Datos iniciales

[Yodo] (N) 0,167 ± 0,001 Volumen de HCl 3

[Tiosulfato] (N) 0,339 ± 0,002 Volumen de yodo 30
Masa molar I2 (g/mol) 253.80894 Volumen Filtrado (F) 10

Indice de yodo (nosotros

volumen de HCl
Normalidad yodo 0.1674 volumen de yodo
Normalidad tiosulfato 0.339 Volumen Filtrado (F)
Masa I2

Pesos carbón (g) Vtiosulfato 1 (mL) Vtiosulfato 2 (mL) Promedio volumen (mL)A (mg I2 inicial)
0.4012 3.9 3.9 3.9 1274.62849668
0.4701 3.2 3.4 3.3 1274.62849668
0.553 2.6 2.4 2.5 1274.62849668

C
1900
1700 f(x) = 6788.43946085063 x + 1354.44576266901
R² = 0.986557808318572
1500
1300 Chart Title
X/M

Indice de yodo 1422.284 1100

0.5
0.45900
f(x) = 0.0093 x − 0.003
0.4
700 R² = 0.999089081853917
0.35
0.3500
0.25 0.04 0.045 0.05 0.055 Column
0.06B 0.0
Axis Title Linear (Column B)
0.2 C
Tartrazina 0.15
[ppm] A 0.1
0 0 0.05
10 0.094 0
0 10 20 30 40 50 60
20 0.175
Axis Title
30 0.274
40 0.366
50 0.468
 3
30
10
253.80894

B X/M C log (x/M) Log C

553.6753193 1796.99196755459 0.066105 3.25454614 -1.17976569
454.29769788 1745.0133988411 0.055935 3.24179877 -1.25231636
369.11687953 1637.45319556709 0.042375 3.2141689 -1.37289029

3.3

3.25
f(x) = 0.211109767520284 x + 3.50459354079101
R² = 0.995506558001621
3.2
Axis Title

3.15

3.1
4.44576266901
3.05

3
-1.4 -1.35 -1.3 -1.25 -1.2 -1.15
Axis Title

55 Column
0.06B 0.065 0.07
Linear (Column B)
 Estandarización de las soluciones de yodo y tiosulfato

Peso Yodato de potasio

valor error Vol tiosulfato error [] tiosulfato promedio
0.0702 0.00014142 5.8 0.0200 0.33933316 0.3392848223
0.0726 0.00014142 6 0.0200 0.33923648 6.836034E-05
 Para yodo Vol yodo
Error Vol tio sulfato error Concentración de yodo error
14.8 15 0.015 0.167380512351179
14.8 15 0.015 0.167380512351179
 Vtiosulfato 1 (mL) Vtiosulfato 2 (mL) Promedio
Pesos carbón (g)
volumen (mL)
0.4012 3.9 3.9 3.9
0.4701 3.2 3.4 3.3
0.553 2.6 2.4 2.5

Calculos 1 Calculos 2 Calculos 3

mg I2i 1271.5827894 mg I2i 1271.5827894 mg I2i
mg I2f 553.6753192971 mg I2f 468.4945009437 mg I2f
X/M 1789.40047383574 X/M 1708.33501054308 X/M
Cir 0.066105 Cir 0.055935 Cir
errores 0.000793261296232 error 0.00076229843034
errores caso 1
[yodo] 0.001 error mgIi 7.70807011670357
[tiosulfato] 0.002 error mgIf 5.31465189130226
pipeta 15 0.02 numerador 9.36268495944093
por 30 mL 0.028284271247462 X/M 23.3452249380395
Bureta 0.02 caso 2

Masas
por medida 0.028284271247462 error mgIi 7.70807011670357

0.4012
balanza 0.0001 error mgIf 4.98023162257528

0.4701
por medida 0.000141421356237 numerador 9.17698490455975

0.5530
pipeta 10 0.02 X/M 19.5281099605684
pipeta 3 0.02 Caso 3
Vprom 0.04 error mgIi 7.70807011670357
error mgIf 4.5940032399978
numerador 8.97324972867293
X/M 16.2320276755669
In d ice d e yo d o (m g I2 / g C A )

error pendien
Índice de yodo Vs [Residual] error pendie
1850 error extra
1800

1750 f(x) = 5455.40367493495 x + 1419.46773829741

R² = 0.954701136580111 Índice de yodo Vs
[Residual]
1700
Linear (Índice de yodo
1650 Vs [Residual]) Log X/M Vs Log [Residual]
1.4
Log X/M

1600

1550
0.04 0.06
1.35
f(x) = 0.80187244002292 x + 2.30677783371705
R² = 0.982537298265516
[Residual] (M) 1.3
1800

1750 f(x) = 5455.40367493495 x + 1419.46773829741

R² = 0.954701136580111 Índice de yodo Vs
[Residual]
1700
Linear (Índice de yodo
1650 Vs [Residual]) Log X/M Vs Log [Residual]
1.4

Log X/M
1600

1550
0.04 0.06
1.35
f(x) = 0.80187244002292 x + 2.30677783371705
R² = 0.982537298265516
[Residual] (M) 1.3

