CÁLCULO DE PUNTO FLASH

Algoritmo para el FLASH

Datos P, T, Zi:

Bi
Ai−
1.- Calcular PSi f (T), Psi =e T +Ci

Ai z i +2.414 Bi
2.- Calcular s
ϕ f ( T ) , ϕ =e s
z i −1−ln ( z i −Bi )−
2 √ 2 Bi (
ln
z i −0.414 Bi )
i i

L
Vi s
∗(P −Pi )
3.- Calcular R∗T
FP f ( T , P ) , FP=e

4.- Suponer B

5.- 1ra Iteración ¿Calcular? SI ϕ Vi =1

No
n
Bi Bi 2 z +2.414 B
Calcular
ϕ Vi f ( P ,T , yi ) , ϕsi =e
B
( z−1) −ln ( z−B ) +
A
[
2,828 B B aα j=1 j ](
− ∑ y ( aα )ij ln i
zi −0.414 B )

6.- 1ra Iteración Calcular? SI γ i=1

L
Vi 2

No Calcular γ f ( P ,T , xi ) , γ =e RT [ δ −δ́ ] +1+ln (Θ )−Θ i i i

i i

γ i∗ϕsi ∗Psi∗FP i
7.- Calcular ki= V
ϕi ∗P

zi
8.- Calcular xi=
1+B∗(ki−1)

zi∗ki
9.- Calcular yi=
1+ B∗(ki−1)

n n
10.- Verificar ∑ xi−∑ yi≈ 0 SI ¿1ra Iteración? SI Volver a Paso 5
i=1 i=1
 NO NO FIN

xi yi
x i , N= n
, y i , N= n
11.- Normalizar ;
∑ xi ∑ yi
i=1 i=1

12.- Verificar x i , N ≠ x i , N−1 ; y i , N ≠ y i ,N −1 SI Volver al paso 5

No, Volver al paso 4

Cálculo de coeficientes de Fugacidad con Ecuación de PENG - ROBINSON

RT aα
P= − Ec. 1
V −b V ( V + b ) +b ( V −b )

R 2 Tc i2
a i=0.45724 Ec .2
Pc i

R Tc i
b i=0.0778 Ec .3
Pci

[ ( √ )]
α i= 1 + Si 1−
T
Tc i
Ec .4

Si=0.37464+1.54226 ω−0.26992 ω2Ec.5

n n
aα =∑ ∑ yi y j ( aα )ij Ec .6
i=1 j=1

( aα )ij =√ ai a j α i α j Ec .7

b=∑ x i b i Ec .8

aiα i P
Ai = Ec .9
R2 T 2

bi P
Bi= Ec .10
RT

n n
A=∑ ∑ y i y j A ij Ec .11
i=1 j=1
 Aij =√ Ai A j Ec .12

B=∑ x i B i Ec .13

Ai z i +2.414 Bi
s
ln φ i =z i−1−ln ( z i−Bi )−
2 √ 2 Bi
ln ( z i−0.414 Bi) Ec .14

Bi Bi 2 n z +2.414 B
ln φ^ Vi =
B
( z−1 )−ln ( z−B ) +
A
[
− ∑ y j ( aα )ij ln i
2,828 B B aα j=1 z i−0.414 B](
Ec.15
)
Cálculo del Volumen:

RT 2 aα 2 bRT RT b 2 aαb 3
(
V 3 + b−
P ) (
V +
P
−3 b2 −
P
V+
P
− ) (
P
+ b =0 ) Ec.16

Cálculo de la Presión de Saturación:

Ec.17
Ban
ln ( P s )= Aan−
T +Can

Ec.18

Ban
Aan−
Ps =e T +Can

Coeficiente de Actividad Modelo SHFH:

Ec.19

V Li 2
ln γ i= [ δ i− δ́ ] +1+ ln ( Θ i ) −Θ i
RT

Ec.20

n
x j V Lj δ j
δ =∑ n
j=1
∑ x k V Lk
k=1
 Ec.21

V iL
Θi= n

∑ x k V Lk
k=1

Factor de POYNTOING:
Ec.22

Pi L
V
∫ R∗Ti dP
FP=e PiS

Ec.23

L
Vi s
∗(P −Pi )
R∗T
FP=e

Constante de Equilibrio:

Ec.24

γ i∗ϕsi ∗Psi∗FP i
ki =
ϕVi ∗P

Fracción del Líquido:

Ec.24

γ i∗ϕsi ∗Psi∗FP i
ki= V
ϕi ∗P

Facción del vapor:

Ec.26

zi∗ki
yi=
1+ B∗(ki−1)
 FASE VAPOR
Simulación en PRO II

Iniciar el Simulador PRO II

.
Insertar la lista de componentes

Una vez insertados los componentes presionar OK

Posteriormente insertar el paquete de Fluidos
Luego insertar una corriente de la paleta PFD

Ingresar a la corriente
Insertar la composición de los compuestos de la fase vapor

Luego seleccionar la primera especificación Presión de trabajo y la segunda especificación punto de burbuja.
Posteriormente presionar OK
Luego presionar RUN y RUN SIMULATION

La simulación se lleva a cabo y generamos el reporte de resultados.

T burbuja = 224.4642 K
Luego seleccionar la primera especificación Presión de trabajo y la segunda especificación punto de rocio.
Posteriormente presionar OK

Luego presionar RUN y RUN SIMULATION

La simulación se lleva a cabo y generamos el reporte de resultados.

T Rocío = 238.1771 K

Temperatura de Operación

T burbuja = 224.4642 K

T Rocío = 238.1771 K
T Burbuja +T Rocio
T=
2

224.4642 K +238.1771 K
T=
2

T =231.32065 K
 FASE LÍQUIDA
Simulación en PRO II

Iniciar el Simulador PRO II

Insertar la lista de componentes

Una vez insertados los componentes presionar OK

Posteriormente insertar el paquete de Fluidos

Luego insertar una corriente de la paleta PFD

Ingresar a la corriente
Insertar la composición de los compuestos de la fase liquida

Luego seleccionar la primera especificación Presión de trabajo y la segunda especificación punto de burbuja.
Posteriormente presionar OK
Luego presionar RUN y RUN SIMULACION

La simulación se lleva a cabo y generamos el reporte de resultados.

T burbuja = 280.7277 K
Luego seleccionar la primera especificación Presión de trabajo y la segunda especificación punto de rocio.
Posteriormente presionar OK

Luego presionar RUN y RUN SIMULATION

La simulación se lleva a cabo y generamos el reporte de resultados.

T rocío = 348.8226 K

Temperatura de Operación

T burbuja = 280.7277 K

T Rocío = 348.8226 K
T Burbuja +T Rocio
T=
2

280.7277 K + 348.8226 K
T=
2

T =314.7752 K
DATOS

COMPONENTE Zliq Zvap Pc Kpa Tc K w δ √(J/m3) VL

N2 3.2380E-03 9.9825E-03 3390 126.2 0.040 9081.9 0.034707
CO2 9.0393E-03 1.3596E-02 7380 304.1 0.225 14564 0.037417
C1 4.8310E-01 9.2238E-01 4600 190.4 0.008 11618 0.037831
C2 2.3824E-01 4.6972E-02 4880 305.4 0.098 12375 0.055205
C3 1.7472E-01 6.4866E-03 4250 369.8 0.152 13091 0.075642
iC4 2.1992E-02 2.5584E-04 3660 408.2 0.176 14027 0.097704
nC4 3.5596E-02 2.7873E-04 3800 425.2 0.193 14470 0.096647
iC5 1.4328E-02 2.8997E-05 3390 460.4 0.227 13857 0.117106
nC5 1.0593E-02 1.6045E-05 3370 469.7 0.251 14439 0.116126
C6 (+) 6.8622E-03 2.3849E-06 3010 507.5 0.296 14989 0.131287
C7 (+) 2.2915E-03 1.7258E-07 2740 540.3 0.351 15203 0.147113

Fase Vapor
P Kpa TK R Kpa m3/Kmol K
9684.37609 231.32065 8.3145
Fase Líquida
P Kpa TK R Kpa m3/Kmol K
9684.37609 314.7752 8.3145

FASE VAPOR
Ejemplo para N2

Suponer β=0.9359

Coeficiente de fugacidad Molar Parcial:

R 2 Tc N 22
a N 2=0.45724
Pc N 2
8.3142 ¿126.22
a N 2=0.45724 =148.50
3390 N 2

R Tc N 2
b N 2=0.0778
Pc N 2
8.314∗126.2
b N 2=0.0778 =0.0241
3390
 S N 2=0.37464 +1.54226 ω−0.26992ω 2=0.4355
S N 2=0.37464 +1.54226∗0.040−0.26992 ¿ 0.0402=0.4355

[ ( √ )]
α N 2= 1+ S N 2 1−
T
TcN 2

[
α N 2= 1+0.4355 1−
231.32065
( √
126.2 )] =0.7153

n n
aα =∑ ∑ yi y j ( aα )ij =241.086
i=1 j=1

ai α i P
A N 2= =0.2781
R2T 2

bi P
BN 2= =0.1213
RT

n n
A=∑ ∑ y i y j A ij =0.6312
i=1 j=1

B=∑ x i B i=0.1369

RT 2 aα 2 bRT RT b 2 aαb 3
(
V 3 + b−
P ) (
V +
P
−3 b2 −
P
V+ ) (
P
−
P
+ b =0 )
m3
V =0.1044
Kmol
 PV
z= =0.5257
RT
9684.37609∗0.1044
z= =0.5257
8.314∗231.32065

n
Bi Bi 2 zi +2.414 B
V
ϕ =e
B
( z −1 ) −ln ( z −B ) +
[
A
−
2,828 B B aα
∑
j=1
y j ( aα ) ij
](
ln
z i −0.414 B )
N2

ϕ VN 2 =1.095

Coeficiente de fugacidad en la saturación:

Ban
Aan−
PSN 2=e T +Can

PSN 2=222885.6 mmHg

PSN 2=29715.6 Kpa

RT aN 2 α N 2 2 b N 2 RT RT b N 22 aN 2 α N 2 b N 2
3
( PN 2
2
V + b N 2− S V + S
PN 2 ) ( 2
−3 b N 2 −
PN2S
V+ S
PN 2
− S
PN2
+b N 23 =0
) ( )
m3
V N 2=0.067
Kmol

P SN 2 V N 2
z N 2= =¿
RT

29715.6∗0.067
z N 2= =1
8.314∗231.32065
 Ai z i +2.414 Bi
S
ϕ =e
z i −1−ln ( zi −Bi )−
2 √ 2 Bi (
ln
z i −0.414 Bi )
N2

ϕ SN 2 =1.068

Coeficiente de Actividad:

V LN 2
Θ N 2= L L L L L L L L L L L
x N 2 V N 2+ x CO 2 V CO 2+ x C 1 V C1 + x C 2 V C 2 + x C 3 V C 3 + x iC 4 V Ic 4 + x nC 4 V nC 4 + x iC5 V iC5 + x nC 5 V nC5 + x C 6 V C 6 + x C 7 V C 7

Θ N 2=0.7418

n
x j V Lj δ j
δ =∑ n
=12273.9
j=1 L
∑ xk V k
k=1

L
VN2 2
[ δ −δ́ ] +1+ln ( ΘN 2 )−Θ N 2
RT N 2
γ N 2=e

γ N 2=1.1542

Factor de POYNTING:

L
Vi s
∗(P− Pi )
R∗T
FP N 2=e

FP N 2=0.6967

Constante de Equilibrio:

γ N 2∗ϕsN 2∗PsN 2∗FP N 2

k N 2=
ϕVN 2∗P

1.1542∗1.068∗29715.6∗0.6967
k N 2=
1.095∗9684.37609

k N 2=2.41
Fracción del Líquido:

zN 2
xN 2=
1+B∗(kN 2−1)

9.9825∗10−3
xN 2=
1+0.9359∗(2.41−1)

xN 2=0.0043

Facción del vapor:

zN 2∗kN 2
yN 2=
1+ B∗(kN 2−1)

9.9825∗10−3∗2.41
yN 2=
1+0.9359∗(2.41−1)

yN 2=0.0104

Tablas para las dos primeras Iteraciones

Primera Iteración
 PARAMETROS PENG ROBINSONG
COMP Pc Kpa Tc K w ai bi α
N2 3390 126. 0.040 148.503094 0.02408105 0.71528939
2
CO2 7380 304. 0.225 396.089172 0.02665482 1.18920035
1
C1 4600 190. 0.008 249.110795 0.02677471 0.92244407
4
C2 4880 305. 0.098 604.136026 0.04048228 1.14031164
4
C3 4250 369. 0.152 1017.09466 0.05628513 1.2679859
8
iC4 3660 408. 0.176 1439.0683 0.07214523 1.34016144
2
nC4 3800 425. 0.193 1503.90155 0.07238114 1.37776866
2
iC5 3390 460. 0.227 1976.45724 0.08785194 1.45678544
4
nC5 3370 469. 0.251 2069.32027 0.09015844 1.49353296
7
C6 3010 507. 0.296 2704.71861 0.10906497 1.5934775
(+) 5
C7 2740 540. 0.351 3367.71913 0.12755578 1.70338751
(+) 3

