Muestr A a b c d e f g h i B

a
V C H OH /mL
3
0.16 0.34 0.53 0.76 1.0 1.29 1.70 2.0 2.5

V CHC l /mL
3
2.81 2.77 2.47 2.24 2.0 1.71 1.45 1.0 0.54
η 1.445 1.439 1.4317 1.425 1.415 1.405 1.396 1.382 1.366 1.346 1.3265
4 1 3 0 0 1 5 9 7
Tabla 1. Registro de datos de refracción de metanol y cloroformo

Tabla 2. Cálculo de número de moles de metanol

C H 3 OH mL totales mL de Masa MM Número
de la metanol
ρ ( molg ) de
disolución moles
3 0.16 0.7866 0.125 32.04 3.901
¿ 1 0−3
3 0.34 0.7866 0.267 32.04 8.333∗1 0−3
3 0.53 0.7866 0.416 32.04 0.013
3 0.76 0.7866 0.597 32.04 0.018
3 1.0 0.7866 0.7866 32.04 0.025
3 1.29 0.7866 1.015 32.04 0.031
3 1.70 0.7866 1.338 32.04 0.042
3 2.0 0.7866 1.573 32.02 0.049
3 2.5 0.7866 1.967 32.04 0.061

Tabla 3. Cálculo de número de moles de cloroformo

CHC l 3 mL totales mL de g Masa MM Número
de la cloroformo
ρ
mol ( ) de
disolución moles
3 2.81 1.49 4.187 119.38 0.035
3 2.77 1.49 4.127 119.38 0.034
3 2.47 1.49 3.680 119.38 0.031
3 2.24 1.49 3.338 119.38 0.028
3 2.0 1.49 2.98 119.38 0.025
3 1.71 1.49 2.548 119.38 0.021
3 1.45 1.49 2.161 119.38 0.018
3 1.0 1.49 1.49 119.38 0.012
3 0.54 1.49 0.804 119.38 6.735∗10−3
Tabla 4. Cálculo de fracción mol de metanol
Número de moles Número de moles de χC H 3 OH
metanol cloroformo
3.901¿ 1 0−3 0.035 0.100
8.333∗1 0−3 0.034 0.197
0.013 0.031 0.295
0.018 0.028 0.419
0.025 0.025 0.543
0.031 0.021 0.596
0.042 0.018 0.7
0.049 0.012 0.803
0.061 6.735∗10−3 0.901

Tabla 5. Cálculo de la fracción mol del cloroformo

χC H 3 OH χCHC l 3
0.100 0.9
0.197 0.803
0.295 0.705
0.419 0.581
0.543 0.457
0.596 0.404
0.7 0.3
0.803 0.197
0.901 0.099

Gráfica 1. Índice de refracción v.s Fracción mol de metanol

 1.46
1.44
1.44 1.43
1.43
1.42
1.42
1.41
Índice de refracción

1.4
1.4
1.38
1.38 1.37
1.36 1.35
1.34

1.32

1.3
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Fracción mol de metanol

Ecuación de regresión lineal del metanol

y=a+bx
y=1.4565−0.1120 x
r =−0.9821

Gráfica 2. Índice de refracción v.s Fracción mol de cloroformo

Gráfica 2. η v.s χ de cloroformo

1.46
1.44
1.44 1.43
1.43
1.42
1.42 1.41
Índice de refracción

1.4
1.4
1.38
1.38 1.37
1.36 1.35
1.34
1.32
1.3
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Fracción mol de cloroformo
Ecuación de regresión lineal del cloroformo
y=a+bx
y=1.3463+ 0.1106 x
r =0.9808

ANEXO DE CÁLCULOS

Calcular la refracción molar

n 2❑ −1
∗M
n2❑ + 2
RM=
ρ

Para a

(1.4391)2−1 g
2
∗119.38
( 1.4391) +2 mol mL
R M (CHC l ) = =21.07
3
g mol
1.49
mL

(1.4391)2−1 g
2
∗32.04
(1.4391) + 2 mol mL
R M (C H OH )= =10.71
3
g mol
0.7866
mL

Para b

(1.4317)2−1 g
2
∗119.38
( 1.4317) +2 mol mL
R M (CHC l ) = =20.76
3
g mol
1.49
mL

