OVIEDO

Patrones de Cu (mg/L) Absorbancia %T Abosortancia (100-%T)

0.005 0.015 96.61 3.39
0.01 0.05 89.13 10.87
0.02 0.195 63.83 36.17
0.04 0.402 39.63 60.37
0.06 0.59 25.70 74.30
0.08 0.796 16.00 84.00
0.1 1.112 7.73 92.27
0.12 1.15 7.08 92.92
0.15 1.22 6.03 93.97
0.2 1.35 4.47 95.53
0.25 1.425 3.76 96.24

Curva de Ringbon

120.00

100.00

80.00

60.00

40.00

20.00

0.00
-2.400 -2.200 -2.000 -1.800 -1.600 -1.400 -1.200 -1.000 -0.800 -0.600 -0.400

Se quita los 4 de arriba y el de abajo

Los otros cumplen con la ley de Lambert Beer

Yuver METODO DE PATRON EXTERNO

C (mg/L) Abs Abs corregida

0 0.01 0 Chart Title
0.7
0.6
0.5 f(x) = 0.049017857142857 x − 0.0033928571428
f(x) = 0.270675945766083 ln(x) − 0.145259
R² = 0.999578811917965
0.4 R² = 0.942751317880834
0.3
 Chart Title
2 0.1 0.090 0.7
4 0.2 0.190 0.6
0.5 f(x) = 0.049017857142857 x − 0.0033928571428
6 0.3 0.290 0,34=0,049x-0,0034f(x) = 0.270675945766083 ln(x) − 0.145259
0.4 R² = 0.999578811917965
R² = 0.942751317880834
8 0.405 0.395 x= 7,00816
0.3 mg/L
10 0.5 0.490 ppm 0.2
0.1
12 0.59 0.580 0
muestra 0.34 -0.25 0 2 4 6 8 10

C (mg/L) Abs Chart Title

1 0.23 0.9
2 0.436 0.8 f(x) = 0.2056 x + 0.024
0.7 R² = 0.999947011846637
3 0.638 0.6
4 0.848 0.5
Muestra 0.518 0.4
0.3
0.2
0,518 = 0,2056x+0,024
0.1
x= 2,40 ppm Concentracion0de Fosforo
0.5 1 1.5 2 2.5 3 3.5

1,122 mL equivale a las 24h Una alicuota de 1mL se trató con Mo (VI) y se diluyó hasta un voluemn
C2=2,40ppm C1V1=C2V2
V2= 50 C1 120
V1= 1mL ppm=mgP/Vsln(L) 134.64
C1=?
 logc
-2.301
-2.000
-1.699
-1.398
-1.222
-1.097
-1.000
-0.921
-0.824
-0.699
-0.602

120.00

100.00

80.00

60.00

40.00

20.00

0.00
-0.800 -0.600 -0.400

Chart Title

0.049017857142857 x − 0.003392857142857
f(x) = 0.270675945766083 ln(x) − 0.145259109360404
.999578811917965
R² = 0.942751317880834
 Chart Title

0.049017857142857 x − 0.003392857142857
f(x) = 0.270675945766083 ln(x) − 0.145259109360404
.999578811917965
R² = 0.942751317880834

2 4 6 8 10 12 14

Chart Title

6 x + 0.024
47011846637

2 2.5 3 3.5 4 4.5

o (VI) y se diluyó hasta un voluemn de 50mL

ppm
mg
YUVER METODO DE ADICION COSNTANTE
1.

0.7
C (mg/L) Abs
0.6 f(x) = 1.533 x + 0.2063
0 0.203 b= alpha R² = 0.999640143177076
0.1 0.363 b 0.2063 0.5
0.2 0.516 m=Betta 0.4
0.3 0.663 Betta 1.533 mL-1 0.3
Cx 5.38290933 mg/L
0.2
Cx alpha*Cst/Betta*Vx
0.1
0
0 0.05 0.1

2.

media dela
Concentracion señal Abs Desviacion
de X C analitica Abs corregida estandar
 0 0.031 0 0.0079 Desviacion del blanco
2 0.173 0.142 0.0094
6 0.422 0.391 0.0084
10 0.702 0.671 0.0084
14 0.956 0.925 0.0085
18 1.248 1.217 0.011 Chart Title
1.4
1.2
f(x) = 0.067038356164384 x − 0.000986301369863
1 R² = 0.999567682925541
y=0,067x-0,001
0.8
Sensibilidad S 0.067 ppm-1
0.6
limite de
deteccion LOD 0.35373134 ppm 0.4

limite de 0.2
cuantificacion LOQ 1.17910448 ppm 0
0 2 4 6 8 10 12

concentracion
0.0992
0.1023
 Chart Title
0.7
0.6 f(x) = 1.533 x + 0.2063
R² = 0.999640143177076
0.5
0.4
0.3
0.2
0.1
0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35
 Chart Title

84 x − 0.000986301369863
1

6 8 10 12 14 16 18 20
7

Patrones Zn Absorbancia
0.1 0.15
Absorbancia
0.2 0.3 1.2
0.3 0.45 1 f(x) = 1.28975409836066 x + 0.059959016393443
R² = 0.973907320170118
0.4 0.6 0.8
0.5 0.75
0.6
0.6 0.9
0.8 1.01 0.4
M1 0.5 0.2
M2 0.39
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

1,2898X+0,06
MUESTRA 1 MUESTRA 2
0,5= 1,2898X+0,06 0,39= 1,2898X+0,06
0,3411ppm 0,2558ppm

C1V1=C2V2 C1V1=C2V2
C1 0.85275 ppm C1 0.6395 ppm

10
Solucion Señal
10 5 Absorbancia vs Vst
12 10.1 25
14 15.1 20
f(x) = 2.5 x − 19.95
16 20 15 R² = 0.999920006399488

10

m=Betta 2.5 5
alpha= b 19.95 0
9 10 11 12 13 14 15 16 17
y=mx+b

Cx 0.1197
9016393443

0.6 0.7 0.8 0.9

ia vs Vst

3 14 15 16 17