1.25

1.2

1.15

1.1
-1.4 -1.35 -1.3 -1.25 -1.2 -1.15
Log [Residual]
 Datos iniciales

[Yodo] (N) 0,167 ± 0,001 Volumen de HCl 3

[Tiosulfato] (N) 0,339 ± 0,002 Volumen de yodo 30
Masa molar I2 (g/mol) 253.80894 Volumen Filtrado (F) 10

1271.5827894
354.9200764725
1657.61792572785
0.042375 error 0.000727575812201

numerador 1 717.9074701029
numerador 2 803.0882884563
numerador 3 916.6627129275

Propagación del Concentraci Propagación

Indice de Yodo Resultado
error ón residual del error

1789.40047383574 23.34522493804 1789 ± 23 0.066105 0.00079326

1708.33501054308 19.528109960569 1708 ± 20 0.055935 0.0007623

1657.61792572785 16.232027675567 1657 ± 16 0.042375 0.00072758

LogX/M LogC
1.36819806284077 -1.179765690434
1.2906602118789 -1.252316357583
1.21037277449693 -1.372890288789

Yi de experimento Yi con curva Xi

1.36819806284077 1.36074589 -1.17976569
107.831782141586 1.2906602118789 1.30256751 -1.25231636
4.11308322294079 1.21037277449693 1.20587928 -1.37289029
16.7450343702008 prom prom Prom
1.2897436830722 1.28973089 -1.26832411

1474.054000 0.01
M Vs Log [Residual]
1.4

1.35
7244002292 x + 2.30677783371705
7298265516
1.3
M Vs Log [Residual]
1.4

1.35
7244002292 x + 2.30677783371705
7298265516
1.3
Column F
1.25 Linear (Column
F)
1.2

1.15

1.1
1.3 -1.25 -1.2 -1.15
Log [Residual]
 Errores Asociados
[Yodo] (M) 0.001 Bureta (mL) 0.02
[Tiosulfato 0.002 Balanza (g) 0.0001
Pipeta 3,10 0.02

Resultado

0,0661 ±
0,0008
0,0661 ±
0,0008
0,0661 ±
0,0008

0.0885584 0.00784259 0.00745217 5.553484E-05

0.0160078 0.00025625 -0.011907301 0.0001417838
-0.104566 0.01093409 0.00449349708 2.019152E-05
Longitud de onda (nm) 520
Absorbancia inicial 0.406 Error medida absorbancia 0.004
Absorbancia Sebastian 0.177 Masa CA aproximada (g) 0.4
Absorbancia Andrea 0.231 Volumen melaza (mL) 5

Ab sebas 56.403940887 numerador 0.00565685

ab andrea 43.103448276 numerador sebas 0.229 error deco se
IM Sebas 62.67104543 numerador andrea 0.175 error deco an
IM Andrea 47.892720307
1.50004342 e IM S 1.66671491
1.4565931 eIM A 1.61843677
Masa CA NaOH (g) 0.6094 [NaOH] (M) 0.226 Error [NaOH] (M)
Masa CA NaHCO3 (g) 0.6061 [NaHCO3] (M) 0.254 Error [NaHCO3] (M)
Masa CA Na2CO3 (g) 0.6011 [Na2CO3] (M) 0.2289 Error [Na2CO3] (M)
Solución alcalina (mL) 50 [HCl](M) 0.2429 Error [HCl](M)
Alicuota (mL) 10 Error Pipeta (mL) 0.02 Error Balanza (g)
Error probeta 50 (mL)

mol-ex mol-ex
NaOH NaHCO3
Replica 1 Replica 2 Replica 1 Replica 2
10.869775 10.748325 12.3879 12.26645
mol i 11.30 11.3 12.7 12.7
numerador 0.43 0.55 0.31 0.43
mmol/g 0.70598129 0.905275680997702 0.51493153 0.71531100478469
error mol-ex 0.26295008 0.260037301980932 0.26851893 0.26590803581043
error moli 0.27124896 0.271248963131659 0.27297619 0.272976189437834
error numerador 0.37778135 0.375759761578488 0.38290784 0.381081465711153
error mmol/g 0.61992346 0.616606142744134 0.63175688 0.6287435722454
 0.003
18.7 8.95
0.002 Volumen HCl para Na2CO3 (mL) Volumen HCl para NaOH (mL)
0.002 19.2 8.85
0.0003
0.0001 Bureta 0.02
por medida 0.02828427
balanza 0.0001
x por medida 0.00014142
Na2CO3
Replica 1 Replica 2
11.355575 11.6592
11.445 11.445
0.09 -0.21
0.14876892 -0.356346697720845
0.24917318 0.255819939257333
0.24979033 0.249790332078726
0.35282075 0.357545873031175
0.5869585 -0.594819292268659
Volumen HCl para NaHCO3 (mL) 10.2
10.1
 NaOH NaHCO3 Na2CO3
Item
Replica 1 Replica 2 Replica 1 Replica 2 Replica 1
mmol/g 0.7059812931 0.905275681 0.5149315295 0.7153110048 0.1487689236
error mmol/g 0.6199234638 0.6166061427 0.6317568835 0.6287435722 0.5869584951
Promedio 0.80562848703643 0.615121267117639 -0.103788887040426
Error promedio 0.87436161640756 0.891310966798244 0.835661573500736
Resultado 0,8 ± 0,9 0,6 ± 0,9 0
 Na2CO3
Replica 2
-0.3563466977
-0.5948192923
-0.103788887040426
0.835661573500736
0
 Tartrazina
[patrones] ppm Absorbancia
0 0 -25 625 0.003
10 0.094 -15 225 0.004
20 0.175 -5 25 -0.008
30 0.274 5 25 -0.002
40 0.366 15 225 -0.003
50 0.468 25 625 0.006
Prom patrone 25 suma 0 1750 -1.648E-17
Prom abs 0.2295 Sy/x
abs 0.223 error 0.66950841
[] 24.3010752688172
X/M -6.07760635811122

