Gpo . B.

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cal/g cal/mol cal/g cal/mol 4.1842 Terminar, formatear, letreros,etc.
Compues PM Cp l A B C T hli Hvi
benceno 78.114 0.416 32.4954 94 7343 3.985 1184 217.57 80.00 2599.8 9942 1 0 2.6051 1.32655
toluno 92.141 0.408 37.5935 86.1 7933 4.05 1328 217.63 110.6 4157.9 12091 0 1 2.3498
P= 1.0133 Datos P,x > T por iteración > y P= 1.33 Datos P y T > x > y P= 0.7 Datos P y T > x > y
t Pv1 Pv2 x1 P y1 hl Hv k1 K2 t Pv1 Pv2 x y t Pv1 Pv2 x y
80.012 1.0133 0.3890 1.0000 1.01324 1.0000 2600 9943 1.0000 0.3839 89.116 1.33 0.5276 1 1.0000 68.5 0.7 0.257 1 1.0000
82.079 1.0794 0.4175 0.9000 1.01317 0.9588 2709 10051 1.0652 0.412 93.0 1.489 0.5976 0.822 0.9200 71.0 0.7611 0.2822 0.87242 0.9486
84.296 1.154 0.4500 0.8000 1.01317 0.9112 2825 10173 1.1389 0.4441 96.0 1.619 0.6566 0.7 0.8517 74.0 0.8388 0.3147 0.73514 0.8809
86.685 1.2388 0.4872 0.7000 1.01331 0.8558 2949 10309 1.2226 0.4808 99.0 1.758 0.7201 0.588 0.7767 77.3 0.9309 0.3537 0.59991 0.7978
89.257 1.3354 0.5300 0.6000 1.01324 0.7908 3082 10462 1.3179 0.5231 100.8 1.848 0.7615 0.523 0.7271 81.0 1.0444 0.4024 0.46353 0.6916
92.048 1.4468 0.5798 0.5000 1.01329 0.7139 3226 10637 1.4279 0.5722 105.0 2.063 0.8617 0.39 0.6046 84.0 1.1438 0.4455 0.36445 0.5955
95.76 1.6059 0.6517 0.3789 1.01325 0.6005 3415 10885 1.5849 0.6432 107.3 2.192 0.922 0.321 0.5295 87.0 1.2503 0.4923 0.27402 0.4894
98.406 1.7273 0.7071 0.3000 1.01319 0.5114 3549 11074 1.7047 0.6979 111.0 2.408 1.0245 0.221 0.3998 90.0 1.3644 0.5429 0.19123 0.3727
102.07 1.9067 0.7900 0.2000 1.01332 0.3763 3733 11352 1.8818 0.7796 114.0 2.595 1.1144 0.146 0.2840 92.0 1.4448 0.5789 0.13986 0.2887
106.11 2.1211 0.8902 0.1000 1.01326 0.2093 3935 11685 2.0934 0.8785 117.0 2.794 1.2104 0.076 0.1586 94.0 1.5289 0.6168 0.09126 0.1993
109.66 2.3244 0.9863 0.0200 1.01306 0.0459 4111 12003 2.2940 0.9734 118.0 2.863 1.2438 0.053 0.1146 96.0 1.6167 0.6566 0.04523 0.1045
110.61 2.381 1.0133 0.0000 1.01326 0.0000 4158 12092 2.3 1 120.49 3.039 1.33 0 0.0000 98.1 1.7117 0.7 0 0.0000

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tC 95

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0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x1,y1
 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x1,y1
Diagrama T vs x-y, para benceno-tolueno a 0.7bar, 1 atm y 1.41 bar.

