Diagrama de equilibrio Liquido - Vapor

Usando la Ley de Raoult

Constantes de Antoine
Sistema Tb (°C) A B C
Metanol 80.1 8.081 1582.271 239.726
Agua 110.6 8.0713 1730.63 233.426

P (atm) 1

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) k1 k2

99.9975 0.00 1.00 2651.391 760.000 3.489 1.000
93.7021 0.10 0.90 2165.390 603.846 2.849 0.795
88.4647 0.20 0.80 1818.891 495.277 2.393 0.652
84.0182 0.30 0.70 1561.671 416.428 2.055 0.548
80.1785 0.40 0.60 1364.352 357.099 1.795 0.470
76.8152 0.50 0.50 1208.855 311.145 1.591 0.409
73.8338 0.60 0.40 1083.543 274.685 1.426 0.361
71.1639 0.70 0.30 980.642 245.168 1.290 0.323
68.7521 0.80 0.20 894.785 220.859 1.177 0.291
66.5570 0.90 0.10 822.162 200.542 1.082 0.264
64.5460 1.00 0.00 760.000 183.346 1.000 0.241
 110.0000

105.0000

100.0000

95.0000

90.0000

85.0000
y1 y2 ∑yi
0.000 1.000 1.000 80.0000
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
0.285 0.715 1.000
0.479 0.521 1.000 Linea de Punto de Burbuja Linea de Punto de Rocio
0.616 0.384 1.000
0.718 0.282 1.000
0.795 0.205 1.000
0.855 0.145 1.000
0.903 0.097 1.000
0.942 0.058 1.000
0.974 0.026 1.000
1.000 0.000 1.000
70 0.80 0.90 1.00

Punto de Rocio
 Constantes de Antoine
Sistema Tb (°C) A B C
Etanol 80.1 8.1122 1592.8642 226.184
Benceno 110.6 6.89272 1203.531 219.888

P (atm) 1

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) k1 k2 y1

80.1018 0.00 1.00 815.866 760.000 1.074 1.000 0.000
79.8708 0.10 0.90 808.524 754.608 1.064 0.993 0.106
79.6541 0.20 0.80 801.688 749.578 1.055 0.986 0.211
79.4502 0.30 0.70 795.302 744.871 1.046 0.980 0.314
79.2581 0.40 0.60 789.319 740.454 1.039 0.974 0.415
79.0765 0.50 0.50 783.701 736.299 1.031 0.969 0.516
78.9045 0.60 0.40 778.412 732.382 1.024 0.964 0.615
78.7414 0.70 0.30 773.422 728.681 1.018 0.959 0.712
78.5864 0.80 0.20 768.706 725.178 1.011 0.954 0.809
78.4389 0.90 0.10 764.238 721.856 1.006 0.950 0.905
78.2982 1.00 0.00 760.000 718.700 1.000 0.946 1.000
 y2 ∑yi
1.000 1.000
0.894 1.000
0.789 1.000
0.686 1.000
0.585 1.000
0.484 1.000
0.385 1.000
0.288 1.000
0.191 1.000
0.095 1.000
0.000 1.000
 Constantes de Antoine
Sistema Tb (°C) A B C
Acetona 7.11714 1210.595 229.664
Cloroformo 6.90328 1163.03 227.4

P (atm) 1

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) k1 k2 y1

61.7336 0.00 1.00 917.689 760.000 1.207 1.000 0.000
61.0958 0.10 0.90 898.633 744.596 1.182 0.980 0.118
60.4770 0.20 0.80 880.448 729.888 1.158 0.960 0.232
59.8763 0.30 0.70 863.071 715.827 1.136 0.942 0.341
59.2925 0.40 0.60 846.448 702.368 1.114 0.924 0.445
58.7249 0.50 0.50 830.527 689.473 1.093 0.907 0.546
58.1726 0.60 0.40 815.264 677.103 1.073 0.891 0.644
57.6347 0.70 0.30 800.617 665.227 1.053 0.875 0.737
57.1107 0.80 0.20 786.547 653.814 1.035 0.860 0.828
56.5997 0.90 0.10 773.018 642.835 1.017 0.846 0.915
56.1013 1.00 0.00 760.000 632.266 1.000 0.832 1.000
 y2 ∑yi
1.000 1.000
0.882 1.000
0.768 1.000
0.659 1.000
0.555 1.000
0.454 1.000
0.356 1.000
0.263 1.000
0.172 1.000
0.085 1.000
0.000 1.000
 Diagrama de equilibrio Liquido - Vapor
Usando la Ley de Raoult Modificada

