P(bar) T(K) R (cc-bar/mol-K)

50 400 83.14

COMPONENTE yi Pc (bar) Tc(K) ωi

Etano (1) 0.150 48.320 305.300 0.100
Propano (2) 0.350 42.480 369.800 0.152
n-butano (3) 0.500 37.960 425.100 0.200

(a) Correlación de Pitzer/Abbott

Tri Pri 𝑩_𝒊𝒋^𝒐 𝑩_𝒊𝒋^𝟏 𝝓_𝒊
1.310 1.035 -0.1909 0.0837 0.8658
1.082 1.177 -0.2892 0.0153 0.7319
0.941 1.317 -0.3822 -0.0831 0.5722
 𝐵_𝑖𝑗^𝑜=0.083−0.422/( 〖𝑇𝑟〗 _𝑖𝑗^1.6 )

𝝓_𝒊=𝒆𝒙𝒑[𝑷𝒓𝒊/𝑻𝒓𝒊 (𝑩_𝒊^𝒐−𝝎_𝒊 𝑩_𝒊^𝟏 )]

𝐵_𝑖𝑗^1=0.139−0.172/( 〖𝑇𝑟〗 _𝑖𝑗^4.2 )

PROBLEMA DE FUGACIDAD DE MEZCL

En el sistema etano(1)/propano(2)/n-butano(3), a una P, T y co

Determine el coeficiente de fugacidad de cada componente, u
(a). La correlacion de Pitzer/Abbott.
(b). La ecuación del virial truncado en dos términos.
(c). La ecuación de Redlich-Kwong-Soave (RKS)
A DE FUGACIDAD DE MEZCLA

)/n-butano(3), a una P, T y composición dada.

idad de cada componente, usando:
tt.
o en dos términos.
g-Soave (RKS)
 P(bar) T(K) R (cc/bar-K)
50 400 83.14

ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol)

11 0.150 48.320 305.300 0.100 0.279 145.50
22 0.350 42.480 369.800 0.152 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00

(b) Ecuacion del Virial truncado en dos términos

ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol)
11 0.150 48.320 305.300 0.100 0.279 145.50
22 0.350 42.480 369.800 0.152 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00
12 45.25251283 336.01 0.126 0.278 171.308
13 42.43497642 360.25 0.150 0.2765 195.160
23 40.04228658 396.49 0.176 0.275 226.388

ij Trij Prij 𝑩_𝒊𝒋^𝒐 𝑩_𝒊𝒋^𝟏 𝑩_𝒊𝒋 𝜹_𝒊𝒋

11 1.310 1.034768212 -0.1909 0.0837 -95.8794
22 1.082 1.177024482 -0.2892 0.0153 -207.6182
33 0.941 1.317175975 -0.3822 -0.0831 -371.2847
12 1.190 1.104911018 -0.2363 0.0563 -141.4828 20.5321
13 1.110 1.178273307 -0.2739 0.0282 -190.3672 86.4298
23 1.009 1.24867994 -0.3331 -0.0267 -278.0805 22.7420

ij 𝑩 ̅_𝒊 𝝓 ̂_𝒊
11 -57.0183 0.9178
22 -204.7074 0.7351
33 -361.9006 0.5804
 𝐵𝑖𝑗=𝑅𝑇𝑐𝑖𝑗/𝑃𝑐𝑖𝑗 (𝐵_𝑖𝑗^𝑜−𝜔_𝑖𝑗 𝐵_𝑖𝑗^1 )

𝐵_𝑖𝑗^1=0.139−0.172/( 〖𝑇𝑟〗
𝐵_𝑖𝑗^𝑜=0.083−0.422/(
_𝑖𝑗^4.2 ) 〖𝑇𝑟〗 _𝑖𝑗^1.6 )
𝛿𝑖𝑗=2𝐵𝑖𝑗−𝐵𝑖𝑖−𝐵𝑗𝑗

