REACCIÓN: H2 + CO2 --> H2O + CO T (K) 1000 R= 8.

314

H2 CO2 H2O CO
vi -1 -1 1 1 Σv = 0
nio 1 1 0 0 Σno = 2
∆G°f 0 -395790 -192420 -200240 ε= 0.4531
yi 0.27346036 0.27346036 0.22653964 0.22653964 G = -208674.921
lnyi -1.29659862 -1.29659862 -1.48483532 -1.48483532

DATOS GRAFICA G vs ε

yi ln yi
ε H2 CO2 H2O CO H2 CO2 H2O
0 0.5 0.5 0 0 -0.69314718 -0.69314718 Err:502
0.1 0.45 0.45 0.05 0.05 -0.7985077 -0.7985077 -2.99573227
0.2 0.4 0.4 0.1 0.1 -0.91629073 -0.91629073 -2.30258509
0.3 0.35 0.35 0.15 0.15 -1.04982212 -1.04982212 -1.89711998
0.4 0.3 0.3 0.2 0.2 -1.2039728 -1.2039728 -1.60943791
0.5 0.25 0.25 0.25 0.25 -1.38629436 -1.38629436 -1.38629436
0.6 0.2 0.2 0.3 0.3 -1.60943791 -1.60943791 -1.2039728
0.7 0.15 0.15 0.35 0.35 -1.89711998 -1.89711998 -1.04982212
0.8 0.1 0.1 0.4 0.4 -2.30258509 -2.30258509 -0.91629073
0.9 0.05 0.05 0.45 0.45 -2.99573227 -2.99573227 -0.7985077
1 0 0 0.5 0.5 Err:502 Err:502 -0.69314718
 Energía de Gibbs vs grado de la reacción
-203000
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

-204000

i
-205000
CO G
Err:502 Err:502
-2.99573227 -206204.065 -206000
-2.30258509 -207505.171
-1.89711998 -208267.051
-207000
-1.60943791 -208627.245
-1.38629436 -208638.151
-1.2039728 -208314.245 -208000
-1.04982212 -207641.051
-0.91629073 -206566.171 -209000
-0.7985077 -204952.065
-0.69314718 Err:502 Energía de Gibbs vs grado de la reacción
0.9 1
 HCl O2 H20 Cl2
ni0 5 1 0 0 n0 = 6.0000
vi -4 -1 2 2 v= -1.0000
Ai 3.1560 3.6390 3.4700 4.4420 ∆A = -0.4390
Bi 6.23E-04 5.06E-04 1.45E-03 8.90E-05 ∆B = 8.000E-05
Ci 0.00E+00 0.00E+00 0.00E+00 0.00E+00 ∆C = 0.000E+00
Di 1.51E+04 -2.27E+04 1.21E+04 -3.44E+04 ∆D = -8.230E+04
H0 i -92307 0 -241818 0 ∆H0 = -114408.00
G0 i -95299 0 -228572 0 ∆G0 = -75948.00

T0 298.15 R 8.314
 Cálculo de la constante de equilibrio
T (° C ) T (K) Ꞇ ∆Cp/R dT ∆Cp/RT dT ∆G/RT K
500 773.15 2.5932 -357.7582 -0.7744 -1.9714 7.1804

Cálculo del grado de avance

P P0 (P/P0)^-v K calculada K solver ε
2 1 2.0000 7.1804 7.1804 0.79340628

COMPOSICIONES EN EL EQUILIBRIO yi
HCl O2 H20 Cl2
0.3508 0.0397 0.3048 0.3048