El sistema n-pentano(1)/n-hexano(2)/n-heptano(3) se asemeja bastante a la ley de Raoult. Determine.

Datos y ecuaciones necesarios para resolver los incisos:

LN(Psat)=A-(B/(T+C)) Psat AS mmHg AND T AS K

Sustancias A B C
n-pentano 15.8333 2477.07 -39.94
n-hexano 15.8366 2697.55 -48.78
n-heptano 15.8737 2911.32 -56.51

a) P y yi , dado T=70°C, x1= 0,09, x2= 0,57, x3= 0,34 b) P y xi , dado T=80°C, y1= 0,43, y2= 0,36, y3= 0,21

T(°C) 70 T(°C) 80
T (K) 343.15 T (K) 353.15
x1 0.09 y1 0.43
x2 0.57 y2 0.36
x3 0.34 y3 0.21
P1sat (mmHg) 2129.86421 P1sat(mmHg) 2764.58128
P2sat (mmHg) 790.600313 P2sat(mmHg) 1068.34622
P3sat (mmHg) 303.987854 P3sat(mmHg) 428.10976
Pburbuja (mmHg) 745.685828 Procío (mmHg) 1017.25597
Pburbuja (kPa) 99.4115222 Procío (kPa) 135.616047
y1 0.25706239 x1 0.1582229
y2 0.6043325 x2 0.34278415
y3 0.13860512 x3 0.49899295
y 1 x 1
c) T y yi , dado P=250KPa, x1= 0,48, x2= 0,28, x3= 0,24 d) T y xi , dado P=300KPa, y1= 0,44, y2= 0,47, y3= 0,09

P (kPa) 250 P (kPa) 300

P (mmHg) 1875.25 P (mmHg) 2250.3
x1 0.48 y1 0.44
x2 0.28 y2 0.47
x3 0.24 y3 0.09
T1sat (K) 338.50 T1sat (K) 345.21
T2sat (K) 373.78 T2sat (K) 381.08
T3sat (K) 405.71 T3sat (K) 413.51
Tburbuja (K) 356.26 Trocío (K) 375.0785
Tburbuja (°C) 83.11 Trocío (°C) 101.9285
P1sat(mmHg) 2988.1236 P1sat(mmHg) 4638.36379
P2sat(mmHg) 1168.53846 P2sat(mmHg) 1938.12539
P3sat(mmHg) 473.999494 P3sat(mmHg) 841.295818
y1 0.76485766 x1 0.21346579
y2 0.17447848 x2 0.54570308
y3 0.06066385 x3 0.24073221
y 0.99999999 x 0.99990108