Peng Robinson

PENG ROBINSON
%comp.
N° de componentes
Peso
componentes Molecular Molar
Zi w
Nitrogeno N2 28.01 1 0.01000 0.038
Dioxido de carbono CO2 44.01 0.5 0.00500 0.224
Metano CH4 16.04 68 0.68000 0.011
Etano C2H6 30.07 13 0.13000 0.099
Propano C3H8 44.1 5 0.05000 0.153
i-Butano i-C4H10 58.12 2 0.02000 0.181
n-Butano n-C4C10 58.12 4 0.04000 0.199
i-Pentano i-C5H12 72.15 1 0.01000 0.228
n-Pentano n-C5H12 72.15 3 0.03000 0.250
n-Hexano n-C6H14 86.18 2 0.02000 0.305
n-Heptano n-C7H16 252 0.5 0.00500 0.442
100 1.00000
DATOS
P (psia) 850
P (kpa) 5860.544
Q (MMPCSD) 30
Q (lbmol/dia) 79080.744
Q (lbmol/hr) 3295.03101
T (F) 40
T ( °R) 500.65
T (K) 277.59
R 8.3144598
METODO NEWTON RAPSON
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
Nº de
iteraciones Z sup f f'
A 464.7967 1 0.9 400.614823 465.414806
B 0.0378 2 0.0392 0.64983217 464.645843
3 0.0378 -1.6545E-06 464.648211
4 0.0378 0 464.648211
Z 0.0378 5 0.0378 0 464.648211
6 0.0378 0 464.648211
7 0.0378 0 464.648211
Ⴔ vap* = 0.6620 Ⴔ liq* =
am vap = 266.9503 am liq =
bm vap = 0.0284 bm liq =
A vap= 0.2937 A liq =
B vap= 0.0722 B liq =
Z vap = 0.7826 Z liq =
V vap (m3/Kmol) 0.3082 V liq (m3/Kmol)
Primera Iteración
Componente zi Pvap (Kpa) Ki f(Ⴔ) yi*
Nitrógeno N2 0.01000 933059.295 159.21036 0.01496 0.0151
Dióxido de CO2 0.00500 3893.272 0.66432 -0.00216 0.0043

Metano CH4 0.68000 38480.495 6.56603 0.80792 0.9531
Etano C2H6 0.13000 2662.962 0.45439 -0.11104 0.0925
Propano C3H8 0.05000 543.188 0.09269 -0.11360 0.0116
i-Butano i-C4H10 0.02000 182.101 0.03107 -0.05404 0.0017
n-Butano n-C4H10 0.04000 122.424 0.02089 -0.11132 0.0024
i-Pentano i-C5H12 0.01000 41.776 0.00713 -0.02897 0.0002
n-Pentano n-C5H12 0.03000 29.753 0.00508 -0.08744 0.0004
n-Hexano n-C6H14 0.02000 7.259 0.00124 -0.05896 0.0001
n-Heptano C7+ 0.00500 0.008 0.00000 -0.01479 0.0000
sumatorias 0.24057 1.08131
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 309.0662 am liq =
A vap= 0.3400 A liq =
B vap= 0.0795 B liq =
Z vap = 0.7380 Z liq =
segunda Iteración
Componente Yi * Xi * a vap i a liq i φ vap
Nitrógeno N2 0.013 0.003 161.9358 288.1254 1.1046
Dióxido de CO2 0.005 0.004 322.6782 589.6515 0.7240

Metano CH4 0.793 0.370 255.0668 467.9416 0.8701
Etano C2H6 0.118 0.162 442.4989 817.5500 0.5609
Propano C3H8 0.033 0.098 603.9350 1121.8086 0.3920
i-Butano i-C4H10 0.009 0.049 737.3198 1376.0890 0.2960
n-Butano n-C4H10 0.016 0.105 764.0636 1425.2074 0.2754
i-Pentano i-C5H12 0.003 0.030 896.5487 1677.7283 0.2081
n-Pentano n-C5H12 0.007 0.093 925.8876 1732.9687 0.1942
n-Hexano n-C6H14 0.002 0.068 1090.1660 2046.8730 0.1367
n-Heptano C7+ 0.000 0.019 2083.9624 3943.4462 0.0154
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 277.3319 am liq =
A vap= 0.3051 A liq =
B vap= 0.0758 B liq =
Z vap = 0.7770 Z liq =
tercera Iteración
Nitrógeno N2 0.014 0.002 153.9522 280.8295 1.0680
Dióxido de CO2 0.005 0.005 306.2869 573.1982 0.7280

Metano CH4 0.832 0.369 241.6913 455.4453 0.8613
Etano C2H6 0.106 0.179 418.9869 795.4247 0.5790
Propano C3H8 0.023 0.104 571.5211 1091.1525 0.4191
i-Butano i-C4H10 0.006 0.049 697.3987 1338.1546 0.3254
n-Butano n-C4H10 0.009 0.103 722.7378 1385.9574 0.3048
i-Pentano i-C5H12 0.001 0.028 847.7716 1631.2465 0.2367
n-Pentano n-C5H12 0.003 0.085 875.4949 1684.9423 0.2224
n-Hexano n-C6H14 0.001 0.059 1030.4762 1989.8509 0.1622
n-Heptano C7+ 0.000 0.015 1968.3010 3831.8957 0.0226
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 274.1030 am liq =
A vap= 0.3016 A liq =
B vap= 0.0755 B liq =
Z vap = 0.7808 Z liq =
cuarta Iteración
Nitrógeno N2 0.014 0.002 153.1109 279.4985 1.0647
Dióxido de CO2 0.005 0.005 304.5750 570.2845 0.7285
Metano CH4 0.837 0.371 240.2864 453.1786 0.8606
Etano C2H6 0.104 0.181 416.5182 791.4219 0.5809
Propano C3H8 0.022 0.105 568.1189 1085.6162 0.4219
i-Butano i-C4H10 0.005 0.049 693.2102 1331.3146 0.3285
n-Butano n-C4H10 0.008 0.103 718.4017 1378.8790 0.3079
i-Pentano i-C5H12 0.001 0.028 842.6551 1622.8732 0.2398
n-Pentano n-C5H12 0.003 0.084 870.2090 1676.2911 0.2254
n-Hexano n-C6H14 0.001 0.058 1024.2159 1979.5879 0.1649
n-Heptano C7+ 0.000 0.015 1956.1815 3811.8791 0.0235
1.00000 1
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 273.6530 am liq =
A vap= 0.3011 A liq =
B vap= 0.0754 B liq =
Z vap = 0.7813 Z liq =
quinta Iteración
Nitrógeno N2 0.014 0.002 152.9927 278.9347 1.0643
Dióxido de CO2 0.005 0.005 304.3366 569.0795 0.7286

Metano CH4 0.838 0.373 240.0898 452.2238 0.8605
Etano C2H6 0.104 0.181 416.1731 789.7387 0.5812
Propano C3H8 0.022 0.105 567.6435 1083.2910 0.4223
i-Butano i-C4H10 0.005 0.049 692.6250 1328.4454 0.3289
n-Butano n-C4H10 0.008 0.102 717.7959 1375.9094 0.3083
i-Pentano i-C5H12 0.001 0.027 841.9405 1619.3634 0.2402
n-Pentano n-C5H12 0.003 0.083 869.4706 1672.6650 0.2259
n-Hexano n-C6H14 0.001 0.058 1023.3414 1975.2890 0.1653
n-Heptano C7+ 0.000 0.015 1954.4902 3803.5149 0.0236
1.00000 1
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 273.5658 am liq =
A vap= 0.3010 A liq =
B vap= 0.0754 B liq =
Z vap = 0.7814 Z liq =
sexta Iteración
Nitrógeno N2 0.014 0.002 152.9697 278.6992 1.0642
Dióxido de CO2 0.005 0.005 304.2907 568.5797 0.7286

Metano CH4 0.838 0.374 240.0517 451.8259 0.8605
Etano C2H6 0.104 0.181 416.1063 789.0374 0.5812
Propano C3H8 0.022 0.104 567.5514 1082.3226 0.4224
i-Butano i-C4H10 0.005 0.049 692.5117 1327.2509 0.3290
n-Butano n-C4H10 0.008 0.102 717.6786 1374.6730 0.3084
i-Pentano i-C5H12 0.001 0.027 841.8022 1617.9024 0.2403
n-Pentano n-C5H12 0.003 0.083 869.3277 1671.1555 0.2260
n-Hexano n-C6H14 0.001 0.057 1023.1722 1973.4999 0.1654
n-Heptano C7+ 0.000 0.015 1954.1633 3800.0360 0.0236
1.00000 1
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 273.5452 am liq =
A vap= 0.3009 A liq =
B vap= 0.0754 B liq =
Z vap = 0.7815 Z liq =
septima Iteración
Componente Yi Xi a vap i a liq i φ vap
Nitrógeno N2 0.014 0.002 152.9642 278.6083 1.0642
Dióxido de CO2 0.005 0.005 304.2799 568.3870 0.7286

Metano CH4 0.838 0.374 240.0427 451.6723 0.8605
Etano C2H6 0.104 0.181 416.0904 788.7667 0.5812
Propano C3H8 0.022 0.104 567.5296 1081.9489 0.4224
i-Butano i-C4H10 0.005 0.049 692.4849 1326.7899 0.3290
n-Butano n-C4H10 0.008 0.102 717.6509 1374.1959 0.3084
i-Pentano i-C5H12 0.001 0.027 841.7694 1617.3387 0.2403
n-Pentano n-C5H12 0.003 0.083 869.2939 1670.5731 0.2260
n-Hexano n-C6H14 0.001 0.057 1023.1321 1972.8096 0.1654
n-Heptano C7+ 0.000 0.015 1954.0860 3798.6942 0.0236
1.00000 1
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 273.5397 am liq =
A vap= 0.3009 A liq =
B vap= 0.0754 B liq =
Z vap = 0.7815 Z liq =
OCTAVA Iteración
Componente Yi Xi a vap i a liq i φ vap
Nitrógeno N2 0.014 0.002 152.9627 278.5748 1.0642
Dióxido de CO2 0.005 0.005 304.2770 568.3162 0.7286

Metano CH4 0.838 0.374 240.0403 451.6157 0.8605
Etano C2H6 0.104 0.181 416.0862 788.6672 0.5813
Propano C3H8 0.022 0.104 567.5238 1081.8114 0.4224
i-Butano i-C4H10 0.005 0.049 692.4778 1326.6204 0.3290
n-Butano n-C4H10 0.008 0.102 717.6435 1374.0204 0.3084
i-Pentano i-C5H12 0.001 0.027 841.7607 1617.1313 0.2403
n-Pentano n-C5H12 0.003 0.083 869.2849 1670.3589 0.2260
n-Hexano n-C6H14 0.001 0.057 1023.1214 1972.5557 0.1654
n-Heptano C7+ 0.000 0.015 1954.0655 3798.2006 0.0236
1.00000 1
calculo de flujos
Ⴔ vap* = 0.6288
SON
Tc (K) Tc(°R) Pc (bar) Pc (psia) Pc (Kpa) Tr Pr mi
126.24 227.232 33.94 492.266 3394.053 2.199 1.727 0.432

304.25 547.65 73.83 1070.830 7383.115 0.912 0.794 0.706
190.62 343.116 46.04 667.764 4604.072 1.456 1.273 0.391
305.46 549.828 48.80 707.795 4880.076 0.909 1.201 0.525
369.86 665.748 42.49 616.275 4249.066 0.751 1.379 0.604
408.18 734.724 36.48 529.106 3648.057 0.680 1.606 0.645
425.22 765.396 37.97 550.717 3797.059 0.653 1.543 0.671
460.47 828.846 33.81 490.380 3381.053 0.603 1.733 0.712
469.69 845.442 33.69 488.640 3369.053 0.591 1.740 0.743
507.47 913.446 30.12 436.860 3012.047 0.547 1.946 0.819
754.00 1213.67 336.800 2322.154 0.368 2.524 1.003
446.3938 649.779
Co
A
Nitrógeno 35.4113
Dióxido de Carb 133.62
Metano 31.35
Etano 44.0103
Propano 52.3785
i-Butano 58.7845
−2𝐵−3𝐵^2 )𝑍− n-Butano 66.945
2𝐵−3𝐵^2 )=0 i-Pentano 66.7563
Zcal Diferencia
n-Pentano 63.3315
0.0392 0.8608 n-Hexano 70.4265
0.0378 0.0014 n-Heptano 67.6419512
0.0378 0.0000
0.0378 0.0000
0.0378 0.0000
0.0378 0.0000
0.0378 0.0000
0.3380 𝑓(𝜑)=∑_(𝑖=1)^𝑐▒ 〖 (𝑧_𝑖∗(1−𝐾_𝑖))/(1+𝜑∗(𝐾_𝑖−1))=0 〗
𝑥_𝑖=𝑦_𝑖/𝐾_𝑖 =𝑧_𝑖/(1+
1117.7588
0.0614
1.2297
0.1560
0.2331
0.0918
xi* Yi* Norm Xi* Norm a vap i a liq i φ vap φ liq Ki P-R
0.0001 0.0139 0.0001 157.5839 270.4159 1.0434 6.8983 6.6113
0.0064 0.0039 0.0076 313.1715 552.7710 0.7059 1.2709 1.8003

