METODO GRAFICO - MCCABE -THIELE

DATOS
P 14.7 psia presion de la alimentacion
F 700 lbmol/h flujo de la alimentacion
q 0.9999999 Condicion termica de la alimentacion

Fracciones moleare
Componentes No. zF yD xB
Benceno 113 0.45 0.92 0.05
Tolueno 125 0.55 0.08 0.95

Constantes de Antoine
Componentes No. Pc A1 A2
Psia
Benceno 113 714.2 5.658375 5307.813
Tolueno 125 587.8 5.944251 5836.287

Calculo del incremento de temperatura

N 15
DTT 30.5 °C
DT 2.17857142857143 °C

No. T T Ps-ben Ps-tol

°C °F Psia psia
1 80.1 176.18 14.5393369 5.62388878
2 82.2785714285714 180.101429 15.5460082 6.06112078
3 84.4571428571429 184.022857 16.6068978 6.5254844
4 86.6357142857143 187.944286 17.7240045 7.01819965
5 88.8142857142857 191.865714 18.8993585 7.54051667
6 90.9928571428572 195.787143 20.1350211 8.09371551
7 93.1714285714286 199.708571 21.4330832 8.67910591
8 95.35 203.63 22.7956648 9.29802697
9 97.5285714285714 207.551429 24.2249137 9.95184684
10 99.7071428571429 211.472857 25.7230049 10.6419624
11 101.885714285714 215.394286 27.2921393 11.3697989
12 104.064285714286 219.315714 28.9345428 12.1368095
13 106.242857142857 223.237143 30.6524654 12.9444749
14 108.421428571429 227.158571 32.4481802 13.794303
15 110.6 231.08 34.3239821 14.6878282
DOMO 84.2803173489032 183.704571 16.5187207 6.48675334
FONDO 108.357442309147 227.043396 32.3943085 13.7687276
ALIMENTACION 93.8263765804841 200.887478 21.8358386 8.86158656

METODO APROXIMADO PARA SEPARACION POR DESTILACION DE MEZCLAS MULTICOMPONENTES

LCULO DE ETAPAS MINIMAS CON LA ECUACION DE FENSKE

αDOMO 2.54653134 VOLATILIDAD MEDIA

αFONDO 2.35274525 2.44772129

Componente x-Dest X-Fondo

Benceno 0.92 0.05 18.4
Tolueno 0.08 0.95 11.875

Nmin 6.01769630488193 6

BALANCE DE MASA

F=D+B
F*zF=D*yD+B*xB

D B IND
1 1 700
0.92 0.05 315

-0.057471264367816 1.14942528735632 D 321.83908 lbmol/h

1.05747126436782 -1.14942528735632 B 378.16092 lbmol/h

CALCULO DE LA RELACION DE REFLUJO MINIMO

ECUACION DE UNDERWOOD
ϴ 1.48543119960011

Condicion termica de la alimentacion

q 1 liq.sat
 EC-8-32
pag.484
pag.357

componente α z LADO1 LADO2

Benceno 2.46410036 0.45 1.13301329
Tolueno 1 0.55 -1.13301329
0 0

CONDICIONES DEL DESTILADO

componente α Yd lado 1
Benceno 2.54653134 0.92 2.2079055
Tolueno 1 0.08 -0.16480193
2.04310356

Relacion de reflujo minima

Rmin 1.04310356388505

RELACION DE REFLUJO Y ETAPAS REALES

Rreal 1.56465534582757 R=1.5*Rmin
X 0.203361353326104
Y 0.457599661234333
S 11.9055966593417
12
 limentacion

