reacción de fase gaseosa irreversible elemental 2A -> B se lleva a cabo de forma isotérmica sin

caída de presión en un PFR.

Dado:

Utilice medidas distintas de la conversión para trazar los caudales molares de A y B en el reactor.

3
dm
yA0 := 1 P0 := 8.2 atm T0 := 227 + 273 = 500 K v0 := 25
mol

d
Balance molar: FA := rA
dV

d
FB := rB
dV

2
Ley de velocidad: -rA := kA CA

 FT  P0 T
Estequiometría v := v0    
 FT0  P T0
FA P T0
C A := CT0   
FT P0 T
Para 2A--->B
-rA rB
:=
(2) (1)

1 kA
( )
2
rB :=  -rA rB :=  CA
2 2

Para isotermicos y sin caida de presión

 FA
C A := CT0 
FT

FB
C B := CT0 
FT

FT := FA + FB

combinando
2
2  A
2
F
d d
FA := -kA CA FA := -kA CT0   
dV dV  FT 
2
2  A
-1 2
kA F
d d
FB := k C FB :=  C T0   
2 A A 2
dV dV  FT 
3
atm  dm 3
R := 0.082 V := 0 Vf := 100 dm
mol K
3
kA := 10 dm
FB0 := 0
mol K
P0 mol
C T0 := = 0.2
R  T0 3 FA0 := CT0  v0 = 5
dm

2
2
FA 
d
FA := -kA CT0   
dV  FA + FB 
2
2
kA FA 
d
FB :=  C T0   
dV 2
 FA + FB 

 2
2 0 
x
   
-kA CT0   x + x  
 0 1 
D( V , x) :=  5
 2 F0 :=  
 kA  x  0
2 0  
 2  CT0   x + x  
  0 1 

(
S := rkfixed F0 , 0 , Vf , 1000 , D )
0 1 2
0 0 5 0
1 0.1 4.96 0.02
2 0.2 4.921 0.04
3 0.3 4.881 0.059
 3 0.3 4.881 0.059
4 0.4 4.843 0.079
5 0.5 4.804 0.098
6 0.6 4.766 0.117
S= 7 0.7 4.728 0.136
8 0.8 4.69 0.155
9 0.9 4.653 0.174
10 1 4.616 0.192
11 1.1 4.579 0.21
12 1.2 4.543 0.229
13 1.3 4.507 0.247
14 1.4 4.471 0.265
15 1.5 4.435 ...

0 1 2

V := S FA := S FB := S

FA 3

FB
2

0
0 20 40 60 80 100
V