Fugacidad en la saturación
COM Aan Ban Can Ps Kpa Ai Bi Vs Zi ɸis
P
N2 14.934 588.72 -6.60 29715.558 0.8532967 0.37205636 0.067321814 1 1.06779653
2 2 6 8 6
CO2 22.589 3103.3 -0.16 1273.5453 0.1621665 0.01764979 1.261330244 0.8352042 1.01144225
8 9 7 5 1 1
C1 15.224 897.84 -7.16 9936.5015 0.6172555 0.13832727 0.108107592 0.5585205 1.09098778
3 6 5 9
C2 15.663 1511.4 - 728.7274 0.1357132 0.01533838 2.28752395 0.8667227 1.00859490
7 2 17.16 6 5 3
C3 15.726 1872.4 - 102.3587 0.0356861 0.00299549 18.158434983 0.9663905 1.00166912
0 6 25.16 3 1 2 5
iC4 15.538 2032.7 - 26.1969 0.0136579 0.00098266 72.476093957 0.9871733 1.0006459
1 3 33.15 8 7 6
nC4 15.678 2154.9 - 15.1669 0.0084955 0.00057078 125.796442009 0.9920053 1.00040330
2 0 34.42 4 3 9 3
iC5 15.633 2348.6 - 3.8172 0.0029711 0.00017435 502.437483089 0.9971797 1.00013953
8 7 40.05 5 8 5
nC5 15.833 2477.0 - 2.3992 0.0020045 0.00011246 800.100787536 0.9980876 1.00009323
3 7 39.94 5 8 4 2
C6 (+) 15.836 2697.5 - 0.3844 0.0004478 2.17954E- 5,001.793688886 0.9995538 1.00001981
6 5 48.78 1 05 3 4
C7 (+) 15.873 2911.3 - 0.0611 9.4735E- 4.05148E- 31,480.43407027 0.9998935 1.00000386
7 2 56.51 05 06 2 9 7
 Cálculo factor de POYNTING
COMPONENTE Ps Kpa VL P Kpa TK FP
N2 29715.5582 0.034707 9684.376094 231.3 0.696651
CO2 1273.5453 0.037417 1.17777597
C1 9936.5015 0.037831 0.99505305
C2 728.7274 0.055205 1.29311538
C3 102.3587 0.075642 1.45768677
iC4 26.1969 0.097704 1.63335037
nC4 15.1669 0.096647 1.62560449
iC5 3.8172 0.117106 1.80295261
nC5 2.3992 0.116126 1.79423486
C6 (+) 0.3844 0.131287 1.93679924
C7 (+) 0.0611 0.147113 2.09750003
FLASH
COMP z P Kpa T K β Ps ɸis ɸi ƴ FP k xi yi xi yi Norm
v Norm
N2 0.009982 9684.3760 231. 0. 29715.55 1.067796 1 1 0.696651 2.282527 0.006082 0.013882 6.07E- 1.39E-02
53 94 3 5 82 54 5 22 84 03
CO2 0.013596     1273.545 1.011442 1 1 1.1777759 0.156655 0.023509 0.003682 2.35E- 3.69E-03
28 3 25 66 82 65 92 02
C1 0.922380     9936.501 1.090987 1 1 0.9950530 1.113853 0.872700 0.97206 8.71E- 9.74E-01
12 5 79 52 26 24 01
C2 0.046972     728.7274 1.008594 1 1 1.2931153 0.098140 0.085548 0.008395 8.54E- 8.41E-03
34 9 79 32 89 8 02
C3 0.006486     102.3587 1.001669 1 1 1.4576867 0.015432 0.012775 0.000197 1.28E- 1.98E-04
56 12 74 69 95 17 02
iC4 0.000255     26.1969 1.000645 1 1 1.6333503 0.004421 0.000509 2.2522E- 5.09E- 2.26E-06
84 9 71 17 42 06 04
nC4 0.000278     15.1669 1.000403 1 1 1.6256044 0.002546 0.000556 1.4162E- 5.55E- 1.42E-06
73 3 95 92 05 06 04
iC5 0.000029     3.8172 1.000139 1 1 1.8029526 0.000710 5.7953E- 4.119E-08 5.78E- 4.13E-08
00 53 09 75 05 05
nC5 0.000016     2.3992 1.000093 1 1 1.7942348 0.000444 3.2075E- 1.4259E- 3.20E- 1.43E-08
04 23 62 55 05 08 05
C6 (+) 0.000002     0.3844 1.000019 1 1 1.9367992 7.6869E- 4.7694E- 3.6662E- 4.76E- 3.67E-10
38 81 37 05 06 10 06
C7 (+) 0.000000     0.0611 1.000003 1 1 2.0975000 1.3231E- 3.4515E- 4.5667E- 3.45E- 4.57E-12
17 87 33 05 07 12 07
 
                Σ ≈1 1.001777 0.998222    
55 45
Σ x- y ≈ 0 0.003555
11
Segunda Iteración
PARÁMETROS PENG ROBINSONG
COM Pc Tc w ai bi α Ai Bi Am Bm aα ∑(yj(aα)i
P Kpa K j)
N2 3390 126. 0.04 148.5030 0.024081 0.715289 0.278091 0.1212541 0.6049557 0.135137 231.0750 156.668963
2 0 94 05 39 59 18 12 38 3
CO2 7380 304. 0.22 396.0891 0.026654 1.189200 1.233157 0.1342137 329.912505
1 5 72 82 35 53 15
C1 4600 190. 0.00 249.1107 0.026774 0.922444 0.601593 0.1348174 230.431091
4 8 95 71 07 53 02
C2 4880 305. 0.09 604.1360 0.040482 1.140311 1.803552 0.2038384 398.983115
4 8 26 28 64 78 23
C3 4250 369. 0.15 1017.094 0.056285 1.267985 3.376341 0.2834097 545.900222
8 2 66 13 9 47 69
iC4 3660 408. 0.17 1439.068 0.072145 1.340161 5.049043 0.3632693 667.566652
2 6 3 23 44 23 48
nC4 3800 425. 0.19 1503.901 0.072381 1.377768 5.424581 0.3644571 691.947627
2 3 55 14 66 9 71
iC5 3390 460. 0.22 1976.457 0.087851 1.456785 7.537955 0.4423565 815.674486
4 7 24 94 44 65 44
nC5 3370 469. 0.25 2069.320 0.090158 1.493532 8.091202 0.4539703 845.07768
7 1 27 44 96 77 61
C6 3010 507. 0.29 2704.718 0.109064 1.593477 11.28336 0.5491694 997.95138
5 6 61 97 5 37 77
(+)
C7 2740 540. 0.35 3367.719 0.127555 1.703387 15.01826 0.6422753 1151.33056
3 1 13 78 51 92 36
(+)

FUGACIDAD EN LA SATURACION
COM Aan Ban Can Ps Kpa Ai Bi Vs Zi ɸis
P
N2 14.934 588.72 -6.60 29715.558 0.8532967 0.37205636 0.067321814 1 1.06779653
2 2 6 8 6
CO2 22.589 3103.3 -0.16 1273.5453 0.1621665 0.01764979 1.261330244 0.8352042 1.01144225
8 9 7 5 1 1
C1 15.224 897.84 -7.16 9936.5015 0.6172555 0.13832727 0.108107592 0.5585205 1.09098778
3 6 5 9
C2 15.663 1511.4 - 728.7274 0.1357132 0.01533838 2.28752395 0.8667227 1.00859490
7 2 17.16 6 5 3
C3 15.726 1872.4 - 102.3587 0.0356861 0.00299549 18.158434983 0.9663905 1.00166912
0 6 25.16 3 1 2 5
iC4 15.538 2032.7 - 26.1969 0.0136579 0.00098266 72.476093957 0.9871733 1.0006459
1 3 33.15 8 7 6
nC4 15.678 2154.9 - 15.1669 0.0084955 0.00057078 125.796442009 0.9920053 1.00040330
2 0 34.42 4 3 9 3
iC5 15.633 2348.6 - 3.8172 0.0029711 0.00017435 502.437483089 0.9971797 1.00013953
8 7 40.05 5 8 5
nC5 15.833 2477.0 - 2.3992 0.0020045 0.00011246 800.100787536 0.9980876 1.00009323
3 7 39.94 5 8 4 2
C6 (+) 15.836 2697.5 - 0.3844 0.0004478 2.17954E- 5,001.793688886 0.9995538 1.00001981
6 5 48.78 1 05 3 4
C7 (+) 15.873 2911.3 - 0.0611 9.4735E- 4.05148E- 31,480.43407027 0.9998935 1.00000386
7 2 56.51 05 06 2 9 7

FUGACIDAD MOLAR PARCIAL

COMP y P Kpa TK V Z ɸvi
N2 1.1740E-02 9684.376094 231.3 0.11112888 0.55956177 1.0531639
CO2 3.4357E-03     1.0000000
C1 9.7803E-01     0.6229175
 C2 6.6555E-03     1.0000000
C3 1.3592E-04     1.0000000
iC4 1.3892E-06     1.0000000
nC4 9.8378E-07     1.0000000
iC5 1.8906E-08     1.0000000
nC5 7.7992E-09     1.0000000
C6 (+) 2.0364E-10     1.0000000
C7 (+) 2.3172E-12     1.0000000

Calculo Coeficiente de actividad

COM x P Kpa TK δ VL δ √(J/m3) Ɵ ƴ
P √(J/m3)
N2 0.007295 9684.3760 231. 9081.9 0.03470 11847.02 0.859370 1.135471386
05 94 3 7 33 9
CO2 0.029133     14564 0.03741 0.926472 1.151158043
54 7 5
C1 0.837281     11618 0.03783 0.936723 0.998941633
18 1 45
C2 0.108623     12375 0.05520 1.366916 0.954700326
71 5 49
C3 0.016197     13091 0.07564 1.872951 0.831457287
78 2 68
iC4 0.000644     14027 0.09770 2.419223 0.745007557
93 4 06
nC4 0.000703     14470 0.09664 2.393050 0.839658431
46 7 96
iC5 0.000073     13857 0.11710 2.899630 0.554847887
31 6 88
nC5 0.000040     14439 0.11612 2.875365 0.661301585
57 6 36
C6 0.000006     14989 0.13128 3.250762 0.671660916
(+) 03 7 9
C7 0.000000     15203 0.14711 3.642626 0.613573703
(+) 44 3 32