mica de la alimentacion

A3 Pebulli
°C
379.456 80.1
374.745 110.6

pag 101 pag 105

ec 3-5,3-6 ec 3-7

x-ben y-ben x-tol y-tol Kben Ktol Volatilidad 1

f(x) = 1.07884 x⁶ − 2.3
0.9 + 0.415091 x + 4.380
1.01802076 1.00689434 -0.01802076 -0.00689434 0.98907053 0.38257747 2.58528172 R² = 0.999999881144
0.8
0.91080461 0.96322285 0.08919539 0.03677715 1.05755158 0.41232114 2.56487353
0.81085015 0.91603439 0.18914985 0.08396561 1.12972094 0.4439105 2.54492951 0.7
0.717536 0.86514362 0.282464 0.13485638 1.20571459 0.47742855 2.52543463 0.6
0.63030047 0.81035881 0.36969953 0.18964119 1.28567064 0.51296032 2.50637447 0.5
0.54863523 0.75148177 0.45136477 0.24851823 1.36972932 0.55059289 2.48773521
0.4
0.47207973 0.68830776 0.52792027 0.31169224 1.45803287 0.59041537 2.46950359
0.40021618 0.62062543 0.59978382 0.37937457 1.5507255 0.63251884 2.45166688 0.3
0.33266524 0.54821678 0.66733476 0.45178322 1.64795331 0.67699638 2.43421288 0.2
0.26908203 0.47085704 0.73091797 0.52914296 1.74986428 0.72394302 2.41712984 0.1
0.20915274 0.38831467 0.79084726 0.61168533 1.85660811 0.77345571 2.40040651
0
0.15259145 0.30035129 0.84740855 0.69964871 1.96833624 0.8256333 2.38403205 0 0.1 0.2
0.09913745 0.20672159 0.90086255 0.79327841 2.08520173 0.88057652 2.36799605
0.04855275 0.10717336 0.95144725 0.89282664 2.2073592 0.93838796 2.35228850
0.00061987 0.00144737 0.99938013 0.99855263 2.33496477 0.99917198 2.33689976
0.81870748 0.92000001 0.18129252 0.07999999 1.1237225 0.44127574 2.54653134
0.04999964 0.11018393 0.95000036 0.88981607 2.20369445 0.93664814 2.35274525
0.45 0.66844404 0.55 0.33155596 1.4854312 0.60282902 2.46410036
EC. 12-13
PAG 478
FOBJ
0

EC 12-35
PAG 488
 1
f(x) = 1.07884 x⁶ − 2.34561 x⁵ + 2.25597 x⁴ − 0.807796 x³ + 0.403464 x²
0.9 + 0.415091 x + 4.38078E-05
R² = 0.999999881144301
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Etapa min
7
METODO GRAFICO - MCCABE -THIELE
DATOS
P 14.7 psia presion de la alimentacion
F 700 lbmol/h flujo de la alimentacion
q 0.9999999 Condicion termica de la alimentacion

Fracciones moleare
Componentes No. zF yD xB
Benceno 113 0.45 0.92 0.05
Tolueno 125 0.55 0.08 0.95

Constantes de Antoine
Componentes No. Pc A1 A2 A3 Pebulli
Psia °C
Benceno 113 714.2 5.658375 5307.813 379.456 80.1
Tolueno 125 587.8 5.944251 5836.287 374.745 110.6

pag 101
Calculo del incremento de temperatura ec 3-5,3-6
N 15
DTT 30.5 °C
DT 2.17857143 °C

No. T T Ps-ben Ps-tol x-ben y-ben x-tol

°C °F Psia psia
1 80.1 176.18 14.5393369 5.62388878 1.01802076 1.00689434 -0.01802076
2 82.2785714 180.101429 15.5460082 6.06112078 0.91080461 0.96322285 0.08919539
3 84.4571429 184.022857 16.6068978 6.5254844 0.81085015 0.91603439 0.18914985
4 86.6357143 187.944286 17.7240045 7.01819965 0.717536 0.86514362 0.282464
5 88.8142857 191.865714 18.8993585 7.54051667 0.63030047 0.81035881 0.36969953
6 90.9928571 195.787143 20.1350211 8.09371551 0.54863523 0.75148177 0.45136477
7 93.1714286 199.708571 21.4330832 8.67910591 0.47207973 0.68830776 0.52792027
8 95.35 203.63 22.7956648 9.29802697 0.40021618 0.62062543 0.59978382
9 97.5285714 207.551429 24.2249137 9.95184684 0.33266524 0.54821678 0.66733476
10 99.7071429 211.472857 25.7230049 10.6419624 0.26908203 0.47085704 0.73091797
11 101.885714 215.394286 27.2921393 11.3697989 0.20915274 0.38831467 0.79084726
12 104.064286 219.315714 28.9345428 12.1368095 0.15259145 0.30035129 0.84740855
13 106.242857 223.237143 30.6524654 12.9444749 0.09913745 0.20672159 0.90086255
14 108.421429 227.158571 32.4481802 13.794303 0.04855275 0.10717336 0.95144725
15 110.6 231.08 34.3239821 14.6878282 0.00061987 0.00144737 0.99938013
DOMO 84.2803173 183.704571 16.5187207 6.48675334 0.81870748 0.92000001 0.18129252
FONDO 108.357442 227.043396 32.3943085 13.7687276 0.04999964 0.11018393 0.95000036
ALIMENTACION 93.8263766 200.887478 21.8358386 8.86158656 0.45 0.66844404 0.55

