3.

Se va a fraccionar continuamente una solución de tetracloruro de carbono y

disulfuro de carbono que contiene 50% en peso de cada uno de ellos, a
presión atmosférica, a un flujo de 4000 kg/h. El producto destilado va a
contener 95% en peso de disulfuro de carbono y el residuo 0.5%. Se va a
evaporar 30% en mol de la alimentación antes de que entre a la torre. Los
datos en el equilibrio son los siguientes:

T (°C) x y
76.7 0 0
74.9 0.02 0.0823
73.1 0.0615 0.1555
70.3 0.1106 0.266
68.6 0.1435 0.3325
63.8 0.2585 0.495
59.3 0.3908 0.634
55.3 0.5318 0.747
52.3 0.6630 0.829
50.4 0.7574 0.878
48.5 0.8604 0.932
46.3 1 1

a) Calcule el flujo de los productos, kg/h.

b) Calcule la relación de reflujo mínimo.
c) Calcule el número mínimo de platos ideales.

D
xD, d = 0.95
xD, t = 0.05
F = 4000 kg/h
101.325
xF, d = 0.5 kPa
xF, t = 0.5

W
xW, d = 0.005
xw, t = 0.995

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  Balance global
F=D+W

 Balance para disulfuro de carbono

Fx F , d=D x D ,d +W x W , d

x F ,d =D x D, d + ( 1−D ) x W ,d

x F , d−x W , d
D=
x D ,d −xW ,d

0.5−0.005
D= =0.5238
0.95−0.005
W =1−0.5238=0.4762
a)
D=4000 kg/h( 0.5238)=2095.2 kg/h
W =4000 kg /h(0.4762)=1904.8 kg/h

 Alimentación
L/V
0.7 / 0.3
F = 4000 kg/h
q = fracción líquida = 0.7
xF, p = 0.5
xF, b = 0.5 q 0.7
m= = =−2.33 3
q−1 0.7−1

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 b) Relación de reflujo mínimo

Diagrama de composiciones xy
CS2 (1)/ CCl4 (2)
1

0.95

0.9

0.85

0.8

0.75

0.7

0.65

0.6

0.55

0.5
y

0.45

0.4

0.35

0.3

0.25

0.2

0.15

0.1

0.05

0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1

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 '
Rm x −y
= D
R m+ 1 x D −x '
Rm 0.95−0. 67
=
R m+ 1 0.95−0. 43
Rm=0.5384 Rm +0. 5384
0. 4616 Rm =0.5384
Rm=1.1667

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 c) Número mínimo de platos ideales

Diagrama de composiciones xy
CS2 (1)/ CCl4 (2)
1

0.95

0.9

0.85

0.8

0.75

0.7

0.65

0.6

0.55

0.5
y

0.45

0.4

0.35

0.3

0.25

0.2

0.15

0.1

0.05

0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1

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