Sistema: Etanol(1)/ Agua(2) Modelo UNIFAC

Frecuencia
k Rk Qk vk1 vk2 q1=Gk1 q2=Gk2
1 CH3 (1) 0.9011 0.8480 1 0 0.848 0
2 CH2 (1) 0.6744 0.5400 1 0 0.54 0
3 OH (5) 1.0000 1.2000 1 0 1.2 0
4 H2O (7) 0.9200 1.4000 0 1 0 1.4
2.588 1.4

Parámetros de interacción
k r1 r2 1 2 3 4
1 0.9011 0 0 0 986.5 1318
2 0.6744 0 0 0 986.5 1318
3 1 0 156.4 156.4 0 353.5
4 0 0.92 300 300 -229.1 0
2.5755 0.92

P= 101.33
n 0 1 2 3 A
t(°C) 70 81.473178 81.455841 81.45586 Etanol (1) 16.8958
T(K) 343.15 354.62318 354.60584 354.60586 Agua (2) 16.3872
L1 1.4735 1.4735 1.4735 1.4735
L2 0.7971 0.7971 0.7971 0.7971 i xi
J1 1.8180 1.8180 1.8180 1.8180 1 0.3
J2 0.6494 0.6494 0.6494 0.6494 2 0.7
θ1 0.2544 0.2544 0.2544 0.2544
θ2 0.1620 0.1620 0.1620 0.1620 Para T=70°C
θ3 0.3600 0.3600 0.3600 0.3600 x1 Ganma 1
θ4 0.9800 0.9800 0.9800 0.9800 0 7.053
s11 2.1487 2.1487 2.1487 2.1487 0.1 3.400
s21 2.1487 2.1600 2.1600 2.1600 0.2 2.192
s31 1.2783 1.2860 1.2859 1.2859 0.3 1.661
s41 0.4581 0.4766 0.4766 0.4766 0.4 1.386
s12 0.5840 0.6008 0.6008 0.6008 0.5 1.228
s22 0.5840 0.6008 0.6008 0.6008 0.6 1.133
s32 2.7295 2.6712 2.6712 2.6712 0.7 1.072
s42 1.4000 1.4000 1.4000 1.4000 0.8 1.033
η1 1.0535 1.0652 1.0652 1.0652 0.9 1.010
η2 1.0535 1.0686 1.0686 1.0686 1 1.000
η3 2.2941 2.2556 2.2556 2.2556
η4 1.1174 1.1230 1.1230 1.1230
Ganma 1 1.6606973 1.6658933 1.6658864 1.6658864
Ganma 2 1.2243634 1.2211922 1.2211969 1.2211969
Psat1(KPa) 116.7923 116.7114 116.7114 116.7114 Psat1 P(dato)/(X1ϒ1+
Psat2(KPa) 50.3387 50.3038 50.3038 50.3038 Psat2 P(dato)/(X2ϒ2+
t (°C) 81.473178 81.455841 81.45586 81.45586
1 2
a11 a12
Para P=101.33 KPa a21 a22
x1 T(x1) Ganma 1 P1(t) y1 a31 a32
0 100.00 6.6766 235.098 0.000 a41 a42
0.1 85.54 3.3731 137.144 0.457
0.2 82.79 2.1934 123.083 0.533
0.3 81.46 1.6658 116.711 0.576 USANDO MARGULES Y1=(x1*ϒ1*Psat1)/P)
0.4 80.45 1.3903 112.097 0.615
0.5 79.60 1.2317 108.294 0.658
0.6 78.88 1.1347 105.170 0.707
0.7 78.30 1.073 102.749 0.762
0.8 77.91 1.0333 101.116 0.825 105.00
0.9 77.75 1.009 100.458 0.900
100.00
1 77.96 1 101.330 1.000
95.00

TEMPERATURA (°c)
90.00

85.00

80.00

75.00
0 0.1 0.2

1
0.9
0.8
0.7
0.6
0.5
y1

0.4
0.3
0.2
0.1
0
0 0.1 0.2 0
0.3
0.2
0.1
0
0 0.1 0.2 0
 Etanol Ch3Ch2OH Vk1 La cantidad de terminos
Agua H2O Vk2 La cantidad de terminos