Cálculo factor de POYNTING

COMPONENTE Ps Kpa VL P Kpa TK FP
N2 29715.5582 0.034707 9684.376094 231. 0.696651
3
CO2 1273.5453 0.037417 1.17777597
C1 9936.5015 0.037831 0.99505305
C2 728.7274 0.055205 1.29311538
C3 102.3587 0.075642 1.45768677
iC4 26.1969 0.097704 1.63335037
nC4 15.1669 0.096647 1.62560449
iC5 3.8172 0.117106 1.80295261
nC5 2.3992 0.116126 1.79423486
C6 (+) 0.3844 0.131287 1.93679924
C7 (+) 0.0611 0.147113 2.09750003
 FLASH
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi Norm
Norm
N2 0.009982 9684.3760 231. 0. 29715.55 1.067796 1.05316 1.1354713 0.696651 2.460912 0.0057687 0.014196 7.30E- 1.17E-02
53 94 3 5 82 54 39 86 94 3 33 03
CO2 0.013596     1273.545 1.011442 1 1.1511580 1.1777759 0.180335 0.023038 0.004154 2.91E- 3.44E-03
28 3 25 43 66 61 57 02
C1 0.922380     9936.501 1.090987 0.62291 0.9989416 0.9950530 1.786230 0.6620988 1.182661 8.37E- 9.78E-01
12 5 79 75 33 52 74 7 36 01
C2 0.046972     728.7274 1.008594 1 0.9547003 1.2931153 0.093694 0.0858966 0.008048 1.09E- 6.66E-03
34 9 26 79 6 4 05 01
C3 0.006486     102.3587 1.001669 1 0.8314572 1.4576867 0.012831 0.0128087 0.000164 1.62E- 1.36E-04
56 12 87 74 62 6 36 02
iC4 0.000255     26.1969 1.000645 1 0.7450075 1.6333503 0.003293 0.0005099 1.6798E- 6.45E- 1.39E-06
84 9 57 71 81 9 06 04
nC4 0.000278     15.1669 1.000403 1 0.8396584 1.6256044 0.002138 0.0005562 1.1896E- 7.03E- 9.84E-07
73 3 31 95 54 8 06 04
iC5 0.000029     3.8172 1.000139 1 0.5548478 1.8029526 0.000394 5.7971E- 2.2861E- 7.33E- 1.89E-08
00 53 87 09 36 05 08 05
nC5 0.000016     2.3992 1.000093 1 0.6613015 1.7942348 0.000293 3.208E-05 9.431E-09 4.06E- 7.80E-09
04 23 85 62 98 05
C6 0.000002     0.3844 1.000019 1 0.6716609 1.9367992 5.163E-05 4.7695E- 2.4625E- 6.03E- 2.04E-10
(+) 38 81 16 37 06 10 06
C7 0.000000     0.0611 1.000003 1 0.6135737 2.0975000 8.1182E- 3.4515E- 2.802E-12 4.36E- 2.32E-12
(+) 17 87 03 33 06 07 07
                  Σ ≈1 0.7907724 1.209227    
3 57
Σ x- y ≈ 0 -
0.4184551
5
 Iteraciones
FLASH
1ra Iteración
COMP Z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.5 29715.558 1.0677965 1 1 0.696651 2.2825275 0.0060822 0.0138828 0.0060714 0.0139075
3 9 5 2 4 2 4 3 6
CO2 0.0135962 1273.5453 1.0114422 1 1 1.1777759 0.1566558 0.0235096 0.0036829 0.0234679 0.0036894
8 2 5 7 2 5 2 3 8
C1 0.9223801 9936.5014 1.0909877 1 1 0.9950530 1.1138532 0.8727002 0.97206 0.8711517 0.9737909
2 5 9 5 6 4 2 7
C2 0.0469723 728.72738 1.0085949 1 1 1.2931153 0.0981403 0.0855488 0.0083958 0.0853970 0.0084107
4 3 8 2 9 9 5
C3 0.0064865 102.35870 1.0016691 1 1 1.4576867 0.0154326 0.0127759 0.0001971 0.0127532 0.0001975
6 7 2 7 9 5 7 8 2
iC4 0.0002558 26.196856 1.0006459 1 1 1.6333503 0.0044211 0.0005094 2.2522E- 0.0005085 2.2563E-
4 9 7 7 2 06 2 06
nC4 0.0002787 15.166878 1.0004033 1 1 1.6256044 0.0025469 0.0005560 1.4162E- 0.0005550 1.4187E-
3 8 9 2 5 06 6 06
iC5 2.8997E- 3.8171740 1.0001395 1 1 1.8029526 0.0007107 5.7953E-05 4.119E-08 5.785E-05 4.1263E-
05 4 3 1 5 08
nC5 1.6045E- 2.3992445 1.0000932 1 1 1.7942348 0.0004445 3.2075E-05 1.4259E- 3.2018E- 1.4285E-
05 8 3 6 5 08 05 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 1 1.9367992 7.6869E- 4.7694E-06 3.6662E- 4.7609E- 3.6727E-
06 1 4 05 10 06 10
C7 (+) 1.7258E- 0.0610890 1.0000038 1 1 2.0975000 1.3231E- 3.4515E-07 4.5667E- 3.4454E- 4.5748E-
07 8 7 3 05 12 07 12
Σ ≈1 1.0017775 0.9982224
5 5
Σ x- y ≈ 0 0.0035551
1
2da Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.5 29715.558 1.0677965 1.0531639 1.1354713 0.696651 2.4609129 0.0057687 0.0141963 0.0072950 0.01174
3 9 5 2 4 9 4 3 3 5
CO2 0.0135962 1273.5453 1.0114422 1 1.1511580 1.1777759 0.1803356 0.023038 0.0041545 0.0291335 0.0034357
8 2 5 4 7 1 7 4 2
C1 0.9223801 9936.5014 1.0909877 0.6229175 0.9989416 0.9950530 1.7862307 0.6620988 1.1826613 0.8372811 0.9780304
2 5 9 3 5 4 7 6 8 3
C2 0.0469723 728.72738 1.0085949 1 0.9547003 1.2931153 0.0936946 0.0858966 0.0080480 0.1086237 0.0066555
4 3 3 8 4 5 1 3
C3 0.0064865 102.35870 1.0016691 1 0.8314572 1.4576867 0.0128316 0.0128087 0.0001643 0.0161977 0.0001359
6 7 2 9 7 2 6 6 8 2
iC4 0.0002558 26.196856 1.0006459 1 0.7450075 1.6333503 0.0032938 0.0005099 1.6798E- 0.0006449 1.3892E-
 4 9 6 7 1 9 06 3 06
nC4 0.0002787 15.166878 1.0004033 1 0.8396584 1.6256044 0.0021385 0.0005562 1.1896E- 0.0007034 9.8378E-
3 8 3 9 4 8 06 6 07
iC5 2.8997E- 3.8171740 1.0001395 1 0.5548478 1.8029526 0.0003943 5.7971E-05 2.2861E- 7.3309E- 1.8906E-
05 4 3 9 1 6 08 05 08
nC5 1.6045E- 2.3992445 1.0000932 1 0.6613015 1.7942348 0.0002939 3.208E-05 9.431E-09 4.0568E- 7.7992E-
05 8 3 8 6 8 05 09
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.6716609 1.9367992 5.163E-05 4.7695E-06 2.4625E- 6.0314E- 2.0364E-
06 1 2 4 10 06 10
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.6135737 2.0975000 8.1182E- 3.4515E-07 2.802E-12 4.3647E- 2.3172E-
07 8 7 3 06 07 12
Σ ≈1 0.7907724 1.2092275
3 7
Σ x- y ≈ 0 -
0.4184551
5
3ra Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.7 29715.558 1.0677965 1.0610862 1.1420502 0.696651 2.4566910 0.0049426 0.0121424 0.0063054 0.0111131
3 9 5 2 4 6 5 3 2 9 2
CO2 0.0135962 1273.5453 1.0114422 1 1.1346510 1.1777759 0.1777497 0.0320346 0.0056941 0.0408672 0.0052114
8 2 5 9 7 1 4 3 2
C1 0.9223801 9936.5014 1.0909877 0.6229542 0.9974238 0.9950530 1.7834114 0.5957034 1.0623843 0.7599514 0.9723212
2 5 9 6 5 4 8 9 6
C2 0.0469723 728.72738 1.0085949 1 0.9632458 1.2931153 0.0945332 0.128279 0.0121266 0.1636482 0.0110986
4 3 6 8 6 3 1
C3 0.0064865 102.35870 1.0016691 1 0.8472782 1.4576867 0.0130757 0.0209817 0.0002743 0.0267668 0.0002510
6 7 2 6 7 8 1 5 9
iC4 0.0002558 26.196856 1.0006459 1 0.7631184 1.6333503 0.0033738 0.0008461 2.8547E- 0.0010794 2.6127E-
4 9 7 7 8 3 06 3 06
nC4 0.0002787 15.166878 1.0004033 1 0.8553418 1.6256044 0.0021784 0.0009244 2.0138E- 0.0011792 1.8431E-
3 8 8 9 8 1 06 9 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.5762967 1.8029526 0.0004096 9.6564E-05 3.9553E- 0.0001231 3.62E-08
05 4 3 7 1 08 9
nC5 1.6045E- 2.3992445 1.0000932 1 0.6811826 1.7942348 0.0003028 5.3445E-05 1.6184E- 6.8181E- 1.4812E-
05 8 3 7 6 2 08 05 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.6919620 1.9367992 5.3191E- 7.9486E-06 4.2279E- 1.014E-05 3.8695E-
06 1 5 4 05 10 10
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.6347628 2.0975000 8.3986E- 5.7524E-07 4.8313E- 7.3385E- 4.4217E-
07 8 7 2 3 06 12 07 12
Σ ≈1 0.7838704 1.0926269
9 3
Σ x- y ≈ 0 -
0.3087564
5
4ta Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.9 29715.558 1.0677965 1.0846499 1.1477960 0.696651 2.4154114 0.0043901 0.0106039 0.0047829 0.0105080
3 9 5 2 4 6 1 8 1 2 2
CO2 0.0135962 1273.5453 1.0114422 1 1.0997143 1.1777759 0.1722766 0.0533085 0.0091838 0.0580784 0.0091007
8 2 5 7 5 2 1 3 7
C1 0.9223801 9936.5014 1.0909877 0.6234170 0.9901751 0.9950530 1.7691363 0.5450701 0.9643034 0.5938415 0.9555833
2 5 9 4 5 8 6 5 8 6
C2 0.0469723 728.72738 1.0085949 1 0.9810432 1.2931153 0.0962799 0.2516574 0.0242295 0.2741750 0.0240104
4 3 6 8 4 5 8 5
C3 0.0064865 102.35870 1.0016691 1 0.8854984 1.4576867 0.0136656 0.0577614 0.0007893 0.0629298 0.0007822
6 7 2 4 7 2 6 5 1 1
iC4 0.0002558 26.196856 1.0006459 1 0.8117164 1.6333503 0.0035887 0.0024783 8.8941E- 0.0027000 8.8136E-
4 9 9 7 4 3 06 8 06
nC4 0.0002787 15.166878 1.0004033 1 0.9002622 1.6256044 0.0022928 0.0027309 6.2618E- 0.0029753 6.2052E-
3 8 9 9 9 7 06 3 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.6334106 1.8029526 0.0004501 0.0002888 1.3002E- 0.0003146 1.2884E-
05 4 3 2 1 9 07 4 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7370438 1.7942348 0.0003276 0.0001599 5.2417E- 0.0001742 5.1943E-
05 8 3 2 6 5 8 08 9 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7530957 1.9367992 5.789E-05 2.3836E-05 1.3799E- 2.5969E- 1.3674E-
06 1 4 4 09 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7002288 2.0975000 9.2648E- 1.7256E-06 1.5988E- 1.88E-06 1.5843E-
07 8 7 6 3 06 11 11
Σ ≈1 0.9178713 1.0091254
2 1
Σ x- y ≈ 0 -
0.0912540
9
5ta Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.95 29715.558 1.0677965 1.1011376 1.1498595 0.696651 2.3835223 0.0043133 0.0102809 0.0041098 0.0103077
3 9 5 2 4 7 7 3 1 5 7
CO2 0.0135962 1273.5453 1.0114422 1 1.0768248 1.1777759 0.1686908 0.0646652 0.0109084 0.0616148 0.0109369
8 2 5 7 7 8 8 4 3 4
C1 0.9223801 9936.5014 1.0909877 0.6239917 0.9840902 0.9950530 1.7566453 0.5366378 0.9426823 0.5113230 0.9451451
2 5 9 3 8 5 2 4 4 9 1
C2 0.0469723 728.72738 1.0085949 1 0.9889787 1.2931153 0.0970586 0.3303125 0.0320597 0.3147307 0.0321434
4 3 2 8 9 3 4 6
C3 0.0064865 102.35870 1.0016691 1 0.9052940 1.4576867 0.0139711 0.1025177 0.0014322 0.0976816 0.0014360
6 7 2 6 7 2 9 5 3
iC4 0.0002558 26.196856 1.0006459 1 0.8371955 1.6333503 0.0037013 0.0047805 1.7695E- 0.0045550 1.7741E-
4 9 8 7 8 5 05 3 05
nC4 0.0002787 15.166878 1.0004033 1 0.9225437 1.6256044 0.0023496 0.0053364 1.2539E- 0.0050846 1.2571E-
3 8 4 9 4 1 05 8 05
iC5 2.8997E- 3.8171740 1.0001395 1 0.6654724 1.8029526 0.0004729 0.0005747 2.7186E- 0.0005476 2.7257E-
 05 4 3 7 1 8 7 07 6 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7669126 1.7942348 0.0003409 0.0003188 1.087E-07 0.0003037 1.0898E-
05 8 3 7 6 3 3 9 07
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7853036 1.9367992 6.0366E- 4.7643E-05 2.876E-09 4.5395E- 2.8835E-
06 1 9 4 05 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7351903 2.0975000 9.7274E- 3.4509E-06 3.3568E- 3.2881E- 3.3656E-
07 8 7 3 06 11 06 11
Σ ≈1 1.0495083 0.9973943
3
Σ x- y ≈ 0 0.0521140
3

6ta Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.93 29715.558 1.0677965 1.0932746 1.1564851 0.696651 2.4144975 0.0043112 0.0104094 0.0043863 0.010396
3 9 5 2 4 7 7 1 5
CO2 0.0135962 1273.5453 1.0114422 1 1.0833441 1.1777759 0.1697121 0.0596767 0.0101278 0.0607168 0.0101148
8 2 5 6 7 7 1 6 4 2
C1 0.9223801 9936.5014 1.0909877 0.6237282 0.9888390 0.9950530 1.7658678 0.5386925 0.9512598 0.5480815 0.9500348
2 5 9 2 7 5 8 3 3 8 4
C2 0.0469723 728.72738 1.0085949 1 0.9846351 1.2931153 0.0966324 0.2938192 0.0283924 0.2989403 0.0283559
4 3 9 8 2 7 7 5
C3 0.0064865 102.35870 1.0016691 1 0.8917648 1.4576867 0.0137623 0.0783410 0.0010781 0.0797064 0.0010767
6 7 2 4 7 3 5 6 9 7
iC4 0.0002558 26.196856 1.0006459 1 0.8156105 1.6333503 0.0036059 0.0034877 1.2577E- 0.0035485 1.256E-05
4 9 2 7 5 3 05 2
nC4 0.0002787 15.166878 1.0004033 1 0.8996092 1.6256044 0.0022912 0.0038642 8.8539E- 0.0039316 8.8425E-
3 8 3 9 3 6 06 1 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.6415624 1.8029526 0.0004559 0.0004117 1.8775E- 0.0004189 1.8751E-
05 4 3 1 1 9 5 07 2 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7401941 1.7942348 0.0003290 0.0002282 7.5095E- 0.0002321 7.4998E-
05 8 3 3 6 5 1 08 9 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7524058 1.9367992 5.7837E- 3.4043E-05 1.969E-09 3.4637E- 1.9664E-
06 1 2 4 05 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.6987979 2.0975000 9.2459E- 2.4651E-06 2.2792E- 2.508E-06 2.2762E-
07 8 7 7 3 06 11 11
Σ ≈1 0.9828692 1.0012894
4 1
Σ x- y ≈ 0 -
0.0184201
8
7ma Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.935 29715.558 1.0677965 1.0950305 1.1536074 0.696651 2.4046277 0.0043152 0.0103765 0.0043265 0.0103746
3 9 5 2 4 2 8 6 3 1 7 2
CO2 0.0135962 1273.5453 1.0114422 1 1.0827694 1.1777759 0.1696221 0.0608071 0.0103142 0.0609670 0.0103123
 8 2 5 6 7 4 8 4 3 6
C1 0.9223801 9936.5014 1.0909877 0.6237786 0.9874811 0.9950530 1.7633002 0.5382434 0.9490848 0.5396584 0.9489118
2 5 9 5 4 5 9 4 1 1 4
C2 0.0469723 728.72738 1.0085949 1 0.9858138 1.2931153 0.0967480 0.3021517 0.0292326 0.3029460 0.0292272
4 3 7 8 9 1 2 7
C3 0.0064865 102.35870 1.0016691 1 0.8956852 1.4576867 0.0138228 0.0832417 0.0011506 0.0834605 0.0011504
6 7 2 9 7 3 4 4 7 3
iC4 0.0002558 26.196856 1.0006459 1 0.8223486 1.6333503 0.0036357 0.0037403 1.3599E- 0.0037501 1.3596E-
4 9 7 4 4 05 7 05
nC4 0.0002787 15.166878 1.0004033 1 0.9072153 1.6256044 0.0023106 0.0041502 9.5896E- 0.0041611 9.5878E-
3 8 3 9 5 06 6 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.6486175 1.8029526 0.000461 0.0004431 2.043E-07 0.0004443 2.0426E-
05 4 3 1 7 3 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7486378 1.7942348 0.0003328 0.0002456 8.176E-08 0.0002463 8.1745E-
05 8 3 4 6 1 7 1 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7631850 1.9367992 5.8665E- 3.6659E-05 2.1506E- 3.6756E- 2.1502E-
06 1 4 4 05 09 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7107411 2.0975000 9.4039E- 2.6547E-06 2.4964E- 2.6616E- 2.496E-11
07 8 7 7 3 06 11 06
Σ ≈1 0.9973780 1.0001822
2 8
Σ x- y ≈ 0 -
0.0028042
5
8va Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.94 29715.558 1.0677965 1.0969207 1.1537719 0.696651 2.4008262 0.0043088 0.0103446 0.0042535 0.0103532
3 9 5 2 4 7 6 7 8 1 7
CO2 0.0135962 1273.5453 1.0114422 1 1.0802286 1.1777759 0.1692241 0.0620634 0.0105026 0.0612670 0.0105113
8 2 5 4 7 6 3 4 6
C1 0.9223801 9936.5014 1.0909877 0.6238460 0.9867725 0.9950530 1.7618445 0.5374756 0.9469484 0.5305785 0.9477348
2 5 9 6 3 5 8 1 9 1 6
C2 0.0469723 728.72738 1.0085949 1 0.9867098 1.2931153 0.0968360 0.3110218 0.0301181 0.3070306 0.0301431
4 3 4 8 2 5 2 9 3
C3 0.0064865 102.35870 1.0016691 1 0.8979527 1.4576867 0.0138578 0.0888248 0.0012309 0.0876850 0.0012319
6 7 2 2 7 3 9 2 6 4
iC4 0.0002558 26.196856 1.0006459 1 0.8252965 1.6333503 0.0036487 0.0040333 1.4717E- 0.0039816 1.4729E-
4 9 7 7 8 9 05 3 05
nC4 0.0002787 15.166878 1.0004033 1 0.9098195 1.6256044 0.0023172 0.0044828 1.0388E- 0.0044252 1.0396E-
3 8 1 9 3 05 8 05
iC5 2.8997E- 3.8171740 1.0001395 1 0.6523112 1.8029526 0.0004636 0.0004798 2.2245E- 0.0004736 2.2263E-
05 4 3 1 1 3 07 4 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7521020 1.7942348 0.0003343 0.0002660 8.8943E- 0.0002626 8.9017E-
05 8 3 8 6 5 2 08 1 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7669427 1.9367992 5.8954E- 3.9711E-05 2.3411E- 3.9202E- 2.3431E-
06 1 3 4 05 09 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7148206 2.0975000 9.4579E- 2.8759E-06 2.7199E- 2.839E-06 2.7222E-
 07 8 7 5 3 06 11 11
Σ ≈1 1.0129992 0.9991702
1 6
Σ x- y ≈ 0 0.0138289
5
9na Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.936 29715.558 1.0677965 1.0954007 1.1546693 0.696651 2.4060276 0.0043101 0.0103703 0.0043088 0.0103706
3 9 5 2 4 6 5 8 7 8 2
CO2 0.0135962 1273.5453 1.0114422 1 1.0816803 1.1777759 0.1694515 0.0610776 0.0103497 0.0610585 0.0103499
8 2 5 1 7 2 3 3 2
C1 0.9223801 9936.5014 1.0909877 0.6237950 0.9875873 0.9950530 1.7634436 0.5379617 0.9486651 0.5377934 0.9486854
2 5 9 5 6 5 3 4 7 3
C2 0.0469723 728.72738 1.0085949 1 0.9858889 1.2931153 0.0967554 0.3039039 0.0294043 0.3038089 0.029405
4 3 5 8 6 7 7 3
C3 0.0064865 102.35870 1.0016691 1 0.8955366 1.4576867 0.0138205 0.0843110 0.0011652 0.0842847 0.0011652
6 7 2 4 7 4 7 2 5
iC4 0.0002558 26.196856 1.0006459 1 0.8215954 1.6333503 0.0036324 0.0037958 1.3788E- 0.0037946 1.3788E-
4 9 7 7 1 1 05 2 05
nC4 0.0002787 15.166878 1.0004033 1 0.9059974 1.6256044 0.0023075 0.0042130 9.7215E- 0.0042117 9.7217E-
3 8 9 2 06 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.6481295 1.8029526 0.0004606 0.0004500 2.0732E- 0.0004499 2.0732E-
05 4 3 8 1 6 5 07 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7475682 1.7942348 0.0003323 0.0002494 8.2913E- 0.0002494 8.2914E-
05 8 3 5 6 3 9 08 1 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7614743 1.9367992 5.8534E- 3.7232E-05 2.1793E- 3.722E-05 2.1794E-
06 1 8 4 05 09 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7087954 2.0975000 9.3781E- 2.6961E-06 2.5285E- 2.6953E- 2.5285E-
07 8 7 9 3 06 11 06 11
Σ ≈1 1.0003128 0.9999786
2 1
Σ x- y ≈ 0 0.0003342
1
10ma Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.934 29715.558 1.0677965 1.0946701 1.1543416 0.696651 2.4069502 0.0043138 0.0103831 0.0043382 0.0103789
3 9 5 2 4 1 2 3 5 7
CO2 0.0135962 1273.5453 1.0114422 1 1.0828131 1.1777759 0.1696289 0.0605804 0.0102762 0.0609238 0.0102721
8 2 5 7 7 9 6 6 1
C1 0.9223801 9936.5014 1.0909877 0.6237686 0.9877970 0.9950530 1.7638927 0.5383093 0.9495200 0.5413607 0.9491419
2 5 9 1 4 5 9 7 2 1 9
C2 0.0469723 728.72738 1.0085949 1 0.9855587 1.2931153 0.0967230 0.3004512 0.0290605 0.3021542 0.0290489
4 3 4 8 5 2 6 9 9
C3 0.0064865 102.35870 1.0016691 1 0.8947958 1.4576867 0.0138091 0.0822147 0.0011353 0.0826808 0.0011348
6 7 2 5 7 1 9 1 1 6
iC4 0.0002558 26.196856 1.0006459 1 0.8207751 1.6333503 0.0036287 0.0036869 1.3379E- 0.0037078 1.3374E-
4 9 1 7 9 8 05 8 05
nC4 0.0002787 15.166878 1.0004033 1 0.9054091 1.6256044 0.002306 0.0040897 9.431E-06 0.0041129 9.4272E-
3 8 2 9 6 4 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.6469920 1.8029526 0.0004598 0.0004365 2.0073E- 0.0004389 2.0065E-
05 4 3 4 1 5 1 07 8 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7466527 1.7942348 0.0003319 0.0002419 8.0315E- 0.0002433 8.0283E-
05 8 3 1 6 3 7 08 4 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7606195 1.9367992 5.8468E- 3.6105E-05 2.111E-09 3.6309E- 2.1101E-
06 1 9 4 05 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7078914 2.0975000 9.3662E- 2.6145E-06 2.4487E- 2.6293E- 2.4478E-
07 8 7 2 3 06 11 06 11
Σ ≈1 0.9943635 1.0003982
8 9
Σ x- y ≈ 0 -
0.0060347
1
11ra Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.935 29715.558 1.0677965 1.0952144 1.1540237 0.696651 2.4050914 0.0043131 0.0103734 0.0043180 0.0103725
3 9 5 5 2 4 7 5 3 1 2 9 9
CO2 0.0135962 1273.5453 1.0114422 1 1.0823017 1.1777759 0.1695488 0.0609390 0.0103321 0.0610094 0.0103313
8 2 5 5 7 7 1 4 1 2
C1 0.9223801 9936.5014 1.0909877 0.6237863 0.9875103 0.9950530 1.7633306 0.5381146 0.9488741 0.5387363 0.9487986
2 5 9 8 7 5 4 8 5 1
C2 0.0469723 728.72738 1.0085949 1 0.9858579 1.2931153 0.0967524 0.3030241 0.0293183 0.3033742 0.0293159
4 3 8 1 4 2 2 8
C3 0.0064865 102.35870 1.0016691 1 0.8956651 1.4576867 0.0138225 0.0837721 0.0011579 0.0838689 0.0011578
6 7 2 2 7 2 4 4 2 5
iC4 0.0002558 26.196856 1.0006459 1 0.8221041 1.6333503 0.0036346 0.0037678 1.3695E- 0.0037721 1.3694E-
4 9 7 6 4 05 9 05
nC4 0.0002787 15.166878 1.0004033 1 0.9067837 1.6256044 0.0023095 0.0041813 9.6569E- 0.0041862 9.6561E-
3 8 5 9 7 06 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.6484889 1.8029526 0.0004609 0.0004465 2.0583E- 0.0004471 2.0582E-
05 4 3 1 1 1 8 07 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7482785 1.7942348 0.0003326 0.0002475 8.2351E- 0.0002478 8.2344E-
05 8 3 6 5 6 08 5 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7625804 1.9367992 5.8619E- 3.6943E-05 2.1656E- 3.6986E- 2.1654E-
06 1 4 05 09 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7100501 2.0975000 9.3947E- 2.6752E-06 2.5133E- 2.6783E- 2.5131E-
07 8 7 3 06 11 06 11
Σ ≈1 0.9988460 1.0000795
6 6
Σ x- y ≈ 0 -0.0012335