Constantes de Antoine Parametros de Wilson

Sistema Tb (°C) A B C A12 (cal/mol) A21 (cal/mol)
Metanol 80.1 8.081 1582.271 239.726 82.9876 520.6458
Agua 110.6 8.0713 1730.63 233.426

P (atm) 1

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) ∆12 ∆21

99.9975 0.00 1.00 2651.391 760.000 0.3966615075 1.1166113651
87.7278 0.10 0.90 1774.010 481.405 0.3951538207 1.0902497954
81.7582 0.20 0.80 1442.883 380.581 0.3943847911 1.0770062634
78.0025 0.30 0.70 1261.983 326.761 0.3938883531 1.0685290923
75.2350 0.40 0.60 1141.025 291.343 0.393516094 1.0622092616
72.9789 0.50 0.50 1049.663 264.923 0.3932084827 1.0570106916
71.0174 0.60 0.40 975.239 243.629 0.3929379672 1.0524567232
69.2413 0.70 0.30 911.674 225.617 0.3926904996 1.0483052083
67.5911 0.80 0.20 855.737 209.906 0.3924584063 1.0444241304
66.0327 0.90 0.10 805.563 195.933 0.392237286 1.0407377872
64.5460 1.00 0.00 760.000 183.346 0.3920245371 1.0372013338
ama de equilibrio Liquido - Vapor
ndo la Ley de Raoult Modificada

Parametros de Wilson Marugles van laar

VL12 (cal/mol) VL21 (cal/mol)
40.73 18.07

Y1 Y2 k1 k2 y1 y2 ∑yi
2.243552670 1.000000000 7.827 1.000 0.000 1.000 1.000
1.811463222 1.012416483 4.228 0.641 0.423 0.577 1.000
1.531272897 1.044817262 2.907 0.523 0.581 0.419 1.000
1.347354252 1.092536063 2.237 0.470 0.671 0.329 1.000
1.223493548 1.153195567 1.837 0.442 0.735 0.265 1.000
1.138728753 1.225708070 1.573 0.427 0.786 0.214 1.000
1.080695336 1.309761513 1.387 0.420 0.832 0.168 1.000
1.041827036 1.405559315 1.250 0.417 0.875 0.125 1.000
1.017329539 1.513687344 1.145 0.418 0.916 0.084 1.000
1.004078750 1.635047946 1.064 0.422 0.958 0.042 1.000
1.000000000 1.770831840 1.000 0.427 1.000 0.000 1.000
van laar
 Diagrama de equilibrio Liquido - Vapor
Usando la Ley de Raoult Modificada

Constantes de Antoine Parametros de Wilson

Sistema Tb (°C) A B C A12 (cal/mol) A21 (cal/mol)
Etanol 80.1 8.1122 1592.8642 226.184 1264.4318 266.6118
Benceno 110.6 6.87987 1196.76 219.161