AREA FUNCIONAL
L1 q1/(q1x1+q2x2) ENERGIA PARCIAL POR GRUPO FUNCIONAL
L2 q2/(q1x1+q2x2) Sk11 G11*r11+G21*r21+G31*r31
AREA ……. Sk21 G11*r12+G21*r22+G31*r32
J1 r1/(r1x1+r2x2) Sk31 G11*r13+G21*r23+G31*r33
J2 r2/(r1x1+r2x2) Sk41
AREA DE LA MEZCLA Sk12 G12*r11+G22*r21+G32*r31
ϴ1 G11X1+G12X2 Sk22 G12*r12+G22*r22+G32*r32
ϴ2 G21X1+G22X2 Sk32 G12*r12+G22*r23+G32*r33
ϴ3 G31X1+G32X2 Sk42
ϴ4 G41X1+G42X3

KPa P(DATO)
B C
3795.17 230.918
3885.7 230.17
〖𝑙𝑛𝛾〗 _𝑖^𝐶=1−𝐽_𝑖+𝑙𝑛𝐽_𝑖−5𝑞_𝑖 [1−𝐽_𝑖/𝐿_𝑖 +𝑙𝑛(𝐽_𝑖/𝐿_𝑖 )]
ti (°C) t(°C) Psati(KPa)
23.459982 70 72.517
69.999377 31.256 〖𝑙𝑛𝛾〗 _𝑖^𝑅=𝑞_𝑖 (1− 〖𝑙𝑛𝐿〗 _𝑖 )−[∑▒ 〖𝜃 _𝑘
𝑠_(𝑘,𝑖)/𝜂_𝑘 〗− (∑▒ 〖𝐺 _(𝑘,𝑖) 𝑙𝑛 𝑠_(𝑘,𝑖)/𝜂_𝑘 〗 )]
ara T=70°C
Ganma2 P y1
1.000 31.26 0.000
1.036 53.80 0.458
1.118 59.73 0.532 USANDO MARGULES
1.224 62.92 0.574
1.348 65.48 0.614
1.487 67.78 0.657
1.641 69.80 0.706
1.817 71.46 0.762
2.031 72.62 0.825
2.321 73.15 0.901
2.788 72.52 1.000 85.00
P-x1
75.00 P-y1

65.00
ESIÓN (KPa)

55.00

45.00
 P-x1
75.00 P-y1

65.00

PRESIÓN (KPa)
P(dato)/(X1ϒ1+X2ϒ2*(Psat2/Psat1)) 55.00
P(dato)/(X2ϒ2+X1ϒ1*(Psat1/Psat2))
45.00
3 4
35.00
a13 a14
a23 a24 25.00
a33 a34 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
a43 a44
X1-Y1

Y1=(x1*ϒ1*Psat1)/P)

105.00
T-x1
100.00 T-y1

95.00

90.00

85.00

80.00

75.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1-y1

1
.9
.8
.7
.6
.5
.4
.3
.2
.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1-x1
.3
.2
.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1-x1
 Gk1=q1 Vk1*Qk
Gk2=q2 Vk2*Qk
r1 Rk*Vk1
r2 Rk*Vk2

ENERGIA FUNCIONAL DE LA MEZCLA

r11=s11

ENERGIA DE A MEZCLA
n1 S11*X1+S12*X2
n2 S21*X1+S22*X2
n3 S31*X1+S32*X2
n4 S41*X1+S42*X2

_𝑖 [1−𝐽_𝑖/𝐿_𝑖 +𝑙𝑛(𝐽_𝑖/𝐿_𝑖 )]

〗 _𝑖 )−[∑▒ 〖𝜃 _𝑘
𝑘,𝑖) 𝑙𝑛 𝑠_(𝑘,𝑖)/𝜂_𝑘 〗 )]

Y1=(x1*ϒ1*Psat1)/P)
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X1-Y1
 k Rk Qk vk1 vk2 q1=Gk1 q2=Gk2
1 CH3 (1) 0.9011 0.8480 1 0 0.848 0
2 CH2 (1) 0.6744 0.5400 1 0 0.54 0
3 OH (5) 1.0000 1.2000 1 0 1.2 0
4 H2O (7) 0.9200 1.4000 0 1 0 1.4
2.588 1.4

K r1 r2 1 2 3 4
1 0.9011 0 0 0 986.5 1318
2 0.6744 0 0 0 986.5 1318
3 1 0 156.4 156.4 0 353.5
4 0 0.92 300 300 -229.1 0
2.5755 0.92

Psat1(KPa) 1.3 1.5 1.9

Psat2(KPa)

x1 T(x1) Ganma 1 P1(t) y1

1.9