0.1452 0.8814 0.1726 246.6220 440.2277 0.8390 2.6305 3.1352
0.2035 0.0855 0.2421 427.2206 769.5060 0.5593 0.5970 1.0673
0.1252 0.0107 0.1489 582.4092 1056.3101 0.4020 0.1960 0.4875
0.0558 0.0016 0.0663 710.2998 1296.2187 0.3104 0.0879 0.2832
0.1137 0.0022 0.1352 736.1537 1342.4289 0.2904 0.0655 0.2257
0.0292 0.0002 0.0347 863.1875 1580.6727 0.2243 0.0292 0.1300
0.0879 0.0004 0.1045 891.3955 1632.7435 0.2105 0.0230 0.1092
0.0590 0.0001 0.0702 1048.8203 1928.9663 0.1525 0.0081 0.0534
0.0148 0.0000 0.0176 2001.4663 3718.4614 0.0204 0.0000 0.0004
0.84074 sumatorias
1.0000
1059.4559
0.0556
1.1656
0.1413
0.2061 Ⴔ vap* = 0.63824
0.0812
φ liq Ki P-R f(Ⴔ) yi xi Yi Norm Xi Norm

7.1513 6.4743 -0.01218162 0.0144 0.0022 0.014 0.002
0.9349 1.2913 -0.00122802 0.0054 0.0042 0.005 0.005

2.2656 2.6039 -0.53894385 0.8750 0.3360 0.832 0.369
0.3833 0.6834 0.05158101 0.1113 0.1629 0.106 0.179
0.1009 0.2574 0.07058809 0.0245 0.0951 0.023 0.104
0.0386 0.1305 0.03907585 0.0059 0.0449 0.006 0.049
0.0272 0.0987 0.08487193 0.0093 0.0942 0.009 0.103
0.0103 0.0495 0.02416122 0.0013 0.0254 0.001 0.028
0.0077 0.0399 0.07438026 0.0031 0.0775 0.003 0.085
0.0022 0.0164 0.05285265 0.0009 0.0537 0.001 0.059
0.0000 0.0000 0.01381967 0.0000 0.0138 0.000 0.015
sumatorias -0.1410 1.0510 0.9100 1.000 1.000
1.0000
1002.1178
0.0540
1.1025
0.1372
0.2038 Ⴔ vap* = 0.63227
0.0802

6.9042 6.4646 -0.01226584 0.0145 0.0022 0.014 0.002
0.9307 1.2783 -0.00118341 0.0054 0.0043 0.005 0.005

2.2201 2.5776 -0.53706858 0.8775 0.3404 0.837 0.371
0.3813 0.6586 0.05660621 0.1092 0.1658 0.104 0.181
0.1013 0.2418 0.0728195 0.0232 0.0960 0.022 0.105
0.0390 0.1199 0.03968954 0.0054 0.0451 0.005 0.049
0.0276 0.0905 0.08562051 0.0085 0.0941 0.008 0.103
0.0105 0.0444 0.0241433 0.0011 0.0253 0.001 0.028
0.0079 0.0356 0.07413425 0.0027 0.0769 0.003 0.084
0.0023 0.0142 0.05233378 0.0008 0.0531 0.001 0.058
0.0000 0.0000 0.01359598 0.0000 0.0136 0.000 0.015
sumatorias -0.1316 1.0484 0.9168 1.000 1.000
1.0000
991.9456
0.0538
1.0913
0.1365
0.2035 Ⴔ vap* = 0.6300
0.0801

6.8533 6.4366 -0.0122852 0.0145 0.0023 0.014 0.002
0.9293 1.2757 -0.00117432 0.0054 0.0043 0.005 0.005
2.2108 2.5688 -0.53650564 0.8785 0.3420 0.838 0.373
0.3810 0.6558 0.05713376 0.1089 0.1660 0.104 0.181
0.1014 0.2404 0.07283167 0.0231 0.0959 0.022 0.105
0.0391 0.1190 0.03960241 0.0053 0.0450 0.005 0.049
0.0277 0.0898 0.08535253 0.0084 0.0938 0.008 0.102
0.0106 0.0440 0.02403812 0.0011 0.0251 0.001 0.027
0.0080 0.0353 0.07378831 0.0027 0.0765 0.003 0.083
0.0023 0.0141 0.05205125 0.0007 0.0528 0.001 0.058
0.0000 0.0000 0.01351419 0.0000 0.0135 0.000 0.015
sumatorias -0.1317 1.0487 0.9171 1.000 1.000
1.0000
987.6919
0.0536
1.0866
0.1362
0.2034 Ⴔ vap* = 0.6293
0.0801

6.8301 6.4175 -0.0122874 0.0146 0.0023 0.014 0.002
0.9286 1.2745 -0.00117049 0.0054 0.0043 0.005 0.005

2.2065 2.5642 -0.53603962 0.8787 0.3427 0.838 0.374
0.3808 0.6553 0.05722901 0.1088 0.1660 0.104 0.181
0.1015 0.2404 0.07276483 0.0230 0.0958 0.022 0.104
0.0391 0.1190 0.03954411 0.0053 0.0449 0.005 0.049
0.0277 0.0898 0.08520773 0.0084 0.0936 0.008 0.102
0.0106 0.0440 0.02399202 0.0011 0.0251 0.001 0.027
0.0080 0.0353 0.0736426 0.0027 0.0763 0.003 0.083
0.0023 0.0141 0.0519431 0.0007 0.0527 0.001 0.057
0.0000 0.0000 0.01348532 0.0000 0.0135 0.000 0.015
sumatorias -0.1317 1.0488 0.9171 1.000 1.000
1.0000
985.9233
0.0536
1.0847
0.1361
0.2033 Ⴔ vap* = 0.6290
0.0801

6.8202 6.4088 -0.01228707 0.0146 0.0023 0.014 0.002
0.9283 1.2741 -0.00116889 0.0054 0.0043 0.005 0.005

2.2047 2.5622 -0.53580338 0.8788 0.3430 0.838 0.374
0.3808 0.6551 0.05725557 0.1088 0.1660 0.104 0.181
0.1015 0.2404 0.07273296 0.0230 0.0957 0.022 0.104
0.0391 0.1190 0.03952033 0.0053 0.0449 0.005 0.049
0.0277 0.0899 0.08515061 0.0084 0.0936 0.008 0.102
0.0106 0.0441 0.02397474 0.0011 0.0251 0.001 0.027
0.0080 0.0354 0.07358858 0.0027 0.0763 0.003 0.083
0.0023 0.0141 0.05190422 0.0007 0.0526 0.001 0.057
0.0000 0.0000 0.01347525 0.0000 0.0135 0.000 0.015
sumatorias -0.1317 1.0488 0.9172 1.0000 1.0000
1.0000
985.2412
0.0536
1.0839
0.1361
0.2033 Ⴔ vap* = 0.6289
0.0801

6.8164 6.4053 -0.01228673 0.0146 0.0023 0.014 0.002
0.9282 1.2739 -0.00116826 0.0054 0.0043 0.005 0.005

2.2040 2.5613 -0.53570509 0.8788 0.3431 0.838 0.374
0.3808 0.6551 0.05726421 0.1087 0.1660 0.104 0.181
0.1015 0.2404 0.07272053 0.0230 0.0957 0.022 0.104
0.0392 0.1190 0.03951151 0.0053 0.0448 0.005 0.049
0.0277 0.0899 0.08512965 0.0084 0.0935 0.008 0.102
0.0106 0.0441 0.02396853 0.0011 0.0251 0.001 0.027
0.0080 0.0354 0.07356926 0.0027 0.0763 0.003 0.083
0.0023 0.0141 0.05189051 0.0007 0.0526 0.001 0.057
0.0000 0.0000 0.01347175 0.0000 0.0135 0.000 0.015
sumatorias -0.1316 1.0489 0.9172 1.0000 1.0000
1.0000
984.9904 𝑓(𝜑)=∑_(𝑖=1)^𝑐▒ 〖 (𝑧_𝑖∗(1−𝐾_𝑖))/(1+𝜑∗(𝐾_𝑖−1))=0 〗
0.0536
1.0836
0.1360
0.2033 Ⴔ vap* = 0.6288
0.0801

6.8150 6.4040 -0.01228657 0.0146 0.0023 0.014 0.002
0.9281 1.2738 -0.00116803 0.0054 0.0043 0.005 0.005

2.2038 2.5611 -0.53566766 0.8788 0.343 0.838 0.374
0.3807 0.6550 0.05726714 0.1087 0.1660 0.104 0.181
0.1015 0.2404 0.07271597 0.0230 0.0957 0.022 0.104
0.0392 0.1190 0.03950835 0.0053 0.0448 0.005 0.049
0.0277 0.0899 0.08512216 0.0084 0.0935 0.008 0.102
0.0106 0.0441 0.02396634 0.0011 0.0251 0.001 0.027
0.0080 0.0354 0.07356245 0.0027 0.0763 0.003 0.083
0.0023 0.0141 0.05188572 0.0007 0.0526 0.001 0.057
0.0000 0.0000 0.01347054 0.0000 0.0135 0.000 0.015
sumatorias -0.1316 1.0489 0.9172 1.0000 1.0000
Tabla de resultados
Peng Ronbinson
F(MMPCSD) 30 Ⴔ vap* 0.6288
F (lbmol/dia) 79081 yi vapor xi liquido
F (lbmol/hr) 3295.0 N2 0.0139 0.0025
V (lbmol/hr) 2072.1 CO2 0.0052 0.0047
L (lbmol/hr) 1223.0 CH4 0.8379 0.3741
C2H6 0.1037 0.1810
C3H8 0.0219 0.1044
i-C4H10 0.0051 0.0489
n-C4H10 0.0080 0.1020
i-C5H12 0.0011 0.0273
n-C5H12 0.0026 0.0831
n-C6H14 0.0007 0.0574
n-C7H16 0.0000 0.0147
1.0000 1.0000
coef. Binarios
αi (alpha i) aci ai bi yi*bi Kij N2
0.626 148.418 92.910 0.02406 0.00024 N2 0

1.064 396.309 421.780 0.02666 0.00013 CO2 -2.00E-02
0.845 249.464 210.734 0.02678 0.01821 CH4 3.60E-02
1.050 604.358 634.340 0.04049 0.00526 C2H6 5.00E-02
1.168 1017.638 1188.669 0.05631 0.00282 C3H8 8.00E-02
1.239 1443.624 1788.409 0.07238 0.00145 i-C4H10 9.50E-02
1.274 1505.193 1917.974 0.07244 0.00290 n-C4H10 9.00E-02
1.343 1982.271 2663.091 0.08810 0.00088 i-C5H12 9.50E-02
1.373 2069.794 2841.809 0.09018 0.00271 n-C5H12 0.1
1.472 2702.535 3978.784 0.10898 0.00218 n-C6H14 0.149
1.945 7738.627 15049.748 0.21004 0.00105 C7+ 0.1
0.03783
Aij N2
N2 92.9099
CO2 201.9170
Constantes de Antoine CH4 134.8887
B C D E F C2H6 230.6298
-966.243 0 -4.31849 0.000079319 2 C3H8 305.7386
-4735 0 -21.267 0.040908 1 i-C4H10 368.9041
-1307.52 0 -3.26134 0.000029418 2 n-C4C10 384.1437
-2568.82 0 -4.97635 0.0000146447 2 i-C5H12 450.1663
-3490.55 0 -6.10875 0.0000111869 2 n-C5H12 462.4566
-4136.68 0 -7.01666 0.0000103662 2 n-C6H14 517.4110
-4604.09 0 -8.25491 0.0000115706 2 n-C7H16 1064.2364
-5059.18 0 -8.08935 0.00000925395 2
-5117.78 0 -7.48305 0.00000776606 2

-6055.6 0 -8.37865 0.00000661666 2
-8790.09496 0 -7.24898244 3.85E-18 6
+𝜑∗(𝐾_𝑖−1))=0 〗
𝑥_𝑖=𝑦_𝑖/𝐾_𝑖 =𝑧_𝑖/(1+𝜑∗(𝐾_𝑖−1))𝑦_𝑖=(𝑧_𝑖 𝐾_𝑖)/(1+𝜑∗(𝐾_𝑖−1))
Ⴔ 0.65178356
f(Ⴔ) yi xi Yi Norm Xi Norm 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

-0.01204825 0.01420 0.00215 0.01264 0.00279 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
Nº de
-0.00262983 0.00592 0.00329 0.00527 0.00427 iteraciones Z sup
-0.6071 0.89140 0.28431 0.79342 0.36979 1 0.9
-0.0084 0.13292 0.12454 0.11831 0.16198 2 0.8081
0.0385 0.03660 0.07508 0.03258 0.09766 3 0.7842
0.02690756 0.01063 0.03754 0.00946 0.04882 4 0.7826
0.06252691 0.01823 0.08075 0.01622 0.10503 5 0.7826
0.02009488 0.00300 0.02310 0.00267 0.03004 6 0.7826
0.06372893 0.00781 0.07154 0.00695 0.09304 7 0.7826
0.04942743 0.00279 0.05222 0.00248 0.06791
0.01434136 0.00001 0.01435 0.00001 0.01866
-0.3546 1.1235 0.7689 1.0000 1.0000
METODO NEWTON RAPSON Z vapor METODO NEWTON RAPSON
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
iteraciones Z sup f f' Zcal Diferencia Nº de
iteraciones
1 0.9 0.10902578 0.93515106 0.7834 0.1166 1
2 0.7834 0.02260301 0.560996 0.7431 0.0403 2
3 0.7431 0.00225558 0.4506545 0.7381 0.0050 3
4 0.7381 3.26636E-05 0.43762749 0.7380 0.0001 4
5 0.7380 7.20743E-09 0.43743437 0.7380 0.0000 5
6 0.7380 3.40006E-16 0.43743433 0.7380 0.0000 6
7 0.7380 0 0.43743433 0.7380 0.0000 7
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

(𝐴𝐵−𝐵^2−𝐵^3
〖𝑓 )=0
^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3
〖𝑓 )=0
^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
iteraciones
1 0.9 0.08602195 0.90267703 0.8047 0.0953 1
2 0.8047 0.01526178 0.5914575 0.7789 0.0258 2
3 0.7789 0.00097488 0.51656227 0.7770 0.0019 3
4 0.7770 5.0243E-06 0.51124134 0.7770 0.0000 4
5 0.7770 1.3588E-10 0.51121368 0.7770 0.0000 5
6 0.7770 0 0.51121368 0.7770 0.0000 6
7 0.7770 0 0.51121368 0.7770 0.0000 7
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
iteraciones
1 0.8 0.01049051 0.57427818 0.7817 0.0183 1
2 0.7817 0.00048626 0.52137363 0.7808 0.0009 2
3 0.7808 1.23494E-06 0.51872627 0.7808 0.0000 3
4 0.7808 8.03605E-12 0.51871952 0.7808 0.0000 4
5 0.7808 0 0.51871952 0.7808 0.0000 5
6 0.7808 0 0.51871952 0.7808 0.0000 6
7 0.7808 0 0.51871952 0.7808 0.0000 7
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
iteraciones
1 0.8 0.01020705 0.57382721 0.7822 0.0178 1
2 0.7822 0.0004612 0.52228795 0.7813 0.0009 2
3 0.7813 1.10815E-06 0.51977885 0.7813 0.0000 3
4 0.7813 6.45146E-12 0.5197728 0.7813 0.0000 4
5 0.7813 0 0.5197728 0.7813 0.0000 5
6 0.7813 0 0.5197728 0.7813 0.0000 6
7 0.7813 0 0.5197728 0.7813 0.0000 7
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
iteraciones
1 0.8 0.01015171 0.5737396 0.7823 0.0177 1
2 0.7823 0.00045637 0.52246731 0.7814 0.0009 2
3 0.7814 1.08457E-06 0.5199848 0.7814 0.0000 3
4 0.7814 6.17632E-12 0.51997888 0.7814 0.0000 4
5 0.7814 0 0.51997888 0.7814 0.0000 5
6 0.7814 0 0.51997888 0.7814 0.0000 6
7 0.7814 0 0.51997888 0.7814 0.0000 7
𝑓(𝜑)=∑_(𝑖=1)^𝑐▒ 〖 (𝑧_𝑖∗(1−𝐾_𝑖))/(1+𝜑∗(
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
iteraciones
1 0.8 0.01013848 0.57371876 0.7823 0.0177 1
2 0.7823 0.00045522 0.52251033 0.7815 0.0009 2
3 0.7815 1.07898E-06 0.52003416 0.7815 0.0000 3
4 0.7815 6.1119E-12 0.52002827 0.7815 0.0000 4
5 0.7815 0 0.52002827 0.7815 0.0000 5
6 0.7815 0 0.52002827 0.7815 0.0000 6
7 0.7815 0 0.52002827 0.7815 0.0000 7
(1−𝐾_𝑖))/(1+𝜑∗(𝐾_𝑖−1))=0 〗
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
iteraciones
1 0.8 0.01013492 0.57371319 0.7823 0.0177 1
2 0.7823 0.00045492 0.52252192 0.7815 0.0009 2
3 0.7815 1.07749E-06 0.52004746 0.7815 0.0000 3
4 0.7815 6.09479E-12 0.52004157 0.7815 0.0000 4
5 0.7815 0 0.52004157 0.7815 0.0000 5
6 0.7815 0 0.52004157 0.7815 0.0000 6
7 0.7815 0 0.52004157 0.7815 0.0000 7
coef. Binarios
CO2 CH4 C2H6 C3H8 i-C4H10 n-C4H10 i-C5H12 n-C5H12
-2.00E-02 3.60E-02 5.00E-02 8.00E-02 9.50E-02 9.00E-02 9.50E-02 0.1

0 1.00E-01 0.12980001 0.13500001 0.12980001 0.12980001 0.125 0.125
1.00E-01 0 2.24E-03 6.83E-03 1.31E-02 1.23E-02 1.76E-02 1.79E-02
0.12980001 2.24E-03 0 1.26E-03 4.57E-03 4.10E-03 7.41E-03 7.61E-03
0.13500001 6.83E-03 1.26E-03 0 1.04E-03 8.19E-04 2.58E-03 2.70E-03
0.12980001 1.31E-02 4.57E-03 1.04E-03 0 1.34E-05 3.46E-04 3.90E-04
0.12980001 1.23E-02 4.10E-03 8.19E-04 1.34E-05 0 4.95E-04 5.47E-04
0.125 1.76E-02 7.41E-03 2.58E-03 3.46E-04 4.95E-04 0 1.25E-06
0.125 1.79E-02 7.61E-03 2.70E-03 3.90E-04 5.47E-04 1.25E-06 0
0.125 2.35E-02 1.14E-02 5.14E-03 1.57E-03 1.87E-03 4.40E-04 3.93E-04
0.101 4.37E-02 2.68E-02 1.67E-02 9.49E-03 1.02E-02 6.24E-03 6.06E-03

201.9170 134.8887 230.6298 305.7386 368.9041 384.1437 450.1663 462.4566
421.7801 268.3198 450.1145 612.4768 755.7803 782.6787 927.3509 957.9626
268.3198 210.7339 364.7994 497.0748 605.8538 627.9305 735.9298 759.9922
450.1145 364.7989 634.3395 867.2508 1060.2384 1098.4987 1290.0969 1332.4195
612.4768 497.0748 867.2508 1188.6691 1456.5043 1508.6762 1774.5984 1832.9623
755.7803 605.8538 1060.2384 1456.5043 1788.4090 1852.0342 2181.6047 2253.5202
782.6787 627.9305 1098.4987 1508.6762 1852.0342 1917.9741 2258.9118 2333.3566
927.3509 735.9298 1290.0969 1774.5984 2181.6047 2258.9118 2663.0909 2750.9957
957.9626 759.9922 1332.4195 1832.9623 2253.5202 2333.3566 2750.9957 2841.8093
1133.5123 894.1824 1570.5457 2163.5491 2663.3501 2757.3077 3253.6966 3361.2570
2264.9955 1703.0610 3006.9750 4159.0019 5138.7532 5317.8043 6291.2977 6500.1349
NEWTON RAPSON Z vapor METODO NEWTON RAPSON
=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

𝐵^2−𝐵^3
3𝑍 )=0
〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
f f' Zcal Diferencia Nº de
iteraciones Z sup f
0.08208963 0.89358026 0.8081 0.0919 1 0.9 0.64181645
0.01418126 0.59328156 0.7842 0.0239 2 0.5344 0.19922613
0.00084146 0.52344699 0.7826 0.0016 3 0.2851 0.03167982
3.67811E-06 0.51887349 0.7826 0.0000 4 0.2330 -0.00011086
7.13586E-11 0.51885336 0.7826 0.0000 5 0.2331 -4.7202E-09
0 0.51885336 0.7826 0.0000 6 0.2331 0
0 0.51885336 0.7826 0.0000 7 0.2331 0
METODO NEWTON RAPSON Z liquido

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
Z sup f f' Zcal Diferencia
0.9 0.63233368 1.70740907 0.5297 0.3703
0.5297 0.20174926 0.75505091 0.2625 0.2672
0.2625 0.03305937 0.57899568 0.2054 0.0571
0.2054 -0.00041877 0.59692447 0.2061 -0.0007
0.2061 -1.1908E-07 0.59658549 0.2061 0.0000
0.2061 -9.6034E-15 0.5965854 0.2061 0.0000
0.2061 0 0.5965854 0.2061 0.0000

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
(𝐴𝐵−𝐵^2−𝐵^3
〖𝑓 )=0
^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.9 0.59469804 1.64855076 0.5393 0.3607
0.5393 0.19213767 0.7134419 0.2699 0.2693
0.2699 0.0352254 0.52437367 0.2028 0.0672
0.2028 -0.00054206 0.54502474 0.2038 -0.0010
0.2038 -2.5073E-07 0.54452153 0.2038 0.0000
0.2038 -5.3318E-14 0.5445213 0.2038 0.0000
0.2038 0 0.5445213 0.2038 0.0000

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.9 0.58790713 1.63807557 0.5411 0.3589
0.5411 0.19033048 0.70625647 0.2716 0.2695
0.2716 0.03560938 0.51461201 0.2024 0.0692
0.2024 -0.00056437 0.53571236 0.2035 -0.0011
0.2035 -2.8325E-07 0.53517574 0.2035 0.0000
0.2035 -7.0915E-14 0.53517547 0.2035 0.0000
0.2035 0 0.53517547 0.2035 0.0000

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.9 0.58503682 1.63368381 0.5419 0.3581
0.5419 0.18955656 0.70327288 0.2724 0.2695
0.2724 0.03576969 0.510504 0.2023 0.0701
0.2023 -0.0005733 0.53177758 0.2034 -0.0011
0.2034 -2.9734E-07 0.53122713 0.2034 0.0000
0.2034 -7.9492E-14 0.53122685 0.2034 0.0000
0.2034 0 0.53122685 0.2034 0.0000
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.9 0.58383962 1.63185644 0.5422 0.3578
0.5422 0.18923226 0.702036 0.2727 0.2695
0.2727 0.03583623 0.50879311 0.2022 0.0704
0.2022 -0.00057694 0.53013665 0.2033 -0.0011
0.2033 -3.0329E-07 0.52958046 0.2033 0.0000
0.2033 -8.3267E-14 0.52958017 0.2033 0.0000
0.2033 0 0.52958017 0.2033 0.0000
)^𝑐▒ 〖 (𝑧_𝑖∗(1−𝐾_𝑖))/(1+𝜑∗(𝐾_𝑖−1))=0 〗

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.9 0.58337741 1.63115156 0.5424 0.3576
0.5424 0.18910683 0.70155959 0.2728 0.2696
0.2728 0.03586187 0.50813297 0.2022 0.0706
0.2022 -0.00057834 0.52950318 0.2033 -0.0011
0.2033 -3.0561E-07 0.52894478 0.2033 0.0000
0.2033 -8.4766E-14 0.52894448 0.2033 0.0000
0.2033 0 0.52894448 0.2033 0.0000
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.9 0.58320733 1.63089227 0.5424 0.3576
0.5424 0.18906065 0.70138444 0.2728 0.2696
0.2728 0.0358713 0.50789011 0.2022 0.0706
0.2022 -0.00057886 0.52927008 0.2033 -0.0011
0.2033 -3.0646E-07 0.52871086 0.2033 0.0000
0.2033 -8.5376E-14 0.52871057 0.2033 0.0000
0.2033 0 0.52871057 0.2033 0.0000
n-C6H14 C7+
0.149 0.1
0.125 0.101
2.35E-02 4.37E-02
1.14E-02 2.68E-02
5.14E-03 1.67E-02
1.57E-03 9.49E-03
1.87E-03 1.02E-02
4.40E-04 6.24E-03
3.93E-04 6.06E-03
0 3.38E-03
3.38E-03 0
n-C6H14 n-C7H16
yi*yj*Aij N2 CO2 CH4
517.4110 1064.2364 N2 0.00929099 0.01009585 0.9172433
1133.5123 2264.9955 CO2 0.01009585 0.0105445 0.91228733
894.1824 1703.0610 CH4 0.9172433 0.91228733 97.443346
1570.5457 3006.9750 C2H6 0.29981877 0.29257442 32.2482256
2163.5491 4159.0019 C3H8 0.15286928 0.15311919 16.9005448
2663.3501 5138.7532 i-C4H10 0.07378082 0.07557803 8.23961184
2757.3077 5317.8043 n-C4C10 0.15365749 0.15653573 17.0797099
3253.6966 6291.2977 i-C5H12 0.04501663 0.04636754 5.00432258
3361.2570 6500.1349 n-C5H12 0.13873697 0.14369439 15.5038408
3978.7836 7712.0551 n-C6H14 0.10348221 0.11335123 12.1608811
7712.0551 15049.7478 n-C7H16 0.05321182 0.05662489 5.79040745
SUMA 1.95720412 1.97077311 212.200421
TOTAL A 4
Z liquido
−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
0
−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
f' Zcal Diferencia
1.75545881 0.5344 0.3656
0.79930746 0.2851 0.2492
0.60722951 0.2330 0.0522
0.61420113 0.2331 -0.0002
0.61414886 0.2331 0.0000
0.61414886 0.2331 0.0000
0.61414886 0.2331 0.0000
C2H6 C3H8 i-C4H10 n-C4H10 i-C5H12 n-C5H12 n-C6H14 n-C7H16
0.29981877 0.15286928 0.07378082 0.15365749 0.04501663 0.13873697 0.10348221 0.05321182
0.29257442 0.15311919 0.07557803 0.15653573 0.04636754 0.14369439 0.11335123 0.05662489
32.24827 16.9005448 8.23961184 17.0797099 5.00432258 15.5038408 12.1608811 5.79040745
10.7203379 5.63713007 2.75661983 5.7121935 1.67712593 5.19643605 4.08341887 1.95453374
5.63713007 2.97167268 1.45650434 3.01735238 0.88729918 2.74944352 2.16354907 1.03975048
2.75661983 1.45650434 0.71536362 1.48162737 0.43632093 1.35211214 1.06534005 0.51387532
5.7121935 3.01735238 1.48162737 3.06875864 0.90356474 2.80002791 2.20584617 1.06356086
1.67712593 0.88729918 0.43632093 0.90356474 0.26630909 0.82529872 0.65073931 0.31456488
5.19643605 2.74944352 1.35211214 2.80002791 0.82529872 2.55762836 2.01675419 0.97502024
4.08341887 2.16354907 1.06534005 2.20584617 0.65073931 2.01675419 1.59151344 0.77120551
1.95453374 1.03975048 0.51387532 1.06356086 0.31456488 0.97502024 0.77120551 0.3762437
70.5784591 37.129235 18.1667343 37.6428347 11.0569296 34.2589933 26.9260812 12.9089989
464.796663841403
PENG ROBINSON
%comp.
N° de componentes
Peso
componentes Molecular Molar
Zi w
Nitrogeno N2 28.01 1 0.01000 0.038
Metano CH4 16.04 68 0.68000 0.011
Etano C2H6 30.07 13 0.13000 0.099
Propano C3H8 44.1 5 0.05000 0.153
i-Butano i-C4H10 58.12 2 0.02000 0.181
n-Butano n-C4C10 58.12 4 0.04000 0.199
i-Pentano i-C5H12 72.15 1 0.01000 0.228
n-Pentano n-C5H12 72.15 3 0.03000 0.250
n-Hexano n-C6H14 86.18 2 0.02000 0.305
n-Heptano n-C7H16 252 0.5 0.00500 0.442
100 1.00000
DATOS
P (psia) 800
P (kpa) 5515.806
Q (MMPCSD) 30
Q (lbmol/dia) 79080.744
Q (lbmol/hr) 3295.03101
T (F) 40
T ( °R) 500.65
T (K) 206.86
R 8.3144598
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
Nº de
A 530.4559 1 0.9 457.224482 531.074003
B 0.0378 2 0.0391 0.64996569 530.305333
3 0.0378 -1.2712E-06 530.307409
4 0.0378 0 530.307409
Z 0.0378 5 0.0378 0 530.307409
6 0.0378 0 530.307409
7 0.0378 0 530.307409
Ⴔ vap* = 0.0000 Ⴔ liq* =
am vap = 225.3788 am liq =
A vap= 0.4202 A liq =
B vap= 0.0878 B liq =
Z vap = 0.6338 Z liq =
Primera Iteración sup

Componente zi Pvap (Kpa) Ki xi* yi*
Nitrógeno N2 0.01000 66707.633 12.09391 0.0100 0.1209
Dióxido de CO2 0.00500 328.919 0.05963 0.0050 0.0003

Metano CH4 0.68000 7320.465 1.32718 0.6800 0.9025
Etano C2H6 0.13000 294.329 0.05336 0.1300 0.0069
Propano C3H8 0.05000 30.299 0.00549 0.0500 0.0003
i-Butano i-C4H10 0.02000 6.156 0.00112 0.0200 0.0000
n-Butano n-C4H10 0.04000 3.214 0.00058 0.0400 0.0000
i-Pentano i-C5H12 0.01000 0.646 0.00012 0.0100 0.0000
n-Pentano n-C5H12 0.03000 0.377 0.00007 0.0300 0.0000
n-Hexano n-C6H14 0.02000 0.039 0.00001 0.0200 0.0000
n-Heptano nC7+ 0.00500 0.000 0.00000 0.0050 0.0000
sumatorias 1.00000 1.03098
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 247.2757 am liq =
A vap= 0.4611 A liq =
B vap= 0.0872 B liq =
Z vap = 0.5268 Z liq =
2da Iteración
Componente Yi Normalizado Xi Normalizadoa vap i a liq i φ vap
Nitrógeno N2 0.043 0.010 162.5829 232.2808 1.1413
Dióxido de CO2 0.002 0.005 317.8958 458.7538 0.5251
Metano CH4 0.923 0.680 244.3066 356.8008 0.7645
Etano C2H6 0.027 0.130 421.4770 618.7163 0.3355

Propano C3H8 0.003 0.050 573.7120 845.8440 0.1692
i-Butano i-C4H10 0.000 0.020 698.6326 1033.7394 0.0982
n-Butano n-C4H10 0.001 0.040 724.4001 1071.3437 0.0862
i-Pentano i-C5H12 0.000 0.010 848.7495 1258.1759 0.0501
n-Pentano n-C5H12 0.000 0.030 877.5858 1301.2336 0.0437
n-Hexano n-C6H14 0.000 0.020 1032.9134 1536.4341 0.0221
n-Heptano nC7+ 0.000 0.005 1956.4630 2922.6876 0.0004
1.0000 1.0000
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 259.5996 am liq =
A vap= 0.4841 A liq =
B vap= 0.0887 B liq =
Z vap = 0.4551 Z liq =
3ra Iteración
Componente Yi Normalizado Xi Normalizado a vap i a liq i φ vap
Nitrógeno N2 0.033 0.010 166.3486 232.2808 1.2146
Dióxido de CO2 0.003 0.005 324.9772 458.7538 0.4600
Metano CH4 0.912 0.680 250.3227 356.8008 0.7361
Etano C2H6 0.043 0.130 431.9980 618.7163 0.2689

Propano C3H8 0.006 0.050 588.2666 845.8440 0.1176
i-Butano i-C4H10 0.001 0.020 716.5409 1033.7394 0.0615
n-Butano n-C4H10 0.002 0.040 742.9284 1071.3437 0.0521
i-Pentano i-C5H12 0.000 0.010 870.5704 1258.1759 0.0273
n-Pentano n-C5H12 0.001 0.030 900.1882 1301.2336 0.0231
n-Hexano n-C6H14 0.000 0.020 1060.0131 1536.4341 0.0102
n-Heptano nC7+ 0.000 0.005 2007.3686 2922.6876 0.0001
1.0000 1.0000
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 201.0321 am liq =
A vap= 0.3748 A liq =
B vap= 0.0781 B liq =
Z vap = 0.6748 Z liq =
4ta Iteración
Nitrógeno N2 0.033 0.010 146.4074 232.2808 0.9642
Dióxido de CO2 0.003 0.005 286.1092 458.7538 0.4941
Metano CH4 0.798 0.680 220.2827 356.8008 0.6834
Etano C2H6 0.038 0.130 380.1491 618.7163 0.3426

Propano C3H8 0.005 0.050 517.6275 845.8440 0.1945
i-Butano i-C4H10 0.001 0.020 630.4872 1033.7394 0.1249
n-Butano n-C4H10 0.002 0.040 653.7135 1071.3437 0.1115
i-Pentano i-C5H12 0.000 0.010 766.0329 1258.1759 0.0715
n-Pentano n-C5H12 0.001 0.030 792.0828 1301.2336 0.0639
n-Hexano n-C6H14 0.000 0.020 932.5907 1536.4341 0.0365
n-Heptano nC7+ 0.000 0.005 1766.4769 2922.6876 0.0012
0.8803 1.0000
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 246.4647 am liq =
A vap= 0.4596 A liq =
B vap= 0.0871 B liq =
Z vap = 0.5308 Z liq =
5ta Iteración
Componente Yi Normalizado Xi Normalizadoa vap i a liq i φ vap
Nitrógeno N2 0.044 0.010 162.3291 232.2808 1.0713
Dióxido de CO2 0.002 0.005 317.4202 458.7538 0.4229
Metano CH4 0.924 0.680 243.9053 356.8008 0.6666
Etano C2H6 0.026 0.130 420.7762 618.7163 0.2592

Propano C3H8 0.003 0.050 572.7431 845.8440 0.1202
i-Butano i-C4H10 0.000 0.020 697.4404 1033.7394 0.0662
n-Butano n-C4H10 0.001 0.040 723.1666 1071.3437 0.0565
i-Pentano i-C5H12 0.000 0.010 847.2966 1258.1759 0.0311
n-Pentano n-C5H12 0.000 0.030 876.0809 1301.2336 0.0266
n-Hexano n-C6H14 0.000 0.020 1031.1095 1536.4341 0.0125
n-Heptano nC7+ 0.000 0.005 1953.0696 2922.6876 0.0001
1.0000 1.0000
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 250.6654 am liq =
A vap= 0.4674 A liq =
B vap= 0.0876 B liq =
Z vap = 0.5308 Z liq =
6ta Iteración
Nitrógeno N2 0.040 0.010 163.6263 232.2808 1.0660
Dióxido de CO2 0.002 0.005 319.8425 458.7538 0.4094
Metano CH4 0.920 0.680 245.9768 356.8008 0.6540
Etano C2H6 0.032 0.130 424.3987 618.7163 0.2490

Propano C3H8 0.004 0.050 577.7567 845.8440 0.1138
i-Butano i-C4H10 0.001 0.020 703.6093 1033.7394 0.0621
n-Butano n-C4H10 0.001 0.040 729.5484 1071.3437 0.0528
i-Pentano i-C5H12 0.000 0.010 854.8111 1258.1759 0.0288
n-Pentano n-C5H12 0.000 0.030 883.8655 1301.2336 0.0245
n-Hexano n-C6H14 0.000 0.020 1040.4541 1536.4341 0.0114
n-Heptano nC7+ 0.000 0.005 1970.5782 2922.6876 0.0001
1.0000 1.0000
SON
126.24 227.232 33.94 492.266 3394.053 1.639 1.625 0.43240

304.25 547.65 73.83 1070.830 7383.115 0.680 0.747 0.70599
190.62 343.116 46.04 667.764 4604.072 1.085 1.198 0.39126
305.46 549.828 48.80 707.795 4880.076 0.677 1.130 0.52468
369.86 665.748 42.49 616.275 4249.066 0.559 1.298 0.60429
408.18 734.724 36.48 529.106 3648.057 0.507 1.512 0.64466
425.22 765.396 37.97 550.717 3797.059 0.486 1.453 0.67086
460.47 828.846 33.81 490.380 3381.053 0.449 1.631 0.71153
469.69 845.442 33.69 488.640 3369.053 0.440 1.637 0.74277
507.47 913.446 30.12 436.860 3012.047 0.408 1.831 0.81937
754.00 1213.67 336.800 2322.154 0.274 2.375 1.00333
446.3938 649.779
Co
A
Nitrógeno 35.4113
Metano 31.35
Etano 44.0103
Propano 52.3785
i-Butano 58.7845
−2𝐵−3𝐵^2 )𝑍− n-Butano 66.945
2𝐵−3𝐵^2 )=0 i-Pentano 66.7563
Zcal Diferencia
n-Pentano 63.3315
0.0391 0.8609 n-Hexano 70.4265
0.0378 0.0012 n-Heptano 67.6419512
0.0378 0.0000
0.0378 0.0000
0.0378 0.0000
0.0378 0.0000
0.0378 0.0000
1.0000 𝑓(𝜑)=∑_(𝑖=1)^𝑐▒ 〖 (𝑧_𝑖∗(1−𝐾_𝑖))/(1+𝜑∗(𝐾_𝑖−1))=0 〗
530.4559
0.0378
0.9891
0.1213
0.1794
0.0559
xi* norm yi* norm a vap i a liq i φ vap φ liq Ki P-R yi

0.01 0.1173 155.8539 232.2808 0.9868 4.1705 4.2263 0.0423
0.005 0.0003 306.4109 458.7538 0.4593 0.2094 0.4560 0.0023

0.68 0.8754 233.1886 356.8008 0.6738 0.8897 1.3205 0.8979
0.13 0.0067 401.9742 618.7163 0.3120 0.0639 0.2047 0.0266
0.05 0.0003 546.3029 845.8440 0.1670 0.0088 0.0528 0.0026
0.02 0.0000 664.7896 1033.7394 0.1025 0.0022 0.0210 0.0004
0.04 0.0000 689.4846 1071.3437 0.0901 0.0013 0.0141 0.0006
0.01 0.0000 807.7230 1258.1759 0.0552 0.0003 0.0055 0.0001
0.03 0.0000 834.9413 1301.2336 0.0487 0.0002 0.0040 0.0001
0.02 0.0000 980.2016 1536.4341 0.0266 0.0000 0.0011 0.0000
0.005 0.0000 1862.9066 2922.6876 0.0006 0.0000 0.0000 0.0000
1.00000 1.00000 sumatorias 0.9729
1.0000
530.4559
0.0378
0.9891
0.1213 T(K) 250
0.1794
0.0559
φ liq Ki P-R yi xi Yi Normalizado Xi Normalizado

4.8679 4.2653 0.0427 0.01 0.033 0.010
0.4056 0.7725 0.0039 0.005 0.003 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
1.3420 1.7553 1.1936 0.68000 0.912 0.680 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.1442 0.4297 0.0559 0.13000 0.043 0.130 iteraciones
0.0264 0.1559 0.0078 0.05000 0.006 0.050 1
0.0077 0.0788 0.0016 0.02 0.001 0.020 2
0.0050 0.0582 0.0023 0.04 0.002 0.040 3
0.0015 0.0290 0.0003 0.01 0.000 0.010 4
0.0010 0.0228 0.0007 0.03 0.001 0.030 5
0.0002 0.0090 0.0002 0.02 0.000 0.020 6
0.0000 0.0000 0.0000 0.005 0.000 0.005 7
sumatorias 1.3088 1.0000 1.0000 1.0000
1.0000
530.4559
0.0378
0.9891
0.1213 T(K) 230
0.1794
0.0559

4.5639 3.7577 0.0376 0.01 0.033 0.010
0.3079 0.6694 0.0033 0.005 0.003 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
1.1306 1.5360 1.0445 0.68000 0.798 0.680 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.1027 0.3819 0.0496 0.13000 0.038 0.130 iteraciones
0.0167 0.1420 0.0071 0.05000 0.005 0.050 1
0.0045 0.0739 0.0015 0.02 0.001 0.020 2
0.0028 0.0543 0.0022 0.04 0.002 0.040 3
0.0008 0.0279 0.0003 0.01 0.000 0.010 4
0.0005 0.0219 0.0007 0.03 0.001 0.030 5
0.0001 0.0089 0.0002 0.02 0.000 0.020 6
0.0000 0.0000 0.0000 0.005 0.000 0.005 7
sumatorias 1.1469 1.0000 0.8803 1.0000
1.0000
530.4559
0.0378
0.9891
0.1213 T(K) 210
0.1794
0.0559
4.2268 4.3836 0.0438 0.01 0.044 0.010
0.2218 0.4488 0.0022 0.005 0.002 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
0.9219 1.3490 0.9173 0.68000 0.924 0.680 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.0685 0.2001 0.0260 0.13000 0.026 0.130 iteraciones
0.0097 0.0498 0.0025 0.05000 0.003 0.050 1
0.0024 0.0193 0.0004 0.02 0.000 0.020 2
0.0014 0.0129 0.0005 0.04 0.001 0.040 3
0.0004 0.0049 0.0000 0.01 0.000 0.010 4
0.0002 0.0035 0.0001 0.03 0.000 0.030 5
0.0000 0.0010 0.0000 0.02 0.000 0.020 6
0.0000 0.0000 0.0000 0.005 0.000 0.005 7
sumatorias 0.9930 1.0000 1.0000 1.0000
1.0000
530.4559
0.0378
0.9891
0.1213 T(K) 205
0.1794
0.0559

4.1367 3.8616 0.0386 0.01 0.040 0.010
0.2023 0.4783 0.0024 0.005 0.002 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
0.8707 1.3061 0.8881 0.68000 0.920 0.680 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.0612 0.2361 0.0307 0.13000 0.032 0.130 iteraciones
0.0083 0.0692 0.0035 0.05000 0.004 0.050 1
0.0020 0.0304 0.0006 0.02 0.001 0.020 2
0.0012 0.0210 0.0008 0.04 0.001 0.040 3
0.0003 0.0091 0.0001 0.01 0.000 0.010 4
0.0002 0.0068 0.0002 0.03 0.000 0.030 5
0.0000 0.0022 0.0000 0.02 0.000 0.020 6
0.0000 0.0000 0.0000 0.005 0.000 0.005 7
sumatorias 0.9651 1.0000 1.0000 1.0000
1.0000
530.4559
0.0378
0.9891
0.1213 T(K) 200
0.1794
0.0559
φ liq Ki P-R yi xi Yi Normalizado Xi Normalizado xi*ki-1

4.0443 3.7939 0.0379 0.01 0.041 0.010 0.0379
0.1836 0.4486 0.0022 0.005 0.002 0.005 0.0022 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
0.8199 1.2536 0.8524 0.68000 0.858 0.680 0.8524 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.0543 0.2182 0.0284 0.13000 0.029 0.130 0.0284 iteraciones
0.0071 0.0622 0.0031 0.05000 0.003 0.050 0.0031 1
0.0017 0.0269 0.0005 0.02 0.001 0.020 0.0005 2
0.0010 0.0184 0.0007 0.04 0.001 0.040 0.0007 3
0.0002 0.0078 0.0001 0.01 0.000 0.010 0.0001 4
0.0001 0.0058 0.0002 0.03 0.000 0.030 0.0002 5
0.0000 0.0018 0.0000 0.02 0.000 0.020 0.0000 6
0.0000 0.0000 0.0000 0.005 0.000 0.005 0.0000 7
sumatorias 0.9256 1.0000 0.9350 1.0000 -0.0744
Constantes para mi w<0,49 Constantes para aci y bi
C1 C2 C3 Ωa Ωb
0.37464 1.54226 0.26992 0.45724 0.0778
Constantes para mi w>0,49
C1 C2 C3 C4
0.37964 1.485 0.1644 0.01667
coef. Binarios
αi (alpha i) aci aci*αi bi yi*bi Kij N2
0.772 148.4184 114.645 0.02406 0.00024 N2 0.0000

1.263 396.3089 500.561 0.02666 0.00013 CO2 -0.0200
0.968 249.4636 241.384 0.02678 0.01821 CH4 0.0360
1.194 604.3582 721.872 0.04049 0.00526 C2H6 0.0500
1.328 1017.6385 1351.370 0.05631 0.00282 C3H8 0.0800
1.406 1443.6241 2029.681 0.07238 0.00145 i-C4H10 0.0950
1.447 1505.1933 2178.145 0.07244 0.00290 n-C4H10 0.0900
1.524 1982.2710 3021.586 0.08810 0.00088 i-C5H12 0.0950
1.562 2069.7941 3233.219 0.09018 0.00271 n-C5H12 0.1000
1.680 2702.5348 4540.869 0.10898 0.00218 n-C6H14 0.1490
2.184 7738.6271 16900.314 0.21004 0.00105 C7+ 0.1000
0.03783
Aij N2
N2 114.645
CO2 244.346
B C D E F C2H6 273.295
-966.243 0 -4.31849 0.000079319 2 C3H8 362.121
-4735 0 -21.267 0.040908 1 i-C4H10 436.557
-1307.52 0 -3.26134 0.000029418 2 n-C4C10 454.740
-2568.82 0 -4.97635 0.0000146447 2 i-C5H12 532.654
-3490.55 0 -6.10875 0.0000111869 2 n-C5H12 547.947
-4136.68 0 -7.01666 0.0000103662 2 n-C6H14 614.013
-4604.09 0 -8.25491 0.0000115706 2 C7+ 1252.761
-5059.18 0 -8.08935 0.00000925395 2
-5117.78 0 -7.48305 0.00000776606 2

-6055.6 0 -8.37865 0.00000661666 2
-8790.09496 0 -7.24898244 3.85E-18 6
+𝜑∗(𝐾_𝑖−1))=0 〗
xi yi norm xi norm 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

0.01 0.043 0.010 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.005 0.002 0.005

Nº de
iteraciones Z sup f
0.68000 0.923 0.680 1 0.9 0.16091659
0.13000 0.027 0.130 2 0.7406 0.04137434
0.05000 0.003 0.050 3 0.6604 0.00791033
0.02 0.000 0.020 4 0.6361 0.00061884
0.04 0.001 0.040 5 0.6338 5.04159E-06
0.01 0.000 0.010 6 0.6338 3.442E-10
0.03 0.000 0.030 7 0.6338 0
0.02 0.000 0.020
0.005 0.000 0.005
1.0000 1.0000 1.0000
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
Z sup f f' Zcal Diferencia Nº de
iteraciones Z sup
0.9 0.19523852 1.05085042 0.7142 0.1858 1 0.9
0.7142 0.05527649 0.49032917 0.6015 0.1127 2 0.5480
0.6015 0.01419643 0.25117959 0.5450 0.0565 3 0.2636
0.5450 0.00266754 0.15997962 0.5283 0.0167 4 0.1767
0.5283 0.00019611 0.13673513 0.5268 0.0014 5 0.1794
0.5268 1.37938E-06 0.13481367 0.5268 0.0000 6 0.1794
0.5268 6.99004E-11 0.13480001 0.5268 0.0000 7 0.1794
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 0.21127976 1.07273312 0.7030 0.1970 1 0.9
0.7030 0.06174429 0.48453425 0.5756 0.1274 2 0.5480
0.5756 0.01738119 0.22797721 0.4994 0.0762 3 0.2636
0.4994 0.00429714 0.1210645 0.4639 0.0355 4 0.1767
0.4639 0.00069456 0.08318835 0.4555 0.0083 5 0.1794
0.4555 3.29E-05 0.07537711 0.4551 0.0004 6 0.1794
0.4551 8.66469E-08 0.07498027 0.4551 0.0000 7 0.1794
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 0.13988374 0.9709313 0.7559 0.1441 1 0.9
0.7559 0.03391685 0.52085515 0.6908 0.0651 2 0.5480
0.6908 0.00543082 0.35829521 0.6757 0.0152 3 0.2636
0.6757 0.00026085 0.32410653 0.6748 0.0008 4 0.1767
0.6748 7.15257E-07 0.32232974 0.6748 0.0000 5 0.1794
0.6748 5.4295E-12 0.32232485 0.6748 0.0000 6 0.1794
0.6748 -1.0061E-16 0.32232485 0.6748 0.0000 7 0.1794
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 0.19417855 1.04940919 0.7150 0.1850 1 0.9
0.7150 0.05485069 0.49078274 0.6032 0.1118 2 0.5480
0.6032 0.01399193 0.25288458 0.5479 0.0553 3 0.2636
0.5479 0.00257562 0.16284452 0.5321 0.0158 4 0.1767
0.5321 0.00017883 0.14048151 0.5308 0.0013 5 0.1794
0.5308 1.10509E-06 0.1387469 0.5308 0.0000 6 0.1794
0.5308 4.31002E-11 0.13873607 0.5308 0.0000 7 0.1794
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 0.19417855 1.04940919 0.7150 0.1850 1 0.9
0.7150 0.05485069 0.49078274 0.6032 0.1118 2 0.5480
0.6032 0.01399193 0.25288458 0.5479 0.0553 3 0.2636
0.5479 0.00257562 0.16284452 0.5321 0.0158 4 0.1767
0.5321 0.00017883 0.14048151 0.5308 0.0013 5 0.1794
0.5308 1.10509E-06 0.1387469 0.5308 0.0000 6 0.1794
0.5308 4.31002E-11 0.13873607 0.5308 0.0000 7 0.1794
coef. Binarios
-0.0200 0.0360 0.0500 0.0800 0.0950 0.0900 0.0950 0.1000

0.0000 0.1000 0.1298 0.1350 0.1298 0.1298 0.1250 0.1250
0.1000 0.0000 0.0022 0.0068 0.0131 0.0123 0.0176 0.0179
0.1298 0.0022 0.0000 0.0013 0.0046 0.0041 0.0074 0.0076
0.1350 0.0068 0.0013 0.0000 0.0010 0.0008 0.0026 0.0027
0.1298 0.0131 0.0046 0.0010 0.0000 0.0000 0.0003 0.0004
0.1298 0.0123 0.0041 0.0008 0.0000 0.0000 0.0005 0.0005
0.1250 0.0176 0.0074 0.0026 0.0003 0.0005 0.0000 0.0000
0.1250 0.0179 0.0076 0.0027 0.0004 0.0005 0.0000 0.0000
0.1250 0.0235 0.0114 0.0051 0.0016 0.0019 0.0004 0.0004
0.1010 0.0437 0.0268 0.0167 0.0095 0.0102 0.0062 0.0061

244.346 160.365 273.295 362.121 436.557 454.740 532.654 547.947
500.561 312.842 523.092 711.429 877.125 908.638 1076.104 1113.151
312.842 241.384 416.496 567.239 690.773 716.178 838.973 867.594
523.092 416.495 721.872 986.440 1204.906 1248.794 1465.940 1516.109
711.429 567.239 986.440 1351.370 1654.432 1714.252 2015.492 2084.636
877.125 690.773 1204.906 1654.432 2029.681 2102.575 2475.603 2560.719
908.638 716.178 1248.794 1714.252 2102.575 2178.145 2564.164 2652.303
1076.104 838.973 1465.940 2015.492 2475.603 2564.164 3021.586 3125.608
1113.151 867.594 1516.109 2084.636 2560.719 2652.303 3125.608 3233.219
1319.186 1022.369 1789.840 2464.437 3031.119 3139.074 3702.507 3830.153
2614.783 1931.525 3399.241 4699.249 5801.242 6005.334 7101.457 7347.257
Z vapor METODO NEWTON RAPSON Z liquido
−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
0
−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
f' Zcal Diferencia Nº de
1.00953305 0.7406 0.1594 1 0.9 0.54587337 1.55068457
0.51580487 0.6604 0.0802 2 0.5480 0.18207209 0.64016414
0.32500637 0.6361 0.0243 3 0.2636 0.03889517 0.44754558
0.27474668 0.6338 0.0023 4 0.1767 -0.00132107 0.48550009
0.27027515 0.6338 0.0000 5 0.1794 -2.5618E-06 0.48362452
0.27023825 0.6338 0.0000 6 0.1794 -9.5558E-12 0.48362091
0.27023824 0.6338 0.0000 7 0.1794 0 0.48362091
NEWTON RAPSON Z liquido

=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
f f' Zcal Diferencia
0.54587337 1.55068457 0.5480 0.3520
0.18207209 0.64016414 0.2636 0.2844
0.03889517 0.44754558 0.1767 0.0869
-0.00132107 0.48550009 0.1794 -0.0027
-2.5618E-06 0.48362452 0.1794 0.0000
-9.5558E-12 0.48362091 0.1794 0.0000
0 0.48362091 0.1794 0.0000

=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.54587337 1.55068457 0.5480 0.3520
0.18207209 0.64016414 0.2636 0.2844
0.03889517 0.44754558 0.1767 0.0869
-0.00132107 0.48550009 0.1794 -0.0027
-2.5618E-06 0.48362452 0.1794 0.0000
-9.5558E-12 0.48362091 0.1794 0.0000
0 0.48362091 0.1794 0.0000
=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.54587337 1.55068457 0.5480 0.3520
0.18207209 0.64016414 0.2636 0.2844
0.03889517 0.44754558 0.1767 0.0869
-0.00132107 0.48550009 0.1794 -0.0027
-2.5618E-06 0.48362452 0.1794 0.0000
-9.5558E-12 0.48362091 0.1794 0.0000
0 0.48362091 0.1794 0.0000

=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.54587337 1.55068457 0.5480 0.3520
0.18207209 0.64016414 0.2636 0.2844
0.03889517 0.44754558 0.1767 0.0869
-0.00132107 0.48550009 0.1794 -0.0027
-2.5618E-06 0.48362452 0.1794 0.0000
-9.5558E-12 0.48362091 0.1794 0.0000
0 0.48362091 0.1794 0.0000
=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.54587337 1.55068457 0.5480 0.3520
0.18207209 0.64016414 0.2636 0.2844
0.03889517 0.44754558 0.1767 0.0869
-0.00132107 0.48550009 0.1794 -0.0027
-2.5618E-06 0.48362452 0.1794 0.0000
-9.5558E-12 0.48362091 0.1794 0.0000
0 0.48362091 0.1794 0.0000
n-C6H14 C7+
0.1490 0.1000
0.1250 0.1010
0.0235 0.0437
0.0114 0.0268
0.0051 0.0167
0.0016 0.0095
0.0019 0.0102
0.0004 0.0062
0.0004 0.0061
0.0000 0.0034
0.0034 0.0000
n-C6H14 C7+
614.013 1252.761 N2 0.01146454 0.01221732 1.09048413
1319.186 2614.783 CO2 0.01221732 0.01251403 1.06366428
1022.369 1931.525 CH4 1.09048413 1.06366428 111.616126
1789.840 3399.241 C2H6 0.35528393 0.34000965 36.8181984
2464.437 4699.249 C3H8 0.18106072 0.17785734 19.2861118
3031.119 5801.242 i-C4H10 0.08731147 0.08771251 9.39451925
3139.074 6005.334 n-C4C10 0.18189601 0.18172767 19.4800417
3702.507 7101.457 i-C5H12 0.05326536 0.05380518 5.70501949
3830.153 7347.257 n-C5H12 0.16438406 0.16697269 17.6989193
4540.869 8730.663 n-C6H14 0.12280257 0.13191863 13.9042243
8730.663 16900.314 n-C7H16 0.06263806 0.06536958 6.56718533
SUMA 2.32280818 2.29376887 242.624494
TOTAL A 5
Z liquido
−2𝐵−3𝐵^2 )𝑍−
2𝐵−3𝐵^2 )=0
Zcal Diferencia
0.5480 0.3520
0.2636 0.2844
0.1767 0.0869
0.1794 -0.0027
0.1794 0.0000
0.1794 0.0000
0.1794 0.0000
0.35528393 0.18106072 0.08731147 0.18189601 0.05326536 0.16438406 0.12280257 0.06263806
0.34000965 0.17785734 0.08771251 0.18172767 0.05380518 0.16697269 0.13191863 0.06536958
36.8182491 19.2861118 9.39451925 19.4800417 5.70501949 17.6989193 13.9042243 6.56718533
12.1996435 6.41185934 3.13275648 6.49373044 1.90572163 5.91282451 4.65358452 2.20950645
6.41185934 3.37842411 1.65443158 3.42850387 1.00774612 3.12695385 2.46443683 1.17481234
3.13275648 1.65443158 0.81187227 1.68205981 0.49512053 1.53643153 1.21244774 0.58012417
6.49373044 3.42850387 1.68205981 3.48503191 1.0256655 3.18276406 2.51125942 1.20106672
1.90572163 1.00774612 0.49512053 1.0256655 0.30215856 0.93768226 0.74050134 0.35507285
5.91282451 3.12695385 1.53643153 3.18276406 0.93768226 2.90989675 2.29809184 1.1020885
4.65358452 2.46443683 1.21244774 2.51125942 0.74050134 2.29809184 1.81634773 0.87306632
2.20950645 1.17481234 0.58012417 1.20106672 0.35507285 1.1020885 0.87306632 0.42250784
80.4331696 42.2921979 20.6747873 42.853747 12.5817588 39.0370093 30.7286812 14.6134382
530.455860327898
PENG ROBINSON
%comp.
N° de componentes componentes Peso Molecular Molar
Zi w
Nitrogeno N2 28.01 1 0.01000 0.038
Metano CH4 16.04 68 0.68000 0.011
Etano C2H6 30.07 13 0.13000 0.099
Propano C3H8 44.1 5 0.05000 0.153
i-Butano i-C4H10 58.12 2 0.02000 0.181
n-Butano n-C4C10 58.12 4 0.04000 0.199
i-Pentano i-C5H12 72.15 1 0.01000 0.228
n-Pentano n-C5H12 72.15 3 0.03000 0.250
n-Hexano n-C6H14 86.18 2 0.02000 0.305
n-Heptano n-C7H16 252 0.5 0.00500 0.442
100 1.00000
DATOS
P (psia) 700
P (kpa) 4826.330
Q (MMPCSD) 30
Q (lbmol/dia) 79080.744
Q (lbmol/hr) 3295.03101
T (F) 50
T ( °R) 510.65
T (K) 445.82
R 8.3144598
Ⴔ vap* = 0.0000 Ⴔ liq* =
am vap = 348.9909 am liq =
A vap= 0.1226 A liq =
B vap= 0.0493 B liq =
Z vap = 0.9368 Z liq =
Primera Iteración sup

Componente zi Pvap (Kpa) Ki yi* xi*
Nitrógeno N2 0.01000 6980568006.2 ### 0.0100 0.0000
Dióxido de CO2 0.00500 99684.9 20.65438 0.0050 0.0002

Metano CH4 0.68000 1741330.5 360.79805 0.6800 0.0019
Etano C2H6 0.13000 49199.5 10.19397 0.1300 0.0128
Propano C3H8 0.05000 13487.9 2.79465 0.0500 0.0179
i-Butano i-C4H10 0.02000 6405.7 1.32724 0.0200 0.0151
n-Butano n-C4H10 0.04000 5235.3 1.08473 0.0400 0.0369
i-Pentano i-C5H12 0.01000 2705.8 0.56062 0.0100 0.0178
n-Pentano n-C5H12 0.03000 2320.5 0.48080 0.0300 0.0624
n-Hexano n-C6H14 0.02000 1152.2 0.23873 0.0200 0.0838
n-Heptano n-C7H16 0.00500 42.0 0.00870 0.0050 0.57
sumatorias 1.00 0.82
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 1715.3796 am liq =
A vap= 0.6026 A liq =
B vap= 0.0493 B liq =
Z vap = 0.0614 Z liq =
2da Iteración vapor

Componente xi yi a vap i a liq i φ vap
Nitrógeno N2 0.0003 0.01 638.1983 132.8321 24.5286
Dióxido de CO2 0.0005 0.005 1428.5302 281.8142 0.1757
Metano CH4 0.0443 0.68 1127.3673 233.2650 1.3283
Etano C2H6 0.0209 0.13 2004.9212 409.0512 0.0216

Propano C3H8 0.0155 0.05 2774.9178 560.1691 0.0009
i-Butano i-C4H10 0.0099 0.02 3434.1683 686.6391 0.0001
n-Butano n-C4H10 0.0238 0.04 3551.2417 710.8273 0.0000
i-Pentano i-C5H12 0.0096 0.01 4204.5995 836.0899 0.0000
n-Pentano n-C5H12 0.0326 0.03 4329.8757 860.6937 0.0000
n-Hexano n-C6H14 0.0387 0.02 5116.6048 1010.9528 0.0000
n-Heptano n-C7H16 0.8038 0.005 10170.4351 1976.3063 0.0000
1.0000 1.0000
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 348.9909 am liq =
A vap= 0.1226 A liq =
B vap= 0.0493 B liq =
Z vap = 0.9368 Z liq =
3ra Iteración
Nitrógeno N2 0.204 0.010 132.8321 84.3960 1.0567
Dióxido de CO2 0.001 0.005 281.8142 179.1113 0.9053
Metano CH4 0.792 0.680 233.2650 143.7623 0.9552
Etano C2H6 0.003 0.130 409.0512 250.4299 0.8251

Propano C3H8 0.000 0.050 560.1691 340.4548 0.7376
i-Butano i-C4H10 0.000 0.020 686.6391 415.3087 0.6780
n-Butano n-C4H10 0.000 0.040 710.8273 430.3568 0.6603
i-Pentano i-C5H12 0.000 0.010 836.0899 504.9276 0.6069
n-Pentano n-C5H12 0.000 0.030 860.6937 519.3920 0.5950
n-Hexano n-C6H14 0.000 0.020 1010.9528 605.1293 0.5377
n-Heptano n-C7H16 0.000 0.005 1976.3063 1186.1265 0.2627
1.0000 1.0000
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 348.9909 am liq =
A vap= 0.1226 A liq =
B vap= 0.0493 B liq =
Z vap = 0.9368 Z liq =
4ta Iteración
Nitrógeno N2 0.011 0.010 132.8321 126.8354 1.0501
Dióxido de CO2 0.005 0.005 281.8142 268.4280 0.8650
Metano CH4 0.707 0.680 233.2650 222.1840 0.9257
Etano C2H6 0.127 0.130 409.0512 389.3644 0.7743

Propano C3H8 0.046 0.050 560.1691 532.9434 0.6768
i-Butano i-C4H10 0.018 0.020 686.6391 652.9769 0.6129
n-Butano n-C4H10 0.035 0.040 710.8273 676.0146 0.5929
i-Pentano i-C5H12 0.008 0.010 836.0899 794.9028 0.5367
n-Pentano n-C5H12 0.025 0.030 860.6937 818.2796 0.5239
n-Hexano n-C6H14 0.016 0.020 1010.9528 960.8504 0.4649
n-Heptano n-C7H16 0.003 0.005 1976.3063 1876.9837 0.1969
1.0000 1.0000
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 348.9909 am liq =
A vap= 0.1226 A liq =
B vap= 0.0493 B liq =
Z vap = 0.9368 Z liq =
5ta Iteración
Nitrógeno N2 0.010 0.010 132.8321 131.8030 1.0390
Dióxido de CO2 0.005 0.005 281.8142 279.5135 0.8005
Metano CH4 0.684 0.680 233.2650 231.3668 0.8774
Etano C2H6 0.129 0.130 409.0512 405.6779 0.6946

Propano C3H8 0.049 0.050 560.1691 555.5032 0.5845
i-Butano i-C4H10 0.020 0.020 686.6391 680.8691 0.5159
n-Butano n-C4H10 0.039 0.040 710.8273 704.8602 0.4933
i-Pentano i-C5H12 0.010 0.010 836.0899 829.0293 0.4351
n-Pentano n-C5H12 0.029 0.030 860.6937 853.4226 0.4216
n-Hexano n-C6H14 0.019 0.020 1010.9528 1002.3630 0.3628
n-Heptano n-C7H16 0.005 0.005 1976.3063 1959.2712 0.1204
1.0000 1.0000
Ⴔ vap* = 0.0000 Ⴔ liq* =

am vap = 348.9909 am liq =
A vap= 0.1226 A liq =
B vap= 0.0493 B liq =
Z vap = 0.9368 Z liq =
6ta Iteración
Nitrógeno N2 0.010 0.010 132.8321 132.1343 1.0333
Dióxido de CO2 0.005 0.005 281.8142 280.2513 0.7694
Metano CH4 0.683 0.680 233.2650 231.9771 0.8537
Etano C2H6 0.130 0.130 409.0512 406.7622 0.6572

Propano C3H8 0.050 0.050 560.1691 557.0028 0.5423
i-Butano i-C4H10 0.020 0.020 686.6391 682.7232 0.4724
n-Butano n-C4H10 0.039 0.040 710.8273 706.7776 0.4490
i-Pentano i-C5H12 0.010 0.010 836.0899 831.2978 0.3909
n-Pentano n-C5H12 0.029 0.030 860.6937 855.7588 0.3773
n-Hexano n-C6H14 0.019 0.020 1010.9528 1005.1229 0.3196
n-Heptano n-C7H16 0.005 0.005 1976.3063 1964.7418 0.0936
1.0000 1.0000
ON
126.24 227.232 33.94 492.266 3394.053 3.531 1.422 0.43240

304.25 547.65 73.83 1070.830 7383.115 1.465 0.654 0.70599
190.62 343.116 46.04 667.764 4604.072 2.339 1.048 0.39126
305.46 549.828 48.80 707.795 4880.076 1.459 0.989 0.52468
369.86 665.748 42.49 616.275 4249.066 1.205 1.136 0.60429
408.18 734.724 36.48 529.106 3648.057 1.092 1.323 0.64466
425.22 765.396 37.97 550.717 3797.059 1.048 1.271 0.67086
460.47 828.846 33.81 490.380 3381.053 0.968 1.427 0.71153
469.69 845.442 33.69 488.640 3369.053 0.949 1.433 0.74277
507.47 913.446 30.12 436.860 3012.047 0.879 1.602 0.81937
754.00 1213.67 336.800 2322.154 0.591 2.078 1.00333
446.3938 649.779
Co
A
Nitrógeno 35.4113
Metano 31.35
Etano 44.0103
Propano 52.3785
i-Butano 58.7845
n-Butano 66.945
i-Pentano 66.7563
n-Pentano 63.3315
n-Hexano 70.4265
n-Heptano 67.6419512
1.0000 𝑓(𝜑)=∑_(𝑖=1)^𝑐▒ 〖 (𝑧_𝑖∗(1−𝐾_𝑖))/(1+𝜑∗(𝐾_𝑖−1))=0 〗
7923.4045
0.1729
2.7832
0.2251
0.2763
0.2122 T (K) 400.00
yi* norm xi* norm a vap i a liq i φ vap φ liq Ki P-R xi

0.01 0.00000001 132.8321 603.8532 1.0637 16.0397 15.0796 0.0007
0.005 0.00029395 281.8142 1351.7437 0.9497 4.4597 4.6958 0.0011

0.68 0.00228858 233.2650 1071.2775 0.9874 7.5151 7.6113 0.0893
0.13 0.01548535 409.0512 1904.3232 0.8824 2.7257 3.0891 0.0421
0.05 0.02172522 560.1691 2634.7857 0.8075 1.2943 1.6027 0.0312
0.02 0.01829786 686.6391 3259.7162 0.7541 0.7538 0.9996 0.0200
0.04 0.04477725 710.8273 3370.9626 0.7398 0.6155 0.8320 0.0481
0.01 0.02165954 836.0899 3990.2781 0.6909 0.3566 0.5160 0.0194
0.03 0.07576605 860.6937 4109.1228 0.6804 0.3100 0.4557 0.0658
0.02 0.10172865 1010.9528 4854.7956 0.6268 0.1604 0.2558 0.0782
0.005 0.69797754 1976.3063 9644.4440 0.3559 0.0011 0.0031 1.6221
1.00000 1.00000 sumatorias 2.0180
1.0000
1715.3796
0.1822
0.6026
0.2373 T(K) 500
0.8989
0.6904
φ liq Ki P-R xi yi xi Norm yi Norm

1.4749 0.0601 0.1663 0.01 0.204 0.010
1.3626 7.7543 0.0006 0.005 0.001 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
1.4011 1.0548 0.6446 0.68 0.792 0.680 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
1.3053 60.3007 0.0022 0.13 0.003 0.130 iteraciones
1.2387 1313.7793 0.0000 0.05 0.000 0.050 1
1.1928 13445.9848 0.0000 0.02 0.000 0.020 2
1.1766 28711.5694 0.0000 0.04 0.000 0.040 3
1.1328 ### 0.0000 0.01 0.000 0.010 4
1.1220 ### 0.0000 0.03 0.000 0.030 5
1.0721 ### 0.0000 0.02 0.000 0.020 6
0.7674 ### 0.0000 0.005 0.000 0.005 7
sumatorias 0.8138 1.0000 1.0000 1.0000
1.0000
131.9507
0.0263
0.0463
0.0342 T(K) 290
0.9919
0.7618

1.0106 0.9564 0.0105 0.01 0.011 0.010
0.9202 1.0165 0.0049 0.005 0.005 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
0.9554 1.0002 0.6799 0.68 0.707 0.680 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.8817 1.0686 0.1217 0.13 0.127 0.130 iteraciones
0.8322 1.1283 0.0443 0.05 0.046 0.050 1
0.7985 1.1779 0.0170 0.02 0.018 0.020 2
0.7861 1.1904 0.0336 0.04 0.035 0.040 3
0.7538 1.2420 0.0081 0.01 0.008 0.010 4
0.7461 1.2540 0.0239 0.03 0.025 0.030 5
0.7123 1.3246 0.0151 0.02 0.016 0.020 6
0.4893 1.8628 0.0027 0.005 0.003 0.005 7
sumatorias 0.9615 1.0000 1.0000 1.0000
1.0000
316.1703
0.0361
0.1111
0.0471 T(K) 230
0.9453
0.7260
1.0421 0.9924 0.0101 0.01 0.010 0.010
0.8679 1.0033 0.0050 0.005 0.005 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
0.9254 0.9997 0.6802 0.68 0.684 0.680 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.7822 1.0102 0.1287 0.13 0.129 0.130 iteraciones
0.6895 1.0187 0.0491 0.05 0.049 0.050 1
0.6284 1.0254 0.0195 0.02 0.020 0.020 2
0.6090 1.0272 0.0389 0.04 0.039 0.040 3
0.5550 1.0340 0.0097 0.01 0.010 0.010 4
0.5425 1.0355 0.0290 0.03 0.029 0.030 5
0.4853 1.0438 0.0192 0.02 0.019 0.020 6
0.2171 1.1027 0.0045 0.005 0.005 0.005 7
sumatorias 0.99384 1.0000 1.0000 1.0000
1.0000
343.2472
0.0375
0.1206
0.0489 T(K) 170
0.9453
0.7260

1.0344 0.9956 0.0100 0.01 0.010 0.010
0.8008 1.0004 0.0050 0.005 0.005 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
0.8765 0.9989 0.6807 0.68 0.683 0.680 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.6983 1.0053 0.1293 0.13 0.130 0.130 iteraciones
0.5910 1.0112 0.0494 0.05 0.050 0.050 1
0.5243 1.0163 0.0197 0.02 0.020 0.020 2
0.5017 1.0171 0.0393 0.04 0.039 0.040 3
0.4448 1.0222 0.0098 0.01 0.010 0.010 4
0.4314 1.0231 0.0293 0.03 0.029 0.030 5
0.3734 1.0293 0.0194 0.02 0.019 0.020 6
0.1286 1.0684 0.0047 0.005 0.005 0.005 7
sumatorias 0.9967 1.0000 1.0000 1.0000
1.0000 𝑓(𝜑)=∑_(𝑖=1)^𝑐▒ 〖 (𝑧_𝑖∗(1−𝐾_𝑖))/(1+𝜑∗(𝐾_𝑖−1))=0 〗

345.0880
0.0376
0.1212
0.0490 T(K) 150
0.9453
0.7260
φ liq Ki P-R xi yi xi Norm yi Norm yi/ki-1

1.0290 0.9959 0.0100 0.01 0.010 0.010 0.010
0.7698 1.0005 0.0050 0.005 0.005 0.005 0.005 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍
0.8529 0.9991 0.6806 0.68 0.683 0.680 0.681 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2
Nº de
0.6607 1.0054 0.1293 0.13 0.130 0.130 0.129 iteraciones
0.5483 1.0112 0.0494 0.05 0.050 0.050 0.049 1
0.4801 1.0163 0.0197 0.02 0.020 0.020 0.020 2
0.4567 1.0170 0.0393 0.04 0.039 0.040 0.039 3
0.3995 1.0221 0.0098 0.01 0.010 0.010 0.010 4
0.3860 1.0230 0.0293 0.03 0.029 0.030 0.029 5
0.3289 1.0292 0.0194 0.02 0.019 0.020 0.019 6
0.1000 1.0680 0.0047 0.005 0.005 0.005 0.005 7
sumatorias 0.9966 1.0000 1.0000 1.0000 -0.0034
Constantes para mi w<0,49 Constantes para aci y bi
C1 C2 C3 Ωa Ωb
0.37464 1.54226 0.26992 0.45724 0.0778
Constantes para mi w>0,49
C1 C2 C3 C4
0.37964 1.485 0.1644 0.01667
coef. Binarios
αi (alpha i) aci aci*αi bi yi*bi Kij N2
0.384 148.418 57.019 0.02406 0.00024 N2 0

0.725 396.309 287.272 0.02666 0.00013 CO2 -2.00E-02
0.629 249.464 156.836 0.02678 0.01821 CH4 3.60E-02
0.794 604.358 479.592 0.04049 0.00526 C2H6 5.00E-02
0.885 1017.638 900.804 0.05631 0.00282 C3H8 8.00E-02
0.943 1443.624 1360.925 0.07238 0.00145 i-C4H10 9.50E-02
0.968 1505.193 1457.249 0.07244 0.00290 n-C4H10 9.00E-02
1.023 1982.271 2027.777 0.08810 0.00088 i-C5H12 9.50E-02
1.039 2069.794 2149.712 0.09018 0.00271 n-C5H12 0.1
1.105 2702.535 2987.407 0.10898 0.00218 n-C6H14 0.149
1.517 7738.627 11742.603 0.21004 0.00105 C7+ 0.1
0.03783
Aij N2
N2 57.0193
CO2 130.5438
B C D E F C2H6 157.0978
-966.243 0 -4.31849 0.000079319 2 C3H8 208.5041
-4735 0 -21.267 0.040908 1 i-C4H10 252.1024
-1307.52 0 -3.26134 0.000029418 2 n-C4C10 262.3125
-2568.82 0 -4.97635 0.0000146447 2 i-C5H12 307.7300
-3490.55 0 -6.10875 0.0000111869 2 n-C5H12 315.0964
-4136.68 0 -7.01666 0.0000103662 2 n-C6H14 351.2267
-4604.09 0 -8.25491 0.0000115706 2 n-C7H16 736.4368
-5059.18 0 -8.08935 0.00000925395 2
-5117.78 0 -7.48305 0.00000776606 2

-6055.6 0 -8.37865 0.00000661666 2
-8790.09496 0 -7.24898244 3.85E-18 6
+𝜑∗(𝐾_𝑖−1))=0 〗
yi xi norm yi norm 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

0.01 0.000 0.010 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.005 0.001 0.005

