Sistema: ACETONA(1)/ Agua(2) Modelo UNIFAC

Frecuencia
k Rk Qk vk1 vk2 Gk1 Gk2
1 CH3 (1) 0.9011 0.848 2 0 1.696 0
2 H2O(7) 0.92 1.4 0 1 0 1.4
3 CH3CO(9) 1.6724 1.488 1 0 1.488 0
3.184 1.4

q1
Parámetros de interacción (TABLAS)
k Gk1 Gk2 1 (1) 2 (7) 3 (9)
1 CH3 (1) 1.8022 0 0 1318 476.4
3 H2O(7) 0 0.92 300 0 -195.4
3 CH3CO(9) 1.6724 0 26.76 472.5 471.7
3.4746 0.92

P= 101.33 KPa
n 0 1 2 3 SUSTANCIA (i) A B C
t(°C) 70 38.920627 181.61907 188.55128 acetona (1) 14.3145 2756.22 228.06
T(K) 343.15 312.07063 273.15 461.70128 agua (7) 16.3872 3885.7 230.17
L1 2.1014 2.1014 2.1014 2.1014
L2 0.9240 0.9240 0.9240 0.9240 i yi ti (°C) t(°C) Psati(KPa)
J1 2.4636 2.4636 2.4636 2.4636 1 0.3 -142.781949 70 158.745366
J2 0.6523 0.6523 0.6523 0.6523 2 0.4 -98.1023558 14908.0805
θ1 0.5088 0.5088 0.5088 0.5088
θ2 0.5600 0.5600 0.5600 0.5600 Para T (°C) = 70 (MODIFICAR/ACTUALIZAR GAMMAS)
θ3 0.4464 0.4464 0.4464 0.4464 x1 Ganma 1 Ganma2 P y1
0 7.053 1.000 14908.08 0.000
s11 3.0724 6.2564 3.0724 6.2564 0.1 3.400 1.036 13954.27 0.004
s21 0.4119 3.5362 3.4615 3.8164 0.2 2.192 1.118 13397.41 0.005
s31 0.7995 3.8807 3.7451 4.3241 0.3 1.661 1.224 12856.51 0.006
0.4 1.386 1.348 12149.22 0.007
s12 0.5840 1.9353 1.8668 2.1310 0.5 1.228 1.487 11181.66 0.009
s22 1.4000 2.8000 2.8000 2.8000 0.6 1.133 1.641 9894.74 0.011
s32 2.4742 4.0185 4.2629 3.5376 0.7 1.072 1.817 8245.98 0.014
0.8 1.033 2.031 6186.85 0.021
η1 1.4817 2.9969 2.0417 2.9969 0.9 1.010 2.321 3603.68 0.040
η2 0.6836 2.1809 2.1584 2.2649 1 1.000 2.788 158.75 1.000
η3 1.2295 2.7716 2.8287 2.7123

Ganma 1 0.1324524 0.2446135 0.181586 0.2626008

Ganma 2 36.14579 0.2406359 0.2060534 0.2419631
Psat1(KPa) 0.0746 11.1195 12.9997 11.0525
Psat2(KPa) 7.0082 1044.2542 1220.8223 1037.9609
t (°C) 38.920627 181.61907 188.55128 181.35544

Para P=101.33 Kpa (MODIFICAR/ACTUALIZAR TABLA)

x1 T(x1) Ganma 1 Psat1 y1
0 100.00 6.6766 235.098 0.000
0.1 85.54 3.3731 137.144 0.457
0.2 82.79 2.1934 123.083 0.533
0.3 81.46 1.6658 116.711 0.576
0.4 80.45 1.3903 112.097 0.615
0.5 79.60 1.2317 108.294 0.658
0.6 78.88 1.1347 105.170 0.707
0.7 78.30 1.073 102.749 0.762
0.8 77.91 1.0333 101.116 0.825
0.9 77.75 1.009 100.458 0.900
1 77.96 1 101.330 1.000
 16025.00
P-x1
R GAMMAS) 14025.00
12025.00
PRESIÓN (KPa)

10025.00
8025.00
6025.00
4025.00
2025.00
 12025.00

PRESIÓN (KPa)
10025.00
8025.00
6025.00
4025.00
2025.00
25.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1-Y1