2.7

2.6

2.5

2.4

2.3

2.2

2.1

1.9

1.8

1.7

1.6

1.5

1.4

1.3

1.2

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0.4
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
 0.4
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

Presión en bar vs x,y, a 85°C, 100°C y 115°C de benceno -tolueno

Entalpía -x1,y1, hexano-octano a 1 atm

16000

15000

14000

13000

12000

11000

10000
Hv, hl

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0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
x1,y1

Tref=0 compuesto i
sust pura T ebullición

hli=Cpi*(ti-Tref)
Hvi=Cpi*(ti-Tref)+li

hl de la mezcla liquida composición x

Hv de la mezcla vapor
hl=x1*h1+x2*h2=x1*Cp1*t+x2*Cp2*t

Hv=y1*(Cp1*t+l1)+y2*(Cp2*t+l2)
Hv=(y1*Cp1+y2*Cp2)*t+(y1*l1+y2*l2)
Hv=Cpmv*t+lmv
Figura 2 P-x,y benceno tolueno a 85°C, 100°C y 115°C
t°C Pv1 Pv2 t°C Pv1 Pv2 t°C Pv1 Pv2 t Pv1 Pb Pv2 rocio t o p
87.22 1.25842 0.4959 100 1.80379 0.74233 115 2.656911 1.14575 77.3 0.93094 0.7 0.3537212 84.0
x P y x P y x P y 87.22 1.25842 0.9534 0.4959 0.777133
0.9999 1.25835 0.99996 0.9999 1.803683 0.999959 0.9999 2.65676 0.999957 89.26 1.33541 1.013 0.5299875 90
0.9900 1.2508 0.99604 0.9000 1.697643 0.956273 0.9000 2.505795 0.954276 100 1.80379 1.3792 0.74233 1.147217
0.8000 1.10591 0.91032 0.8000 1.591497 0.906713 0.8000 2.354678 0.902683 100.8 1.84788 1.33 0.761473 107.3
0.7000 1.02965 0.85552 0.7000 1.485351 0.85007 0.7000 2.203562 0.844014 115 2.65691 2.05245 1.14575 1.73927
0.6000 0.9534 0.79196 0.6000 1.379205 0.784709 0.6000 2.052445 0.776706 84.0 1.14377 0.4455247 0.7
0.5000 0.87714 0.71734 0.5000 1.273058 0.708447 0.5000 1.901329 0.698699 85 1.25842 0.5972804 0.777133
0.3688 0.77713 0.59728 0.3814 1.147217 0.599753 0.3928 1.73927 0.59998 95.76 1.60592 0.6517 1.01325
0.3000 0.72463 0.52099 0.3000 1.060766 0.510138 0.3000 1.599096 0.498453 100 1.80379 0.74233 1.147217
0.2000 0.64838 0.38818 0.2000 0.95462 0.377908 0.2000 1.447979 0.366982 107.3 2.19172 0.9220165 1.33
0.1000 0.57212 0.21996 0.1000 0.848473 0.212592 0.1000 1.296863 0.204872 115 2.65691 1.14575 1.73927
0.0500 0.53399 0.11783 0.0500 0.7954 0.113389 0.0500 1.221304 0.108774 120.5 3.20829 18 1.24105406858892
0.0001 0.49594 0.00025 0.0001 0.742433 0.000243 0.0001 1.145897 0.000232 98.1 2.14202 19.25 1.3272383789076
110.6 2.38097 20.5 1.41342268922627
55 3.7921096540217

2.7

2.6

2.5

2.4

2.3

2.2

2.1

1.9

1.8

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0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
 0.4
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000

Presión en bar vs x,y, a 85°C, 100°C y 115°C de benceno -tolueno

2.7

2.6

2.5

2.4

2.3

2.2

2.1

1.9

1.8

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1.6
P bar

1.5

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0.9

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0.3
70.0 80.0 90.0 100.0 110.0 120.0

T °C
 T °C
Temperatura vs Presión de benceno -tolueno puros y con 0.6 de benceno. Envolvente
de fases.

