de vida medio 5.0659 minutos
D) Tiempo de reacción A=0.182 M 8.2877 minutos
0.182
 Orden 0 Orden 1 Orden 2
1.200 0.0000 90.0000
f(x) = 0− 0.328351201315374
2 4 6x + 0.549027752966851
8 10 12
-0.5000
R² = 0.739705709836252 80.0000
1.000
f(x) = − 0.0987 x + 1.00004545454545 -1.0000 70.0000
0.800 R² = 0.999999227992745 -1.5000 60.0000
-2.0000 50.0000
0.600 -2.5000 40.0000
0.400 -3.0000 30.0000
-3.5000 20.0000 f(x) = 3.87154139611778 x −
0.200 -4.0000 R² = 0.326368456644557
10.0000
-4.5000
0.000 0.0000
0 2 4 6 8 10 12 -5.0000 0 2 4 6
 Orden 2
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000 f(x) = 3.87154139611778 x − 9.83936870045304
R² = 0.326368456644557
0.0000
0.0000
0 2 4 6 8 10 12
Tiempo A(M) In(A) 1/(A)
0 0.75 -0.28768207 1.33333333 Orden 1
1 0.581 -0.54300452 1.7211704 0
0 2 4 6
2 0.449 -0.80073239 2.22717149
-0.5 R² = 0.999996917383682
3 0.348 -1.0555528 2.87356322
4 0.269 -1.3130439 3.71747212 -1
5 0.209 -1.56542103 4.784689
6 0.161 -1.82635091 6.21118012 -1.5
7 0.125 -2.07944154 8
-2
8 0.097 -2.3330443 10.3092784
9 0.075 -2.59026717 13.3333333 -2.5
10 0.058 -2.84731227 17.2413793
-3

a) Primer orden
c) Tiempo de vida medio

b) b=m=K 2.70902786 horas

K 0.25586565 1/h
 Orden 1
2 4 6 8 10 12
0.999996917383682

Tiempod)donde la concentración es 0.066 M

9.49880705 horas
Tiempo A(M) In(A) 1/(A)
0 1.75 0.55961579 0.57142857
2 1.471 0.38594244 0.67980965
4 1.269 0.23822919 0.78802206
6 1.115 0.1088544 0.89686099
8 0.995 -0.00501254 1.00502513
10 0.898 -0.10758521 1.11358575
15 0.722 -0.32573014 1.38504155
20 0.604 -0.50418108 1.65562914
25 0.519 -0.6558514 1.92678227
30 0.455 -0.78745786 2.1978022
40 0.365 -1.00785793 2.73972603
60 0.262 -1.33941078 3.81679389

a) Primer orden
c) Tiempo de vida medio

b) b=m=K 10.5576056093099
K 0.05412483 1/M S
 Orden 2
4.5
4
3.5 R² = 0.999997767214241
3
2.5
2
1.5
1
0.5
0
0 10 20 30 40 50 60 70

d) Tiempo donde la concentración es 0.5 M

26.394014 segundos

segundos
60 70
 1er orden
k= 1.02 años^-1
[X]= 0.0000005 gr/cm^3

A)
[A]=[Ao]e^-kt [A]= 2.585775E-05

B) t= 31.1032997 años
[A]=[Ao]e^-kt
ln([Ao]/[A])=kt 365 días
31.1032997 años = 11352.7044
t=(ln([Ao]/[A])/K) 1 año
30000000
días