UNIVERSIDAD DE LAS FUERZAS ARMADAS ESPE

DEPARTAMENTO DE CIENCIAS EXACTAS

ACTIVIDADES DE TRABAJO AUTÓNOMO

Nombre : Shayson Daniel Taco Loachamin

Nivel : Tercer semestre
Fecha : 08/07/2021

1. TEMA:
Actividad de aprendizaje 4 IIP

2. OBJETIVO:
Diseñar todos los isómeros de fórmula C8H14 (octinos y octadienos), para lo cual
deberá hacer las siguientes consideraciones.

3. PROCEDIMIENTO:
1. Diseñar todos los isómeros alquinos y dienos de esqueleto, posición y
geométricos posibles en ChemSketch según corresponda.
2. Nombrar con nomenclatura IUPAC y en base al acetileno y etileno cada uno de
ellos según corresponda.
3. Copiar en word en el formato de deberes e imprimir su trabajo.
4. En el impreso identificar carbonos alílicos y vinílicos.
5. Identificar carbonos asimétricos o quirales en cada alquino y dieno isómero
óptico, pintándolos con un color diferente al item anterior.
6. Poner un identificador para el color y su significado.
4. DESARROLLO:
1. CH
H3C

2. oct-1-yne
CH3 CH3
H3C H3C

3. oct-2-yne 4. oct-3-yne
CH3 CH3
H3C H3C

5. oct-4-yne 6. octa-2,3-diene
CH3 CH3
H3C H2C

7. octa-3,4-diene 8. octa-1,2-diene
CH3 H3C CH2 H
CH2 C
H CH2 CH2
H C C H C
C H
C C H
C
H3C H H CH3

9. (2E,4E)-octa-2,4-diene
10. (2Z,4Z)-octa-2,4-diene
H H CH3
C C H H CH2 CH2
H3C C C C C
H CH2 H C H
H2C
C CH3
CH3
H
11. (2E,4Z)-octa-2,4-diene 12. (2Z,4E)-octa-2,4-diene
CH H H
H2C C
C H
C CH2 CH3 HC C
H CH2 CH2
CH2 H2C
CH2

H2C
CH3
13. (3E)-octa-1,3-diene
14. (3Z)-octa-1,3-diene
 H2C CH H H
CH2 C C CH2
C CH2 H C CH2 CH3
H CH2 CH3 CH2
HC
15. (4E)-octa-1,4-diene CH2

16. (4Z)-octa-1,4-diene
H H
H3C C H C
C CH2 H C CH2 CH3

H C C CH3 C CH2
H C
H CH2 CH3
H
17. (2E,5E)-octa-2,5-diene
18. (2Z,5Z)-octa-2,5-diene
H H

H C H3C C H3C
C CH2 C CH2 CH2
CH3 C H H C C
H C
H H
H2C
CH3 20. (2E,5Z)-octa-2,5-diene
19. (2Z,5E)-octa-2,5-diene
H3C CH2 H H H
C C H H3C CH2 C C
H C C C C CH2 CH3
H CH2 CH3 H H

21. (3E,5E)-octa-3,5-diene 22. (3Z,5Z)-octa-3,5-diene

CH2 H CH3 H3C
H3C C H2C CH3
C
C C H3C
H C H
C CH
H2C CH2
H
24. 4,4-dimethyl-3-methylidenepent-1-ene
23. (3Z,5E)-octa-3,5-diene
H3C H 3C CH3
CH3
C CH C C
H3C
CH C H 3C CH
CH3
H3C CH
26. 3,3,4-trimethylpent-1-yne
25. 3,4,4-trimethylpent-1-yne
 H2C CH3 CH3 CH3

C C CH C CH
H2C C CH3
H3C CH3 CH2
CH2
27. 2,3,3-trimethylpenta-1,4-diene 28. 2,4-dimethyl-3-methylidenepent-1-ene
CH CH2
C HC

H3C CH CH3 H3C C CH3

CH CH2 C CH2

CH3 CH3

29. 3-ethyl-4-methylpent-1-yne 30. 3-ethyl-4-methylpenta-1,3-diene

CH2 CH2
C HC

H3C C CH3 H3C CH CH3

CH CH2 C CH2

CH3 CH2

31. 3-ethyl-4-methylpenta-1,2-diene 32. 3-ethyl-2-methylpenta-1,4-diene

CH2 CH3
HC H2C

H3C CH CH2 H3C C CH3

CH CH C CH

CH3 CH2

33. 3-(propan-2-yl)penta-1,4-diene 34. (3E)-3-ethyl-2-methylpenta-1,3-diene

CH3 CH2
H2C HC
CH3 CH3
C C
H2C H2C
C CH CH CH2
CH3 CH3
35. 3-ethyl-3-methylpent-1-yne 36. 3-ethyl-3-methylpenta-1,4-diene
CH3 CH3
H3C H3C
C C CH3 C C CH3
C CH2 CH2 C
H3C H3C

