Moles iniciales A

100

50 °C x y obs
Medición Tiempo (h) % conversión A Moles A Tiempo (h) Moles A
1 12.5 7 93 12.5 93
2 25 13 87 25 87
3 55 40 60 55 60
4 76 49 51 76 51
5 90 62 38 90 38
6 96 66 34 96 34
7 119 71 29 119 29
8 122 65 35 122 35
9 148 70 30 148 30
10 172 74 26 172 26
11 195 76 24 195 24
12 217 70 30 217 30
13 247 81 19 247 19
14 286 80 20 286 20
15 313 76 24 313 24
16 337 74 26 337 26
17 362 79 21 362 21

Conversión A Concentración A
90 100
80 90
f(x) = − 0.0000057984 x³ + 0.004
80
70 + 106.837
70
60 R² = 0.971782721466909
% conversión

60
50
Moles A

50
40
40
30
30
20
20
10 10
0 0
0 50 100 150 200 250 300 350 400 0 50 100 150 200
Tiempo (h) Tiempo (h)
 y calc poli 3 dy/dx
94.2245 1.4995 -0.9561
82.9138 16.6974 -0.8546
60.6703 0.4492 -0.6338
48.8097 4.7972 -0.4985
42.4090 19.4393 -0.4171
40.0052 36.0622 -0.3844
32.5047 12.2832 -0.2710
31.7119 10.8115 -0.2576
26.3984 12.9712 -0.1552
23.5913 5.8018 -0.0822
22.3173 2.8316 -0.0317
21.9856 64.2303 -0.0013
22.2292 10.4275 0.0121
22.2767 5.1832 -0.0188
21.1049 8.3815 -0.0723
18.5750 55.1309 -0.1419
13.8914 50.5317 -0.2365

Concentración A

0000057984 x³ + 0.00437621 x² − 1.06332 x

7
1782721466909

100 150 200 250 300 350 400

Tiempo (h)
 Cálculo de la constante K

X tiempo Y [B] observado

0 0.002
2 0.169
4 0.292
6 0.287
8 0.445
10 0.476
12 0.498
14 0.499
16 0.493
18 0.479

Y [B] calculado Diferencia*2

0.000 0.000004000
0.172 0.000012175
0.297 0.000026329
0.384 0.000007851
0.442 0.000009334
0.477 0.000000981
0.495 0.000011376
0.499 0.000000006
0.494 0.000000470
0.481 0.000004451
Objetivo 0.000000006
K1 0.100215683
K2 0.050336070
 Orden 3 Orden 4
Tiempo CA Polinomio 3 dy/dx Tiempo CA
0 20 19.955 2.1311 0 20
2 15.98 16.013 1.9797 2 15.98
4 12.63 12.677 1.8547 4 12.63
6 9.86 9.894 1.7561 6 9.86
8 7.61 7.610 1.6839 8 7.61
10 5.79 5.774 1.6381 10 5.79
15 2.71 2.794 1.6391 15 2.71
18 1.61 1.845 1.7189 18 1.61
20 1.11 1.453 1.8051 20 1.11
25 0.37 0.927 2.1361 25 0.37

Diferencial orden 3 Diferencial orden 4

Concentración Polynomial (Concentración) Concentración Polynomial (Co
Diferencial orden 3 Diferencial orden 4
Concentración

25 25
20 20
f(x) = 0.0000170925 x⁴ − 0.00199026 x³ + 0.095

Concentración
f(x) = − 0.001138254 x³ + 0.0823287387 x² − 2.131056593 x 15
15 + 19.95463612 + 20.0002
R² = 0.999966914271229 10 R² = 0.999999735390582
10
5
5
0
0 0 5 10 15 20
0 5 10 15 20 25 30 -5
Tiempo Tiempo

Log CA Log dy/dx

1.30103 0.32860383 Log dy/dx
1.20357677 0.29659938 0.35
1.10140335 0.26827367
0.99387691 0.24454924 0.3

0.88138466 0.2263163 0.25

f(x) = − 0.000679795669144289 x + 0.261907855848393
0.76267856 0.21434041 R² = 7.83914490432025E-05
0.43296929 0.21460545 0.2
0.20682588 0.23525061 0.15
0.04532298 0.25650127
-0.43179828 0.32962158 0.1

0.05

0
-0.6 -0.4 -0.2 0 0.2 0.4 0.6 0.8
K 1.2993966
 Orden 4
Polinomio 4 dy/dx
20 -2.1936
15.97872 -1.83536
12.62912 -1.52128
9.86672 -1.24752
7.61472 -1.01024
5.804 -0.8056
2.8235 -0.4116
1.86032 -0.23664
1.488 -0.1376
1.3475 0.0764