12da Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
 Norm Norm
N2 0.0099825 9684.3760 231.3206 0.935 29715.558 1.0677965 1.0953253 1.1541673 0.696651 2.4051472 0.0043122 0.0103715 0.0043133 0.0103713
3 9 5 8 2 4 4 7 7 3 4 4 5
CO2 0.0135962 1273.5453 1.0114422 1 1.0820751 1.1777759 0.1695133 0.0610162 0.0103430 0.0610319 0.0103428
8 2 5 5 7 7 3 7 8 8
C1 0.9223801 9936.5014 1.0909877 0.6237907 0.9875005 0.9950530 1.7633008 0.5380515 0.9487467 0.5381904 0.9487299
2 5 9 3 7 5 4 5 5 1 6
C2 0.0469723 728.72738 1.0085949 1 0.9858982 1.2931153 0.0967563 0.3035475 0.0293701 0.3036258 0.0293696
4 3 2 8 7 2 6 6 4
C3 0.0064865 102.35870 1.0016691 1 0.8957226 1.4576867 0.0138234 0.0840925 0.0011624 0.0841142 0.0011624
6 7 2 1 7 1 5 5 5 3
iC4 0.0002558 26.196856 1.0006459 1 0.8221060 1.6333503 0.0036346 0.0037845 1.3755E- 0.0037854 1.3755E-
4 9 5 7 7 05 8 05
nC4 0.0002787 15.166878 1.0004033 1 0.9067139 1.6256044 0.0023093 0.0042002 9.6997E- 0.0042013 9.6995E-
3 8 9 2 4 06 2 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.6485501 1.8029526 0.0004609 0.0004486 2.0681E- 0.0004487 2.068E-07
05 4 3 8 1 6 5 07 7
nC5 1.6045E- 2.3992445 1.0000932 1 0.7482567 1.7942348 0.0003326 0.0002487 8.2731E- 0.0002487 8.273E-08
05 8 3 6 4 1 08 8
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7624852 1.9367992 5.8612E- 3.7116E-05 2.1754E- 3.7125E- 2.1754E-
06 1 8 4 05 09 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7099352 2.0975000 9.3932E- 2.6877E-06 2.5247E- 2.6884E- 2.5246E-
07 8 7 2 3 06 11 06 11
Σ ≈1 0.9997419 1.0000177
8
Σ x- y ≈ 0 -
0.0002757
2
13ra Iteración
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi
Norm Norm
N2 0.0099825 9684.3760 231.3206 0.935 29715.558 1.0677965 1.0953623 1.1541889 0.696651 2.4051108 0.0043120 0.0103709 0.0043118 0.0103709
3 9 5 9 2 4 8 3 7 3 4 3
CO2 0.0135962 1273.5453 1.0114422 1 1.0820129 1.1777759 0.1695036 0.0610414 0.0103467 0.0610388 0.0103467
8 2 5 3 7 2 8 5 8
C1 0.9223801 9936.5014 1.0909877 0.6237921 0.9874905 0.9950530 1.7632789 0.5380340 0.9487040 0.5380104 0.9487069
2 5 9 1 5 6 2 7 1 2
C2 0.0469723 728.72738 1.0085949 1 0.9859150 1.2931153 0.0967580 0.3037217 0.0293875 0.3037084 0.0293876
4 3 2 8 2 7 2 5 1
C3 0.0064865 102.35870 1.0016691 1 0.8957588 1.4576867 0.0138239 0.0841996 0.0011639 0.0841959 0.0011639
6 7 2 7 7 7 2 7 3 8
iC4 0.0002558 26.196856 1.0006459 1 0.8221433 1.6333503 0.0036348 0.0037900 1.3776E- 0.0037899 1.3776E-
4 9 1 7 4 8 05 1 05
nC4 0.0002787 15.166878 1.0004033 1 0.9067372 1.6256044 0.0023093 0.0042065 9.7146E- 0.0042063 9.7146E-
3 8 9 8 6 06 8 06
iC5 2.8997E- 3.8171740 1.0001395 1 0.6486046 1.8029526 0.0004609 0.0004493 2.0715E- 0.0004493 2.0715E-
05 4 3 9 1 9 5 07 3 07
nC5 1.6045E- 2.3992445 1.0000932 1 0.7482971 1.7942348 0.0003326 0.0002491 8.2864E- 0.0002490 8.2865E-
 05 8 3 7 6 6 08 9 08
C6 (+) 2.3849E- 0.3843536 1.0000198 1 0.7625195 1.9367992 5.8614E- 3.7174E-05 2.1789E- 3.7172E- 2.1789E-
06 1 3 4 05 09 05 09
C7 (+) 1.7258E- 0.0610890 1.0000038 1 0.7099707 2.0975000 9.3937E- 2.6919E-06 2.5287E- 2.6918E- 2.5287E-
07 8 7 9 3 06 11 06 11
Σ ≈1 1.0000438 0.999997
7
Σ x- y ≈ 0 4.6878E-05
 Resultados
PARAMETROS PENG ROBINSONG
COM Pc Tc w ai bi α Ai Bi Am Bm aα ∑(yj(aα)ij)
P Kpa K
N2 3390 126. 0.04 148.5030 0.024081 0.715289 0.278091 0.1212541 0.6311650 0.136877 241.0862 160.027583
2 0 94 05 39 59 18 95 28 32
CO2 7380 304. 0.22 396.0891 0.026654 1.189200 1.233157 0.1342137 336.984715
1 5 72 82 35 53 15
C1 4600 190. 0.00 249.1107 0.026774 0.922444 0.601593 0.1348174 235.370755
4 8 95 71 07 53 02
C2 4880 305. 0.09 604.1360 0.040482 1.140311 1.803552 0.2038384 407.535411
4 8 26 28 64 78 23
C3 4250 369. 0.15 1017.094 0.056285 1.267985 3.376341 0.2834097 557.60172
8 2 66 13 9 47 69
iC4 3660 408. 0.17 1439.068 0.072145 1.340161 5.049043 0.3632693 681.876098
2 6 3 23 44 23 48
nC4 3800 425. 0.19 1503.901 0.072381 1.377768 5.424581 0.3644571 706.779685
2 3 55 14 66 9 71
iC5 3390 460. 0.22 1976.457 0.087851 1.456785 7.537955 0.4423565 833.158658
4 7 24 94 44 65 44
nC5 3370 469. 0.25 2069.320 0.090158 1.493532 8.091202 0.4539703 863.192117
7 1 27 44 96 77 61
C6 3010 507. 0.29 2704.718 0.109064 1.593477 11.28336 0.5491694 1019.3427
5 6 61 97 5 37 77
(+)
C7 2740 540. 0.35 3367.719 0.127555 1.703387 15.01826 0.6422753 1176.0096
3 1 13 78 51 92 36
(+)

Fugacidad en la saturación
COMP
Aan
Ban
Can
Ps Kpa
Ai
Bi
Vs
Zi
ɸis
N2
14.9342
588.72
-6.60
29715.5582
0.85329676
0.372056368
0.067321814
1
1.067796536
CO2
22.5898
3103.39
-0.16
1273.5453
0.16216657
0.017649795
1.261330244
0.83520421
1.011442251
C1
15.2243
897.84
 -7.16
9936.5015
0.61725556
0.13832727
0.108107592
0.55852055
1.090987789
C2
15.6637
1511.42
-17.16
728.7274
0.13571326
0.01533838
2.28752395
0.86672275
1.008594903
C3
15.7260
1872.46
-25.16
102.3587
0.03568613
0.002995491
18.158434983
0.96639052
1.001669125
iC4
15.5381
2032.73
-33.15
26.1969
0.01365798
0.000982667
72.476093957
0.98717336
1.0006459
nC4
15.6782
2154.90
-34.42
15.1669
0.00849554
0.000570783
125.796442009
0.99200539
1.000403303
iC5
15.6338
2348.67
-40.05
3.8172
0.00297115
0.000174358
502.437483089
0.99717975
1.00013953
nC5
15.8333
2477.07
-39.94
2.3992
 0.00200455
0.000112468
800.100787536
0.99808764
1.000093232
C6 (+)
15.8366
2697.55
-48.78
0.3844
0.00044781
2.17954E-05
5,001.793688886
0.99955383
1.000019814
C7 (+)
15.8737
2911.32
-56.51
0.0611
9.4735E-05
4.05148E-06
31,480.434070272
0.99989359
1.000003867

Fugacidad molar parcial

COMP
y
P Kpa
TK
V
Z
ɸvi

N2
0.01037094
9684.376094
231.3
0.10440569
0.52570884
1.0953624

CO2
0.01034676
 
 

1.0000000
C1
0.94870695
 
 

0.6237922

C2
0.02938759
 
 

1.0000000

C3
0.00116397
 
 

1.0000000

iC4
0.00001378
 
 

1.0000000

nC4
0.00000971
 
 

1.0000000

iC5
0.00000021
 
 
 1.0000000

nC5
0.00000008
 
 

1.0000000

C6 (+)
0.00000000
 
 

1.0000000

C7 (+)
0.00000000
 
 

1.0000000

Calculo Coeficiente de actividad

COMP
x
P Kpa
TK
δ √(J/m3)
VL
δ √(J/m3)
Ɵ
ƴ
N2
0.00431180
9684.376094
231.3
9081.9
0.034707
12273.9885
0.74183036
1.154199796
CO2
0.06103912
 
