FACULTAD DE INGENIERIA QUIMICA

METODOS NUMERICOS
ACELERACION DE CONVERGENCIA

BALTAZAR ALANIA, ABIGAIL CRISTINA

FACTOR DE COMPRESIBILIDAD

El factor de comprensibilidad para el metano está dado por:

2 3
Z=1+Bp+C p + D p

Si p está dada en atm los valores de las constantes son los siguientes

Temperatura de 200 K; y sabiendo que para que tenga un comportamiento ideal (Z=1)
−3 −4 2 −9 3
0=−5.74 ¿ 10 p+6.86 ¿ 10 p +18 ¿ 10 p
2 3
0=−0.00574 p+0.000686 p +0.000000018 p

ALGORITMO DE AITKEN

0.000686 p2 +0.000000018 p 3
p=
0.00574

10-4 10-3
ALGORITMO DE AITKENS
i Xi d=|Xi+1-Xi| |f(Xi+1)| |g'(Xi+1)| X'i d' f'
0 5 -39.54853374 1.29885851
2.98819686 2.0118031 0.7143359 38.808781
1 4 4 -0.01102626 4 -0.739751896 8 0.00462157
1.06724636 0.2551086 0.7194713
2 7 1.9209505 -0.00534461 3 -0.020280583 1 0.00011669
0.13612997 0.0325385 0.0202439
3 2 0.9311164 -0.00076867 6 -3.66378E-05 4 2.103E-07
0.00221473 0.1339152 0.0005293
4 3 4 -1.2709E-05 8 -1.55204E-10 3.6638E-05 8.9087E-13
0.0022141
5 5.86212E-07 5 -3.3649E-09 1.4012E-07 -2.96462E-21 1.552E-10 1.7017E-23
6 4.10697E-14 5.8621E-07 -2.3574E-16 9.8167E-15 0 2.9646E-21 0
7 2.01584E-28 4.107E-14 -1.1571E-30 4.8183E-29 0 0 0
8 4.85651E-57 2.0158E-28 -2.7876E-59 1.1608E-57 0 0 0
9 2.8188E-114 4.8565E-57 -1.618E-116 6.738E-115
10 9.4958E-229 2.819E-114 -5.451E-231 2.27E-229
FACULTAD DE INGENIERIA QUIMICA
METODOS NUMERICOS
ACELERACION DE CONVERGENCIA

La raíz de la ecuación mediante el factor distancia serian: 4.10697E-14 y -1.55204E-10

La raíz de la ecuación mediante la función serían: 0.002214733 y -0.020280583

ALGORITMO DE STEFFENSEN

0.000686 p2 +0.000000018 p 3
p=
0.00574

10-4 10-3
i Xi d=|Xi+1-Xi| |f(Xi+1)| |g'(Xi+1)|

0 -0.03

1 0.000107561 0.03010756 -6.17392E-07 2.571E-05

2 1.38268E-09 0.00010756 -7.93657E-12 3.3049E-10

3 -0.029999617 0.02999962 0.000172815 0

4 0.000107558 0.00010756 -6.17376E-07 2.5709E-05

5 1.38261E-09 0.00010756 -7.93617E-12 3.3048E-10

10-4 10-3

i Xi d=|Xi+1-Xi| |f(Xi+1)| |g'(Xi+1)|

0 8.31

1 8.254845647 0.05515435 -0.00062695 1.97375051

2 8.14562092 0.10922473 -0.001229253 1.94762628

3 8.530639145 0.38501822 0.000966763 0

4 8.699064793 8.69906479 0.001991395 2.08000057

5 9.045997706 0.34693291 0.004224728 2.16298392

La raíz de la ecuación mediante la función serían: -0.029999617 y 8.530639145

FACULTAD DE INGENIERIA QUIMICA
METODOS NUMERICOS
ACELERACION DE CONVERGENCIA
 FACULTAD DE INGENIERIA QUIMICA
METODOS NUMERICOS
ACELERACION DE CONVERGENCIA

METODO ILLIONIS

FALSA POSICION

0.001 0.0001
i XD Xi XM F(Xd) F(Xi) F(XM) d=│XM(i+i)-XM(i)│
0 -4 12 131.74808 0.033934848 0.0299351 11.1922127
1 12 131.74808 11.6788584 0.029935104 11.1922127 0.0265595 120.0692214
2 131.74808 11.6788584 11.3932524 11.19221266 0.0265595 0.0236764 0.285606079
3 11.6788584 11.3932524 9.04781259 0.026559499 0.0236764 0.00423685 2.345439772
4 11.3932524 9.04781259 8.53662468 0.023676405 0.00423685 0.00100251 0.511187906
5 9.04781259 8.53662468 8.37817778 0.004236846 0.00100251 7.2835E-05 0.158446901
6 9.04781259 8.37817778 8.35433475 0.002118423 7.2835E-05 -6.4078E-05 0.023843035
7 9.04781259 8.35433475 8.39389428 0.001059212 -6.4078E-05 0.00016351 0.039559534
8 8.35433475 8.39389428 8.36547283 -6.40782E-05 0.00016351 -2.173E-07 0.028421448
9 8.35433475 8.36547283 8.36554889 -3.20391E-05 -2.173E-07 2.1937E-07 7.60594E-05
10 8.35433475 8.36554889 8.3653974 -1.60196E-05 2.1937E-07 -6.5038E-07 0.000151493