(1.4317)2−1 g
2
∗32.04
(1.4317) +2 mol mL
R M (C H OH )= =10.56
3
g mol
0.7866
mL
Para c

(1.4253)2−1 g
2
∗119.38
( 1.4253) +2 mol mL
R M (CHC l ) = =20.50
3
g mol
1.49
mL

(1.4253)2−1 g
2
∗32.04
(1.4253) +2 mol mL
R M (C H OH )= =10.42
3
g mol
0.7866
mL

Para d

(1.4150)2−1 g
2
∗119.38
( 1.4150) +2 mol mL
R M (CHC l ) = =20.06
3
g mol
1.49
mL

(1.4150)2−1 g
2
∗32.04
(1.4150) +2 mol mL
R M (C H OH )= =10.20
3
g mol
0.7866
mL

Para f

( 1.3961 )2−1 g
2
∗119.38
( 1.3961 ) +2 mol mL
R M (CHC l )= =19.25
3
g mol
1.49
mL

(1.3961)2−1 g
2
∗32.04
(1.3961) + 2 mol mL
R M (C H OH )= =9.79
3
g mol
0.7866
mL
Para g

( 1.3825 )2−1 g
2
∗119.38
( 1.3825 ) +2 mol mL
R M (CHC l )= =18.68
3
g mol
1.49
mL

(1.3825)2−1 g
2
∗32.04
(1.3825) +2 mol mL
R M (C H OH )= =9.49
3
g mol
0.7866
mL

Para h

( 1.3669 )2−1 g
2
∗119.38
( 1.3669 ) +2 mol mL
R M (CHC l )= =17.99
3
g mol
1.49
mL

(1.3669)2−1 g
2
∗32.04
(1.3669) +2 mol mL
R M (C H OH )= =9.14
3
g mol
0.7866
mL

Para i

( 1.3467 )2−1 g
2
∗119.38
( 1.3467 ) +2 mol mL
R M (CHC l )= =17.09
3
g mol
1.49
mL
 (1.3467)2−1 g
2
∗32.04
(1.3467) +2 mol mL
R M (C H OH )= =8.69
3
g mol
0.7866
mL

Calcular refracción específica

n2−1
∗1
n2 +2
R=
ρ

Para a

(1.4391)2 −1
∗1
(1.4391)2+2 mL
R(CHC l )= =0.177
3
g mol
1.49
mL

(1.4391)2−1
∗1
(1.4391)2 +2 mL
R(C H OH )= =0.334
3
g mol
0.7866
mL

Para b

(1.4317)2−1
∗1
(1.4317)2 +2 mL
R(CHC l )= =0.174
3
g mol
1.49
mL
 (1.4317)2−1
∗1
(1.4317)2+ 2 mL
R(C H OH )= =0.330
3
g mol
0.7866
mL

Para c

(1.4253)2−1
∗1
(1.4253)2+ 2 mL
R(CHC l )= =0.172
3
g mol
1.49
mL

(1.4253)2 −1
∗1
(1.4253)2+2 mL
R(C H OH )= =0.325
3
g mol
0.7866
mL

Para d

(1.4150)2−1
∗1
(1.4150)2+ 2 mL
R(CHC l )= =0.168
3
g mol
1.49
mL

(1.4150)2 −1
∗1
(1.4150)2+2 mL
R(C H OH )= =0.318
3
g mol
0.7866
mL

Para f

( 1.3961 )2−1
2
∗1
( 1.3961 ) + 2 mL
R( CHC l )= =0.161
3
g mol
1.49
mL
 (1.3961)2−1
∗1
(1.3961)2 +2 mL
R(C H OH )= =0.305
3
g mol
0.7866
mL