 
 14564
0.037417

0.79975413
1.082006201
C1
0.53800958
 
 
11618
0.037831

0.808603
0.987492935
C2
0.30370884
 
 
12375
0.055205

1.17995635
0.98591411
C3
0.08419609
 
 
13091
0.075642

1.61677852
0.895753037
iC4
0.00378992
 
 
14027
0.097704

2.08833358
0.822129835
nC4
0.00420638
 
 
14470
0.096647

2.06574117
0.906719477
iC5
 0.00044933
 
 
13857
0.117106

2.50303357
0.648592626
nC5
0.00024909
 
 
14439
0.116126

2.48208696
0.748279402
C6 (+)
0.00003717
 
 
14989
0.131287

2.80613946
0.762494461
C7 (+)
0.00000269
 
 
15203
0.147113

3.14440573
0.709942641

Calculo factor de POYNTING

COMPONENTE Ps Kpa VL P Kpa TK FP
N2 29715.5582 0.034707 9684.376094 231. 0.696651
3
CO2 1273.5453 0.037417 1.17777597
C1 9936.5015 0.037831 0.99505305
C2 728.7274 0.055205 1.29311538
C3 102.3587 0.075642 1.45768677
iC4 26.1969 0.097704 1.63335037
nC4 15.1669 0.096647 1.62560449
iC5 3.8172 0.117106 1.80295261
nC5 2.3992 0.116126 1.79423486
C6 (+) 0.3844 0.131287 1.93679924
C7 (+) 0.0611 0.147113 2.09750003
 FLASH
COMP
z
P Kpa
T K
β
Ps
ɸis
ɸiv
ƴ
FP
k
xi
yi
xi Norm
yi Norm
N2
0.00998253
9684.376094
231.3
0.9359
29715.5582
1.06779654
1.09536242
1.154199796
0.696651
2.40513343
0.00431199
0.01037091
4.31E-03
1.04E-02
CO2
0.01359628
 
 

1273.5453
1.01144225
1
1.082006201
1.177775966
0.16950257
0.06104175
0.01034673
6.10E-02
1.03E-02
C1
0.92238012
 
 

9936.5015
1.09098779
0.62379215
0.987492935
0.995053052
1.7632832
0.53803278
0.94870415
5.38E-01
9.49E-01
C2
0.04697234
 
 

728.7274
1.0085949
1
0.98591411
1.293115379
0.09675793
0.30372194
0.02938751
3.04E-01
2.94E-02
C3
0.00648656
 
 

102.3587
1.00166912
1
0.895753037
1.457686774
0.01382388
0.08419972
0.00116397
8.42E-02
1.16E-03
iC4
0.00025584
 
 

26.1969
1.0006459
1
0.822129835
1.633350371
0.00363478
0.00379008
1.3776E-05
3.79E-03
1.38E-05
nC4
0.00027873
 
 

15.1669
1.0004033
1
0.906719477
1.625604495
0.00230934
0.00420656
9.7144E-06
4.21E-03
9.71E-06
iC5
0.00002900
 
 

3.8172
1.00013953
1
0.648592626
1.802952609
0.00046099
0.00044935
2.0714E-07
4.49E-04
 2.07E-07
nC5
0.00001604
 
 

2.3992
1.00009323
1
0.748279402
1.794234862
0.00033265
0.0002491
8.2862E-08
2.49E-04
8.29E-08
C6 (+)
0.00000238
 
 

0.3844
1.00001981
1
0.762494461
1.936799237
5.8612E-05
3.7174E-05
2.1788E-09
3.72E-05
2.18E-09
C7 (+)
0.00000017
 
 

0.0611
1.00000387
1
0.709942641
2.097500033
9.3933E-06
2.6919E-06
2.5286E-11
2.69E-06
2.53E-11
 
 
 
 

 
 
 
 
 
Σ ≈1
1.00004312
0.99999705
 
 
Σ x- y ≈ 0
4.6075E-05
 FASE LIQUIDA
Ejemplo para N2

Suponer β=0.5634

Coeficiente de fugacidad Molar Parcial

R 2 Tc N 22
a N 2=0.45724 =148.50
Pc N 2

8.3142 ¿126.2 N 22
a N 2=0.45724 =148.50
3390N 2

R TcN 2
b N 2=0.0778 =0.0241
Pc N 2

8.314∗126.2 N 2
b N 2=0.0778 =0.0241
3390 N 2

S N 2=0.37464 +1.54226 ω−0.26992ω 2=0.4355

S N 2=0.37464 +1.54226∗0.040−0.26992∗0.0402=0.4355

[ ( √ )]
α N 2= 1+ S N 2 1−
T
Tc N 2
=0.5587

[
α N 2= 1+0.4355 N 2 ( √
1−
231.32065
126.2N 2 )] =0.7153
 n n
aα =∑ ∑ yi y j ( aα )ij =335.05
i=1 j=1

ai α i P
A N 2= =0.1173
R2T 2

bi P
BN 2= =0.0891
RT

n n
A=∑ ∑ y i y j A ij =0.474
i=1 j=1

B=∑ x i B i=0.1209

RT 2 aα 2 bRT RT b 2 aαb 3
(
V 3 + b−
P
V +) (
P
−3 b2 −
P
V+
P
−
P
+ b =0 ) ( )
m3
V =0.1873
Kmol

PV
z= =¿
RT

9684.37609∗0.1044
z= =0.6924
8.314∗314.7752

n
Bi Bi 2 zi +2.414 B
V
ϕ =e
B
( z −1 ) −ln ( z −B ) +
[
A
−
2,828 B B aα
∑
j=1
y j ( aα ) ij
](
ln
z i −0.414 B )
N2

ϕ VN 2 =1.1968
Coeficiente de fugacidad en la saturación

Ban
Aan−
PSN 2=e T +Can

PSN 2=453095.45mmHg

PSN 2=60407.6 Kpa

RT aN 2 α N 2 2 b N 2 RT RT b N 22 aN 2 α N 2 b N 2
(
V 3 + b N 2− S
PN 2
V 2
) (
+ S
PN 2
−3 b N2
2
−
PN2S
V +
) (S
PN 2
− S
PN2
+b N 23 =0
)
m3
V N 2=0.059
Kmol

P SN 2 V N 2
z N 2= =¿
RT

60407.6∗0.059
z N 2= =1
8.314∗314.7752

Ai z i +2.414 Bi
S
ϕ =e
z i −1−ln ( zi −Bi )−
2 √ 2 Bi (
ln
z i −0.414 Bi )
N2

ϕ SN 2 =1.5304

Coeficiente de Actividad

V LN 2
Θ N 2= L L L L L L L L L L L
x N 2 V N 2+ x CO 2 V CO 2+ x C 1 V C1 + x C 2 V C 2 + x C 3 V C 3 + x iC 4 V Ic 4 + x nC 4 V nC 4 + x iC5 V iC5 + x nC 5 V nC5 + x C 6 V C 6 + x C 7 V C 7

Θ N 2=0.5175

n
x j V Lj δ j
δ =∑ n
=13141.5
j=1 L
∑ xk V k
k=1
 L
VN2 2
[ δ − δ́ ] +1+ln ( ΘN 2 )−Θ N 2
RT N 2
γ N 2=e

γ N 2=1.043

Factor de POYNTING

L
Vi s
∗(P− Pi )
R∗T
FP N 2=e

FP N 2=0.5104

Constante de Equilibrio

γ N 2∗ϕsN 2∗PsN 2∗FP N 2

k N 2= V
ϕN 2∗P

1.043∗1.5304∗60407.6∗0.5104
k N 2=
1.1968∗9684.37609

k N 2=4.25
Fracción del Líquido

zN 2
xN 2=
1+ β∗(kN 2−1)

3.2380∗10−3
xN 2=
1+0.5634∗(4.25−1)

xN 2=0.00114

Facción del vapor

zN 2∗kN 2
yN 2=
1+ B∗(kN 2−1)

3.2380∗10−3∗4.25
yN 2=
1+0.5634∗(4.25−1)
 yN 2=0.0047

Tablas Primeras dos Iteraciones

Primera Iteración

Parámetros PENG ROBINSONG

COMP Pc Kpa Tc K w ai bi α
N2 3390 126. 0.040 148.503094 0.02408105 0.55871822
2
CO2 7380 304. 0.225 396.089172 0.02665482 0.9755129
1
C1 4600 190. 0.008 249.110795 0.02677471 0.79105763
4
C2 4880 305. 0.098 604.136026 0.04048228 0.98412401
4
C3 4250 369. 0.152 1017.09466 0.05628513 1.09548573
8
iC4 3660 408. 0.176 1439.0683 0.07214523 1.16146351
2
nC4 3800 425. 0.193 1503.90155 0.07238114 1.19343552
2
iC5 3390 460. 0.227 1976.45724 0.08785194 1.26128912
4
nC5 3370 469. 0.251 2069.32027 0.09015844 1.28838528
7
C6 3010 507. 0.296 2704.71861 0.10906497 1.37252309
(+) 5
C7 2740 540. 0.351 3367.71913 0.12755578 1.4615817
(+) 3

FUGACIDAD EN LA SATURACIÓN
COM Aan Ban Can Ps Kpa Ai Bi Vs Zi ɸis
P
N2 14.934 588.72 -6.60 60407.591 0.7317227 0.55581500 0.059055301 1 1.530364668
2 7 7 5
CO2 22.589 3103.3 -0.16 44834.373 2.5290871 0.45661508 0.043533358 0.7457557 0.548227774
8 9 6 9 4 9
C1 15.224 897.84 -7.16 29454.457 0.8473804 0.30132782 0.07989376 0.8991398 1.008615274
3 8 3 5
C2 15.663 1511.4 - 5272.5802 0.4576510 0.08155516 0.234216213 0.4718495 1.18894169
7 2 17.16 5 9
C3 15.726 1872.4 - 1402.0273 0.2280611 0.03015182 1.426184098 0.7640036 1.023824968
 0 6 25.16 3
iC4 15.538 2032.7 - 547.4420 0.1335831 0.01509069 4.154779844 0.8690594 1.008394258
1 3 33.15 8
nC4 15.678 2154.9 - 394.2129 0.1032942 0.01090233 5.976448593 0.9001966 1.005702764
2 0 34.42 7 8
iC5 15.633 2348.6 - 159.1188 0.0579095 0.00534116 15.54463606 0.9450728 1.002785158
8 7 40.05 5 6 3 8
nC5 15.833 2477.0 - 122.1663 0.0475501 0.00420844 20.46034667 0.9550538 1.002244899
3 7 39.94 3 1 7 9
C6 (+) 15.836 2697.5 - 39.6568 0.0214924 0.00165259 64.66379084 0.9798118 1.001005058
6 5 48.78 8 6 4 1
C7 (+) 15.873 2911.3 - 13.2781 0.0095415 0.00064714 195.3376288 0.9910234 1.000449118
7 2 56.51 8 55 2

Calculo factor de Poynting

COMPONENTE Ps Kpa VL P Kpa TK FP
N2 60407.5917 0.034707 9684.376094 314. 0.51035588
8
CO2 44834.3736 0.037417 0.60500114
C1 29454.4578 0.037831 0.75143394
C2 5272.5802 0.055205 1.09752621
C3 1402.0273 0.075642 1.27045563
iC4 547.4420 0.097704 1.40648778
nC4 394.2129 0.096647 1.40925887
iC5 159.1188 0.117106 1.53143571
nC5 122.1663 0.116126 1.52848731
C6 (+) 39.6568 0.131287 1.62224308
C7 (+) 13.2781 0.147113 1.72221878
 FLASH
COM z P Kpa T K β Ps ɸis ɸi ƴ FP k xi yi xi yi
P v Norm Norm
N2 0.0032380 9684.37609 314. 0. 60407.591 1.5303646 1 1 0.51035587 4.8717829 0.0011029 0.0053731 1.05E- 5.65E-03
2 4 8 5 7 7 8 1 4 03
CO2 0.0090393     44834.373 0.5482277 1 1 0.60500114 1.5355242 0.0071301 0.0109485 6.80E- 1.15E-02
3 6 7 8 5 2 03
C1 0.4831026     29454.457 1.0086152 1 1 0.75143394 2.3051316 0.2923348 0.6738704 2.79E- 7.08E-01
6 8 7 5 9 2 01
C2 0.2382399     5272.5802 1.1889416 1 1 1.09752620 0.7104393 0.2785716 0.1979082 2.66E- 2.08E-01
7 9 5 4 7 7 01
C3 0.1747188     1402.0273 1.0238249 1 1 1.27045562 0.1883085 0.2940630 0.0553745 2.81E- 5.82E-02
0 7 6 5 1 8 01
iC4 0.0219916     547.4420 1.0083942 1 1 1.40648777 0.0801738 0.0407187 0.0032645 3.88E- 3.43E-03
4 6 7 6 1 8 02
nC4 0.0355956     394.2129 1.0057027 1 1 1.40925886 0.0576925 0.0673080 0.0038831 6.42E- 4.08E-03
2 6 9 4 6 7 02
iC5 0.0143276     159.1188 1.0027851 1 1 1.53143570 0.0252322 0.0279501 0.0007052 2.67E- 7.41E-04
7 6 6 7 4 02
nC5 0.0105925     122.1663 1.0022449 1 1 1.52848731 0.0193248 0.0207835 0.0004016 1.98E- 4.22E-04
8 1 3 2 4 02
C6 (+) 0.0068621     39.6568 1.0010050 1 1 1.62224307 0.0066496 0.0136337 9.0659E- 1.30E- 9.52E-05
8 6 9 5 1 05 02
C7 (+) 0.0022915     13.2781 1.0004491 1 1 1.72221877 0.0023623 0.0045722 1.0801E- 4.36E- 1.13E-05
3 2 9 6 6 05 03
 
                Σ ≈1 1.0481689 0.9518310    
9 1
Σ x- y ≈ 0 0.0963379
7
 Segunda Iteración

Parámetros PENG ROBINSONG

COM Pc Tc w ai bi α Ai Bi Am Bm aα ∑(yj(aα)i
P Kpa K j)
N2 3390 126. 0.04 148.5030 0.024081 0.558718 0.117307 0.0891067 0.4597854 0.119271 325.2047 164.496086
2 0 94 05 22 75 07 95 89 74
CO2 7380 304. 0.22 396.0891 0.026654 0.975512 0.546291 0.0986304 354.97811
1 5 72 82 9 37
C1 4600 190. 0.00 249.1107 0.026774 0.791057 0.278611 0.0990740 253.50891
4 8 95 71 63 49 34
C2 4880 305. 0.09 604.1360 0.040482 0.984124 0.840587 0.1497959 439.930056
4 8 26 28 01 48 07
C3 4250 369. 0.15 1017.094 0.056285 1.095485 1.575311 0.2082709 603.098266
8 2 66 13 73 54 57
iC4 3660 408. 0.17 1439.068 0.072145 1.161463 2.363117 0.2669578 738.664997
2 6 3 23 51 59 22
nC4 3800 425. 0.19 1503.901 0.072381 1.193435 2.537562 0.2678307 765.443629
2 3 55 14 52 33 24
iC5 3390 460. 0.22 1976.457 0.087851 1.261289 3.524523 0.3250770 902.100799
4 7 24 94 12 65 82
nC5 3370 469. 0.25 2069.320 0.090158 1.288385 3.769396 0.3336117 932.912181
7 1 27 44 28 49 93
C6 3010 507. 0.29 2704.718 0.109064 1.372523 5.248559 0.4035713 1100.84178
5 6 61 97 09 22 12
(+)
C7 2740 540. 0.35 3367.719 0.127555 1.461581 6.959167 0.4719925 1267.60373
3 1 13 78 7 89 46
(+)