0.001 0.0001
i XD Xi XM F(Xd) F(Xi) F(XM) d=│XM(i+i)-XM(i)│
0 -4 -1 -0.29920972 0.033934848 0.00642598 0.00177888
1 -1 -0.29920972 -0.03095214 0.006425982 0.00177888 0.00017832 0.268257574
2 -0.29920972 -0.03095214 -0.0010648 0.001778878 0.00017832 6.1127E-06 0.029887343
3 -0.29920972 -0.0010648 0.0009984 0.000889439 6.1127E-06 -5.7301E-06 0.002063199
4 -0.29920972 0.0009984 -0.00282052 0.00044472 -5.7301E-06 1.6195E-05 0.003818921
5 -0.29920972 -0.00282052 0.02046232 0.00022236 1.6195E-05 -0.00011717 0.02328284
6 -0.29920972 0.02046232 -0.14356413 0.00011118 -0.00011717 0.0008382 0.164026451
7 0.02046232 -0.14356413 0.00034599 -0.000117166 0.0008382 -1.9859E-06 0.143910127
8 0.02046232 0.00034599 -0.00035986 -5.85832E-05 -1.9859E-06 2.0657E-06 0.000705855
9 0.02046232 -0.00035986 0.00101182 -2.92916E-05 2.0657E-06 -5.8071E-06 0.001371679
10 0.02046232 0.00101182 -0.01176744 -1.46458E-05 -5.8071E-06 6.764E-05 0.012779258
11 0.02046232 -0.01176744 0.01731389 -7.3229E-06 6.764E-05 -9.9176E-05 0.029081333
12 0.02046232 0.01731389 0.02058301 -3.66145E-06 -9.9176E-05 -0.00011786 0.003269117
13 0.02046232 0.02058301 0.02046041 -1.83073E-06 -0.00011786 -0.00011716 0.000122596
14 0.02046232 0.02046041 0.02046233 -9.15363E-07 -0.00011716 -0.00011717 1.91935E-06
15 0.02046232 0.02046233 0.02046232 -4.57682E-07 -0.00011717 -0.00011717 1.50551E-08
 FACULTAD DE INGENIERIA QUIMICA
METODOS NUMERICOS
ACELERACION DE CONVERGENCIA

BISECCION

0.0001 0.001
i XD Xi XM F(XD) F(Xi) │XM(i+1)-XM(i)│ F(XM)
0 0.29 -0.6 -0.155 -0.001606907 0.00369096 0.00090618
1 -0.6 -0.155 -0.3775 0.003690956 0.00090618 0.11125 0.00226461
2 -0.155 -0.3775 -0.26625 0.000906181 0.00226461 0.0278125 0.0015769
3 -0.3775 -0.26625 -0.321875 0.002264608 0.0015769 0.01390625 0.00191863
4 -0.26625 -0.321875 -0.2940625 0.001576905 0.00191863 0.006953125 0.00174724
5 -0.321875 -0.2940625 -0.30796875 0.001918634 0.00174724 0.003476563 0.0018328
6 -0.2940625 -0.30796875 -0.30101563 0.001747239 0.0018328 0.001738281 0.00178999
7 -0.30796875 -0.30101563 -0.30449219 0.001832804 0.00178999 0.000869141 0.00181139
8 -0.30101563 -0.30449219 -0.30275391 0.001789988 0.00181139 0.00043457 0.00180069
9 -0.30449219 -0.30275391 -0.30362305 0.001811387 0.00180069 0.000217285 0.00180604
10 -0.30275391 -0.30362305 -0.30318848 0.001800686 0.00180604 0.000108643 0.00180336
11 -0.30362305 -0.30318848 -0.30340576 0.001806036 0.00180336 5.43213E-05 0.0018047
12 -0.30318848 -0.30340576 -0.30329712 0.001803361 0.0018047 2.71606E-05 0.00180403

0.0001 0.001
i XD Xi XM F(XD) F(Xi) │XM(i+1)-XM(i)│ F(XM)
0 9.2 8 8.6 0.005269056 -0.00200678 0.00138401
1 8 8.6 8.3 -0.002006784 0.00138401 0.15 -0.00037317
2 8.6 8.3 8.45 0.001384009 -0.00037317 0.0375 0.00048998
3 8.3 8.45 8.375 -0.000373168 0.00048998 0.01875 5.4542E-05
4 8.45 8.375 8.4125 0.000489975 5.4542E-05 0.009375 0.00027129
5 8.375 8.4125 8.39375 5.45424E-05 0.00027129 0.0046875 0.00016268
6 8.4125 8.39375 8.403125 0.000271294 0.00016268 0.00234375 0.00021692
7 8.39375 8.403125 8.3984375 0.000162677 0.00021692 0.001171875 0.00018979
8 8.403125 8.3984375 8.40078125 0.000216925 0.00018979 0.000585937 0.00020335
9 8.3984375 8.40078125 8.39960938 0.000189786 0.00020335 0.000292969 0.00019657
10 8.40078125 8.39960938 8.40019531 0.000203351 0.00019657 0.000146484 0.00019996
11 8.39960938 8.40019531 8.39990234 0.000196568 0.00019996 7.32422E-05 0.00019826
12 8.40019531 8.39990234 8.40004883 0.000199959 0.00019826 3.66211E-05 0.00019911
13 8.39990234 8.40004883 8.39997559 0.000198263 0.00019911 1.83105E-05 0.00019869