𝐵 ̅_1=[𝜕(𝑛𝐵)/(𝜕𝑛_1 )]_(𝑛2,𝑛3)=𝐵_11+𝑦_2 (1

𝐵 ̅_2=[𝜕(𝑛𝐵)/(𝜕𝑛_2 )]_(𝑛1,𝑛3)=𝐵_22+𝑦_1 (
(1−𝑦_2 ) 𝛿_23−𝑦_1 𝑦_3 𝛿_13

𝐵 ̅_3=[𝜕(𝑛𝐵)/(𝜕𝑛_3 )]_(𝑛1,𝑛2)=𝐵_33+𝑦_1 (1−𝑦_3

1 )]_(𝑛2,𝑛3)=𝐵_11+𝑦_2 (1−𝑦_1 ) 𝛿_12+𝑦_3 (1−𝑦_1 ) 𝛿_13−𝑦_2 𝑦_3 𝛿_23

_2 )]_(𝑛1,𝑛3)=𝐵_22+𝑦_1 (1−𝑦_2 ) 𝛿_12+𝑦_3

_1 𝑦_3 𝛿_13

𝑛1,𝑛2)=𝐵_33+𝑦_1 (1−𝑦_3 ) 𝛿_13+𝑦_2 (1−𝑦_3 ) 𝛿_23−𝑦_1 𝑦_2 𝛿_12

 P(bar) T(K) R (cc.bar/mol.K)
50 400 83.14

ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol)

11 0.150 48.320 305.300 0.100 0.279 145.50
22 0.350 42.480 369.800 0.132 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00

(c ) Ecuación de Redlich-Kwong-Soave
ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol) Trij
11 0.150 48.32 305.30 0.100 0.279 145.50 1.310
22 0.350 42.48 369.80 0.132 0.276 200.00 1.082
33 0.500 37.96 425.10 0.200 0.274 255.00 0.941
12 45.25 336.01 0.116 0.278 171.31 1.190
13 42.43 360.25 0.150 0.2765 195.16 1.110
23 40.04 396.49 0.166 0.275 226.39 1.009

ij 𝜶_𝒊𝒋 aij bij 𝜹_𝒊𝒋 𝒂 ̅_𝒊 𝝓 ̂_

11 0.8246 4699983 45.512 3430565 𝒊1.222
22 0.9459 8997980 62.706 8232334 0.803
33 1.0478 14738771 80.667 14442310 0.449
12 6503104 -691756
13 8322979 -2792796
23 11516039 -704672

SOLVER
a A B f(z) z b
10854581.23 0.4907305 0.1039019895 0.000 0.32674486 69.10729126 〖𝑎 ̅ _𝑖=[𝜕(𝑛𝑎)/(

〖𝑏 ̅ _𝑖=[𝜕(𝑛𝑏)/(

𝑎_𝑖=0.42748 (𝑅^2 〖𝑇
𝑎=𝑦_11 𝑎_11+𝑦_22 𝑎_22
 ├ 𝑎 ̅_1 ]_𝑛2𝑛3=𝑎_11+𝑦_2 (1−𝑦_1 ) 𝛿_12+𝑦_3 (1−𝑦_1 ) 𝛿_13−𝑦_2 𝑦_3 𝛿_23
├ 𝑎 ̅_)]
〖𝑎 ̅ _𝑖=[𝜕(𝑛𝑎)/(𝜕𝑛_𝑖 2 〗]_𝑛1𝑛3=𝑎_22+𝑦_1
_𝑛𝑗 (1−𝑦_2 ) 𝛿_12+𝑦_3 (1−𝑦_2 ) 𝛿_13−𝑦_1 𝑦_3 𝛿_13
├ 𝑎 ̅_3 ]_𝑛1𝑛2=𝑎_33+𝑦_1 (1−𝑦_3 ) 𝛿_13+𝑦_2 (1−𝑦_3 ) 𝛿_23−𝑦_1 𝑦_2 𝛿_12