Fugacidad en la saturación
COMP Aan Ban Can Ps Kpa Ai Bi Vs Zi ɸis
N2 14.934 588.72 -6.60 60407.591 0.7317227 0.55581500 0.059055301 1 1.53036466
2 7 7 5 8
CO2 22.589 3103.3 -0.16 44834.373 2.5290871 0.45661508 0.043533358 0.7457557 0.54822777
8 9 6 9 4 9 4
C1 15.224 897.84 -7.16 29454.457 0.8473804 0.30132782 0.07989376 0.8991398 1.00861527
3 8 3 5 4
C2 15.663 1511.4 - 5272.5802 0.4576510 0.08155516 0.234216213 0.4718495 1.18894169
7 2 17.16 5 9
C3 15.726 1872.4 - 1402.0273 0.2280611 0.03015182 1.426184098 0.7640036 1.02382496
0 6 25.16 3 8
iC4 15.538 2032.7 - 547.4420 0.1335831 0.01509069 4.154779844 0.8690594 1.00839425
1 3 33.15 8 8
nC4 15.678 2154.9 - 394.2129 0.1032942 0.01090233 5.976448593 0.9001966 1.00570276
2 0 34.42 7 8 4
iC5 15.633 2348.6 - 159.1188 0.0579095 0.00534116 15.544636063 0.9450728 1.00278515
8 7 40.05 5 6 8 8
nC5 15.833 2477.0 - 122.1663 0.0475501 0.00420844 20.460346677 0.9550538 1.00224489
3 7 39.94 3 1 9 9
C6 (+) 15.836 2697.5 - 39.6568 0.0214924 0.00165259 64.663790844 0.9798118 1.00100505
6 5 48.78 8 6 1 8
C7 (+) 15.873 2911.3 - 13.2781 0.0095415 0.00064714 195.33762885 0.9910234 1.00044911
7 2 56.51 8 5 2 8

Fugacidad molar parcial

COMP y P Kpa TK V Z ɸvi
N2 5.65E-03 9684.376094 314.8 0.19076357 0.7058793 1.178384578
 CO2 1.15E-02     0.621083648
C1 7.08E-01     0.884622029
C2 2.08E-01     0.519292118
C3 5.82E-02     1.000000000
iC4 3.43E-03     1.000000000
nC4 4.08E-03     1.000000000
iC5 7.41E-04     1.000000000
nC5 4.22E-04     1.000000000
C6 (+) 9.52E-05     1.000000000
C7 (+) 1.13E-05     1.000000000

Cálculo Coeficiente de actividad

COMP x P Kpa TK δ √(J/m3) VL δ √(J/m3) Ɵ ƴ
N2 1.05E-03 9684.376094 314.8 9081.9 0.034707 13067.0228 0.52968948 1.04649747
CO2 6.80E-03     14564 0.037417 0.57104882 0.905478636
C1 2.79E-01     11618 0.037831 0.57736718 0.90819712
C2 2.66E-01     12375 0.055205 0.84252479 0.996231558
C3 2.81E-01     13091 0.075642 1.15442913 0.98925163
iC4 3.88E-02     14027 0.097704 1.4911338 0.944410898
nC4 6.42E-02     14470 0.096647 1.47500214 0.986436494
iC5 2.67E-02     13857 0.117106 1.78724224 0.836402904
nC5 1.98E-02     14439 0.116126 1.77228572 0.890033315
C6 (+) 1.30E-02     14989 0.131287 2.00366908 0.883922027
C7 (+) 4.36E-03     15203 0.147113 2.2452015 0.835309207

Calculo factor de POYNTING

COMPONENTE Ps Kpa VL P Kpa TK FP
N2 60407.5917 0.034707 9684.376094 314. 0.51035588
8
CO2 44834.3736 0.037417 0.60500114
C1 29454.4578 0.037831 0.75143394
C2 5272.5802 0.055205 1.09752621
C3 1402.0273 0.075642 1.27045563
iC4 547.4420 0.097704 1.40648778
nC4 394.2129 0.096647 1.40925887
iC5 159.1188 0.117106 1.53143571
nC5 122.1663 0.116126 1.52848731
C6 (+) 39.6568 0.131287 1.62224308
C7 (+) 13.2781 0.147113 1.72221878
 FLASH
COMP z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi Norm
Norm
N2 0.003238 9684.3760 314. 0. 60407.59 1.530364 1.17838 1.04649 0.5103558 4.326523 0.0012158 0.005260 1.26E- 5.08E-03
02 94 8 5 17 67 46 75 78 42 1 24 03
CO2 0.009039     44834.37 0.548227 0.62108 0.90547 0.6050011 2.238642 0.0055821 0.012496 5.78E- 1.21E-02
33 36 77 36 86 4 79 7 49 03
C1 0.483102     29454.45 1.008615 0.88462 0.90819 0.7514339 2.366563 0.2870005 0.679204 2.97E- 6.56E-01
66 78 27 20 71 4 19 81 01
C2 0.238239     5272.580 1.188941 0.51929 0.99623 1.0975262 1.362936 0.2016473 0.274832 2.09E- 2.66E-01
97 2 69 21 16 05 32 9 55 01
C3 0.174718     1402.027 1.023824 1.00000 0.98925 1.2704556 0.186284 0.2945647 0.054872 3.05E- 5.30E-02
80 3 97 00 16 26 54 4 86 01
iC4 0.021991     547.4420 1.008394 1.00000 0.94441 1.4064877 0.075717 0.0408874 0.003095 4.24E- 2.99E-03
64 26 00 09 77 06 1 87 02
nC4 0.035595     394.2129 1.005702 1.00000 0.98643 1.4092588 0.056910 0.0673578 0.003833 6.98E- 3.71E-03
62 76 00 65 69 02 9 34 02
iC5 0.014327     159.1188 1.002785 1.00000 0.83640 1.5314357 0.021104 0.0280630 0.000592 2.91E- 5.72E-04
67 16 00 29 06 35 9 25 02
nC5 0.010592     122.1663 1.002244 1.00000 0.89003 1.5284873 0.017199 0.0208269 0.000358 2.16E- 3.46E-04
58 9 00 33 11 74 4 22 02
C6 (+) 0.006862     39.6568 1.001005 1.00000 0.88392 1.6222430 0.005877 0.0136441 8.0197E- 1.41E- 7.75E-05
18 06 00 20 79 77 7 05 02
C7 (+) 0.002291     13.2781 1.000449 1.00000 0.83530 1.7222187 0.001973 0.0045740 9.0259E- 4.74E- 8.72E-06
53 12 00 92 79 3 3 06 03
                  Σ ≈1 0.9653641 1.034635    
4 86
Σ x- y ≈ 0 -
0.0692717
1
 Iteraciones
FLASH
1ra Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.003238 9684.376 314.77 0.5 60407.59 1.530364 1 1 0.510355 4.871782 0.0011029 0.005373 0.001052 0.005645
02 09 52 17 67 88 9 1 14 23 06
CO2 0.009039 44834.37 0.548227 1 1 0.605001 1.535524 0.0071301 0.010948 0.006802 0.011502
33 36 77 14 28 5 52 48 58
C1 0.483102 29454.45 1.008615 1 1 0.751433 2.305131 0.2923348 0.673870 0.278900 0.707972
66 78 27 94 65 9 42 54 75
C2 0.238239 5272.580 1.188941 1 1 1.097526 0.710439 0.2785716 0.197908 0.265769 0.207923
97 19 69 21 34 7 27 81 75
C3 0.174718 1402.027 1.023824 1 1 1.270455 0.188308 0.2940630 0.055374 0.280549 0.058176
8 27 97 63 55 1 58 24 9
iC4 0.021991 547.4419 1.008394 1 1 1.406487 0.080173 0.0407187 0.003264 0.038847 0.003429
64 73 26 78 86 1 58 47 79
nC4 0.035595 394.2129 1.005702 1 1 1.409258 0.057692 0.0673080 0.003883 0.064214 0.004079
62 3 76 87 54 6 17 9 69
iC5 0.014327 159.1187 1.002785 1 1 1.531435 0.025232 0.0279501 0.000705 0.026665 0.000740
67 61 16 71 27 24 64 93
nC5 0.010592 122.1663 1.002244 1 1 1.528487 0.019324 0.0207835 0.000401 0.019828 0.000421
58 33 9 31 83 2 64 4 96
C6 (+) 0.006862 39.65684 1.001005 1 1 1.622243 0.006649 0.0136337 9.0659E- 0.013007 9.5247E-
18 47 06 08 65 1 05 17 05
C7 (+) 0.002291 13.27806 1.000449 1 1 1.722218 0.002362 0.0045722 1.0801E- 0.004362 1.1348E-
53 08 12 78 36 6 05 14 05
Σ ≈1 1.0481689 0.951831
9 01
Σ x- y ≈ 0 0.0963379
7
2da Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.0032380 9684.3760 314.775 0.5 60407.591 1.5303646 1.1783845 1.0464974 0.5103558 4.3265234 0.00121581 0.0052602 0.0012594 0.0050841
2 9 2 7 7 8 7 8 2 4 3 4
CO2 0.0090393 44834.373 0.5482277 0.6210836 0.9054786 0.6050011 2.2386427 0.00558217 0.0124964 0.0057824 0.0120781
3 6 7 5 4 4 9 9 5 5
C1 0.4831026 29454.457 1.0086152 0.8846220 0.9081971 0.7514339 2.3665631 0.2870005 0.6792048 0.2972976 0.6564675
6 8 7 3 2 4 9 1 6
C2 0.2382399 5272.5801 1.1889416 0.5192921 0.9962315 1.0975262 1.3629363 0.20164739 0.2748325 0.2088822 0.2656321
7 9 9 2 6 1 2 5 5
C3 0.1747188 1402.0272 1.0238249 1 0.9892516 1.2704556 0.1862845 0.29456474 0.0548728 0.3051332 0.0530359
7 7 3 3 4 6 9 1
iC4 0.0219916 547.44197 1.0083942 1 0.9444109 1.4064877 0.0757170 0.04088741 0.0030958 0.0423543 0.0029922
4 3 6 8 6 7 9 4
nC4 0.0355956 394.21293 1.0057027 1 0.9864364 1.4092588 0.0569100 0.06735789 0.0038333 0.0697746 0.0037050
2 6 9 7 2 4 1
iC5 0.0143276 159.11876 1.0027851 1 0.8364029 1.5314357 0.0211043 0.02806309 0.0005922 0.0290699 0.0005724
7 1 6 1 5 5 5 3
nC5 0.0105925 122.16633 1.0022449 1 0.8900333 1.5284873 0.0171997 0.02082694 0.0003582 0.0215741 0.0003462
8 3 2 1 4 2 8 3
C6 (+) 0.0068621 39.656844 1.0010050 1 0.8839220 1.6222430 0.0058777 0.01364417 8.0197E-05 0.0141337 7.7513E-05
8 7 6 3 8 7
C7 (+) 0.0022915 13.278060 1.0004491 1 0.8353092 1.7222187 0.0019733 0.00457403 9.0259E-06 0.0047381 8.7238E-06
3 8 2 1 8 4
Σ ≈1 0.96536414 1.0346358
6
Σ x- y ≈ 0 -
0.06927171
3ra Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.0032380 9684.3760 314.775 0.6 60407.591 1.5303646 1.2041328 1.0338432 0.5103558 4.1828108 0.00111284 0.0046548 0.0010838 0.0047393
2 9 2 7 7 2 4 8 1 1 4 6
CO2 0.0090393 44834.373 0.5482277 0.6175247 0.8872761 0.6050011 2.2062826 0.00524393 0.0115696 0.0051072 0.0117797
3 6 7 5 9 4 3 7 4
C1 0.4831026 29454.457 1.0086152 0.8930042 0.8951309 0.7514339 2.3106215 0.27043774 0.6248792 0.2633898 0.6362288
6 8 7 1 9 4 6 7 7 8
C2 0.2382399 5272.5801 1.1889416 0.5124012 0.9913313 1.0975262 1.3744714 0.19453197 0.2673786 0.1894622 0.272235
7 9 9 8 1 2 3 8
C3 0.1747188 1402.0272 1.0238249 1 0.9944952 1.2704556 0.1872719 0.34100577 0.0638608 0.3321188 0.0650207
7 7 5 3 6 2 3 1
iC4 0.0219916 547.44197 1.0083942 1 0.9575969 1.4064877 0.0767742 0.04930148 0.0037850 0.0480166 0.0038538
4 3 6 3 8 4 8 4 3
nC4 0.0355956 394.21293 1.0057027 1 0.9974799 1.4092588 0.0575471 0.08191784 0.0047141 0.0797829 0.0047997
2 6 3 7 5 4 8 6
iC5 0.0143276 159.11876 1.0027851 1 0.8580386 1.5314357 0.0216502 0.03469252 0.0007511 0.0337884 0.0007647
7 1 6 7 1 7 4
nC5 0.0105925 122.16633 1.0022449 1 0.9094632 1.5284873 0.0175752 0.02580125 0.0004534 0.0251288 0.0004617
8 3 3 1 2 6 4
C6 (+) 0.0068621 39.656844 1.0010050 1 0.9071999 1.6222430 0.0060325 0.01700162 0.0001025 0.0165585 0.0001044
8 7 6 1 8 6 6 4 3
C7 (+) 0.0022915 13.278060 1.0004491 1 0.862776 1.7222187 0.0020381 0.00571136 1.1641E-05 0.0055625 1.1852E-05
3 8 2 8 9 2
Σ ≈1 1.02675832 0.9821611
2
Σ x- y ≈ 0 0.0445972
 4ta Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.003238 9684.376 314.77 0.55 60407.59 1.530364 1.194603 1.047905 0.510355 4.273522 0.0011562 0.004941 0.001166 0.004906
02 09 52 17 67 93 13 88 11 6 29 35 54
CO2 0.009039 44834.37 0.548227 0.620214 0.895600 0.605001 2.217324 0.0054143 0.012005 0.005461 0.011920
33 36 77 27 69 14 97 27 58 83
C1 0.483102 29454.45 1.008615 0.890823 0.905078 0.751433 2.342017 0.2779471 0.650957 0.280374 0.646378
66 78 27 97 68 94 7 5 16 38 81
C2 0.238239 5272.580 1.188941 0.515622 0.996172 1.097526 1.372555 0.1977250 0.271388 0.199451 0.269479
97 19 69 31 38 21 14 5 54 73 79
C3 0.174718 1402.027 1.023824 1 0.991773 1.270455 0.186759 0.3161086 0.059036 0.318869 0.058621
8 27 97 07 63 35 23 08 02
iC4 0.021991 547.4419 1.008394 1 0.946387 1.406487 0.075875 0.0447228 0.003393 0.045113 0.003369
64 73 26 54 78 54 6 37 41 5
nC4 0.035595 394.2129 1.005702 1 0.985468 1.409258 0.056854 0.0739618 0.004205 0.074607 0.004175
62 3 76 37 87 17 8 04 76 47
iC5 0.014327 159.1187 1.002785 1 0.842441 1.531435 0.021256 0.0310330 0.000659 0.031304 0.000655
67 61 16 68 71 72 2 66 02 02
nC5 0.010592 122.1663 1.002244 1 0.892231 1.528487 0.017242 0.0230532 0.000397 0.023254 0.000394
58 33 9 31 21 4 49 56 69
C6 (+) 0.006862 39.65684 1.001005 1 0.884061 1.622243 0.005878 0.0151405 8.9007E- 0.015272 8.8381E-
18 47 06 63 08 7 1 05 73 05
C7 (+) 0.002291 13.27806 1.000449 1 0.835396 1.722218 0.001973 0.0050800 1.0025E- 0.005124 9.955E-06
53 08 12 94 78 51 3 05 4
Σ ≈1 0.9913429 1.007083
1 08
Σ x- y ≈ 0 -
0.0157401
7
5ta Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.0032380 9684.3760 314.775 0.56 60407.591 1.5303646 1.1957515 1.0427004 0.5103558 4.2482154 0.00114864 0.0048796 0.0011510 0.0048716
2 9 2 7 7 8 9 8 9 8 5 8
CO2 0.0090393 44834.373 0.5482277 0.6195143 0.8942851 0.6050011 2.2165692 0.00537646 0.0119173 0.0053877 0.0118977
3 6 7 8 2 4 4 3 6
C1 0.4831026 29454.457 1.0086152 0.8908405 0.9020825 0.7514339 2.3342213 0.27650677 0.645428 0.2770860 0.6443695
6 8 7 2 1 4 4 3 7
C2 0.2382399 5272.5801 1.1889416 0.515032 0.9945242 1.0975262 1.3718549 0.19717955 0.2705017 0.1975926 0.2700581
7 9 9 9 1 1 3 2 4
C3 0.1747188 1402.0272 1.0238249 1 0.9924120 1.2704556 0.1868796 0.32078942 0.0599490 0.3214614 0.0598507
7 7 1 3 6 2 5 1
iC4 0.0219916 547.44197 1.0083942 1 0.9501366 1.4064877 0.0761761 0.04556355 0.0034708 0.0456590 0.0034651
 4 3 6 1 8 2 5 1 6
nC4 0.0355956 394.21293 1.0057027 1 0.9899905 1.4092588 0.0571150 0.07541693 0.0043074 0.0755749 0.0043003
2 6 3 7 7 4 2 8
iC5 0.0143276 159.11876 1.0027851 1 0.8470635 1.5314357 0.0213733 0.03170056 0.0006775 0.0317669 0.0006764
7 1 6 3 1 4 5 7 4
nC5 0.0105925 122.16633 1.0022449 1 0.8980727 1.5284873 0.0173551 0.02355378 0.0004087 0.0236031 0.0004081
8 3 9 1 8 2 1
C6 (+) 0.0068621 39.656844 1.0010050 1 0.8923267 1.6222430 0.0059336 0.01547898 9.1847E-05 0.0155114 9.1696E-05
8 7 6 1 8 6 1
C7 (+) 0.0022915 13.278060 1.0004491 1 0.8451528 1.7222187 0.0019965 0.00519482 1.0372E-05 0.0052057 1.0355E-05
3 8 2 3 8 6
Σ ≈1 0.99790946 1.0016425
7
Σ x- y ≈ 0 -
0.00373311
6ta Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.0032380 9684.3760 314.775 0.58 60407.591 1.5303646 1.2006254 1.0404671 0.5103558 4.2219080 0.00112874 0.0047654 0.0011160 0.0048050
2 9 2 7 7 3 7 8 4 4 5 2
CO2 0.0090393 44834.373 0.5482277 0.6187023 0.8905589 0.6050011 2.2102308 0.00531121 0.011739 0.0052514 0.0118365
3 6 7 5 4 2 8
C1 0.4831026 29454.457 1.0086152 0.8923290 0.8995751 0.7514339 2.3238503 0.27327389 0.6350476 0.2702003 0.6403220
6 8 7 5 5 4 3 2 5 2
C2 0.2382399 5272.5801 1.1889416 0.5136824 0.9936151 1.0975262 1.3742017 0.19575408 0.2690056 0.1935524 0.2712398
7 9 9 3 8 1 8 1 2 4
C3 0.1747188 1402.0272 1.0238249 1 0.9934404 1.2704556 0.1870733 0.33059217 0.0618449 0.3268739 0.0623586
7 7 6 3 3 8 6 3
iC4 0.0219916 547.44197 1.0083942 1 0.9525627 1.4064877 0.0763706 0.04736567 0.0036173 0.0468329 0.0036473
4 3 6 6 8 3 5 4 9
nC4 0.0355956 394.21293 1.0057027 1 0.9918910 1.4092588 0.0572247 0.07854452 0.0044946 0.0776611 0.0045320
2 6 5 7 1 9 2 2
iC5 0.0143276 159.11876 1.0027851 1 0.8512051 1.5314357 0.0214778 0.03313085 0.0007115 0.0327582 0.0007174
7 1 6 8 1 4 8 2 9
nC5 0.0105925 122.16633 1.0022449 1 0.9016284 1.5284873 0.0174238 0.02462784 0.0004291 0.0243508 0.0004326
8 3 3 1 1 1 5 7
C6 (+) 0.0068621 39.656844 1.0010050 1 0.8964687 1.6222430 0.0059612 0.01620513 9.6602E-05 0.0160228 9.7404E-05
8 7 6 4 8 7
C7 (+) 0.0022915 13.278060 1.0004491 1 0.8500408 1.7222187 0.0020081 0.00544093 1.0926E-05 0.0053797 1.1017E-05
3 8 2 4 8 4
Σ ≈1 1.01137504 0.9917629
Σ x- y ≈ 0 0.01961213

