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RESOLUCION 1 Sacar el promedio de las concentraciones de modo delta CA/delta T=CA1-CA0/t1-t0, luego ln de esa
DATOS
t, min C A mol/l lnCA (-c/t) ln c/t
0 0.195 -1.6347557204 0.005 -5.2983173665
5 0.17 -1.7719568419 0.005 -5.2983173665
10 0.145 -1.9310215366 0.005 -5.2983173665
15 0.12 -2.1202635362 0.003 -5.8091429903
20 0.105 -2.2537949288 0.003 -5.8091429903
25 0.09 -2.4079456087 0.003 -5.8091429903
30 0.075 -2.5902671654 0.002 -6.2146080984
35 0.065 -2.7333680091 0.002 -6.2146080984
40 0.055 -2.9004220937 0.002 -6.2146080984
45 0.045 -3.1010927892
suma
OPCION 3 Ajustar una polinmica a los datos CA vs t, derivar la polinomica para obtener -dCA/dt, luego linealizar
0.0054
1.00E-04
(-dCA/dt)
t, min C A mol/l 10e-5*t-0.0054 Lnca
0 0.195 0.0054 -1.6347557204
5 0.17 0.0049 -1.7719568419
10 0.145 0.0044 -1.9310215366
15 0.12 0.0039 -2.1202635362
20 0.105 0.0034 -2.2537949288
25 0.09 0.0029 -2.4079456087
30 0.075 0.0024 -2.5902671654
35 0.065 0.0019 -2.7333680091
40 0.055 0.0014 -2.9004220937
45 0.045 0.0009 -3.1010927892
A/delta T=CA1-CA0/t1-t0, luego ln de esa "velocidad"y graficar para saber el orden de la reaccin
ln c/t
k= 0.02214375 min-1
Ln CA
-4.8000
-3.2 -3 -2.8 -2.6 -2.4 -2.2 -2 -1.8 -1.6 -1.4
ln dc/dt
Ln CA
btener -dCA/dt, luego linealizar
0.25
C A mol/l
0.2
f(x) = - 2.44755244755248E-08x^4 + 1.71328671328675E-06x^3 + 1.89685314685302E-05x^2 - 0.00543
0.25
LN dCA/dt y=1.15565x-3.1809
-5.2213563254 ln(-rA)=nLn(CA)+ln(k) C A mol/l
-5.3185200739 n=1.15565 0.2
f(x) = - 2.44755244755248E-08x^4 + 1.71328671328675E-06x^3
Polynomial (C+A1.89685314685302E-05x^2 - 0.00543
-5.4261507381 (lnK)=-3.1809 R = 0.9994522233 mol/l)
-5.5467787258 k= 0.04154824 0.15
-5.6839798474
-5.843044542
0.1
-6.0322865416
-6.2659013928
-6.5712830424 0.05
-7.0131157946
0
0 5 10 15 20 25 30 35 40 45 50
-4.8
-3 -2.8 -2.6 -2.4 -2.2 -2 -1.8 -1.6 -1.4
-5
-5.2
f(x) = 0.8688025982x - 3.8101625587
R = 0.9082689393 -5.4
ln c/t
-5.6
Column E
-5.8 Linear (Column E)
-6
-6.2
-6.4
Ln CA
-4.8000
-2.4 -2.2 -2 -1.8 -1.6 -1.4
-5.0000
-5.2000
55x - 3.9577943766
08 -5.4000
-5.6000
Column G
-5.8000
Linear (Column G)
-6.0000
-6.2000
-6.4000
Ln CA
0
-3.2 -3 -2.8 -2.6 -2.4 -2.2 -2 -1.8 -1.6 -1.4
-1
C A mol/l
-2
.71328671328675E-06x^3 + 1.89685314685302E-05x^2 - 0.0054399767x + 0.195472028
0
-3.2 -3 -2.8 -2.6 -2.4 -2.2 -2 -1.8 -1.6 -1.4
-1
C A mol/l
-2
.71328671328675E-06x^3
Polynomial (C+A1.89685314685302E-05x^2 - 0.0054399767x + 0.195472028
mol/l) -3
ln (-rA)
-4
Column F
-5
f(x) = 1.1564811973x - 3.1808844613 Linear (Column F)
R = 0.9500031805 -6
-7
-8
Ln CA
25 30 35 40 45 50
Determinar la ecuacin cintica de la reaccin en fase lquida irreversible en
Empleando un reactor discontinuo se ha realizado un experimento en el qu
con una concentracin de 0,335 y 50 mol l-1, respectivamente.
