El sistema ternario: n-hexano(1)/Benceno(2)/Tolueno(3)

a)Dada T, {xi}, Hallar punto de burbuja

COMPONENTES A B C
n-hexano (1) 8.87776 1171.53 〖 𝑙𝑜𝑔 〗 _10 𝑃_𝑖^𝑠𝑎𝑡 (𝑚𝑚𝐻𝑔)=𝐴𝑖−𝐵𝑖/((𝑇(°𝐶)+𝐶𝑖) )
224.366
Benceno (2) 6.90565 1211.033 220.79
Tolueno (3) 6.95334 1343.943 219.377

Dado T, xi. Calcule P, {yi} P. burbuja T (°C)

x1 x2 x3 65.6
0.2 0.5 0.3

Psat1 Psat2 Psat3 mmHg

68790.3781612 475.373726 172.730862
𝑷=∑_𝟏▒ 〖𝒙𝒊∗𝑷 _𝒊^𝒔𝒂𝒕 〗
P(mmHg) Presión de burbuja
14047.5817535

y1 y2 y3 Composición de burbuja
0.97939103496 0.01692013 0.00368884 1.00000
b) Dado T, yi, Calcule P, {xi} Punto de rocío
T(°C)
65.5
y1 y2 y3
0.2 0.5 0.3

Presion de rocío (mmHg)

𝑃=1/(∑_𝑖▒𝑦𝑖/(𝑃_𝑖^𝑠𝑎𝑡 ))
358.228105145

Composición de Rocío
x1 x2 x3
0.00104150643 0.37678576 0.62217273 1.00000
El sistema ternario: n-hexano(1)/Benceno(2)/Tolueno(3)
a) Dado P, {xi}. Determinar Punto de burbuja
COMPONENTES A B C
n-hexano (1) 8.87776 1171.53 224.366 〖𝑙𝑜𝑔〗 _10 𝑃_𝑖^𝑠𝑎𝑡 (𝑚𝑚𝐻𝑔)=𝐴𝑖−𝐵𝑖/((𝑇(°𝐶)+𝐶𝑖) )
Benceno (2) 6.90565 1211.033 220.79
Tolueno (3) 6.95334 1343.943 219.377

x1=0.20, x2= 0.45, x3=0.35 P(mmHg)

Calculo de T, yi Punto burbuja 5320 𝛼_𝑖𝑗=10^[ 〖 (𝐴 〗 _𝑖−𝐴_𝑗)−(𝐵_𝑖/(𝑡+𝐶_𝑖 )−𝐵_𝑗/(𝑡+𝐶_𝑗 )

i xi tsat xi*tsat(°C)
n-hexano (1) 0.2 3.034 0.6068
Benceno (2) 0.45 160.069 72.0312𝑃_𝑗^𝑠𝑎𝑡=𝑃/(∑_𝑖^𝑁▒ 〖𝑥 _𝑖 𝛼_𝑖𝑗 〗 )𝑡_𝑗^𝑠𝑎𝑡=𝑡_𝑛=𝐵_𝑗/(𝐴
Tolueno (3) 0.35 197.036 68.9626
To= 141.6006 °C
n ij xi T(°C) αij xi*αij Psatj(KPa) Tsatj(°C)
13 0.2 141.601 279.442 55.888
0 23 0.45 2.156 0.970
33 0.35 1.000 0.350
57.208 92.993 50.226
13 0.2 50.226 439.416 87.883
1 23 0.45 2.942 1.324
33 0.35 1.000 0.350
89.557 59.403 40.095
13 0.2 40.095 472.141 94.428
2 23 0.45 3.089 1.390
33 0.35 1.000 0.350
96.168 55.320 38.555
13 0.2 38.555 477.585 95.517
3 23 0.45 3.113 1.401
33 0.35 1.000 0.350
97.268 54.694 38.311
13 0.2 38.311 478.460 95.692
4 23 0.45 3.117 1.403
33 0.35 1.000 0.350
97.445 54.595 38.272
13 0.2 38.272 478.600 95.720
5 23 0.45 3.117 1.403
33 0.35 1.000 0.350
97.473 54.579 38.265