CALCULO DEL NUMERO MINIMO DE ETAPAS

 Composicion en el domo 1
0.92 0 0.9
0.92 0.92
0.8
Composicion en el fondo
0.7
0.05 0
0.05 0.05 0.6

0.5
Recta de 45°
0 0 0.4
1 1
0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5

CALCULO DE LA RELACION DE REFLUJO MINIMO

q 0.9999999 liquido saturado 1

f(x) = − 0.203477 x⁶ + 0.930943 x⁵ − 1.962525 x⁴ + 2.66761 x³ −
XF 0.45 + 1.1409E-05
0.9 R² = 0.999999998675012 f(x) = 0.53523783
R² = 1
Recta de alimentacion
0.8
x y
0.45 0.45 Recta-alim FOBJ 0.7
0.449999978156 0.6684382 0.6684382 1.01476E-19
0.6
pag.357
0.5

0.4
Recta de Rectificacion
x y 0.3
0.92 0.92
0.2
0.449999978156 0.6684382
pag.361 0.1
(L/V)min 0.53523784 pag.357
Rmin 1.15163816 0
0 0.1 0.2 0.3 0.4 0.5 0.6

REFLUJO REAL Y ETAPAS REALES

Reflujo real
 R 1.72745724 R=1.5Rmin 1

Pendiente de la recta de rectificacion real 0.9

L/V 0.63335814 m
0.8

RECTA DE OPERACIÓN EN LA RECTIFICACION 0.7

x y
0.92 0.92 Recta-rec FOBJ 0.6
0.449999982768 0.62232166 0.62232166 1.8818E-20
0.5

0.4

0.3
RECTA DE OPERACIÓN EN LA ZONA DE AGOTAMIENTO
0.2
x y
0.05 0.05 m
0.1
0.449999982768 0.62232166 1.43080422
0
0 0.1 0.2 0.3 0.4

RESUMEN
Nmin 7
Rmin 1.15163816
Rreal 1.72745724
Nreal 12
Etapa.alim 5
 pag 105
ec 3-7

y-tol Kben Ktol Volatilidad 1

f(x) = 1.07884 x⁶ − 2.34561 x⁵ + 2.25597 x⁴ − 0.807796 x³ + 0.4034
0.9 + 0.415091 x + 4.38078E-05
-0.00689434 0.98907053 0.38257747 2.58528172 R² = 0.999999881144301
0.8
0.03677715 1.05755158 0.41232114 2.56487353
0.08396561 1.12972094 0.4439105 2.54492951 0.7
0.13485638 1.20571459 0.47742855 2.52543463 0.6
0.18964119 1.28567064 0.51296032 2.50637447 0.5
0.24851823 1.36972932 0.55059289 2.48773521
0.4
0.31169224 1.45803287 0.59041537 2.46950359
0.37937457 1.5507255 0.63251884 2.45166688 0.3
0.45178322 1.64795331 0.67699638 2.43421288 0.2
0.52914296 1.74986428 0.72394302 2.41712984 0.1
0.61168533 1.85660811 0.77345571 2.40040651
0
0.69964871 1.96833624 0.8256333 2.38403205 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
0.79327841 2.08520173 0.88057652 2.36799605
0.89282664 2.2073592 0.93838796 2.35228850
0.99855263 2.33496477 0.99917198 2.33689976
0.07999999 1.1237225 0.44127574 2.54653134
0.88981607 2.20369445 0.93664814 2.35274525 Etapa min
0.33155596 1.4854312 0.60282902 2.46410036 7
 x1 x2 y1
1 0.92 0.8187708504 0.92
2 0.81877085 0.6427857726 0.8187708504
3 0.64278577 0.422852431 0.6427857726
4 0.42285243 0.2332138254 0.422852431
5 0.23321383 0.1137751861 0.2332138254
6 0.11377519 0.0516395118 0.1137751861
7 0.05163951 0.0224587418 0.0516395118