Los resultados de la evolucin de C A con el tiempo se muestran en la tabla
k ' kC nB
B 0 k ' cte _ aparente
terminos de
la Ec 0.00000024 0.00003 0.0012 0.0186
y=1.0501x-3.0448
t, min CA, mol/l dCA/dt (-dCA/dt) ln CA ln (-ra) ln(-rA)=nLn(CA)+ln(k')
0 0.35 -0.0186 0.0186 -1.04982212 -3.9845937 nA=1.0501
2.23 0.2965 -0.01607053 0.016070526 -1.21570806 -4.1307684 (lnk')=-3.0448
4.5 0.266 -0.01378563 0.01378563 -1.32425897 -4.28412853 k'= 0.04760583
6.33 0.245 -0.01214519 0.012145194 -1.40649707 -4.41082172 k= 0.00095212
8 0.2255 -0.01079712 0.01079712 -1.48943512 -4.52847585
10.25 0.205 -0.00919342 0.009193421 -1.5847453 -4.68926713
12 0.191 -0.00810528 0.00810528 -1.65548185 -4.81523958
13.5 0.1794 -0.00727701 0.00727701 -1.71813733 -4.92303522
15.6 0.1632 -0.00626966 0.00626966 -1.81277884 -5.07203313
17.85 0.15 -0.0053737 0.005373696 -1.89711998 -5.2262393
19.6 0.1429 -0.00479771 0.004797711 -1.94561019 -5.33961627
27 0.116 -0.00334608 0.00334608 -2.15416509 -5.69996577
30 0.1053 -0.00312 0.00312 -2.25094186 -5.76992228
38 0.083 -0.00315072 0.00315072 -2.48891467 -5.76012428
41 0.0767 -0.00328896 0.00328896 -2.56785357 -5.71718387
45 0.0705 -0.00348 0.00348 -2.65214257 -5.66072299
47 0.0678 -0.00355248 0.00355248 -2.69119308 -5.64010933
57 0.05553 -0.00322368 0.00322368 -2.89083186 -5.73723171
63 0.0482 -0.00205872 0.00205872 -3.03239626 -6.18567085
0.15
0.4
f(x) = -0.0816974662 ln(x) + 0.3859652077
0.35 R = 0.9894359884
f(x) = 5.89318612859343E-08x^4 - 9.54889513140409E-06x^3 + 0.0005887607x^2 - 0.0185559037x + 0.3421558249
0.3
R = 0.9986411376
0.25
0.2
CA, mol/l
0.15
0.1
0.05
0
0 10 20 30 40 50 60 70
t, min
uida irreversible entre A y B para R.
perimento en el que se han alimentado A y B
mente.
uestran en la tabla
0
-3.5 -3 -2.5 -2 -1.5 -1 -0.5
-1
-2
-3
ln (-rA)
-4 Column F
f(x) = 1.0501142374x - 3.0448101594 Linear (Column F)
R = 0.9072388559 -5
-6
-7
Ln CA
1.2
-2 -1.8 -1.6 -1.4 -
1
f(x) = -0.1972124549 ln(x) + 1.0596698018
0.8 R = 0.9934282529
CA, mol/l
0.6
f(x) = 2.03005265
ln (-rA) R = 0.995103121
0.4
0.2
0
0 20 40 60 80 100 120 140 160
t, min
n un reactor discontinuo isotrmico.
mitido determinar las correspondientes conversiones
ncontrar la velocidad de A
y=2.0301x-3.1159
ln(-rA)=nLn(CA)+ln(k')
n=2.0301
(lnK)=-3.1159
k'=k 0.04433858
0
-2 -1.8 -1.6 -1.4 -1.2 -1 -0.8 -0.6 -0.4 -0.2 0
-1
-2
-3
f(x) = 2.0300526592x - 3.1158645447
ln (-rA)
R = 0.9951031218 Column F
-4
Linear (Column F)
-5
-6
-7
Ln CA -8
Se ha estudiado la reaccin en fase lquida A + B C + 2D en un reac
isotrmico.