〖𝑏 ̅ _𝑖=[𝜕(𝑛𝑏)/(𝜕𝑛_𝑖 )] 〗 _𝑛𝑗

𝑏 ̅_𝑖=𝑏_𝑖
𝑏_𝑖=0.08664 (𝑅 〖𝑇𝑐〗 _𝑖)/ 〖𝑃𝑐〗 _𝑖
𝑎_𝑖=0.42748 (𝑅^2 〖𝑇𝑐〗 _𝑖^2)/ 〖𝑃𝑐〗 _𝑖 𝛼_𝑖 (𝑇𝑟𝑖, 𝜔𝑖)

𝐴=𝑎𝑃/(𝑅𝑇)^2
𝛼_𝑖 (𝑇𝑟𝑖, 𝜔𝑖)=[1+(0.48+1.574𝜔_𝑖−0.176𝜔_𝑖^2 )(1− 〖𝑇𝑟〗 _𝑖^0.5 )]^2

𝜙 ̂_𝑖=𝑒𝑥𝑝[𝑏 ̅_𝑖/𝑏 (𝑧−1)−𝑙𝑛(𝑧−𝐵)−𝐴/𝐵 (1+𝑎 ̅_𝑖/𝑎−𝑏 ̅_𝑖/𝑏)𝑙𝑛((𝑧+𝐵)/𝑧)]

𝐵=𝑏𝑃/𝑅𝑇

𝑎_𝑖𝑗=√(𝑎_𝑖 𝑎_𝑗 )
𝑧^3−𝑧^2+(𝐴−𝐵−𝐵^2 )𝑧−𝐴×𝐵=0
𝑎=𝑦_11 𝑎_11+𝑦_22 𝑎_22+𝑦_33 𝑎_33+𝑦_1 〖𝑦 _2 𝛿 〗 _12+𝑦_1 〖𝑦 _3 𝛿 〗 _13+𝑦_2 〖𝑦 _3 𝛿 〗 _23

𝑏=𝑦_1 𝑏_1+𝑦_2 𝑏_2+𝑦_3 𝑏_3

𝛿_𝑖𝑗=2𝑎_𝑖𝑗−𝑎_𝑖𝑖−𝑎_𝑗𝑗
 P(bar) T(K) R (cc.bar/mol.K) (d) Ecuación de Redlich-Kwong
50 400 83.14

ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol) 𝛼_𝑖 (𝑇𝑟𝑖, 𝜔𝑖)=[1+(0.48

11 0.150 48.320 305.300 0.100 0.279 145.50
𝑎_𝑖=0.42748 (𝑅^2 〖𝑇𝑐〗 _𝑖^2.5)/
22 0.350 42.480 369.800 0.132 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00 𝜙 ̂_𝑖=𝑒𝑥𝑝[𝑏 ̅_𝑖/𝑏 (𝑧−1)

LA ECUACIÓN DE REDLICH-KWOG
ij yi Pc (bar) Tc(K) ωi Zc Vc(cc/mol)
11 0.150 48.320 305.300 0.100 0.279 145.50
22 0.350 42.480 369.800 0.132 0.276 200.00
33 0.500 37.960 425.100 0.200 0.274 255.00
12 45.25251283 336.01 0.116 0.278 171.308
13 42.43497642 360.25 0.150 0.2765 195.160
23 40.04228658 396.49 0.166 0.275 226.388

𝜹_𝒊𝒋 𝒂 ̅_𝒊 𝝓 ̂_𝒊

ij Trij aij bij
11 1.310 4979616.88 45.51225378 3843812.177 1.1686
22 1.082 9146156.00 62.70625476 8463500.536 0.7825
33 0.941 14501315.59 80.66652805 14240386.29 0.4586
12 1.190 6748655.63 -628461.62
13 1.110 8497705.33 -2485521.81
23 1.009 11516566.09 -614339.403

a A B F(z) Z b
10871837.16 0.491510636 0.10390199 8.11471E-09 0.32275 69.10729126 〖𝑎 ̅ _𝑖=[𝜕(𝑛