7ma Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.0032380 9684.3760 314.775 0.57 60407.591 1.5303646 1.1987220 1.0432878 0.5103558 4.2400754 0.00113741 0.0048227 0.0011325 0.0048384
 2 9 2 7 7 2 3 8 5 3 3
CO2 0.0090393 44834.373 0.5482277 0.6192426 0.892204 0.6050011 2.2123814 0.00534537 0.011826 0.0053224 0.0118645
3 6 7 2 4 8 3 9
C1 0.4831026 29454.457 1.0086152 0.8918956 0.9015607 0.7514339 2.3301113 0.27477687 0.6402607 0.2735973 0.6423497
6 8 7 4 3 4 7 1 9 2
C2 0.2382399 5272.5801 1.1889416 0.5143263 0.9945840 1.0975262 1.3738196 0.19639309 0.2698086 0.1955500 0.2706889
7 9 9 5 3 1 1 7 7 9
C3 0.1747188 1402.0272 1.0238249 1 0.9929001 1.2704556 0.1869715 0.32561932 0.0608815 0.3242216 0.0610802
7 7 6 3 9 6
iC4 0.0219916 547.44197 1.0083942 1 0.9503232 1.4064877 0.0761910 0.04645184 0.0035392 0.0462524 0.0035507
4 3 6 4 8 8 2 4 6
nC4 0.0355956 394.21293 1.0057027 1 0.9894851 1.4092588 0.0570859 0.07695701 0.0043931 0.0766266 0.0044074
2 6 1 7 1 6 8 9
iC5 0.0143276 159.11876 1.0027851 1 0.8480969 1.5314357 0.0213994 0.03240106 0.0006933 0.0322619 0.0006956
7 1 6 1 1 1 6 7 3
nC5 0.0105925 122.16633 1.0022449 1 0.8981857 1.5284873 0.0173572 0.02407986 0.0004179 0.0239765 0.0004193
8 3 3 1 8 6 2
C6 (+) 0.0068621 39.656844 1.0010050 1 0.8918429 1.6222430 0.0059304 0.01583409 9.3903E-05 0.0157661 9.421E-05
8 7 6 8 4 3
C7 (+) 0.0022915 13.278060 1.0004491 1 0.8445694 1.7222187 0.0019951 0.00531508 1.0605E-05 0.0052922 1.0639E-05
3 8 2 5 8 8 6
Σ ≈1 1.00431099 0.9967478
5
Σ x- y ≈ 0 0.00756314

8va Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.0032380 9684.3760 314.775 0.56 60407.591 1.5303646 1.1973453 1.0433225 0.5103558 4.2450915 0.00114277 0.0048511 0.0011415 0.0048550
2 9 2 5 7 7 6 8 9 8 9 6
CO2 0.0090393 44834.373 0.5482277 0.6194057 0.8932015 0.6050011 2.2142717 0.0053612 0.0118711 0.0053556 0.0118806
3 6 7 2 4 4 6 4 6
C1 0.4831026 29454.457 1.0086152 0.8914313 0.9019622 0.7514339 2.3323633 0.27561999 0.6428459 0.2753340 0.6433603
6 8 7 5 6 4 5 4 7
C2 0.2382399 5272.5801 1.1889416 0.5146723 0.9946512 1.0975262 1.3729888 0.19677241 0.2701663 0.1965682 0.2703825
7 9 9 7 8 1 2 7 1
C3 0.1747188 1402.0272 1.0238249 1 0.9926474 1.2704556 0.1869239 0.32318702 0.0604114 0.3228517 0.0604597
7 7 3 3 9 1 2 5
iC4 0.0219916 547.44197 1.0083942 1 0.9500272 1.4064877 0.0761673 0.04600429 0.0035040 0.0459565 0.0035068
4 3 6 8 4 2 7 3
nC4 0.0355956 394.21293 1.0057027 1 0.9894521 1.4092588 0.057084 0.07618069 0.0043487 0.0761016 0.0043521
2 6 1 7 6 8
iC5 0.0143276 159.11876 1.0027851 1 0.847375 1.5314357 0.0213812 0.03204719 0.0006852 0.0320139 0.0006857
7 1 6 1 1 4 6
nC5 0.0105925 122.16633 1.0022449 1 0.8978028 1.5284873 0.0173498 0.0238141 0.0004131 0.0237894 0.0004135
8 3 6 1 8 7
C6 (+) 0.0068621 39.656844 1.0010050 1 0.8915862 1.6222430 0.0059287 0.01565459 9.2812E-05 0.0156383 9.2886E-05
8 7 6 1 8 4 5
C7 (+) 0.0022915 13.278060 1.0004491 1 0.8442713 1.7222187 0.0019944 0.00525427 1.048E-05 0.0052488 1.0488E-05
 3 8 2 8 7 2
Σ ≈1 1.00103854 0.9992004
1
Σ x- y ≈ 0 0.00183813
9na Iteración

COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm

P
N2 0.0032380 9684.3760 314.775 0.56 60407.591 1.5303646 1.1967521 1.0433461 0.5103558 4.2472920 0.0011449 0.0048627 0.0011451 0.0048617
2 9 2 3 7 7 5 4 8 2 1 8 6
CO2 0.0090393 44834.373 0.5482277 0.6194645 0.8936098 0.6050011 2.2150736 0.0053675 0.0118894 0.0053688 0.0118870
3 6 7 6 5 4 5 5 8
C1 0.4831026 29454.457 1.0086152 0.8912236 0.9021310 0.7514339 2.3333435 0.27595262 0.6438922 0.2760221 0.6437663
6 8 7 2 9 4 9 9 8 7
C2 0.2382399 5272.5801 1.1889416 0.5148154 0.9946816 1.0975262 1.3726491 0.19692484 0.2703087 0.1969744 0.2702558
7 9 9 2 5 1 9 3 8 7
C3 0.1747188 1402.0272 1.0238249 1 0.9925434 1.2704556 0.1869044 0.32222434 0.0602251 0.3223055 0.0602133
7 7 8 3 2 5 6 8
iC4 0.0219916 547.44197 1.0083942 1 0.9498999 1.4064877 0.0761571 0.04582772 0.0034901 0.0458392 0.0034894
4 3 6 3 8 4 1 7 3
nC4 0.0355956 394.21293 1.0057027 1 0.9894303 1.4092588 0.0570827 0.07587458 0.0043311 0.0758937 0.0043302
2 6 5 7 5 3 8
iC5 0.0143276 159.11876 1.0027851 1 0.8470730 1.5314357 0.0213735 0.03190781 0.0006819 0.0319158 0.0006818
7 1 6 8 1 8 8 5 5
nC5 0.0105925 122.16633 1.0022449 1 0.8976364 1.5284873 0.0173466 0.02370944 0.0004112 0.0237154 0.0004112
8 3 3 1 7 8 2
C6 (+) 0.0068621 39.656844 1.0010050 1 0.8914665 1.6222430 0.0059279 0.01558392 9.2381E-05 0.0155878 9.2362E-05
8 7 6 8 8 4 5
C7 (+) 0.0022915 13.278060 1.0004491 1 0.8441320 1.7222187 0.0019941 0.00523034 1.043E-05 0.0052316 1.0428E-05
3 8 2 6 8 4 5
Σ ≈1 0.99974801 1.0001955
9
Σ x- y ≈ 0 -
0.00044758
10ma Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.0032380 9684.3760 314.775 0.56 60407.591 1.5303646 1.1969267 1.0430761 0.5103558 4.2455735 0.00114397 0.0048568 0.0011435 0.0048583
2 9 2 4 7 7 1 2 8 4 3 1 7
CO2 0.0090393 44834.373 0.5482277 0.6194103 0.8934477 0.6050011 2.2148657 0.005364 0.0118805 0.0053618 0.0118843
3 6 7 1 2 4 2 4 1
C1 0.4831026 29454.457 1.0086152 0.8912604 0.9019393 0.7514339 2.3327513 0.2757952 0.6433616 0.2756821 0.6435655
6 8 7 2 5 4 4 1 9 6
C2 0.2382399 5272.5801 1.1889416 0.5147533 0.9945901 1.0975262 1.3726883 0.19686061 0.2702282 0.1967799 0.2703139
7 9 9 4 1 9 7 4 3
C3 0.1747188 1402.0272 1.0238249 1 0.9925990 1.2704556 0.1869148 0.32270474 0.0603183 0.3225725 0.0603374
7 7 4 3 8 2 4
iC4 0.0219916 547.44197 1.0083942 1 0.9501190 1.4064877 0.0761747 0.04591516 0.0034975 0.0458963 0.0034986
 4 3 6 7 8 1 7 5 8
nC4 0.0355956 394.21293 1.0057027 1 0.9896643 1.4092588 0.0570962 0.07602615 0.0043408 0.075995 0.0043421
2 6 7 4 1 8
iC5 0.0143276 159.11876 1.0027851 1 0.8473774 1.5314357 0.0213812 0.0319772 0.0006837 0.0319640 0.0006839
7 1 6 1 6 1 9 3
nC5 0.0105925 122.16633 1.0022449 1 0.8979714 1.5284873 0.0173531 0.02376151 0.0004123 0.0237517 0.0004124
8 3 1 4 4 8 7
C6 (+) 0.0068621 39.656844 1.0010050 1 0.8919144 1.6222430 0.0059309 0.01561912 9.2636E-05 0.0156127 9.2665E-05
8 7 6 3 8 2 2
C7 (+) 0.0022915 13.278060 1.0004491 1 0.8446609 1.7222187 0.0019953 0.00524227 1.046E-05 0.0052401 1.0464E-05
3 8 2 3 8 9 2
Σ ≈1 1.00040993 0.9996831
Σ x- y ≈ 0 0.00072683

