a) Proceso con catalizadores en lecho fluidizado a temperaturas

superiores a los 370°C.

9
(𝐶10 𝐻8 (𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜) + 0 → 𝐶8 𝐻4 03 (𝐴𝑛ℎí𝑑𝑟𝑖𝑑𝑜 𝐹𝑡á𝑙𝑖𝑐𝑜) + 2𝐻2 𝑂 + 2𝐶𝑂2 )
2 2
(𝐶10 𝐻8 (𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜) + 6 02 → 2𝐶4 𝐻2 03 (𝐴𝑛ℎí𝑑𝑟𝑖𝑑𝑜 𝑀𝑎𝑙𝑒í𝑐𝑜) + 2𝐻2 𝑂 + 2𝐶𝑂2 )
(𝐶10 𝐻8 (𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜) + 2 02 → 𝐶10 𝐻6 03 (𝑁𝑎𝑓𝑡𝑜𝑞𝑢𝑖𝑛𝑜𝑛𝑎) + 𝐻2 𝑂)
∆𝑛𝐴𝑛ℎ𝑖𝑑𝑟𝑖𝑑𝑜 𝑓𝑡𝑎𝑙𝑖𝑐𝑜
𝑆1 = 0.74
∆𝑛𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜
∆𝑛𝐴𝑛ℎ𝑖𝑑𝑟𝑖𝑑𝑜 𝑚𝑎𝑙𝑒𝑖𝑐𝑜
𝑆2 = 0.1
∆𝑛 𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜
∆𝑛𝑁𝑎𝑓𝑡𝑜𝑞𝑢𝑖𝑛𝑜𝑛𝑎
𝑆3 = 0.16
∆𝑛𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜
Datos adicionales

𝑥𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 = 0.70
𝑡𝑜𝑛
𝑊𝐴𝐹 = 75000
𝑎ñ𝑜
𝑜
𝑛𝑂 2
𝑜 =8
𝑛𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜

| | 𝑛 𝑛𝑜 ∆𝑛𝑜 ∆𝑛

Base de Calculo
𝑡𝑜𝑛 1 𝑎ñ𝑜 1000 𝑘𝑔 𝑘𝑔
𝑊𝐴𝐹 = 75000 |
𝑎ñ𝑜 8000 ℎ
| | 1 𝑡𝑜𝑛 | = 9375 ℎ

𝑘𝑔 1 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝐴𝐹 = 9375 |
ℎ 148 𝑘𝑔
| = 63.3446 ℎ

Calculo de Anhídrido Maleico

∆𝑛𝐴𝐹 𝑘𝑚𝑜𝑙
𝜀1 = = ∆𝑛𝐴𝐹 = 63.3446
𝜐𝐴𝐹 ℎ
∆𝑛𝐴𝑀
𝜀2 = ∆𝑛𝐴𝑀 = 𝜀2 ∗
2
𝜀1 𝑆1 𝑆2 ∗ 𝜀1
= 𝜀2 =
𝜀2 𝑆2 𝑆1
0.1 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
𝜀2 = (63.3446 ) = 8.56
0.74 ℎ ℎ
 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝐴𝑀 = (8.56 ) ∗ 2 = 17.12
ℎ ℎ
Calculo de Naftoquinona
∆𝑛𝑁𝑎𝑓𝑡𝑜𝑞𝑢𝑖𝑛𝑜𝑛𝑎
𝜀3 = ∆𝑛𝑁𝑎𝑓𝑡𝑜𝑞𝑢𝑖𝑛𝑜𝑛𝑎 = 𝜀3
1
𝜀1 𝑆1 𝑆3 ∗ 𝜀1
= 𝜀3 =
𝜀3 𝑆3 𝑆1
0.16 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
𝜀3 = (63.3446 ) = 13.696
0.74 ℎ ℎ
𝑘𝑚𝑜𝑙
∆𝑛𝑁𝑎𝑓𝑡𝑜𝑞𝑢𝑖𝑛𝑜𝑛𝑎 = 13.696
ℎ
Calculo de moles iniciales de Nafataleno totales
∆𝑛𝐴𝐹 ∆𝑛𝐴𝐹
𝑆1 = ∆𝑛 𝑇𝑂𝑇_𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 =
∆𝑛 𝑇𝑂𝑇_𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 𝑆1
𝑘𝑚𝑜𝑙
63.3446
∆𝑛 𝑇𝑂𝑇_𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 = ℎ = 85.6 𝑘𝑚𝑜𝑙
0.74 ℎ

∆𝑛𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 𝑜
∆𝑛𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜
𝑋𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 = 𝑜 𝑛𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 =
𝑛𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 𝑋𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜

𝑘𝑚𝑜𝑙
85.6
𝑜
𝑛𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜 = ℎ = 122.28 𝑘𝑚𝑜𝑙
0.70 ℎ
Calculo de moles iniciales de O2
𝑛𝑂𝑜2
𝑜 =8 𝑛𝑂𝑜2 = 8 ∗ 𝑛𝐴𝐹
𝑜
𝑛𝐴𝐹
𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
𝑛𝑂𝑜2 = 8 ∗ (122.28 ) = 978.24
ℎ ℎ
Obtención de ∆𝑛𝑖 en la reacción 1
9
𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝑂2 = ( 2 ) (63.3446 ) = 285.051
1 ℎ ℎ

2 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝐻2 𝑂 = ( ) (63.3446 ) = 126.689
1 ℎ ℎ
2 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝐶𝑂_2 = ( ) (63.3446 ) = 126.689
1 ℎ ℎ
Obtención de ∆𝑛𝑖 en la reacción 2

6 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝑂2 = ( ) (17.12 ) = 51.36
2 ℎ ℎ
2 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝐻2 𝑂 = ( ) (17.12 ) = 17.12
2 ℎ ℎ
2 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝐶𝑂2 = ( ) (17.12 ) = 17.12
2 ℎ ℎ

Obtención de ∆𝑛𝑖 en la reacción 3

2 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝑜2 = ( ) (13.696 ) = 27.392
1 ℎ ℎ
1 𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛𝐻2 𝑂 = ( ) (13.696 ) = 13.696
1 ℎ ℎ
Obtención de ∆𝑛 𝑇𝑂𝑇𝑜2
𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛 𝑇𝑂𝑇𝑜2 = (285.051 + 51.36 + 27.392) = 362.8
ℎ ℎ
Obtencion de ∆𝑛 𝑇𝑂𝑇𝐻
2𝑂

𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
∆𝑛 𝑇𝑂𝑇𝐻 = (126.689 + 17.12 + 13.696) = 157.505
2𝑂 ℎ ℎ
Obtencion de ∆𝑛 𝑇𝑂𝑇𝐶𝑂
2

𝑘𝑚𝑜𝑙
∆𝑛 𝑇𝑂𝑇𝐶𝑂2 = (126.689 + 17.12) = 143.809
ℎ
9
(𝐶10 𝐻8 (𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜) + 0 → 𝐶8 𝐻4 03 (𝐴𝑛ℎí𝑑𝑟𝑖𝑑𝑜 𝐹𝑡á𝑙𝑖𝑐𝑜) + 2𝐻2 𝑂 + 2𝐶𝑂2 )
2 2
(𝐶10 𝐻8 (𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜) + 6 02 → 2𝐶4 𝐻2 03 (𝐴𝑛ℎí𝑑𝑟𝑖𝑑𝑜 𝑀𝑎𝑙𝑒í𝑐𝑜) + 2𝐻2 𝑂 + 2𝐶𝑂2 )
(𝐶10 𝐻8 (𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜) + 2 02 → 𝐶10 𝐻6 03 (𝑁𝑎𝑓𝑡𝑜𝑞𝑢𝑖𝑛𝑜𝑛𝑎) + 𝐻2 𝑂)
______________________________________________________________________
3(𝐶10 𝐻8 (𝑁𝑎𝑓𝑡𝑎𝑙𝑒𝑛𝑜) + 12 02 → 𝐶8 𝐻4 03 (𝐴𝑛ℎí𝑑𝑟𝑖𝑑𝑜 𝐹𝑡á𝑙𝑖𝑐𝑜) + 2𝐶4 𝐻2 03 (𝐴𝑛ℎí𝑑𝑟𝑖𝑑𝑜 𝑀𝑎𝑙𝑒í𝑐𝑜) + 𝐶10 𝐻6 03 (𝑁𝑎𝑓𝑡𝑜𝑞𝑢𝑖𝑛𝑜𝑛𝑎) +

2𝐻2 𝑂 + 2𝐶𝑂2
 Balance de entradas y salidas

Nafta O2 N2 A.F A.M Naftoqui CO2

PM (Kmol/kg) 128 32 28 148 98 174 18 44

85.6006 363.803 0 63.3446 17.12 13.691 157.505 143.809
(kmol/h)
122.28 978.24 3680.04571 0 0 0 0 0
(kmol/h)
36.6794 614.437 3680.04571 63.3446 17.12 13.691 157.505 143.809
(kmol/h)
15651.84 31303.68 103041.28 0 0 0 0 0
(kg/h)
4694.9632 19661.984 103041.28 9375.0008 1677.76 2382.234 2835.09 6327.596
(kg/h)

Componente Entrada (kg/h) Salida (kg/h)

Naftaleno 15651.84 4694.9632
𝑂2 31303.68 19661.984
𝑁2 103041.28 103041.28
Anhídrido Ftálico 0 9375.0008
Anhídrido Maleico 0 1677.76
Naftoquinona 0 2382.234
𝐻2 𝑂 0 2835.09
𝐶𝑂2 0 6327.596
Σ 149996.8 149995.908

Materia prima perdida

kg kg
Σ(Entra − Sale) = (149996.8 − 149995.908) = 0.892
h h