37. 2,2-dimethylhex-3-yne 38. 5,5-dimethylhex-2-yne

 CH3 CH3
H3C H3C
C C CH3 C CH CH2
CH CH CH CH
H3C H3C

39. 5,5-dimethylhexa-2,3-diene 40. (3E)-5,5-dimethylhexa-1,3-diene

CH3 CH3
H3C H3C
C CH2 CH C CH CH2
CH2 C CH2 C
H3C H3C

41. 5,5-dimethylhex-1-yne 42. 5,5-dimethylhexa-1,2-diene

CH3 CH3
C CH2
CH C
H3C CH CH H2C C CH3

CH3 CH2

43. 3,4-dimethylpent-1-yne 44. 2-methyl-3-methylidenepent-1-ene

CH3 CH3
CH CH
CH C
H3C C CH2 H2C CH CH2

CH2 CH3

45. 4-methyl-3-methylidenepent-1-ene 46. 2,3-dimethylpenta-1,4-diene

CH3 CH3
H2C C H H2C C CH3
C C C C
H3C CH3 H3C H

47. (3E)-2,3-dimethylpenta-1,3-diene 48. (3Z)-2,3-dimethylpenta-1,3-diene

CH3 CH3 CH3 CH2
CH CH CH C C CH3
H3C CH2 C H2C CH2 CH2
49. 3,5-dimethylhex-1-yne
50. 2-methyl-4-methylidenehex-1-ene
CH3 CH3 CH3

C CH CH2 C CH2 CH3

H2C CH2 CH
H2C CH2 C
51. 2,4-dimethylhexa-1,5-diene
CH2

52. 2,5-dimethylhexa-1,5-diene
 CH3 CH3
H2C C CH3 H2C C CH2 CH3
C C C C
H CH2 CH3 H CH3

53. (3E)-2,4-dimethylhexa-1,3-diene 54. (3Z)-2,4-dimethylhexa-1,3-diene

H3C CH3 H3C H
H3C C C H3C C C
C CH2 H C CH2 CH3
H2C H2C

55. (4E)-2,4-dimethylhexa-1,4-diene 56. (4Z)-2,4-dimethylhexa-1,4-diene

CH3 CH3

CH C CH3 C CH CH3
H3C C CH H2C CH2 C

CH3 CH3

57. 2,5-dimethylhex-3-yne 58. 2,5-dimethylhexa-1,4-diene

H3C H

H CH CH3 H3C C H
C C
C C

H3C C H CH2 CH
H3C CH3
CH2
60. (3Z)-2,5-dimethylhexa-1,3-diene
59. (3E)-2,5-dimethylhexa-1,3-diene
CH3 CH3

C C CH2 CH2 C C

HC CH3 CH2 CH3 H3C CH3 C CH3

61. 3,3-dimethylhex-1-yne 62. 4,4-dimethylhex-2-yne

H3C CH3
CH2
C C CH2 C CH
H2C CH
CH3 H3C C CH2
CH3
CH3
63. 4,4-dimethylhex-1-yne 64. 4,4-dimethylhexa-1,2-diene
 CH3 HC
C
CH C CH2

H2C CH3 CH CH2 CH CH2

65. 3,3-dimethylhexa-1,5-diene H3C CH CH3

CH3

66. 3,4-dimethylhex-1-yne
H CH3 H H

C C C C
H3C H3C
C H C CH3
CH3 CH3
HC HC

CH2 CH2

67. (4E)-3,3-dimethylhexa-1,4-diene 68. (4Z)-3,3-dimethylhexa-1,4-diene

H2C H2C
C CH

C CH2 C CH2
H3C CH CH3 H2C CH CH3

CH3 CH3

69. 3,4-dimethylhexa-1,2-diene 70. 4-methyl-3-methylidenehex-1-ene

H2C H2C
CH CH

CH CH2 CH CH
H3C C CH3 H3C CH CH2

CH2 CH3

71. 3-methyl-4-methylidenehex-1-ene 72. 3,4-dimethylhexa-1,5-diene

H3C H3C
CH2
C H

C CH2
H3C C CH3
H2C C CH3
C C
CH2
H3C H
73. 3,4-dimethylidenehexane
74. (2Z,4E)-3,4-dimethylhexa-2,4-diene
 CH3 CH3

