El sistema ternario: Acetona(1)/Tetracloruro de carbono(2)/Metanol(3)

Componente A B C 〖𝑙𝑜𝑔〗 _10 𝑃_𝑖^𝑠𝑎𝑡 (𝑚𝑚𝐻𝑔)

Acetona (1) 7.2316 1277.03 237.23
Tetracl C (2) 6.8941 1219.58 227.17
𝛼_𝑖𝑗=10^[ 〖 (𝐴 〗 _𝑖−𝐴_𝑗)−(𝐵_𝑖
Metanol (3) 8.0724 1574.99 238.87

(a) Dado P=760 mmHg y {xi}, calcule temperatura y {yi} burbuja

i xi tsat P(mmHg) xi*tsat(°C) 𝑃_𝑗^𝑠𝑎𝑡=𝑃/(∑_𝑖^𝑁▒ 〖𝑥 _𝑖 𝛼
Acetona (1) 0.2 56.287 760 11.2574
Tetracl C (2) 0.45 76.716 34.5220 𝑡_𝑗^𝑠𝑎𝑡=𝑡_𝑛=𝐵_𝑗/(𝐴_𝑗−𝑙𝑜
Metanol (3) 0.35 64.504 22.5762
68.3557

n 0 1 2 3 4 5
T(°C) 68.3557 67.0874 66.9549 66.9409 66.9395 66.9393
α13 1.2786 1.2899 1.2911 1.2913 1.2913 1.2913
α23 0.6628 0.6681 0.6687 0.6687 0.6687 0.6687
α33 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000
Psat3 840.7314 836.4232 835.9716 835.9242 835.9192 835.9186
T (°C) 67.0874 66.9549 66.9409 66.9395 66.9393 66.9393

Composición de burbuja SOLVER

i Psati yi f(t) t(°C)
1 1079.397 0.2841 -2.5011E-12 66.9393
2 558.998 0.3310
3 835.919 0.3850

(b) Dado P, {yi}, Calcule de T, Xi Punto Rocío

i yi tsat yi*tsat
Acetona (1) 0.2 56.287 11.2574
Tetracl C (2) 0.45 76.716 34.5220
Metanol (3) 0.35 64.504 22.5762
To= 68.3557

n 0 1 2 3 4 5
T(°C) 68.3557 68.8815 68.9433 68.9506 68.9514 68.9515
α13 1.2786 1.2740 1.2734 1.2733 1.2733 1.2733
α23 0.6628 0.6606 0.6604 0.6603 0.6603 0.6603
α33 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000
Psat3 900.8806 903.0151 903.2661 903.2956 903.2991 903.2995 〖𝑙𝑜𝑔〗 _10 𝑃_𝑖^
T (°C) 68.8815 68.9433 68.9506 68.9514 68.9515 68.9516
Composición de rocío SOLVER
i Psati xi f(T) T(°C)
1 1150.202 0.1322 -6.079E-09 68.9516
2 596.470 0.5734
3 903.299 0.2945

(c) Cálculo de evaporación instantanea. Para P=760 mmHg y T=1/2(TB+TR), {zi}

T(°C) P(mmHg)
67.94542207 760

zi Psati(mmHg) Ki F(v) v yi xi
0.2 1114.35 1.4663 4.584E-11 0.4953 0.238234 0.162478
0.45 577.49 0.7599 0.388098 0.510749
0.35 869.07 1.1435 0.373668 0.326773
1.000000 1.000000
〗 _10 𝑃_𝑖^𝑠𝑎𝑡 (𝑚𝑚𝐻𝑔)=𝐴𝑖−𝐵𝑖/((𝑇(°𝐶)+𝐶𝑖) )

^[ 〖 (𝐴 〗 _𝑖−𝐴_𝑗)−(𝐵_𝑖/(𝑡+𝐶_𝑖 )−𝐵_𝑗/(𝑡+𝐶_𝑗 ) )]

/(∑_𝑖^𝑁▒ 〖𝑥 _𝑖 𝛼_𝑖𝑗 〗 )

𝑠𝑎𝑡=𝑡_𝑛=𝐵_𝑗/(𝐴_𝑗−𝑙𝑜𝑔𝑃)−𝐶_𝑗

〖𝑙𝑜𝑔〗 _10 𝑃_𝑖^𝑠𝑎𝑡 (𝑚𝑚𝐻𝑔)=𝐴𝑖−𝐵𝑖/((𝑇(°𝐶)+𝐶𝑖) )

𝐹𝑦=∑_𝑖^𝑁▒𝐾𝑖𝑍𝑖/(1+𝑣(𝑘𝑖−1))
El sistema ternario: Acetona(1)/Tetracloruro de carbono(2)/Metanol(3)

