Sol:

Componente Ai Bi Ci Zi P (kPa) T (°C)

Benceno (1) 13.7819 2726.81 217.572 0.33 120 105
Tolueno (2) 13.932 3056.96 217.625 0.67

ki=yi/xi=Pisat/P x1=(P-X2*P2sat)/P1sat

a)
Componente Ai Bi Ci P (kPa) T (°C) Ti sat
Benceno (1) 13.7819 2726.81 217.572 90 90 76.19911223
Etilbenceno (2) 13.9726 3259.93 212.3 131.8361929

Yi=Xi*Pisat/P Pisat=exp(Ai-(Bi/(T+Ci)))

Diagrama P-x-y P=X1*P1sat + (1-X1)*P2sat

160
Xi P y
140
0 24.2603212 0
0.1 35.4839674 0.38467171 120
0.2 46.7076137 0.58447338 100
0.3 57.9312599 0.70685559
80
0.4 69.1549062 0.78951323
0.5 80.3785524 0.8490871 60

0.6 91.6021986 0.89406228 40

0.7 102.825845 0.92921919 20
0.8 114.049491 0.9574565
0
0.9 125.273137 0.98063406 0 0.2 0.4 0.6 0.8 1 1.2

P P-y
 40

20

0
0 0.2 0.4 0.6 0.8 1 1.2
1 136.496784 1
P P-y

a)

b)

c)

a) Sol:
Se asigna valores a xi según el diagrama derecho hasta llegar a valor 1.00
Comp xi T (°F) Psup (Psia) Ki yi
Metano 0.1 -60 220 5.2 0.52
Etileno 0.5 0.645 0.3225
Etano 0.4 0.418 0.1672
1 1.0097
ki=yi/xi=Pisat/P
b) Sol:
Se asigna valores a xi según el diagrama derecho hasta llegar a valor 1.00
Comp yi T (°F) Psup (Psia) Ki xi
Metano 0.5 -60 200 5.65 0.08849558
Etileno 0.25 0.7 0.35714286
Etano 0.25 0.445 0.56179775
1 1.00743619

Sol:
Según depriester
Componente %mol zi P (psia) T (°F) ki Vsup
Metano 50 0.5 250 80 10 0.845693467
Etano 10 0.1 2.1
Propano 20 0.2 0.64
n-butano 20 0.2 0.21
Total: 100

Sol:

Componente: Ai Bi Ci Mol Zi=ni/n P (kPa)

1clorobutano (1) 13.96 2826.26 224.1 300 0.3 165.57
Benceno (2) 13.8858 2788.51 220.79 500 0.5
Clorobenceno (3) 13.9926 3295.12 217.55 200 0.2
 1000 1

Sxi=1.00 Antoine
Xi=Zi/(1+V(ki-1)) Ec. A Componente: T(°C) sup Pisat
X3=0.3877=z3/(1+V*(K3-1) 1clorobutano 110.001273 244.8653985
Benceno 234.1548566
V=(Z3/x3-1)/(k3-1) Ec. B Clorobenceno 51.04664549
Raoult:
Yi*P=Xi*Pisat Pisat=exp(Ai-(Bi/(T+Ci)))
ki=Yi/xi=Pisat/P Ec. C
RPTA: T (°C)= 110.0013
V= 0.6999
Pi sat (kPa) K1 Xi sup Xi Yi vap sup (V) liq sup (L)
206.141423 1.71784518805 0.281774976 0.281774975 0.48404578 0.238417952 0.7615820477
86.2048853 0.71837404415 0.718225024 0.718225025 0.51595422

V vap Vliq
0.2384180198 0.76158205
Zi=Xi*L + Yi*V

Pisat
136.496784
24.2603212

Diagrama T-x-y P=X1*P1sat + (1-X1)*P2sat

140

Pisat P2sat Xi T y 130

394.578671058 90 0 131.836193 0 120
361.833975178 80.884576427 0.0324450724 128 0.130441439
110
314.744771646 68.107639045 0.0887634426 122 0.310420327
272.414007947 56.989730989 0.1532337463 116 0.463811322 100
234.532148462 47.371335669 0.2277649028 110 0.593535467 90
200.793076625 39.101093244 0.314789303 104 0.702305696
80
170.895285253 32.036107173 0.4174293239 98 0.792630038
144.543072381 26.042191575 0.5397243294 92 0.866815698 70
121.447730297 20.994054725 0.6869429603 86 0.926974038 60
0 0.2 0.4 0.6
101.328714302 16.775414686 0.8660168869 80 0.975026419
T-x
 70

60
0 0.2 0.4 0.6

90 14.483081478 1 76.1991122 1 T-x

Sol: Burb P =exp(0.95*x2^2)+exp(0.95*x1^2)

=xi*yi*Pisat
Coef. De activi
Comp. xi T (°K) Pi sat yi=ci Bubl P
Etanoato 0.05 343.15 79.8 2.35696553 9.404292471
n-heptano 0.95 40.5 1.00237782 38.56648672
47.9708

Sol:

Comp. xi T (°K) Pi sat yi=ci xi/(yi.Pisat) Rocio P (DEW)

Etanoato 0.05 343.15 79.8 2.35696553 0.00027 42.2530
n-heptano 0.95 40.5 1.00237782 0.02340
S 0.02367

Sol:
Comp. Pi sat P2sat/P1sat Xi (1° supst) g1 g1/g2 Pz=g1*P1sat
Etanoato 79.8 0.507518797 0.8570 1.01962775 0.507518212 81.3663
n-heptano 40.5 0.1430 2.00904662 81.3664
S

Rpta: x1= 0.8570

Pz= 81.3663
 1-V 1-L
Sxi=1.0 Syi=1.0=S(ki*xi) L (Fase líqu) V (fase vapor)
0.0581 0.5806 0.1543065327 0.8456934673
0.0518 0.1088
0.2875 0.1840
0.6026 0.1265
1.0000 1.0000

T sup (°C) Vsup xi

80 0.1

0.3877
 Ec. C Ec. B Ec. A
Ki V Xi
1.47892371 0.69993233934 0.22468
1.4142348 0.38762
0.30830854 0.38770
S= 1.00000
sat=exp(Ai-(Bi/(T+Ci)))
140

130

120

110

100

90

80

70

60
0 0.2 0.4 0.6 0.8 1 1.2

T-x T-y
70

60
0 0.2 0.4 0.6 0.8 1 1.2

T-x T-y
SOL

Compon: ij Tc (°K) Pc (Bar) Vc (cm3/mol) Zc

Metil etil cetona 11 535.5 41.5 267 0.249
Tolueno 22 591.8 41.06 316 0.264

ij Tcij (°K) Pcij (kPa) Vcij (cm3/mol) Zcij wij

11 535.5 4152.00226 267 0.249 0.323
22 591.8 4110.56789 316 0.264 0.262
12 562.946623 4128.11481 290.812346121 0.2565 0.2925

d12 lnf1 f1 lnf2 f2

27.499014 -0.01279586 0.98728565913 -0.0174171925 0.98273361

Por Redlich Kwong:

Componente T (°C) P (bar) T (°k) Tc (°K) Pc (bar)

Isobutileno 280 20 553.15 417.9 40

Vc /cm3/mol)w Tr Pr
238.9 0.194 1.32364201962 0.5

a(Tr) s e Ω ¥ Zc
 0.8691900121552 1 0 0.08664 0.42748 0.33333333

Z sup q*B eb sb Zcalc

0.9260388143948 0.10603749 0 0.03272788213 0.92603880471

Componente nj yi T (°K) P (Bar) Bij

Propano (1) 1 0.5 348.15 2 -276
n-pentanol (2) 2 0.5 -809
2 1 -466

Componente Tcij (°K) Pcij (bar) Vcij (cm3/mol) Zcij wij

Etileno (1) 282.3 50.4 131 0.281 0.087
Propileno (2) 365.6 46.65 188.4 0.289 0.14

ij Tcij (°K) Pcij (bar) Vcij (cm3/mol) Zcij wij

11 282.3 50.344951 131 0.281 0.087
22 365.6 46.626536 188.4 0.289 0.14
12 321.261389 48.1891728 157.96611647 0.285 0.1135

d12 ^f1 ^f2 ^f1 ^f2

20.960487194979 0.9574126 0.87479778 10.052832286 17.0585567045

4
Yi.P=Xi.gi.Pisat
wc T(°K) P (kPa) R (kPa.cm3/mol°K)
0.323 323.15 25 8314
0.262

Tr Bo B1 Bij
0.6035 -0.8638 -1.2959 -1375.1296
0.5460 -1.0281 -2.0446 -1871.7693
0.5740 -0.9427 -1.6311 -1609.7000

B q I
 0.03272788 3.2399741 0.9587667

B Z Z R (bar.cm3/mol.K) V (cm3) HR
-504.25 0.96515829 0.96515829 83.14 13968.3455 -1008.5

yi T (°K) P (bar) R (bar.cm3/mol°K)

0.35 423.15 30 83.14
0.65

Tr Bo B1 Bij
1.4989373 -0.13783042 0.10757771 -59.8922500006106
1.15741247 -0.25098841 0.04591533 -159.429598781743
1.31715175 -0.18857835 0.08491734 -99.1806807936873

a) sol
Compon: zi Xi Ai Bi Ci P (kPa)
Acetona (1) 0.25 0.175 14.3145 2756.22 228.06 100
Metanol (2) 0.75 0.825 16.5785 3638.27 239.5

Compon: gi Pisat Yi Ki V Xi recalc

Acetona (1) 1.54589031 111.98766 0.302961119383315 1.7312064 0.5861 0.175
Metanol (2) 1.04081077 81.1765466 0.697037750627656 0.84489424 0.5861 0.82500
1.00000

V=(Zi/Xi -1)/(Ki-1)
P (bar) T sup (°C)
1 59.1625958
yi recalc
0.30296112
0.69703837
1.00000