H2C C CH2 C CH3

CH C CH3 HC C

CH3 CH2 H2C

CH3
75. (3E)-3,4-dimethylhexa-1,3-diene
76. (3Z)-3,4-dimethylhexa-1,3-diene
H2C H2C

CH CH

H3C HC H H3C HC CH3

C C C C

H3C CH3 H3C H

77. (4E)-3,4-dimethylhexa-1,4-diene 78. (4Z)-3,4-dimethylhexa-1,4-diene

CH3 CH3

H2C H2C

H C CH2 H3C C CH2

C C C C

H3C CH3 H CH3

79. (2E)-3-methyl-4-methylidenehex-2-ene 80. (2Z)-3-methyl-4-methylidenehex-2-ene

H3C H CH3

C H C C CH3

H3C C H H3C C C

C C H3C H

H3C CH3 82. (2Z,4Z)-3,4-dimethylhexa-2,4-diene

81. (2E,4E)-3,4-dimethylhexa-2,4-diene
H3C CH2 H3C CH2

CH CH2 CH C

HC C CH2 CH3 H3C CH2 C CH3

83. 3-ethylhex-1-yne 84. 4-ethylhex-2-yne

 H3C CH2 H3C CH2

CH CH2 C CH2

H3C CH2 C CH H2C C CH2 CH3

85. 4-ethylhex-1-yne 86. 3-ethylhexa-1,2-diene

H2C CH H3C CH2

CH CH2 C CH

H2C CH CH2 CH3 H3C CH2 CH CH2

88. 4-ethylhexa-1,3-diene
87. 3-ethenylhex-1-ene
H3C CH2 H3C CH2

C C CH CH2

H3C CH2 CH CH3 H2C CH CH CH2

89. 4-ethylhexa-2,3-diene 90. 3-ethylhexa-1,5-diene

CH3 H

H C H3C C

C CH2 C CH2

H2C CH CH2 CH3 H2C CH CH2 CH3

91. (3E)-3-ethylidenehex-1-ene 92. (3Z)-3-ethylidenehex-1-ene

H3C H3C

H2C CH2 H2C CH2

CH HC H CH HC CH3

C C C C

H CH3 H H

93. (4E)-3-ethylhexa-1,4-diene 94. (4Z)-3-ethylhexa-1,4-diene

H2C CH H3C CH2

C CH C CH

H3C CH2 CH2 CH3 H2C CH CH2 CH3

95. (3E)-3-ethylhexa-1,3-diene 96. (3Z)-3-ethylhexa-1,3-diene

 H3C H3C
CH2 CH2

H3C C CH H C CH
C CH2 CH2 C CH2 CH2

H CH3

97. (4E)-4-ethylhexa-1,4-diene 98. (4Z)-4-ethylhexa-1,4-diene

H3C H3C

H3C CH2 H3C CH2

C C H C C CH3

H C C H C C

H CH3 H H

99. (2E,4E)-3-ethylhexa-2,4-diene 100. (2E,4Z)-3-ethylhexa-2,4-diene

H3C H3C

H CH2 H3C CH2 C H

C C H C C

H3C C C H C H

H CH3 CH3

101. (2Z,4E)-3-ethylhexa-2,4-diene 102. (2Z,4Z)-3-ethylhexa-2,4-diene

CH3 CH3

H3C CH2 CH2 H3C C CH2

CH CH2 CH C

HC C H3C CH2
103. 3-methylhept-1-yne 104. 5-methylhept-3-yne
CH3 CH

H3C C C H3C CH2 C

CH CH2 CH CH2

H3C CH2 H3C CH2

105. 5-methylhept-2-yne 106. 5-methylhept-1-yne

 CH3 CH3

H3C CH2 CH2 H2C CH2 CH2

C CH2 C CH2

H2C C H2C CH

107. 3-methylhepta-1,2-diene 108. 3-methylidenehept-1-ene

CH2 CH2

H3C CH2 CH H2C CH2 CH

CH CH2 C CH2

H2C CH H3C CH2

109. 3-methylhepta-1,6-diene 110. 5-methylidenehept-1-ene

CH3 CH3

H3C CH CH2 H3C C CH

C C CH CH

H3C CH2 H3C CH2

111. 3-methylhepta-3,4-diene 112. 5-methylhepta-2,3-diene

CH2 HC

H3C CH C C CH2

CH CH2 CH CH2

H3C CH2 H3C CH2 CH3

113. 5-methylhepta-1,2-diene 114. 4-methylhept-1-yne