〖𝑏 ̅ _𝑖=[𝜕(𝑛

𝑎=𝑦_11 𝑎_11+𝑦_22
𝛼_𝑖 (𝑇𝑟𝑖, 𝜔𝑖)=[1+(0.48+1.574𝜔_𝑖−0.176𝜔_𝑖^2 )(1− 〖𝑇𝑟〗 _𝑖^0.5 )]^2
8 (𝑅^2 〖𝑇𝑐〗 _𝑖^2.5)/(𝑇^0.5 〖𝑏_𝑖=0.08664
𝑃𝑐〗 ^𝑖 ) (𝑅 〖𝑇𝑐〗 _𝑖)/ 〖𝑃𝑐〗 _𝑖

𝜙 ̂_𝑖=𝑒𝑥𝑝[𝑏 ̅_𝑖/𝑏 (𝑧−1)−𝑙𝑛(𝑧−𝐵)−𝐴/𝐵 (1+𝑎 ̅_𝑖/𝑎−𝑏 ̅_𝑖/𝑏)𝑙𝑛((𝑧+𝐵)/𝑧)]

├ 𝑎 ̅_1 ]_𝑛2𝑛3=𝑎_11+𝑦_2 (1−𝑦_1 ) 𝛿_12+𝑦_3 (1−𝑦_1 ) 𝛿_13−𝑦_2 𝑦_3 𝛿_23

〖𝑎 ̅ _𝑖=[𝜕(𝑛𝑎)/(𝜕𝑛_𝑖├)]𝑎 ̅〗_2_𝑛𝑗
]_𝑛1𝑛3=𝑎_22+𝑦_1 (1−𝑦_2 ) 𝛿_12+𝑦_3 (1−𝑦_2 ) 𝛿_13−𝑦_1 𝑦_3 𝛿_13
├ 𝑎 ̅_3 ]_𝑛1𝑛2=𝑎_33+𝑦_1 (1−𝑦_3 ) 𝛿_13+𝑦_2 (1−𝑦_3 ) 𝛿_23−𝑦_1 𝑦_2 𝛿_12

〖𝑏 ̅ _𝑖=[𝜕(𝑛𝑏)/(𝜕𝑛_𝑖 )] 〗 _𝑛𝑗 𝑏 ̅_𝑖=𝑏_𝑖 𝛿_𝑖𝑗=2𝑎_𝑖𝑗−𝑎_𝑖𝑖−𝑎_𝑗𝑗

𝐴=𝑎𝑃/(𝑅𝑇)^2
𝐵=𝑏𝑃/𝑅𝑇

𝑎_𝑖𝑗=√(𝑎_𝑖 𝑎_𝑗 )

𝑎=𝑦_11 𝑎_11+𝑦_22 𝑎_22+𝑦_33 𝑎_33+𝑦_1 〖𝑦 _2 𝛿 〗 _12+𝑦_1 〖𝑦 _3 𝛿 〗 _13+𝑦_2 〖𝑦 _3 𝛿 〗 _23

𝑏=𝑦_1 𝑏_1+𝑦_2 𝑏_2+𝑦_3 𝑏_3
𝑧^3−𝑧^2+(𝐴−𝐵−𝐵^2 )𝑧−𝐴×𝐵=0
𝑧^3−𝑧^2+(𝐴−𝐵−𝐵^2 )𝑧−𝐴×𝐵=0

PROBLEMA DE FUGACIDAD DE MEZCLA

En el sistema metano(1)/etileno(2)/propano(3), a una P, T y composición dada.
Determine el coeficiente de fugacidad de cada componente, usando:
(a). La correlacion de Pitzer/Abbott.
(b). La ecuación del virial truncado en dos términos.
(c). La ecuación de Redlich-Kwong-Soave (RKS)
3−𝑦_2 𝑦_3 𝛿_23
3−𝑦_1 𝑦_3 𝛿_13
3−𝑦_1 𝑦_2 𝛿_12

〖𝑦 _3 𝛿 〗 _23
D DE MEZCLA
na P, T y composición dada.
ponente, usando: