Ecuación de Antoine

〖𝑙𝑜𝑔〗 _10 𝑃(𝑚𝑚𝐻𝑔)=𝐴−𝐵/(𝐶+𝑇(°𝐶))

Alcohol A B C
1-propanol 7.0253 1271.254 222.927
2-butanol 72.013 1157 1682.79
1-octanol 8.366 2170.2403 205.9214
1-decanol 7.03752 1579.82 149.864
Etanol 8.13484 1662.48 238.131

Presión de vapor (1 atm)

Temperatura (°C)
Presión (mmHg)
1-propanol 2-butanol 1-octanol
1 −15.0 −12.2 54.0
5 5.0 7.2 76.5
10 14.7 16.9 88.3
20 25.3 27.3 101.0
40 36.4 38.1 115.2
60 43.5 45.2 123.8
100 52.8 54.1 135.2
200 66.8 67.9 152.0
400 82.0 83.9 173.8
760 97.8 99.5 195.2

Equilibrio Ternario
Fase orgánica (%) Fase acuosa
Acetona Acetato de etilo Agua Acetona
0.00 96.50 3.50 0.00
4.80 91.00 4.20 3.20
9.40 85.60 5.00 6.00
13.50 80.50 6.00 9.50
16.60 77.20 6.20 12.80
20.00 73.00 7.00 14.80
22.40 70.00 7.60 17.50
26.00 65.00 9.00 19.80
27.80 62.00 10.20 21.20
32.60 54.00 13.40 26.40

Composición de mezcla (g)

Experimento
Experimento
Acetona Acetato de etilo Agua
1 5.01 4.49 0.50
2 4.10 4.50 1.41
3 3.50 4.50 2.00
4 3.08 4.33 2.60
5 2.50 4.49 3.01
ne

Rango (°C)
(-31,00 - 99,00)
(72,00 - 107)
(55,00 - 150,00)
(6,9 - 416,85)
(-114,1 - 243,1)

atm)
atura (°C)
1-decanol Etanol
69.5 −31.3
97.3 −12.0
111.3 −2.3
125.8 8.0
142.1 19.0
152.0 26.0
165.8 34.9
186.2 48.4
208.8 63.5
231.0 78.4

o
Fase acuosa (%)
Acetato de etilo Agua
7.40 92.60
8.30 88.50
8.00 86.00
8.30 82.20
9.20 78.00
9.80 75.40
10.20 72.30
12.20 68.00
11.80 67.00
15.00 58.60