CH3 CH3

H3C CH2 CH2 H2C CH CH2 CH2

C C C C

H2C CH H H3C H

115. (3E)-3-methylhepta-1,3-diene 116. (3Z)-3-methylhepta-1,3-diene

 H2C CH3 H2C CH3 H3C

CH HC H CH HC CH2

C C C C

H CH2 CH3 H H

117. (4E)-3-methylhepta-1,4-diene 118. (4Z)-3-methylhepta-1,4-diene

H CH3 H H

H2C C C H2C C C

C CH2 H C CH2 CH3

H3C CH2 H3C CH2

119. (2E)-5-methylidenehept-2-ene 120. (2Z)-5-methylidenehept-2-ene

H CH3 H H

H3C C C H3C C C

CH CH2 H CH CH2 CH3

H2C CH H2C CH

121. (5E)-3-methylhepta-1,5-diene 122. (5Z)-3-methylhepta-1,5-diene

H3C CH3 H CH3

C C C C

H CH2 CH2 H3C CH2 CH2

CH CH2 CH CH2

123. (5E)-5-methylhepta-1,5-diene 124. (5Z)-5-methylhepta-1,5-diene

H CH3 H3C CH2 H3C

H2C C CH2 CH2 C CH2

C C C C

H3C CH2 H H H
(3E)-5-methylidenehept-3-ene 126. (3Z)-5-methylidenehept-3-ene
125.
 CH2 H3C H

H3C CH2 CH C C

C C H3C CH2 CH2

H3C CH2 H HC

127. (4E)-5-methylhepta-1,4-diene
CH2

128. (4Z)-5-methylhepta-1,4-diene
H CH2 H H

H3C C CH C C

CH C H3C HC CH CH2

H3C CH2 H CH2

H3C
129. (3E)-5-methylhepta-1,3-diene
130. (3Z)-5-methylhepta-1,3-diene
H3C H3C

C H C H

H3C C H H3C C CH2 CH3

C C C C

H CH2 CH3 H H

131. (2E,4E)-3-methylhepta-2,4-diene 132. (2E,4Z)-3-methylhepta-2,4-diene

H CH3 CH3
H
C C H C H

H3C C C C C

H3C C H
H CH2 CH3

133. (2Z,4E)-3-methylhepta-2,4-diene
H3C CH2

134. (2Z,4Z)-3-methylhepta-2,4-diene
 H3C H H CH3
C H
C C H

C C CH3
H3C CH2 C
H3C CH2 C
C CH3
H
H
135. (2E,5E)-3-methylhepta-2,5-diene
136. (2Z,5E)-3-methylhepta-2,5-diene
H CH3 H CH3

C C H H3C CH2 C C

H3C CH2 C C C H

C H H3C H

H3C
138. (2E,4Z)-5-methylhepta-2,4-diene

137. (2Z,5Z)-3-methylhepta-2,5-diene
H H H H

H3C C C H3C CH2 C C

C C CH3 C C CH3

H3C CH2 H H3C H

139. (2Z,4E)-5-methylhepta-2,4-diene 140. (2Z,4Z)-5-methylhepta-2,4-diene

H H3C

H C CH3 C C

C C CH CH2

CH2 C H H3C CH2 CH3

142. 4-methylhept-2-yne
H3C CH3

141. (2E,4E)-5-methylhepta-2,4-diene
 H2C H2C

C CH CH CH2

CH CH2 CH CH2

H3C CH2 CH3 H3C CH CH2

143. 4-methylhepta-1,2-diene 144. 4-methylhepta-1,6-diene

H3C H3C

CH C CH2 CH2

C CH2 C C

H3C CH2 CH3 H3C CH CH3

145. 4-methylhepta-2,3-diene 146. 4-methylhepta-2,3-diene

H2C H2C H3C

CH CH2 CH CH2 CH2

H
C C C C

H3C CH2 CH3 H3C H

147. (4E)-4-methylhepta-1,4-diene 148. (4Z)-4-methylhepta-1,4-diene

CH3 H2C
CH
H CH2 CH2

C CH2 CH3
C C
H C CH2
H2C CH CH3
CH3
149. (3E)-4-methylhepta-1,3-diene
150. (3Z)-4-methylhepta-1,3-diene
H3C H H H

