PARIONA CAHUANA , Edith Raquel I.

Q
Determinar los coeficientes de actividad de acetona(1) + n-pentano(2) a 307K con una fraccion molar de acetona x1=0.04

DATOS
Fracciones molares
x1 0.047
x2 0.953
T 307
GRUPOS FUNCIONALES
Acetona CH3-CO-CH3
n-pentano CH3- CH2-CH2-CH2-CH3

TABLA 1
SUBGRUPO k Rk Qk Vk(ACETONA) Vk2(N-PENTANO)
CH3 1 0.9011 0.848 1 2
CH3CO 2 1.6724 1.488 1 0
CH2 3 0.6744 0.54 0 3

R1 0.9011 Q1 0.848 V11 1 V12

R2 1.6724 Q2 1.488 V21 1 V22
R3 0.6744 Q3 0.54 V31 0 V32

PARTE COMBINATORIAL
r1 2.574 q1 2.336 Z 10
r2 3.825 q2 3.316
L1 -0.386
ɸ1 0.032 Ɵ1 0.034 L2 -0.278
ɸ2 0.968 Ɵ2 0.966

PARTE RESIDUAL
X11 0.5 X12 0.4 Ɵ11 0.363
X21 0.5 X22 0 Ɵ21 0.637
X31 0 X32 0.6 Ɵ31 0

ln 11 0.409 ln12 0.000

ln21 0.139 ln22 2.433
ln31 0.260 ln32 0

CALCULO DEL COEFICIENTE DE ACTIVIDAD

X1 0.402 Ɵ1 0.506
X2 0.010 Ɵ2 0.021
X3 0.588 Ɵ3 0.472
Ln r1 0.001 LnR1 1.660630081
Ln r2 2.207 LnR2 0.005349
Ln r3 0.000871
raccion molar de acetona x1=0.047 mediante el modelo de UNIFAC

PARAMETRO DE INTERACCION
K
SUBGRUPO CH3 CH3CO CH3OH
GRUPO P. 1 9 1
CH3 1 0 476.42 0
J CH3CO 9 26.76 0 26.76
CH3OH 1 0 476.42 0

a11 0 a12 476.42 a13 0

a21 26.76 a22 0 a23 26.76
2 a31 0 a32 476.42 a33 0
0
3

LNY C1 -0.053
LNY C2 -0.000102

Ɵ12 0.51145959 ᵠ11 1 ᵠ12 0.212 ᵠ13

Ɵ22 0 ᵠ21 0.917 ᵠ22 1 ᵠ23
Ɵ32 0.48854041 ᵠ31 1.000 ᵠ32 0.212 ᵠ33

lny1 1.61
lny2 0.00524682
y1 4.99238
y2 1.005261
1.000
0.917
1