11ra Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.00323802 9684.3760 314.7752 0.563 60407.5917 1.53036467 1.19683173 1.04322352 0.51035588 4.2465105 0.00114442 0.00485978 0.00114433 0.00486007
9 5
CO2 0.00903933 44834.3736 0.54822777 0.61943693 0.89352878 0.60500114 2.21497148 0.00536575 0.01188498 0.00536534 0.01188568

C1 0.48310266 29454.4578 1.00861527 0.89123849 0.90204115 0.75143394 2.33307204 0.27587168 0.64362851 0.27585065 0.64366654

C2 0.23823997 5272.58019 1.18894169 0.51478545 0.99463967 1.09752621 1.37267117 0.1968925 0.27026866 0.19687749 0.27028463

C3 0.1747188 1402.02727 1.02382497 1 0.99257061 1.27045563 0.18690953 0.3224644 0.06027167 0.32243981 0.06027523

iC4 0.02199164 547.441973 1.00839426 1 0.95000151 1.40648778 0.07616528 0.04587143 0.00349381 0.04586793 0.00349402

nC4 0.03559562 394.21293 1.00570276 1 0.98953664 1.40925887 0.05708888 0.07595035 0.00433592 0.07594455 0.00433618

iC5 0.01432767 159.118761 1.00278516 1 0.8472165 1.53143571 0.0213772 0.03194247 0.00068284 0.03194004 0.00068288

nC5 0.01059258 122.166333 1.0022449 1 0.89779115 1.52848731 0.01734966 0.02373546 0.0004118 0.02373365 0.00041183

C6 (+) 0.00686218 39.6568447 1.00100506 1 0.89167149 1.62224308 0.0059293 0.01560151 9.2506E-05 0.01560032 9.2512E-05

C7 (+) 0.00229153 13.2780608 1.00044912 1 0.84437399 1.72221878 0.00199472 0.0052363 1.0445E-05 0.0052359 1.0446E-05

Σ ≈1 1.00007626 0.99994092

Σ x- y ≈ 0 0.00013534

12 Iteración
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi Norm yi Norm
P
N2 0.0032380 9684.3760 314.775 0.56 60407.591 1.5303646 1.1967980 1.0432019 0.5103558 4.2465424 0.00114454 0.0048603 0.0011445 0.0048604
2 9 2 34 7 7 2 9 8 3 4 3
CO2 0.0090393 44834.373 0.5482277 0.6194385 0.8935513 0.6050011 2.2150214 0.00536604 0.0118859 0.0053659 0.0118860
3 6 7 8 3 4 8 7 3
C1 0.4831026 29454.457 1.0086152 0.8912255 0.9020395 0.7514339 2.3331017 0.27589005 0.6436795 0.2758861 0.6436866
6 8 7 7 4 4 1 5 1 8
C2 0.2382399 5272.5801 1.1889416 0.5147927 0.9946343 1.0975262 1.3726445 0.19690101 0.2702750 0.1968982 0.2702780
 7 9 9 1 9 1 3 9 9
C3 0.1747188 1402.0272 1.0238249 1 0.9925661 1.2704556 0.1869086 0.3224163 0.0602624 0.3224116 0.0602630
7 7 4 3 9 1 9 8
iC4 0.0219916 547.44197 1.0083942 1 0.9500092 1.4064877 0.0761659 0.04586256 0.0034931 0.0458619 0.0034932
4 3 6 8 8 1 6 1
nC4 0.0355956 394.21293 1.0057027 1 0.9895552 1.4092588 0.0570899 0.07593497 0.0043351 0.0759338 0.0043351
2 6 1 7 5 2 9 7
iC5 0.0143276 159.11876 1.0027851 1 0.8472160 1.5314357 0.0213771 0.03193551 0.0006826 0.0319350 0.0006827
7 1 6 3 1 9 9 5
nC5 0.0105925 122.16633 1.0022449 1 0.8978055 1.5284873 0.0173499 0.02373022 0.0004117 0.0237298 0.0004117
8 3 6 1 4 2 8 2
C6 (+) 0.0068621 39.656844 1.0010050 1 0.8917 1.6222430 0.0059294 0.01559798 9.2488E-05 0.0155977 9.2489E-05
8 7 6 8 9 5
C7 (+) 0.0022915 13.278060 1.0004491 1 0.8444078 1.7222187 0.0019948 0.0052351 1.0443E-05 0.0052350 1.0443E-05
3 8 2 4 8 3
Σ ≈1 1.00001429 0.9999889
3
Σ x- y ≈ 0 2.5362E-05
 Resultados

Parámetros PENG ROBINSONG

COM Pc Tc w ai bi α Ai Bi Am Bm aα ∑(yj(aα)i
P Kpa K j)
N2 3390 126. 0.04 148.5030 0.024081 0.558718 0.117307 0.0891067 0.4736832 0.120911 335.0346 166.727992
2 0 94 05 22 75 07 99 16 45
CO2 7380 304. 0.22 396.0891 0.026654 0.975512 0.546291 0.0986304 359.796841
1 5 72 82 9 37
C1 4600 190. 0.00 249.1107 0.026774 0.791057 0.278611 0.0990740 256.947671
4 8 95 71 63 49 34
C2 4880 305. 0.09 604.1360 0.040482 0.984124 0.840587 0.1497959 446.310343
4 8 26 28 01 48 07
C3 4250 369. 0.15 1017.094 0.056285 1.095485 1.575311 0.2082709 610.981672
8 2 66 13 73 54 57
iC4 3660 408. 0.17 1439.068 0.072145 1.161463 2.363117 0.2669578 748.320464
2 6 3 23 51 59 22
nC4 3800 425. 0.19 1503.901 0.072381 1.193435 2.537562 0.2678307 775.449134
2 3 55 14 52 33 24
iC5 3390 460. 0.22 1976.457 0.087851 1.261289 3.524523 0.3250770 913.892619
4 7 24 94 12 65 82
nC5 3370 469. 0.25 2069.320 0.090158 1.288385 3.769396 0.3336117 945.106753
7 1 27 44 28 49 93
C6 3010 507. 0.29 2704.718 0.109064 1.372523 5.248559 0.4035713 1115.23144
5 6 61 97 09 22 12
(+)
C7 2740 540. 0.35 3367.719 0.127555 1.461581 6.959167 0.4719925 1284.17323
3 1 13 78 7 89 46
(+)

Fugacidad en la saturación
COMP Aan Ban Can Ps Kpa Ai Bi Vs Zi ɸis
N2 14.934 588.72 -6.60 60407.591 0.7317227 0.55581500 0.059055301 1 1.53036466
2 7 7 5 8
CO2 22.589 3103.3 -0.16 44834.373 2.5290871 0.45661508 0.043533358 0.7457557 0.54822777
8 9 6 9 4 9 4
C1 15.224 897.84 -7.16 29454.457 0.8473804 0.30132782 0.07989376 0.8991398 1.00861527
3 8 3 5 4
C2 15.663 1511.4 - 5272.5802 0.4576510 0.08155516 0.234216213 0.4718495 1.18894169
7 2 17.16 5 9
C3 15.726 1872.4 - 1402.0273 0.2280611 0.03015182 1.426184098 0.7640036 1.02382496
0 6 25.16 3 8
iC4 15.538 2032.7 - 547.4420 0.1335831 0.01509069 4.154779844 0.8690594 1.00839425
1 3 33.15 8 8
nC4 15.678 2154.9 - 394.2129 0.1032942 0.01090233 5.976448593 0.9001966 1.00570276
2 0 34.42 7 8 4
iC5 15.633 2348.6 - 159.1188 0.0579095 0.00534116 15.544636063 0.9450728 1.00278515
8 7 40.05 5 6 8 8
nC5 15.833 2477.0 - 122.1663 0.0475501 0.00420844 20.460346677 0.9550538 1.00224489
3 7 39.94 3 1 9 9
C6 (+) 15.836 2697.5 - 39.6568 0.0214924 0.00165259 64.663790844 0.9798118 1.00100505
6 5 48.78 8 6 1 8
C7 (+) 15.873 2911.3 - 13.2781 0.0095415 0.00064714 195.33762885 0.9910234 1.00044911
7 2 56.51 8 5 2 8

Fugacidad molar parcial

COMP y P Kpa TK V Z ɸvi
N2 0.0048604 9684.376094 314. 0.18726646 0.692939 1.196798025
0 8
CO2 0.0118860     0.619438579
3
 C1 0.6436866     0.891225569
8
C2 0.2702780     0.514792709
9
C3 0.0602630     1.000000000
8
iC4 0.0034932     1.000000000
0
nC4 0.0043351     1.000000000
7
iC5 0.0006827     1.000000000
0
nC5 0.0004117     1.000000000
2
C6 0.0000924     1.000000000
(+) 9
C7 0.0000104     1.000000000
(+) 4

Calculo Coeficiente de actividad

COM x P Kpa TK δ VL δ √(J/m3) Ɵ ƴ
P √(J/m3)
N2 0.0011445 9684.37609 314. 9081.9 0.03470 13141.531 0.5174884 1.043201986
3 4 8 7 1
CO2 0.0053659     14564 0.03741 0.5578950 0.893551328
7 7 5
C1 0.2758861     11618 0.03783 0.5640678 0.902039543
1 1 7
C2 0.1968982     12375 0.05520 0.8231177 0.994634387
0 5 3
C3 0.3224116     13091 0.07564 1.1278375 0.992566144
9 2 5
iC4 0.0458619     14027 0.09770 1.4567864 0.950009285
1 4 3
nC4 0.0759338     14470 0.09664 1.4410263 0.989555206
9 7 5
iC5 0.0319350     13857 0.11710 1.7460741 0.847216026
5 6 9
nC5 0.0237298     14439 0.11612 1.7314621 0.897805559
8 6 9
C6 0.0155977     14989 0.13128 1.9575157 0.891700001
(+) 5 7 7
C7 0.0052350     15203 0.14711 2.1934846 0.844407836
(+) 3 3 4

Calculo factor de POYNTING

COMPONENTE Ps Kpa VL P Kpa TK FP
N2 60407.5917 0.034707 9684.376094 314. 0.51035588
8
CO2 44834.3736 0.037417 0.60500114
C1 29454.4578 0.037831 0.75143394
C2 5272.5802 0.055205 1.09752621
C3 1402.0273 0.075642 1.27045563
iC4 547.4420 0.097704 1.40648778
nC4 394.2129 0.096647 1.40925887
iC5 159.1188 0.117106 1.53143571
nC5 122.1663 0.116126 1.52848731
C6 (+) 39.6568 0.131287 1.62224308
C7 (+) 13.2781 0.147113 1.72221878
 FLASH
COM z P Kpa T K β Ps ɸis ɸiv ƴ FP k xi yi xi yi Norm
P Norm
N2 0.0032380 9684.37609 314. 0.563 60407.591 1.5303646 1.196798 1.043202 0.51035587 4.2465424 0.0011445 0.0048603 1.14E-03 4.86E-03
2 4 8 4 7 7 0 0 8 3 4 4
CO2 0.0090393     44834.373 0.5482277 0.619438 0.893551 0.60500114 2.2150214 0.0053660 0.0118859 5.37E-03 1.19E-02
3 6 7 6 3 8 4
C1 0.4831026     29454.457 1.0086152 0.891225 0.902039 0.75143394 2.3331017 0.2758900 0.6436795 2.76E-01 6.44E-01
6 8 7 6 5 1 5 5
C2 0.2382399     5272.5802 1.1889416 0.514792 0.994634 1.09752620 1.3726445 0.1969010 0.2702750 1.97E-01 2.70E-01
7 9 7 4 5 3 1 9
C3 0.1747188     1402.0273 1.0238249 1.000000 0.992566 1.27045562 0.1869086 0.3224163 0.0602624 3.22E-01 6.03E-02
0 7 0 1 6 9 1
iC4 0.0219916     547.4420 1.0083942 1.000000 0.950009 1.40648777 0.0761659 0.0458625 0.0034931 4.59E-02 3.49E-03
4 6 0 3 7 1 6 6
nC4 0.0355956     394.2129 1.0057027 1.000000 0.989555 1.40925886 0.0570899 0.0759349 0.0043351 7.59E-02 4.34E-03
2 6 0 2 9 5 7 2
iC5 0.0143276     159.1188 1.0027851 1.000000 0.847216 1.53143570 0.0213771 0.0319355 0.0006826 3.19E-02 6.83E-04
7 6 0 0 6 9 1 9
nC5 0.0105925     122.1663 1.0022449 1.000000 0.897805 1.52848731 0.0173499 0.0237302 0.0004117 2.37E-02 4.12E-04
8 0 6 1 4 2 2
C6 (+) 0.0068621     39.6568 1.0010050 1.000000 0.891700 1.62224307 0.0059294 0.0155979 9.2488E- 1.56E-02 9.25E-05
8 6 0 0 9 9 8 05
C7 (+) 0.0022915     13.2781 1.0004491 1.000000 0.844407 1.72221877 0.0019948 0.0052351 1.0443E- 5.24E-03 1.04E-05
3 2 0 8 9 05
                  Σ ≈1 1.0000142 0.9999889    
9 3
Σ x- y ≈ 0 2.5362E-
05
 FASE VAPOR
Simulación en PRO II

Iniciar el Simulador PRO II

Insertar la lista de componentes

Una vez insertados los componentes presionar OK

Posteriormente insertar el paquete de Fluidos

Luego insertar una corriente de la paleta PFD

Ingresar a la corriente
Insertar la composición de los compuestos de la fase vapor

Luego seleccionar la primera especificación Presión y Temperatura de trabajo, Posteriormente presionar OK

Luego presionar RUN y RUN SIMULATION

La simulación se lleva a cabo y generamos el reporte de resultados.

β=0.7579
 FASE LÍQUIDA
Simulación en PRO II

Iniciar el Simulador PRO II

Insertar la lista de componentes

Una vez insertados los componentes presionar OK

Posteriormente insertar el paquete de Fluidos

Luego insertar una corriente de la paleta PFD

Ingresar a la corriente
Insertar la composición de los compuestos de la fase Liquida

Luego seleccionar la primera especificación Presión y Temperatura de trabajo, Posteriormente presionar OK

Luego presionar RUN y RUN SIMULATION

La simulación se lleva a cabo y generamos el reporte de resultados.

β=0.5708
Calculo del error

FASE VAPOR

β Calculada β PRO II (la más Exacta) % error

0.9359 0.7579 23.4

FASE LIQUIDA

β Calculada β PRO II (la más Exacta) % error

0.5634 0.5708 1.3