C C C C

H C CH2 H3C C CH2

H2C CH2 CH3 H2C CH2 CH3

151. (2E)-4-methylidenehept-2-ene 152. (2Z)-4-methylidenehept-2-ene

 H2C CH CH3 H2C CH CH3

CH2 HC H CH2 HC CH3

C C C C

H CH3 H H
(5E)-4-methylhepta-1,5-diene 154. (5Z)-4-methylhepta-1,5-diene
153.
H3C H H H

C C H C C H

H C C H3C C C

H3C CH2 CH3 H3C CH2 CH3

155. (2E,4E)-4-methylhepta-2,4-diene 156. (2Z,4E)-4-methylhepta-2,4-diene

CH3 CH2 H
H3C C
H C

H C
H3C CH2 C H
C CH3
C C
C
H CH3 H CH3

(2E,4Z)-4-methylhepta-2,4-diene 158. (2Z,4Z)-4-methylhepta-2,4-diene

157.
H3C H H H

C C H H C C

H CH C C HC CH3

H3C C CH3 H C CH3

H CH3
159. (2E,5E)-4-methylhepta-2,5-diene (2Z,5Z)-4-methylhepta-2,5-diene
160.
 H H H3C

C C H CH C

H3C CH C H3C C CH2

H3C C CH3 CH2 CH3

162. 2-methylhept-3-yne
H
161. (2Z,5E)-4-methylhepta-2,5-diene
H3C H3C

CH C CH CH2

H3C C CH2 H3C C C

CH2 CH3 CH2 CH3

163. 2-methylhept-3-yne 164. 6-methylhept-3-yne

H3C H3C

CH CH2 CH CH2

H3C CH2 C H3C CH2 CH2

C CH3 C CH

165. 6-methylhept-2-yne 166. 6-methylhept-1-yne

H2C H3C

C CH2 C C

H3C CH2 CH2 H3C CH CH2

CH CH2 CH2 CH3

167. 2-methylhepta-1,6-diene 168. 2-methylhepta-2,3-diene

H3C H3C

C CH CH CH

H3C CH2 CH2 H3C C CH

CH CH2 CH2 CH3

169. 6-methylhepta-1,5-diene 170. 2-methylhepta-3,4-diene

 H3C H3C CH2 CH
CH CH2 C
CH CH2 CH
CH3
H3C CH C

CH CH3 172. 6-methylhepta-1,2-diene

171. 6-methylhepta-2,3-diene
H2C H2C

C CH2 H C CH2 CH2 CH3

H3C C C H3C C C

H CH2 CH3 H H
(4E)-2-methylhepta-1,4-diene 174. (4Z)-2-methylhepta-1,4-diene
173.
H CH3 H H

C C C C
CH3
CH CH2 H CH CH2

H3C C H3C C

CH3 CH3
175. (5E)-2-methylhepta-2,5-diene (5Z)-2-methylhepta-2,5-diene
176.
H CH3 H H

C C C C

CH2 CH2 H CH2 CH2 CH3

H2C C H2C C

CH3 CH3

177. (5E)-2-methylhepta-1,5-diene 178. (5Z)-2-methylhepta-1,5-diene

H3C H3C

CH CH2 H CH CH2 CH CH2

H3C C C H3C C C

H CH CH2 H H
(3E)-6-methylhepta-1,3-diene 180. (3Z)-6-methylhepta-1,3-diene
179.
 CH2 H H

H CH2 CH C C

C C H3C HC CH2 CH

H3C HC H CH3 CH2

182. (4Z)-6-methylhepta-1,4-diene
CH3

181. (4E)-6-methylhepta-1,4-diene
H3C H3C

C CH C CH CH2 CH3
H
H3C C C H3C C C

H CH2 CH3 H H

183. (4E)-2-methylhepta-2,4-diene 184. (4Z)-2-methylhepta-2,4-diene

CH3 H H

H CH2 CH2 C C
CH3
C C H2C C
CH2 CH2
H2C C H CH3

186. (3Z)-2-methylhepta-1,3-diene
CH3

185. (3E)-2-methylhepta-1,3-diene
H3C H H
H

CH C H H C C
CH3
H3C C C C C

H C CH3 H3C HC H

H CH3
187. (2E,4E)-6-methylhepta-2,4-diene
188. (2Z,4E)-6-methylhepta-2,4-diene
 H H H H

C C CH3 C C H

H3C HC C C H3C HC C C

CH3 H H CH3 H CH3

189. (2Z,4Z)-6-methylhepta-2,4-diene

190. (2E,4Z)-6-methylhepta-2,4-diene