Para g

( 1.3825 )2−1
2
∗1
( 1.3825 ) + 2 mL
R( CHC l )= =0.156
3
g mol
1.49
mL

(1.3825)2 −1
∗1
(1.3825)2+2 mL
R(C H OH )= =0.296
3
g mol
0.7866
mL

Para h

( 1.3669 )2−1
2
∗1
( 1.3669 ) + 2 mL
R( CHC l )= =0.151
3
g mol
1.49
mL

(1.3669)2 −1
∗1
(1.3669)2+2 mL
R(C H OH )= =0.285
3
g mol
0.7866
mL

Para i
 ( 1.3467 )2−1
2
∗1
( 1.3467 ) +2 mL
R( CHC l )= =0.143
3
g mol
1.49
mL

(1.3467)2−1
∗1
(1.3467)2+ 2 mL
R(C H OH )= =0.271
3
g mol
0.7866
mL

Cálculos de masa de metanol

m=ρ∗v
g
m=0.7866 ∗0.16 mL=0.125 g
mL
g
m=0.7866 ∗0.34 mL=0.267 g
mL
g
m=0.7866 ∗0.53 mL=0.416 g
mL
g
m=0.7866 ∗0.76 mL=0.597 g
mL
g
m=0.7866 ∗1mL=0.7866 g
mL
g
m=0.7866 ∗1.29mL=1.015 g
mL
g
m=0.7866 ∗1.70 mL=1.338 g
mL
g
m=0.7866 ∗2mL=1.573 g
mL
g
m=0.7866 ∗2.5 mL=1.967
mL

Números de moles de metanol

 m
n=
MM
0.125 g
n= =3.901∗10−3 mol
g
32.04
mol
0.267 g
n= =8.333∗1 0−3 mol
g
32.04
mol
0.416 g
n= =0.013 mol
g
32.04
mol
0.597 g
n= =0.018 mol
g
32.04
mol
0.7866 g
n= =0.025 mol
g
32.04
mol
1.015 g
n= =0.031 mol
g
32.04
mol
1.338 g
n= =0.042 mol
g
32.04
mol
1.573 g
n= =0.049 mol
g
32.04
mol
1.967 g
n= =0.061 mol
g
32.04
mol

Cálculos de masa de cloroformo

g
m=1.49 ∗2.81 mL=4.187 g
mL
g
m=1.49 ∗2.77 mL=4.127 g
mL
 g
m=1.49 ∗2.47 mL=3.680 g
mL
g
m=1.49 ∗2.24 mL=3.338 g
mL
g
m=1.49 ∗2 mL=2.98 g
mL
g
m=1.49 ∗1.71 mL=2.548 g
mL
g
m=1.49 ∗1.45 mL=2.161 g
mL
g
m=1.49 ∗1 mL=1.49 g
mL
g
m=1.49 ∗0.54 mL=0.804 g
mL

Números de moles de cloroformo

m
n=
MM
4.187 g
n= =0.035 mol
g
119.38
mol
4.127 g
n= =0.034 mol
g
119.38
mol
3.680 g
n= =0.031 mol
g
119.38
mol
3.338 g
n= =0.028 mol
g
119.38
mol
 2.98 g
n= =0.025 mol
g
119.38
mol
2.548 g
n= =0.021 mol
g
119.38
mol
2.161 g
n= =0.018 mol
g
119.38
mol
1.49 g
n= =0.012 mol
g
119.38
mol
0.804 g
n= =6.73 5∗10−3 mol
g
119.38
mol
Fracción molar de metanol
χ nMeOH
C H 3OH =
nTotales

3.901∗1 0−3 mol

χ C H OH = =0.100
3
3.901∗10−3 mol +0.035 mol

8.333∗1 0−3 mol

χ C H OH = =0.197
3
8.333∗1 0−3 mol+0.034 mol
0.013 mol
χ C H OH = =0.295
3
0.013 mol+ 0.031 mol
0.018 mol
χ C H OH = =0.419
3
0.018 mol+ 0.025 mol
0.025 mol
χ C H OH = =0.543
3
0.025 mol+ 0.021 mol
0.031 mol
χ C H OH = =0.596
3
0.031 mol+ 0.021mol
0.042 mol
χ C H OH = =0.7
3
0.042 mol+ 0.018 mol
0.049 mol
χ C H OH = =0.803
3
0.049 mol+ 0.012 mol
 0.061 mol
χ C H OH = =0.901
0.061 mol+ 6.735∗10−3 mol
3

Fracción molar de cloroformo

χ CHC l =1− χ C H
3 3 OH

χ CHC l =1−0.100=0.9
3

χ CHC l =1−0.197=0.803
3

χ CHC l =1−0.295=0.705
3

χ CHC l =1−0.419=0.581
3

χ CHC l =1−0.543=0.457
3

χ CHC l =1−0.596=0.404
3

χ CHC l =1−0.7=0.3
3

χ CHC l =1−0.803=0.197
3

χ CHC l =1−0.901=0.099
3