P (atm) 1

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) ∆12 ∆21

80.0996 0.00 1.00 815.795 760.000 0.2513610505 0.4488376576
71.0240 0.10 0.90 565.945 569.826 0.2396914176 0.4443611479
68.9695 0.20 0.80 519.360 532.519 0.2370427564 0.4433212375
68.2669 0.30 0.70 504.186 520.214 0.2361364547 0.442963302
68.0070 0.40 0.60 498.669 515.720 0.2358011844 0.4428306153
67.9811 0.50 0.50 498.122 515.274 0.2357677478 0.4428173743
68.1831 0.60 0.40 502.401 518.761 0.2360283234 0.4429205242
68.7329 0.70 0.30 514.208 528.350 0.236737611 0.4432008439
69.9316 0.80 0.20 540.759 549.742 0.2382834437 0.4438094884
72.4899 0.90 0.10 601.281 597.682 0.2415797419 0.4450970133
78.2982 1.00 0.00 760.000 718.780 0.2490491283 0.4479640219

Margules
T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) Y1 Y2
80.0996 0.00 1.00 815.795 760.000 6.272656819 1.000000000
71.0256 0.10 0.90 565.983 569.856 4.171488806 1.021505991
68.6512 0.20 0.80 512.439 526.917 2.950149951 1.085668580
67.9373 0.30 0.70 497.197 514.519 2.209077483 1.195279441
67.7347 0.40 0.60 492.942 511.044 1.743781446 1.357243765
67.7184 0.50 0.50 492.601 510.766 1.444733680 1.582569829
67.8877 0.60 0.40 496.153 513.667 1.250830837 1.886622135
68.4419 0.70 0.30 507.930 523.257 1.126742808 2.289414253
69.7801 0.80 0.20 537.339 547.000 1.051397256 2.815669313
72.6118 0.90 0.10 604.301 600.046 1.011870907 3.494275297
78.2982 1.00 0.00 760.000 718.780 1.000000000 4.356635129

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) Y1 Y2

80.0996 0.00 1.00 815.795 760.000 6.404494439 1.000000000
70.9929 0.10 0.90 565.216 569.247 4.178762921 1.022421784
68.6829 0.20 0.80 513.124 527.472 2.931533122 1.088095518
67.9874 0.30 0.70 498.254 515.382 2.191882319 1.198462966
67.7828 0.40 0.60 493.950 511.868 1.733412075 1.359441710
67.7674 0.50 0.50 493.627 511.604 1.440320116 1.581338941
67.9464 0.60 0.40 497.390 514.677 1.250151513 1.879390564
68.5092 0.70 0.30 509.376 524.432 1.127714137 2.274831846
69.8358 0.80 0.20 538.594 548.007 1.052504904 2.796514251
72.6257 0.90 0.10 604.649 600.318 1.012341953 3.483154531
78.2982 1.00 0.00 760.000 718.780 1.000000000 4.386361202
ama de equilibrio Liquido - Vapor
ndo la Ley de Raoult Modificada

Parametros de Wilson Marugles van laar

VL12 (cal/mol) VL21 (cal/mol) a12 a21 A12 A21
58.68 89.41 1.8362 1.4717 1.857 1.4785

Y1 Y2 k1 k2 y1 y2 ∑yi
6.903491290 1.000000000 7.410 1.000 0.000 1.000 1.000
4.107047869 1.028703442 3.058 0.771 0.306 0.694 1.000
2.801499995 1.100906324 1.914 0.771 0.383 0.617 1.000
2.112861806 1.209439987 1.402 0.828 0.421 0.579 1.000
1.703758582 1.357826788 1.118 0.921 0.447 0.553 1.000
1.440988895 1.556865653 0.944 1.056 0.472 0.528 1.000
1.264317304 1.825904233 0.836 1.246 0.501 0.499 1.000
1.143702569 2.197590797 0.774 1.528 0.542 0.458 1.000
1.063519430 2.727772142 0.757 1.973 0.605 0.395 1.000
1.016228086 3.514661343 0.804 2.764 0.724 0.276 1.000
1.000000000 4.730321780 1.000 4.474 1.000 0.000 1.000