2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

− 1.962525 x⁴ + 2.66761 x³ − 2.767564 x² + 2.335021 x

f(x) = 0.535237839057393 x + 0.427581188067199

R² = 1

0.4 0.5 0.6 0.7 0.8 0.9 1

 x1 x2
1 0.92 0.8187708504
2 0.8187708504 0.7017801064
3 0.7017801064 0.5891992224
4 0.5891992224 0.4978773338
5 0.4978773338 0.433174499
6 0.433174499 0.3784964924
7 0.3784964924 0.3085132326
8 0.3085132326 0.2310862477
9 0.2310862477 0.157955781
10 0.157955781 0.0980603029
11 0.0980603029 0.0540761262
12 0.0540761262 0.0243569853

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

597 x⁴ − 0.807796 x³ + 0.403464 x²

0.5 0.6 0.7 0.8 0.9 1

 y2 x3 x4 y3 y4 Etapa Cond.Etapa
0.92 0.8187708504 0.81877085 0.92 0.8187708504 1 continua
0.81877085 0.6427857726 0.642785773 0.8187708504 0.6427857726 2 continua
0.642785773 0.422852431 0.422852431 0.6427857726 0.422852431 3 continua
0.422852431 0.2332138254 0.233213825 0.422852431 0.2332138254 4 continua
0.233213825 0.1137751861 0.113775186 0.2332138254 0.1137751861 5 continua
0.113775186 0.0516395118 0.051639512 0.1137751861 0.0516395118 6 continua
0.051639512 0.0224587418 0.022458742 0.0516395118 0.0224587418 7 ultima etapa
 y1 y2 x3 x4 y3 y4 Etapa
0.92 0.92 0.81877085 0.8187708504 0.92 0.8558856943 1
0.85588569 0.8558856943 0.701780106 0.7017801064 0.8558856943 0.7817886545 2
0.78178865 0.7817886545 0.589199222 0.5891992224 0.7817886545 0.7104846354 3
0.71048464 0.7104846354 0.497877334 0.4978773338 0.7104846354 0.6526451742 4
0.65264517 0.6526451742 0.433174499 0.433174499 0.6526451742 0.598247691 5
0.59824769 0.598247691 0.378496492 0.3784964924 0.598247691 0.5200141682 6
0.52001417 0.5200141682 0.308513233 0.3085132326 0.5200141682 0.4198818246 7
0.41988182 0.4198818246 0.231086248 0.2310862477 0.4198818246 0.3090989677 8
0.30909897 0.3090989677 0.157955781 0.157955781 0.3090989677 0.2044635872 9
0.20446359 0.2044635872 0.098060303 0.0980603029 0.2044635872 0.1187648843 10
0.11876488 0.1187648843 0.054076126 0.0540761262 0.1187648843 0.0558321386 11
0.05583214 0.0558321386 0.024356985 0.0243569853 0.0558321386 0.0133098663 12
 Cond.Etapa Zonas
CONTINUA RECTIFICACION
CONTINUA RECTIFICACION
CONTINUA RECTIFICACION
CONTINUA RECTIFICACION
CONTINUA AGOTAMIENTO
CONTINUA AGOTAMIENTO
CONTINUA AGOTAMIENTO
CONTINUA AGOTAMIENTO
CONTINUA AGOTAMIENTO
CONTINUA AGOTAMIENTO
CONTINUA AGOTAMIENTO
ULTIMA ETAPA AGOTAMIENTO