T= 40 ºC

313.15 K
R= 83.14 bar.cc/mol.K
n = 0.000226923 mol
RT
v
P VAN DER WAALS REDLICH-KWONG
P (10^5Pa) V (mL) P (bar) vexp (cc/mol) moles v (cc/mol) %Error v (cc/mol)
2300000 0.37 23 1131.969174 0.000326864 905.598101 19.99798918
1000000 0.7 10 2603.5291 0.000268866 2406.823958 7.555327192
600000 1.01 6 4339.215167 0.000232761 4129.190649 4.840149888
300000 1.69 3 8678.430333 0.000194736 8492.3381 2.144307509
100000 2.9 1 26035.291 0.000111387 25851.8709 0.704505665
25

20

15
P vs v exp
P vs v VDW
10 P vs v RK

0
500 1000 1500 2000 2500 3000 3500 4000 4500 5000
EDLICH-KWONG VIRIAL
%Error v (cc/mol) %Error
P (10^5Pa) V (mL) P (bar)
2300000 0.37 23
1000000 0.7 10
600000 1.01 6
300000 1.69 3
100000 2.9 1

𝑚=(∑128▒ 〖𝑥 _𝑖 𝑦_𝑖 〗
−∑ 128▒𝑥_𝑖 ∑▒𝑦_𝑖
)/(𝑛𝛴𝑥_𝑖^2−(𝛴𝑥_𝑖 )^2 )
y= mx + b
PRESION
X Y XY X^2 1/x
0.37 0.37 8.51 0.1369
0.7 0.7 7 0.49
1.01 1.01 6.06 1.0201
1.69 1.69 5.07 2.8561
2.9 2.9 2.9 8.41

23 2.7027027
-6.92896208 10 1.42857143
6 0.99009901
3 0.59171598
1 0.34482759
 Grafica Presión vs Volumen
25

20

15
f(x) = − 6.92896207525179 x + 17.8432354083859
R² = 0.631643456283274
Presión(bar)

10

0
0 0.5 1 1.5 2 2.5 3 3.5

Volumen (mL)

Gráfica Presión vs 1/V

3

f(x) = 0.106193847872046 x + 0.298316249043084

2.5 R² = 0.996151725005936

1.5

0.5

0
0 5 10 15 20 25
 Sustancia : Agua

Condiciones de Estado Propiedades críticas

Temperatura = 313.15 °K Tc = 647.1 °K
Presión = 23 bar Pc = 220.55 bar
Constante R = 83.14 bar.cc/mol°K Zc = 0.229
Volumen ideal = 1131.96917 cc/mol vc = 55.9 cc/mol

27 R2Tc2
a
Ecuación de 64 Pc
RT a
a = 5536554.36 bar.cc^2/mol^2 P  2
RTc v b v
b = 30.4918919 cc/mol b
8Pc
RT a
vi f(vi) f'(vi) 1º Paso f v    2 P0
v b v
1000 -1.68243031 -0.0166256014 RT 2a
898.8048450985 0.13032212 -0.0192809343 -101.195155 2º Paso f ' v     3
v  b v
2

905.5639636602 0.00065161 -0.0190884915 6.75911856

905.5981000925 1.64936E-08 -0.0190875252 0.03413643 3º Paso f  vi 
vi 1  vi 
905.5981009566 0 -0.0190875252 8.64105E-07 f '  vi 
Tolerancia
v molar = 905.598101 cc/mol vi 1  vi  0.0001
 1, 68243
898,80485  1000 
0, 01663
 Sustancia : Agua

Condiciones de Estado Propiedades críticas

Temperatura = 313.15 °K Tc = 647.1 °K
Presión = 10 bar Pc = 220.55 bar
Constante R = 83.14 bar.cc/mol°K Zc = 0.229
Volumen ideal = 2603.5291 cc/mol vc = 55.9 cc/mol

27 R2Tc2
Ecuación de Van der Waals a
64 Pc RT a
a = 5536554.36 bar.cc^2/mol^2 P  2
RTc v b v
b = 30.4918919 cc/mol b
8Pc
RT a
vi f(vi) f'(vi) 1º Paso f v    2 P0
v b v
1000 11.3175697 -0.0166256014 RT 2a
1680.731446202 3.81673308 -0.0072279852 680.731446 2º Paso f ' v     3
v  b v
2

2208.780823037 0.81733604 -0.0044593852 528.049377

2392.065290967 0.05695819 -0.0038593048 183.284468 3º Paso f  vi 
vi 1  vi 
2406.823957954 0.00031831 -0.0038162894 14.758667 f '  vi 
Tolerancia
v molar = 2406.82396 cc/mol vi 1  vi  0.0001
 Sustancia : Agua

Condiciones de Estado Propiedades críticas

Temperatura = 313.15 °K Tc = 647.1 °K
Presión = 6 bar Pc = 220.55 bar
Constante R = 83.14 bar.cc/mol°K Zc = 0.229
Volumen ideal = 4339.21517 cc/mol vc = 55.9 cc/mol

27 R2Tc2
a
Ecuación de Van der Waals 64 Pc
RT a
a = 5536554.36 bar.cc^2/mol^2 P  2
b = 30.4918919 cc/mol RTc v b v
b
8Pc
RT a
vi f(vi) f'(vi) 1º Paso f v    2 P0
v b v
1000 15.3175697 -0.0166256014 RT 2a
1921.324246542 6.26940539 -0.0057208633 921.324247 2º Paso f ' v     3
v  b v
2