85.0000
k1 k2 y1 y2 ∑yi
6.733 1.000 0.000 1.000 1.000
3.107 0.766 0.311 0.689 1.000
1.989 0.753 0.398 0.602 1.000 80.0000
1.445 0.809 0.434 0.566 1.000
1.131 0.913 0.452 0.548 1.000
0.936 1.064 0.468 0.532 1.000 75.0000
0.817 1.275 0.490 0.510 1.000
0.753 1.576 0.527 0.473 1.000
0.743 2.027 0.595 0.405 1.000
70.0000
0.805 2.759 0.724 0.276 1.000
1.000 4.120 1.000 0.000 1.000

k1 k2 y1 y2 ∑yi 65.0000
6.875 1.000 0.000 1.000 1.000
3.108 0.766 0.311 0.689 1.000
1.979 0.755 0.396 0.604 1.000 60.0000
1.437 0.813 0.431 0.569 1.000 0.00 0.20

1.127 0.916 0.451 0.549 1.000 Raoult X

0.936 1.064 0.468 0.532 1.000 MARGULES
 60.0000
0.00 0.20

Raoult X
MARGULES
0.818 1.273 0.491 0.509 1.000
0.756 1.570 0.529 0.471 1.000
0.746 2.016 0.597 0.403 1.000
0.805 2.751 0.725 0.275 1.000
1.000 4.148 1.000 0.000 1.000
000

000

000

000

000

000
0.00 0.20 0.40 0.60 0.80 1.00 1.20

Raoult X Raoult Y WILSON X WILSON Y

MARGULES X MARGULES Y van Laar X van Laar Y
000
0.00 0.20 0.40 0.60 0.80 1.00 1.20

Raoult X Raoult Y WILSON X WILSON Y

MARGULES X MARGULES Y van Laar X van Laar Y
 Diagrama de equilibrio Liquid
Usando la Ley de Raoult Mo

Constantes de Antoine
Sistema Tb (°C) A B C A12 (cal/mol)
Acetona 7.11714 1210.595 229.664 116.1171
Cloroformo 6.90328 1163.03 227.4

P (atm) 1

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) ∆12

61.7336 0.00 1.00 917.689 760.000 0.91490305214471
63.2388 0.10 0.90 963.931 797.346 0.915618316720076
64.3786 0.20 0.80 1000.153 826.567 0.916156023011686
64.9014 0.30 0.70 1017.122 840.247 0.916401545141079
64.7376 0.40 0.60 1011.783 835.943 0.91632471126352
63.9561 0.50 0.50 986.603 815.639 0.915957093275638
62.7046 0.60 0.40 947.314 783.932 0.915365150655997
61.1543 0.70 0.30 900.370 746.001 0.914626263180951
59.4614 0.80 0.20 851.230 706.241 0.913812201695053
57.7485 0.90 0.10 803.697 667.725 0.912980789931871
56.1013 1.00 0.00 760.000 632.266 0.912173855225966

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) Y1

61.7336 0.00 1.00 917.689 760.000 0.431537874
63.1943 0.10 0.90 962.537 796.221 0.529691138
64.3536 0.20 0.80 999.347 825.917 0.627300492
64.9299 0.30 0.70 1018.055 840.999 0.719173675
64.7927 0.40 0.60 1013.575 837.388 0.800853856
63.9854 0.50 0.50 987.538 816.394 0.869140923
62.6771 0.60 0.40 946.464 783.245 0.922360439
61.0787 0.70 0.30 898.127 744.187 0.960374852
59.3751 0.80 0.20 848.784 704.260 0.984388739
57.6937 0.90 0.10 802.214 666.523 0.996630888
56.1013 1.00 0.00 760.000 632.266 1.000000000

T (°C) x1 x2 Ps1 (mmHg) Ps2 (mmHg) Y1

61.7336 0.00 1.00 917.689 760.000 0.421346392
63.2294 0.10 0.90 963.635 797.107 0.527698331
64.3910 0.20 0.80 1000.553 826.890 0.629394530
64.9443 0.30 0.70 1018.524 841.377 0.721709312
64.7919 0.40 0.60 1013.550 837.368 0.801570808
63.9968 0.50 0.50 987.903 816.688 0.867426892
62.7194 0.60 0.40 947.771 784.301 0.918950189
61.1468 0.70 0.30 900.147 745.820 0.956699223
59.4442 0.80 0.20 850.743 705.846 0.981804996
57.7353 0.90 0.10 803.340 667.435 0.995714678
56.1013 1.00 0.00 760.000 632.266 1.000000000
grama de equilibrio Liquido - Vapor
sando la Ley de Raoult Modificada