COMPONENTES A B C
Acetona (1) 7.2316 1277.03 237.23
Tetracloruro C (2) 6.8941 1219.58 227.17 〖𝑃𝑠𝑎𝑡〗 _𝑖 (𝑚𝑚𝐻𝑔)=10^[𝐴_𝑖−𝐵_𝑖/(𝑡(°𝐶)+𝐶_𝑖
)]
Metanol (3) 8.0724 1574.99 238.87

Dado T, xi. Calcule P, {yi} P. burbuja T (°C)

x1 x2 x3 65
0.2 0.5 0.3

Psat1 Psat2 Psat3 mmHg

1014.47612127138 524.670151 774.988723
𝑷=∑8_𝟏▒ 〖𝒙𝒊∗𝑷 _𝒊^𝒔𝒂𝒕 〗
P(mmHg) Presión de burbuja
697.726916444735

y1 y2 y3 Composición de burbuja
0.290794606703908 0.37598532 0.33322008 1.00000

Dado T, yi, Calcule P, {xi} P. de rocío T(°C)

65
y1 y2 y3
0.2 0.5 0.3
𝑃=1/(∑8_𝑖▒𝑦𝑖/(𝑃_𝑖^𝑠𝑎𝑡 ))
Presion de rocío (mmHg)
650.521507426359

Composición de Rocío
x1 x2 x3
0.128247771196645 0.61993379 0.25181844 1.00000
𝐻𝑔)=10^[𝐴_𝑖−𝐵_𝑖/(𝑡(°𝐶)+𝐶_𝑖

∗𝑷 _𝒊^𝒔𝒂𝒕 〗
Para el sistema Benceno(1)/Etilbenceno(2)
Determine gráficamente el punto de burbuja y de rocio para una t = 70°C
I TEMPERATURA CONSTANTE
T(°C) Componente A B C Psat1
70 Benceno 13.8594 2773.78 220.07 73.4753192
Etilbenceno 14.0045 3279.47 213.2

x1 P y1 80.00
0 11.30 0.00
70.00 P-x1
0.1 17.51 0.42 Line
ar
0.2 23.73 0.62 60.00 (P-
0.3 29.95 0.74 x1)
P-y1
50.00
0.4 36.17 0.81

Presión (KPa)
0.5 42.39 0.87 40.00
0.6 48.60 0.91
0.7 54.82 0.94 30.00

0.8 61.04 0.96 20.00

0.9 67.26 0.98
1 73.48 1.00 10.00

0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Composición x1-y1
 Psat2
11.2960213

0.7 0.8 0.9 1

Para el sistema binario Benceno(1)/Etilbenceno(2), a la presión de 101.33 KPa, determine gráficamente
el punto de burbuja y punto de rocio
P(kPa) Componente A B C
101.33 Benceno 13.8594 2773.78 220.07
Etilbenceno 14.0045 3279.47 213.2

140
Temperatura P1(T) P2(T) P-P2(T) x1 Y1
136.20 434.28 101.33 0.00 0.000 0.000 130
129.96 378.05 85.44 15.89 0.054 0.203
123.73 327.45 71.60 29.73 0.116 0.376 120

TEMPERATURA (°C)
117.49 282.12 59.59 41.74 0.188 0.522
111.26 241.71 49.26 52.07 0.271 0.645 110
105.03 205.86 40.41 60.92 0.368 0.748
100
98.79 174.23 32.89 68.44 0.484 0.833
92.56 146.49 26.54 74.79 0.624 0.901 90
86.32 122.29 21.23 80.10 0.793 0.957
80.09 101.33 16.82 84.51 1.000 1.000 80

SOLVER 70
0 0.1 0.2 0.3
x1 T(x1) °C F(T) Psat1 y1
0 136.20 0.000 434.28 0.000
0.1 125.28 0.000 339.54 0.335
0.2 116.50 0.000 275.33 0.543
0.3 109.27 0.000 229.79 0.680 140
0.4 103.21 0.000 196.20 0.775
0.5 98.02 0.000 170.61 0.842 130
0.6 93.53 0.000 150.58 0.892
0.7 89.58 0.000 134.52 0.929 120
TEMPERATURA (°C)

0.8 86.08 0.000 121.40 0.958

110
0.9 82.93 0.000 110.51 0.982
1 80.09 0.000 101.33 1.000
100

90

80

70
0 0.1 0.2 0
gráficamente

Tsat1 Tsat2
80.089588 136.19579715474
(Tsat2-Tsat1)/9
6.2340232425406
140
T-
130 x1

120
TEMPERATURA (°C)

110

100

90

80

70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1-y1

140

T-
130 x1
120
TEMPERATURA (°C)

110

100

90

80

70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1-y1