3017.208741741 2.10885145 -0.0025154606 1095.8845

3855.564737137 0.43403618 -0.0015862393 838.355995 3º Paso f  vi 
vi 1  vi 
4129.190648643 0.02736648 -0.0013925009 273.625912 f '  vi 
Tolerancia
v molar = 4129.19065 cc/mol vi 1  vi  0.0001
 Sustancia : Agua

Condiciones de Estado Propiedades críticas

Temperatura = 313.15 °K Tc = 647.1 °K
Presión = 3 bar Pc = 220.55 bar
Constante R = 83.14 bar.cc/mol°K Zc = 0.229
Volumen ideal = 8678.43033 cc/mol vc = 55.9 cc/mol

27 R2Tc2
Ecuación de Van der Waals a
64 Pc RT a
a = 5536554.36 bar.cc^2/mol^2 P  2
RTc v b v
b = 30.4918919 cc/mol b
8Pc
RT a
vi f(vi) f'(vi) 1º Paso f v    2 P0
v b v
1000 18.3175697 -0.0166256014 RT 2a
2101.768846796 8.31633899 -0.0048759115 1101.76885 2º Paso f ' v     3
v  b v
2

3807.365642528 3.51140844 -0.0016245156 1705.5968

5968.876747928 1.22883655 -0.0006862174 2161.51111 3º Paso f  vi 
vi 1  vi 
7759.616136743 0.27651428 -0.0004121147 1790.73939 f '  vi 
8430.580584353 0.02150899 -0.0003504933 670.964448 Tolerancia
8491.948335881 0.00015196 -0.0003455584 61.3677515 vi 1  vi  0.0001
8492.388082099 7.69255E-09 -0.0003455234 0.43974622
8492.388104363 0 -0.0003455234 2.22635E-05

v molar = 7759.6161367 cc/mol

 1, 68243
898,80485  1000 
0, 01663
 Sustancia : Agua

Condiciones de Estado Propiedades críticas

Temperatura = 313.15 °K Tc = 647.1 °K
Presión = 1 bar Pc = 220.55 bar
Constante R = 83.14 bar.cc/mol°K Zc = 0.229
Volumen ideal = 26035.291 cc/mol vc = 55.9 cc/mol

27 R2Tc2
Ecuación de Van der Waals a
64 Pc RT a
a = 5536554.36 bar.cc^2/mol^2 P  2
RTc v b v
b = 30.4918919 cc/mol b
8Pc
RT a
vi f(vi) f'(vi) 1º Paso f v    2 P0
v b v
1000 20.3175697 -0.0166256014 RT 2a
2222.065246966 9.75841535 -0.0044113872 1222.06525 2º Paso f ' v     3
v  b v
2

4434.162009912 4.63059064 -0.0012155483 2212.09676

8243.628485212 2.0884862 -0.000366196 3809.46648 3º Paso f  vi 
vi 1  vi 
13946.82041221 0.84238126 -0.0001303535 5703.19193 f '  vi 
20409.10367761 0.26428718 -6.13896E-05 6462.28327 Tolerancia
24714.18424749 0.04569218 -4.199736E-05 4305.08057 vi 1  vi  0.0001
25802.16158888 0.00191287 -3.855459E-05 1087.97734
25851.7760428 3.64493E-06 -3.84078E-05 49.6144539
25851.87094348 1.32847E-11 -3.840752E-05 0.09490069
25851.87094383 0 -3.840752E-05 3.45888E-07

v molar = 13946.820412 cc/mol

 1, 68243
898,80485  1000 
0, 01663
 Sustancia : Agua

Condiciones de Estado Propiedades críticas

Temperatura = 400 °K Tc = 405.7 °K
Presión = 100 bar Pc = 112.8 bar
Constante R = 83.14 bar.cc/mol°K Zc = 0.242
Volumen ideal = 332.56 cc/mol vc = 72.5 cc/mol

𝑎=27/64 (𝑅^2 𝑇_𝑐^2)/𝑃_𝑐

Ecuación de Van der Waals
𝑃=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2
a = 4255050.77 bar.cc^2/mol^2
b = 37.3779898 cc/mol 𝑏=(𝑅𝑇_𝑐)/(8𝑃_𝑐 )

𝑓(𝑣)=𝑅𝑇/(𝑣−𝑏)−𝑎/𝑣^2 −𝑃=0
vi f(vi) f'(vi) 1º Paso 𝑓'(𝑣)=−𝑅𝑇/(𝑣−𝑏)^2 +2𝑎/𝑣^3
1000 -69.7077418 -0.0273786571 𝑣_(𝑖+1)=𝑣_𝑖−𝑓(𝑣_𝑖 )/(𝑓'(𝑣_𝑖 ) )
-1546.06139417 -122.782511 -0.0155665654 -2546.06139 2º Paso 𝑇𝑜𝑙𝑒𝑟𝑎𝑛𝑐𝑖𝑎
|𝑣_(𝑖+1)−𝑣_𝑖 |≤0.0001
-9433.640149668 -103.559157 -0.0003808829 -7887.57876
-281326.0330125 -100.11825 -4.204649E-07 -271892.393 3º Paso 898,80485=1000−(−
-238394549.3008 -100.000139 -5.851641E-13 -238113223
-1.70892701E+14 -100 -1.138736E-24 -1.7089E+14
-8.78166801E+25 -100 -4.31237E-48 -8.7817E+25
-2.31891066E+49 -100 -6.184463E-95 -2.3189E+49
-1.61695533E+96 -100 -1.27196E-188 -1.617E+96

v molar = -238394549.3 cc/mol

^2 −𝑃=0
+2𝑎/𝑣^3
𝑓'(𝑣_𝑖 ) )

98,80485=1000−(−1,68243)/(−0,01663)