Diagrama x1-y1 y t-x,y para benceno-tolueno a 1 atm

1.0

0.9

0.8

0.7

y1

0.6

0.5

0.4

0.3

x1
8000 0.2

0.1

0.0
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
 P SeaderT Seader
1.24105 92.7778

19.5 121.6667
Ej 1 Calcular la P del destilado de la columna xD= 0.99
P=x1 P1°+x2 P2° T en K= 360 87.22222 360.3722
T en F T en °C P°1 P°2 P
189 86.85 1.258422 0.4959 1.250796
Calcular la temperatura del fondo si x=0.02 a la presion de 20.5 psia
0.02
20.5
 cal/g cal/mol cal/g cal/mol 4.18419728
Compuesto PM Cp hfg A B C T hli Hvi
benceno 78.114 0.416 32.4954 94 7343 3.98523 1184.24 217.572 80.00 2599.77 9942.48344 1
toluno 92.141 0.408 37.5935 86.1 7933 4.05043 1327.62 217.625 110.6 4157.93 12091.2658 0
La alimentación consiste en 281.48 kmol/h de una mezcla con 46%mol de benceno y
el resto de tolueno y 23.4% de fracción vaporizada, debido a que redujo su presión
de 3.79 bar a 1.33 bar, en una válvula, donde se vaporizó adiabáticamente para
entrar al plato de alimentación a la columna

t Pv1 Pv2 x1 P y1 hl Hv Vf/F

Hmez=(1-VfF)*Hl+VfF*Hv
0.46 102.7877 1.943728 0.8072 0.4600 1.32998 0.6723 3623 11048 1.4615 0.6069 0 3623.1
0.46 145.7136 5.31405 2.4916 0.4600 3.78994 0.6450 5136 12551 1.4021 0.65743 0 5136.17
0.46 104.0998 2.012395 0.8392 0.41835 1.33000 0.6330 3691 11137 1.5131 0.63097 0.19404 5136.17
0.46 109.3517 2.305983 0.9776 0.2653 1.33000 0.4600 3963 11516 1.7338 0.735 1 11516.1

89.1163 1.329996 0.5276 1 1.33000 1.0000 2896 10239 1.0000 0.39668 105
91.26671 1.414935 0.5655 0.9 1.32999 0.9575 3012 10353 1.0639 0.42518
93.55114 1.509703 0.6081 0.8 1.32938 0.9085 3135 10480 1.1356 0.45743 x1
96.03148 1.618067 0.6572 0.7 1.32981 0.8517 3267 10623 1.2168 0.49422
98.69476 1.740989 0.7134 0.6 1.32996 0.7854 3408 10785 1.3091 0.53642 X1*Piv=
100 1.80379 0.7423 0.5 1.27306 0.7084 3504 10913 1.4169 0.58311 (1-x1)Pv2=(1-y1)pv2
102.788 1.943742 0.8072 0.46 1.32999 0.6723 3623 11048 1.4615 0.6069
105 2.060571 0.8617 0.4 1.34127 0.6145 3733 11189 1.5363 0.64248
106 2.115113 0.8873 0.3 1.25567 0.5053 3823 11347 1.6844 0.70666
111.8194 2.454674 1.0485 0.2 1.32971 0.3692 4090 11708 1.8460 0.78849
115.9361 2.718764 1.1757 0.1 1.32999 0.2044 4299 12050 2.0442 0.88398
120.4848 3.034937 1.3299 0 1.32995 0.0000 4529 12463 2.2820 1

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Entalpía -x1,y1, hexano-octano a 1 atm
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15000 115

14000 110

105
13000

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12000
95
 16000 120

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Hv, hl

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Dia
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x1,y1
 0
1

CpL=x1Cp1+x2Cp2
CpL*T=hL 35.2484 Cpv=0.6723*32.495+(1-0.6723)*37.59
Hmez=(1-VfF)*Hl+VfF*Hv 3623.28 34.17*102.788 0.6723*7343+(1-0.6723)7933
liquido sat a Pfinal 3512 7536
liq sat a Pinicial
salida valvula entrada a columna
vapor sat a Pfinal

x y V/F

T Y1 P

y1P
(1-x1)Pv2=(1-y1)pv2

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0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x1,y1
Diagrama T vs x-y, para benceno-tolueno a 0.7bar, 1 atm y 1.41 bar.
(1-0.6723)7933