Parametros de Wilson Marugles van laar

A21 (cal/mol) VL12 (cal/mol) VL21 (cal/mol) a12 a21 A12 A21
-506.8519 74.05 80.67 -0.84 -0.56 -0.86 -0.59

∆21 Y1 Y2 k1 k2 y1 y2
1.9666746586 0.415722427 1.000000000 0.502 1.000 0.000 1.000
1.9599773728 0.527972961 0.988149243 0.670 1.037 0.067 0.933
1.9549610814 0.632475670 0.958006508 0.832 1.042 0.166 0.834
1.9526758401 0.725135886 0.915945236 0.970 1.013 0.291 0.709
1.9533906321 0.804044465 0.866471717 1.070 0.953 0.428 0.572
1.9568150667 0.868662401 0.812828693 1.128 0.872 0.564 0.436
1.9623446503 0.919250431 0.757427990 1.146 0.781 0.687 0.313
1.9692738822 0.956546415 0.702089237 1.133 0.689 0.793 0.207
1.9769429431 0.981592832 0.648158482 1.099 0.602 0.880 0.120
1.9848133818 0.995628324 0.596579447 1.053 0.524 0.948 0.052
1.992488971 1.000000000 0.547957006 1.000 0.456 1.000 0.000

Y2 k1 k2 y1 y2 ∑yi
1.000000000 0.521 1.000 0.000 1.000 1.000 66.0000
0.989417196 0.671 1.037 0.067 0.933 1.000
0.960480499 0.825 1.044 0.165 0.835 1.000 64.0000
0.917874691 0.963 1.016 0.289 0.711 1.000
0.866403278 1.068 0.955 0.427 0.573 1.000 62.0000
0.810503192 1.129 0.871 0.565 0.435 1.000
0.753951528 1.149 0.777 0.689 0.311 1.000 60.0000
0.699748986 1.135 0.685 0.794 0.206 1.000
0.650140751 0.880 0.120 1.000 58.0000
1.099 0.602
0.606729149 1.052 0.532 0.947 0.053 1.000
56.0000
0.570638140 1.000 0.475 1.000 0.000 1.000

54.0000
Y2 k1 k2 y1 y2 ∑yi
1.000000000 0.509 1.000 0.000 1.000 1.000
52.0000
0.988503909 0.669 1.037 0.067 0.933 1.000
0.958488327 0.829 1.043 0.166 0.834 1.000 50.0000
0.915975048 0.967 1.014 0.290 0.710 1.000 0.00

0.865861671 1.069 0.954 0.428 0.572 1.000

0.811897246 1.128 0.872 0.564 0.436 1.000
 50.0000
0.00

0.756811371 1.146 0.781 0.688 0.312 1.000

0.702498661 1.133 0.689 0.793 0.207 1.000
0.650205590 1.099 0.604 0.879 0.121 1.000
0.600695361 1.052 0.528 0.947 0.053 1.000
0.554382720 1.000 0.461 1.000 0.000 1.000
 ∑yi
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000
1.000

Chart Title
66.0000

64.0000

62.0000

60.0000

58.0000

56.0000

54.0000

52.0000

50.0000
0.00 0.20 0.40 0.60 0.80 1.00 1.20

Raoult X Raoult Y WILSON X WILSON Y

MARGULES X MARGULES Y van Laar X van Laar Y
50.0000
0.00 0.20 0.40 0.60 0.80 1.00 1.20

Raoult X Raoult Y WILSON X WILSON Y

MARGULES X MARGULES Y van Laar X van Laar Y
1.20
1.20