Absor
0.5
0.45
f(x) = 0.0093 x − 0
0.4 R² = 0.999089081
0.35

Absorbancia
0.3
0.25
0.2
0.15
0.1
0.05
0
0 10 20 30
[Tartrazina
 Ycurva
9E-06 -0.2265 0.05130225 5.6625 -0.003
1.6E-05 -0.2255 0.05085025 3.3825 0.09
6.4E-05 -0.2375 0.05640625 1.1875 0.183
4E-06 -0.2315 0.05359225 -1.1575 0.276
9E-06 -0.2325 0.05405625 -3.4875 0.369
3.6E-05 -0.2235 0.04995225 -5.5875 0.462
0.000138 -1.377 0.3161595 0
0.00587367

Absorbancia Vs [Tartrazina]
0.5
0.45
f(x) = 0.0093 x − 0.003
0.4 R² = 0.999089081853917
0.35
Absorbancia

0.3
Absorbancia Vs [Tartrazina]
0.25
Linear (Absorbancia Vs
0.2 [Tartrazina])
0.15
0.1
0.05
0
0 10 20 30 40 50 60
[Tartrazina]
 Número de Observacion
Grupo Acidez I. Melaza I. Yodo
tartrazina es

Cristina NaHCO3 M = 0,1003

X/M=
Tatiana 0.621064467 57.744937 8.8444344
37
Na2CO3 1201.07
0.19954606
NaOH 51.724138
1.120940883
Mayra NaHCO3 M=0,4032
X/M=6,040
Manuela 0.719226941 65.407772
38658
Na2CO3
1539.075
0.40085992
NaOH 74.712644
1.118705335
Andrea Z. NaHCO3 M= 0,0503
X/M= La acidez de
Paula 0.3164840637 79.365079 16,353492 Na CO ,
2 3
05 corresponde
1583.213 a un valor
Na2CO3 negativo (-
0,053206512
0 71)
NaOH 64.860427
1.047711414
Valores
negativos los
Jorge NaHCO3 59.934319 M=0,8005 cuales son
respectivame
nte

X/M=3,082 NaHCO3=-
Jhonny 0 7507 1,807374417
Na2CO3 = -
Na2CO3 85.659551 2,3305625

0 NaOH=
-1,30607182
NaOH
0
Andrea E. M=0,0115
47.89272
Sebastián Na2CO3 X/M=
0.1475416598 1474.054
NaOH 62.671045
0.805628487
Juan Carlos NaHCO3 M=0,0252

80.45977 X/M=13,86
Andres 0.6120702603
755419
Na2CO3 1088.387
0.3799264706
NaOH 72.413793
0.8935636516
X­/M=7,444
Ma Teresa NAHCO3 16873
80.186097
Romeiro 0.373269 M= 0,2015
Na2CO3 1711.671
0.99866
NaOH 90.859332
2.588964

Reporte el
promedio,
Valor
exprese
promedio
como media
martes
aritmética
(± σ)
 Número de Observacion
Grupo Acidez I. Melaza I. Yodo
tartrazina es
NaHCO3
0.6210645 57.744937
Na2CO3
1201.07
0.1995461
NaOH 51.724138
Tatiana y
Cristina 1.1209409 M = 0,1003
NaHCO3
0.7192269 65.407772
Na2CO3
1539.075
0.4008599
NaOH 74.712644
Maira y Manuela1.1187053
NaHCO3
0.3164841 79.365079
Na2CO3
1583.213
0
NaOH 64.860427
Andrea Z. y Paula1.0477114
NaHCO3 59.934319
0
Na2CO3 85.659551
0
NaOH
Jorge y jhonny 0

47.89272
Na2CO3
0.1475417 1474.054
NaOH 62.671045
0.8056285
Andrea E. y Sebastian
NaHCO3
0.6120703 80.45977
Na2CO3
1088.387
0.3799265
NaOH 72.413793
0.8935637
Juan Carlos y Andres
NAHCO3
0.373269 80.186097
Na2CO3
1711.671

Ma Teresa y Romeiro
 1711.671
0.99866
NaOH 90.859332
Ma Teresa y Romeiro2.588964
Valor promedio