Diferencial orden 4
centración Polynomial (Concentración)
rencial orden 4

000170925 x⁴ − 0.00199026 x³ + 0.0954121 x² − 2.193644 x

02
9999735390582

5 10 15 20 25 30

Tiempo

Log dy/dx

289 x + 0.261907855848393

0.2 0.4 0.6 0.8 1 1.2 1.4

 Orden 3 Orden 3
Tiempo CA Polinomio 3 dy/dx Tiempo CA Polinomio 3
0 40 19.955 2.1311 0 30 19.955
1.3 32.1 17.321 2.029687 1.4 24.2 17.130
7.4 14.3 8.246 1.702788 13.4 3.529
10.6 10.2 5.302 1.629508 15.4 2.637
11.4 9.4 4.726 1.621748 15.8 2.490
13.8 7.7 3.328 1.623812 17.8 1.894
14.6 7.2 2.961 1.632948 26.9 3.2 0.770
17.8 5.8 1.894 1.711732
18.6 5.5 1.711 1.741988
21.8 4.7 1.213 1.905252
22.6 4.5 1.130 1.956628
23.4 4.3 1.057 2.012228
24.2 4.2 0.991 2.072052
25.8 4 0.864 2.204372
26.6 3.9 0.797 2.276868
27.4 3.8 0.723 2.353588

Concentración vs velocidad
25.000

20.000 f(x) = 0.553256926198739 x − 1.07423263585727

R² = 0.990063326174485

15.000

10.000

5.000

0.000
0 5 10 15 20 25 30 35 40 45

CA Ln dy/dx
40 0.75663828 0.9
32.1 0.70788159
14.3 0.53226691 0.8
10.2 0.48827813 0.7
9.4 0.48350458 f(x) = 0.00105268564355083 x + 0.629934684039295
0.6 R² = 0.00731823186277025

0.5

0.4
 0.8

0.7
f(x) = 0.00105268564355083 x + 0.629934684039295
7.7 0.6 R² = 0.00731823186277025
0.48477647
7.2 0.49038697 0.5
5.8 0.53750572
5.5 0.4
0.55502699
4.7 0.64461428 0.3
4.5 0.67122258
0.2
4.3 0.69924257
4.2 0.72853942 0.1
4 0.79044266
0
3.9 0.82280081 0 5 10 15 20 25 30 35 40 45
3.8 0.85594097

K 1.87742283
Eact (273.15 K) -141327772
n3 Orden 3 Orden 3
dy/dx Tiempo CA Polinomio 3 dy/dx Tiempo CA Polinomio 3
2.1311 0 20 19.955 2.1311 0 10 19.955
2.022348 1.6 16.1 16.751 2.007868 1.5 8.5 16.940
1.620828 11.2 5.9 4.865 1.623292 13 3.2 3.743
1.646308 14.6 4.6 2.961 1.632948 14 3 3.232
1.654572 16 4.2 2.421 1.6591 15.9 2.6 2.455
1.711732 18.4 3.6 1.754 1.734028 17.8 2.4 1.894
2.305143 19.4 3.4 1.555 1.776468 20.2 2.1 1.422
21.8 3 1.213 1.905252 22.6 1.9 1.130
22.3 3 1.160 1.936867 24 1.8 1.007
25.6 2.6 0.880 2.186908 26 1.6 0.848
26.6 2.5 0.797 2.276868 26.4 1.6 0.814

Concentración vs velocidad Concentración vs velocidad

25.000 25.000

20.000 f(x) = 1.13261959267856 x − 2.15698143959574 20.000

f(x) = 2.34739046789337 x − 3.40046186431578
R² = 0.997865105697758
R² = 0.99753532775916

15.000 15.000

10.000 10.000

5.000 5.000

0.000 0.000
0 5 10 15 20 25 1 2 3 4 5 6 7 8 9 10 11

0.9 CA
10
CA Ln dy/dx 0.8 8.5
20 0.75663828 3.2
16.1 0.69707346 0.7 3
f(x) = 0.00526056152725623 x + 0.60076610317166
5.9 0.48445619 R² = 0.0670000692240045 2.6
4.6 0.49038697 0.6 2.4
4.2 0.50627529 2.1
0.5

0.4
 0.7
f(x) = 0.00526056152725623 x + 0.60076610317166
R² = 0.0670000692240045
0.6

3.6 0.5 1.9

0.55044703
3.4 0.57462712 1.8
0.4
3 0.64461428 1.6
3 0.66107172 1.6
0.3
2.6 0.78248867
2.5 0.82280081 K
0.2
Eact (273.15
K 1.82357708
0.1
Eact (273.15 -134798738
0
0 5 10 15 20 25
n3
dy/dx
2.1311
2.015075
1.6189
1.6257
1.656803
1.711732
1.815172
1.956628
2.0567
2.2221
2.258348

n vs velocidad

89337 x − 3.40046186431578
5916

6 7 8 9 10 11

0.9
Ln dy/dx
0.75663828 0.8
0.70065642 0.7
0.48174691 f(x) = 0.0078399239610074 x + 0.615051130610385
0.6 R² = 0.0323954416473378
0.48593849
0.50488984 0.5
0.53750572
0.4
0.59618023
0.3

0.2

0.1
 0.5

0.4

0.67122258 0.3

0.72110276 0.2
0.79845269
0.1
0.81463357
0
1 2 3 4 5 6 7 8 9 10 11
1.84984157
1367.63856