Los datos cinticos disponibles se muestran en la tabla.
Son datos de velocidad inicial obtenidos variando la concentracin in
manteniendo constante la concentracin inicial del otro reactivo.
Experimento CA0, mol l -1 CB0, mol l -1 (-rA )0 x10e-7, mol l-1 Ln CA0 Ln(-rA) LnCB0
1 0.1 0.2 5.4 -1 0.73239376 -0.69897
2 0.2 0.2 10.8 -0.69897 1.03342376 -0.69897
3 0.4 0.2 21.5 -0.39794 1.33243846 -0.69897
4 0.6 0.2 32.2 -0.2218487 1.50785587 -0.69897
5 0.2 0.0202 10.2 -0.69897 1.00860017 -1.6946486
6 0.2 0.0404 21.6 -0.69897 1.33445375 -1.3936186
7 0.2 0.0606 34.2 -0.69897 1.53402611 -1.2175274
8 0.2 0.0808 43.3 -0.69897 1.6364879 -1.0925886
C + 2D en un reactor discontinuo
tabla.
o la concentracin inicial de un reactivo
del otro reactivo.
1.6
f(x) = 0.9962253708x + 1.7290295388 1.4
R = 0.9999978669
1.2
1
ln (-rA)
0.8
Column F
0.6 Linear (Column F)
0.4
0.2
0
-1.1 -1 -0.9 -0.8 -0.7 -0.6 -0.5 -0.4 -0.3 -0.2 -0.1
Ln CA
1.8
1.2
1
Column F
ln (-rA)
0.4
0.2
Experimento Q, l/min CA, salida, mol/l V/Q CA0-CA (-rA) log CA Log -rA
1 0.5 25 2 75 37.5 1.39794001 1.57403127
2 0.7 30 1.42857143 70 49 1.47712125 1.69019608
3 2 50 0.5 50 100 1.69897 2
4 10 80 0.1 20 200 1.90308999 2.30103
2.5
1.5
ln (-rA)
Column H
1 Linear (Column H)
0.5
0
1.3 1.4 1.5 1.6 1.7 1.8 1.9 2
Ln CA
eaccion cuya
e A a ka salida C A0 C A
na rA
se ajuste al V /Q
CA0 100 mol/l
V 1l
Column H
Linear (Column H)
2
El reactivo gaseoso A con una concentracin de 500 mmol/l entra en un reactor de
flujo pistn (V=10 l) donde ocurre la reaccin A R isotrmicamente.
Se han obtenido los siguientes datos a distintos caudales volumtricos Q (CA a la
entrada del reactor es 500 mol/l para todos los ensayos).
A partir de los datos incluidos en la tabla determine la ecuacin cintica de la
reaccin
CA0 500
6
, min CA, mol/l XA (-rA) lnCA Ln(-ra)
0.5 424.3 0.1514 151.40 6.05044075 5.01992534
5
1 360.1 0.2798 139.90 5.88638177 4.94092788 f(x) = 0.33441347
1.5 305.6 0.3888 129.60 5.72227706 4.86445278 R = 0.985827475
4
2 259.3 0.4814 120.35 5.55798569 4.79040416
2.5 220.1 0.5598 111.96 5.39408199 4.71814166
3
3 186.7 0.6266 104.43 5.22950305 4.64854891
3.5 158.5 0.683 97.57 5.06575459 4.58058471 2
4 134.5 0.731 91.38 4.9015642 4.51497192
5 96.8 0.8064 80.64 4.57264699 4.3899948 1
6 69.7 0.8606 71.72 4.24420032 4.27272317
7 50.2 0.8996 64.26 3.91601503 4.16289289 0
8 36.2 0.9276 57.98 3.58905912 4.06001188 1 2 3
9 26 0.948 52.67 3.25809654 3.96398274
10 18.8 0.9624 48.12 2.93385687 3.87369789
12 9.7 0.9806 40.86 2.27212589 3.7101108
14 5 0.99 35.36 1.60943791 3.56550043
ntra en un reactor de
amente.
mtricos Q (CA a la
n cintica de la
5
f(x) = 0.3344134784x + 2.9124937195
R = 0.9858274757
4
3 Column F
Linear (Column F)
2
0
1 2 3 4 5 6 7