∆T= 0.006
b) Dado P, {yi}. Determinar punto de rocío
i yi tsat yi*tsat
n-hexano (1) 0.2 3.034 0.6068
Benceno (2) 0.45 160.069 72.0312
Tolueno (3) 0.35 197.036 68.9626
To= 141.6006

n ij yi T(°C) αij yi/αij Psatj(°C) Tsatj(°C)

13 0.2 141.601 279.442 0.001
0 23 0.45 2.156 0.209
33 0.35 1.000 0.350
0.559 2976.359 166.852
13 0.2 166.852 256.745 0.001
1 23 0.45 2.032 0.221
33 0.35 1.000 0.350
0.572 3044.462 167.945
13 0.2 167.945 255.874 0.001
2 23 0.45 2.027 0.222
33 0.35 1.000 0.350
0.573 3047.290 167.991
13 0.2 167.991 255.838 0.001
3 23 0.45 2.027 0.222
33 0.35 1.000 0.350
0.573 3047.406 167.992
13 0.2 167.992 255.836 0.001
4 23 0.45 2.027 0.222
33 0.35 1.000 0.350
0.573 3047.411 167.992
13 0.2 167.992 255.836 0.001
5 23 0.45 2.027 0.222
33 0.35 1.000 0.350
0.573 3047.411 167.992
∆T= 0.000
c) CÁLCULO DE EVAPORACIÓN INSTANTANEA. Para P=760 mmHg y T=1/2(TB+TR), z1=0.2, z2=0.45,
T(°C) P(mmHg)
103.132014483 5320
〖𝑙𝑜𝑔〗 _10 𝑃_𝑖^𝑠𝑎𝑡 (𝑚𝑚𝐻𝑔)=𝐴𝑖−𝐵𝑖/

i zi Psat(mmHg) Ki xi yi 𝐹𝑦=∑_𝑖^𝑁▒𝐾𝑖𝑍𝑖/(1+𝑣(𝑘𝑖−1))
1 0.2 199777.91 37.5522 0.021 0.793
2 0.45 1468.91 0.2761 0.541 0.149
3 0.35 611.21 0.1149 0.440 0.051
1.002 0.993

v Fy
0.00 7.6749
0.05 2.8271
0.10 1.7914
0.15 1.3443
0.20 1.0979 v= 0.2318
0.25 0.9442
0.30 0.8411
0.35 0.7692
0.40 0.7179
0.45 0.6815
0.50 0.6565
0.55 0.6407
0.60 0.6329
0.65 0.6327
0.70 0.6401
0.75 0.6558
0.80 0.6813
0.85 0.7195
0.90 0.7758
0.95 0.8607
1.00 1.0000
(𝑇(°𝐶)+𝐶𝑖) )

𝑡+𝐶_𝑖 )−𝐵_𝑗/(𝑡+𝐶_𝑗 ) )]

𝑡_𝑗^𝑠𝑎𝑡=𝑡_𝑛=𝐵_𝑗/(𝐴_𝑗−𝑙𝑜𝑔𝑃)−𝐶_𝑗

xi Psati yi
0.2 26122.8691 0.9821
0.45 170.15558 0.0144
0.35 54.5792824 0.0036
1.000
 yi Psati xi
0.2 779638.568 0.0014
0.45 6176.0744 0.3876
0.35 3047.41129 0.6110
1.000

_𝑖^𝑠𝑎𝑡 (𝑚𝑚𝐻𝑔)=𝐴𝑖−𝐵𝑖/((𝑇(°𝐶)+𝐶𝑖) )

▒𝐾𝑖𝑍𝑖/(1+𝑣(𝑘𝑖−1))