Soluciones Acuosas de Acido

T Conductividad a 25°C Acetico

°C 84 μS/cm 1413 μS/cm 12.9 mS/cm Solucion
5 65 896 8220 1
10 67 1020 9330 2
15 689 1147 10480 3
16 70 1173 10720 4
17 71 1199 10950 5
18 73 1225 11190 6
19 74 1251 11430 7
20 76 1278 11670 8
21 78 1305 11910
22 79 1332 12150
23 81 1359 12390
24 82 1386 12640
25 84 1413 12880
26 86 1440 13150 Concentracion del NaOH
27 87 1467 13370 Vol C5H8KO4
28 89 1494 13620 6.1
29 90 1521 13870 6.1
30 92 1548 14120 6.1
31 94 1575 14370 Conc. NaOH
Conc. Acido
luciones Acuosas de Acido
Acetico Conductividad (±0.01 µS/cm)
Conc final Grupo N°1 y 2 Grupo N°3 Grupo N°4
Solucion
0.036 Cond (µS/cm) Temp (°C) Cond (µS/cm) Temp (°C) Cond (µS/cm)
0.018 8 38.3 17.7 39.3 17.4 37.4
0.0144 7 55.3 18 54.7 17.5 53.5
0.0108 6 87.9 17.8 88.3 17.5 90.5
0.0072 5 125.5 17.6 127.6 17.6 126.4
0.0036 4 158.6 17.8 156.5 17.7 155
0.00144 3 179.6 17.6 181.5 17.8 180.4
0.00072 2 203.5 17.6 202.7 17.8 200.4
1 287 17.8 287.6 17.9 288.9
Cond (µS/cm) del agua 1.08

Concentracion del NaOH

Conc C5H8KO4
0.049
Vol NaOH
10
0.0803279
0.01N
Grupo N°4
Temp (°C)
18
17.8
17.5
17.7
17.7
17.7
17.7
18
 k vs T Grupo 1 y 2
k vs T grupo 1 Linear (k vs T grupo 1) Linear (k vs T grupo 1)
350
300

Conductividad (µS/cm)
250
200
150 f(x) = − 169.432432432432 x + 3147.27027027025
100 R² = 0.0830406577912504

50
0
17.55 17.6 17.65 17.7 17.75 17.8 17.85 17.9 17.95 18 18.05
Temperatura °C

k vs T Grupo 3
k vs T grupo 2 Linear (k vs T grupo 2)
350
300
Conductividad (µS/cm)

250
f(x) = 453.181818181818 x − 7856.38409090908
200 R² = 0.942998218612803
150
100
50
0
17.3 17.4 17.5 17.6 17.7 17.8 17.9 18
Temperatura °C

k vs T Grupo 4
k vs T grupo 3 Linear (k vs T grupo 3)
350
300
Conductividad (µS/cm)

250
200
150
f(x) = 72.2452830188671 x − 1141.69433962263
100 R² = 0.0214767242813551
50
0
17.4 17.5 17.6 17.7 17.8 17.9 18 18.1
Temperatura °C
0
17.4 17.5 17.6 17.7 17.8 17.9 18 18.1
Temperatura °C
 k 25 vs Concentracion Conductividad M
k 25 vs Concentracion Polynomial (k 25 vs Concentracion)
Conce
1000000.0000 Conductividad Molar E
900000.0000 Power (Conductividad
f(x) = − 488678327.988881 x² + 39301549.7667403 x + 138506.081948429
800000.0000
R² = 0.992318822391513
Conductividad a 25°C

200000.0000

Cond. molar equivalente µS

700000.0000
600000.0000 f(x) = 4847.459180
150000.0000 R² = 0.9997245599
500000.0000
400000.0000 100000.0000
300000.0000
200000.0000 50000.0000
100000.0000
0.0000 0.0000
0.0000 0.0050 0.0100 0.0150 0.0200 0.0250 0.0300 0.0350 0.0400 0.0000 0.0050 0.0100
Concentracion C
 Conductividad Molar Equivalente vs Factor de disociacion de van´t H
Concentracion Concentracion
Conductividad Molar Equivalente vs Concentracion
Factor de disociacion de van´t Hoff vs Concentracion
Power (Conductividad Molar Equivalente vs Concentracion)
Polynomial (Factor de disociacion de van´t Hoff vs Co
200000.0000
600.0000
f(x) = 4847.45918076271 x^-0.504746846819388
150000.0000 R² = 0.999724559948946 500.0000
400.0000
100000.0000
300.0000 f(x) = 589835.941298086 x² − 29996.7151187544
α0

R² = 0.823931583775434
50000.0000 200.0000
100.0000
0.0000
0.0000 0.0050 0.0100 0.0150 0.0200 0.0250 0.0300 0.0350 0.0400 0.0000
0.0000 0.0050 0.0100 0.0150 0.0200 0.0250 0.
Concentracion N
Concentracion N
 isociacion de van´t Hoff vs
Concentracion
ciacion de van´t Hoff vs Concentracion
actor de disociacion de van´t Hoff vs Concentracion)

35.941298086 x² − 29996.7151187544 x + 392.931379111827

31583775434

0.0100 0.0150 0.0200 0.0250 0.0300 0.0350 0.0400

Concentracion N
 Grupo θ
1y2 -169.43
3 453.18
4 72.243

Grupo 1 y 2 Grupo 3 Grupo 4

Solucion Solucion Concentracion
k 25 k 25 k 25
8 -47332.6337 135395.102 18950.6174 1 0.0360
7 -65531.053 185971.795 27881.5036 2 0.0180
6 -107140.958 300206.755 49125.4363 3 0.0144
5 -157224.141 428038.283 66786.461 4 0.0108
4 -193316.906 517891.991 81897.9545 5 0.0072
3 -224999.647 592397.124 95318.6516 6 0.0036
2 -254941.137 661591.719 105886.13 7 0.0014
1 -349823.152 925663.033 146385.919 8 0.0007

log kc raiz de alfa por conc

Err:502 1.539214679634
Err:502 1.301271046974
Err:502 1.231343457716
Err:502 1.151310151472
Err:502 1.046680283359
Err:502 0.876562660172
Err:502 0.689916097097
Err:502 0.588673131626
 Cond. Molar Factor de Constante
k 25, Grupo 3 Equivalente Disociacion de de
(S.cm2/mol) van´t Hoff (α0) Disociacion
925663.0328 25712.8620 65.8106 -2.4057
661591.7192 36755.0955 94.0726 -1.7115
592397.1240 41138.6892 105.2921 -1.5307
517891.9910 47952.9621 122.7329 -1.3364
428038.2832 59449.7616 152.1583 -1.1028
300206.7550 83390.7653 213.4339 -0.7720
185971.7950 129147.0799 330.5446 -0.4774
135395.1024 188048.7533 481.3001 -0.3473

e alfa por conc