Nº de
iteraciones Z sup f
0.68 0.044 0.680 1 0.9 -0.02947051
0.13 0.021 0.130 2 0.9401 0.00287305
0.05 0.015 0.050 3 0.9368 1.9871E-05
0.02 0.010 0.020 4 0.9368 9.73947E-10
0.04 0.024 0.040 5 0.9368 6.54858E-17
0.01 0.010 0.010 6 0.9368 -4.5536E-17
0.03 0.033 0.030 7 0.9368 -4.5536E-17
0.02 0.039 0.020
0.005 0.804 0.005
1.0000 1.0000 1.0000
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 0.37886037 1.21542792 0.5883 0.3117 1 0.9
0.5883 0.13967554 0.41640007 0.2529 0.3354 2 0.8989
0.2529 0.05386053 0.20777981 -0.0064 0.2592 3 0.8989
-0.0064 -0.03033195 0.50899983 0.0532 -0.0596 4 0.8989
0.0532 -0.00323241 0.40406486 0.0612 -0.0080 5 0.8989
0.0612 -5.0113E-05 0.39160016 0.0614 -0.0001 6 0.8989
0.0614 -1.256E-08 0.39140388 0.0614 0.0000 7 0.8989
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 -0.02947051 0.73546153 0.9401 -0.0401 1 0.9
0.9401 0.00287305 0.88046621 0.9368 0.0033 2 1.0151
0.9368 1.9871E-05 0.86829764 0.9368 0.0000 3 0.9929
0.9368 9.73947E-10 0.86821252 0.9368 0.0000 4 0.9919
0.9368 5.9848E-17 0.86821252 0.9368 0.0000 5 0.9919
0.9368 -5.4644E-17 0.86821252 0.9368 0.0000 6 0.9919
0.9368 5.9848E-17 0.86821252 0.9368 0.0000 7 0.9919
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 -0.02947051 0.73546153 0.9401 -0.0401 1 0.9
0.9401 0.00287305 0.88046621 0.9368 0.0033 2 0.9504
0.9368 1.9871E-05 0.86829764 0.9368 0.0000 3 0.9454
0.9368 9.73947E-10 0.86821252 0.9368 0.0000 4 0.9453
0.9368 8.32667E-17 0.86821252 0.9368 0.0000 5 0.9453
0.9368 -2.7756E-17 0.86821252 0.9368 0.0000 6 0.9453
0.9368 -2.7756E-17 0.86821252 0.9368 0.0000 7 0.9453
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 -0.02947051 0.73546153 0.9401 -0.0401 1 0.9
0.9401 0.00287305 0.88046621 0.9368 0.0033 2 0.9504
0.9368 1.9871E-05 0.86829764 0.9368 0.0000 3 0.9454
0.9368 9.73947E-10 0.86821252 0.9368 0.0000 4 0.9453
0.9368 8.32667E-17 0.86821252 0.9368 0.0000 5 0.9453
0.9368 -2.7756E-17 0.86821252 0.9368 0.0000 6 0.9453
0.9368 -2.7756E-17 0.86821252 0.9368 0.0000 7 0.9453
+𝜑∗(𝐾_𝑖−1))=0 〗
〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

(𝐴𝐵−𝐵^2−𝐵^3 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−
iteraciones Z sup
0.9 -0.02947051 0.73546153 0.9401 -0.0401 1 0.9
0.9401 0.00287305 0.88046621 0.9368 0.0033 2 0.9504
0.9368 1.9871E-05 0.86829764 0.9368 0.0000 3 0.9454
0.9368 9.73947E-10 0.86821252 0.9368 0.0000 4 0.9453
0.9368 8.32667E-17 0.86821252 0.9368 0.0000 5 0.9453
0.9368 -2.7756E-17 0.86821252 0.9368 0.0000 6 0.9453
0.9368 -2.7756E-17 0.86821252 0.9368 0.0000 7 0.9453
coef. Binarios
-2.00E-02 3.60E-02 5.00E-02 8.00E-02 9.50E-02 9.00E-02 9.50E-02 0.1

0 1.00E-01 0.12980001 0.13500001 0.12980001 0.12980001 0.125 0.125
1.00E-01 0 2.24E-03 6.83E-03 1.31E-02 1.23E-02 1.76E-02 1.79E-02
0.12980001 2.24E-03 0 1.26E-03 4.57E-03 4.10E-03 7.41E-03 7.61E-03
0.13500001 6.83E-03 1.26E-03 0 1.04E-03 8.19E-04 2.58E-03 2.70E-03
0.12980001 1.31E-02 4.57E-03 1.04E-03 0 1.34E-05 3.46E-04 3.90E-04
0.12980001 1.23E-02 4.10E-03 8.19E-04 1.34E-05 0 4.95E-04 5.47E-04
0.125 1.76E-02 7.41E-03 2.58E-03 3.46E-04 4.95E-04 0 1.25E-06
0.125 1.79E-02 7.61E-03 2.70E-03 3.90E-04 5.47E-04 1.25E-06 0
0.125 2.35E-02 1.14E-02 5.14E-03 1.57E-03 1.87E-03 4.40E-04 3.93E-04
0.101 4.37E-02 2.68E-02 1.67E-02 9.49E-03 1.02E-02 6.24E-03 6.06E-03

130.5438 91.1615 157.0978 208.5041 252.1024 262.3125 307.7300 315.0964
287.2719 191.0346 322.9992 440.0254 544.1050 563.0312 667.8281 687.6141
191.0346 156.8361 273.6434 373.3036 455.9396 472.1858 553.9994 570.2400
322.9992 273.6430 479.5917 656.4539 804.1964 832.5686 978.8460 1007.6475
440.0254 373.3036 656.4539 900.8035 1106.0633 1144.7907 1348.0367 1387.8126
544.1050 455.9396 804.1964 1106.0633 1360.9249 1408.2447 1660.6449 1709.7705
563.0312 472.1858 832.5686 1144.7907 1408.2447 1457.2488 1718.1530 1768.9653
667.8281 553.9994 978.8460 1348.0367 1660.6449 1718.1530 2027.7767 2087.8519
687.6141 570.2400 1007.6475 1387.8126 1709.7705 1768.9653 2087.8519 2149.7123
810.5911 668.4271 1183.3075 1632.0121 2013.1864 2082.5852 2460.1760 2533.1826
1651.1572 1297.7876 2309.5233 3198.0943 3959.6699 4094.4485 4849.2534 4993.8174
Z vapor METODO NEWTON RAPSON
−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

0
−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0 (𝐴𝐵−𝐵^2−𝐵^3 )=0
〖𝑓 ^′=3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
f' Zcal Diferencia Nº de
0.73546153 0.9401 -0.0401 1 0.9 1.49962284 3.21612694
0.88046621 0.9368 0.0033 2 0.4337 0.31718448 2.07306324
0.86829764 0.9368 0.0000 3 0.2807 0.00873878 1.98224283
0.86821252 0.9368 0.0000 4 0.2763 1.22209E-06 1.98170784
0.86821252 0.9368 0.0000 5 0.2763 2.05391E-14 1.98170777
0.86821252 0.9368 0.0000 6 0.2763 0 1.98170777
0.86821252 0.9368 0.0000 7 0.2763 0 1.98170777

=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
0.00112958 1.01624122 0.8989 0.0011
2.3921E-06 1.0119383 0.8989 0.0000
1.08066E-11 1.01192916 0.8989 0.0000
0 1.01192916 0.8989 0.0000
0 1.01192916 0.8989 0.0000
0 1.01192916 0.8989 0.0000
0 1.01192916 0.8989 0.0000

=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
-0.07667215 0.66600254 1.0151 -0.1151
0.02450955 1.10505376 0.9929 0.0222
0.00101209 1.01428211 0.9919 0.0010
2.00334E-06 1.01026774 0.9919 0.0000
7.90388E-12 1.01025977 0.9919 0.0000
3.94107E-17 1.01025977 0.9919 0.0000
3.94107E-17 1.01025977 0.9919 0.0000
=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
-0.03651846 0.72500564 0.9504 -0.0504
0.0045603 0.90861516 0.9454 0.0050
4.76882E-05 0.8896371 0.9453 0.0001
5.41078E-09 0.88943523 0.9453 0.0000
0 0.8894352 0.9453 0.0000
0 0.8894352 0.9453 0.0000
0 0.8894352 0.9453 0.0000

=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3
3𝑍 )=0
〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
-0.03651846 0.72500564 0.9504 -0.0504
0.0045603 0.90861516 0.9454 0.0050
4.76882E-05 0.8896371 0.9453 0.0001
5.41078E-09 0.88943523 0.9453 0.0000
0 0.8894352 0.9453 0.0000
0 0.8894352 0.9453 0.0000
0 0.8894352 0.9453 0.0000
=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−
𝐵^2−𝐵^3 )=0
3𝑍 〗 ^2−(1−𝐵)2𝑍+(𝐴−2𝐵−3𝐵^2 )=0
-0.03651846 0.72500564 0.9504 -0.0504
0.0045603 0.90861516 0.9454 0.0050
4.76882E-05 0.8896371 0.9453 0.0001
5.41078E-09 0.88943523 0.9453 0.0000
0 0.8894352 0.9453 0.0000
0 0.8894352 0.9453 0.0000
0 0.8894352 0.9453 0.0000
n-C6H14 C7+
0.149 0.1
0.125 0.101
2.35E-02 4.37E-02
1.14E-02 2.68E-02
5.14E-03 1.67E-02
1.57E-03 9.49E-03
1.87E-03 1.02E-02
4.40E-04 6.24E-03
3.93E-04 6.06E-03
0 3.38E-03
3.38E-03 0
n-C6H14 n-C7H16
351.2267 736.4368 N2 0.00570193 0.00652719 0.61989792
810.5911 1651.1572 CO2 0.00652719 0.0071818 0.64951769
668.4271 1297.7876 CH4 0.61989792 0.64951769 72.5210078
1183.3075 2309.5233 C2H6 0.2042272 0.2099495 24.1900412
1632.0121 3198.0943 C3H8 0.10425205 0.11000634 12.6923221
2013.1864 3959.6699 i-C4H10 0.05042047 0.0544105 6.2007785
2082.5852 4094.4485 n-C4C10 0.10492501 0.11260625 12.8434527
2460.1760 4849.2534 i-C5H12 0.030773 0.0333914 3.76719572
2533.1826 4993.8174 n-C5H12 0.09452893 0.10314212 11.6328956
2987.4074 5902.8231 n-C6H14 0.07024535 0.08105911 9.09060808
5902.8231 11742.6031 n-C7H16 0.03682184 0.04127893 4.41247771
SUMA 1.32832089 1.40907081 158.620195
TOTAL A 3
Z liquido
−2𝐵−3𝐵^2 )𝑍−
2𝐵−3𝐵^2 )=0
Zcal Diferencia
0.4337 0.4663
0.2807 0.1530
0.2763 0.0044
0.2763 0.0000
0.2763 0.0000
0.2763 0.0000
0.2763 0.0000
0.2042272 0.10425205 0.05042047 0.10492501 0.030773 0.09452893 0.07024535 0.03682184
0.2099495 0.11000634 0.0544105 0.11260625 0.0333914 0.10314212 0.08105911 0.04127893
24.1900745 12.6923221 6.2007785 12.8434527 3.76719572 11.6328956 9.09060808 4.41247771
8.10510044 4.26695024 2.09091069 4.32935655 1.27249974 3.92982544 3.07659949 1.50119018
4.26695024 2.25200883 1.10606331 2.28958131 0.67401833 2.08171883 1.63201211 0.79952356
2.09091069 1.10606331 0.54436994 1.12659577 0.33212897 1.02586229 0.80527454 0.39596699
4.32935655 2.28958131 1.12659577 2.3315981 0.68726119 2.12275832 1.66606819 0.8188897
1.27249974 0.67401833 0.33212897 0.68726119 0.20277767 0.62635558 0.49203521 0.24246267
3.92982544 2.08171883 1.02586229 2.12275832 0.62635558 1.9347411 1.51990956 0.74907262
3.07659949 1.63201211 0.80527454 1.66606819 0.49203521 1.51990956 1.19496298 0.59028231
1.50119018 0.79952356 0.39596699 0.8188897 0.24246267 0.74907262 0.59028231 0.29356508
53.1766839 28.008457 13.732782 28.4330931 8.36089948 25.8208104 20.2190569 9.88153159
348.990901032887

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PENG ROBINSON

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

Dióxido de CO2 0.00500 3893.272 0.66432 -0.00216 0.0043

Ⴔ vap* = 0.0000 Ⴔ liq* =

Dióxido de CO2 0.005 0.004 322.6782 589.6515 0.7240

Ⴔ vap* = 0.0000 Ⴔ liq* =

Dióxido de CO2 0.005 0.005 306.2869 573.1982 0.7280

Ⴔ vap* = 0.0000 Ⴔ liq* =

Ⴔ vap* = 0.0000 Ⴔ liq* =

Dióxido de CO2 0.005 0.005 304.3366 569.0795 0.7286

Ⴔ vap* = 0.0000 Ⴔ liq* =

Dióxido de CO2 0.005 0.005 304.2907 568.5797 0.7286

Ⴔ vap* = 0.0000 Ⴔ liq* =

Dióxido de CO2 0.005 0.005 304.2799 568.3870 0.7286

Ⴔ vap* = 0.0000 Ⴔ liq* =

Dióxido de CO2 0.005 0.005 304.2770 568.3162 0.7286

126.24 227.232 33.94 492.266 3394.053 2.199 1.727 0.432

2𝐵−3𝐵^2 )=0 i-Pentano 66.7563

0.0064 0.0039 0.0076 313.1715 552.7710 0.7059 1.2709 1.8003

φ liq Ki P-R f(Ⴔ) yi xi Yi Norm Xi Norm

0.9349 1.2913 -0.00122802 0.0054 0.0042 0.005 0.005

φ liq Ki P-R f(Ⴔ) yi xi Yi Norm Xi Norm

0.9307 1.2783 -0.00118341 0.0054 0.0043 0.005 0.005

φ liq Ki P-R f(Ⴔ) yi xi Yi Norm Xi Norm

φ liq Ki P-R f(Ⴔ) yi xi Yi Norm Xi Norm

0.9286 1.2745 -0.00117049 0.0054 0.0043 0.005 0.005

φ liq Ki P-R f(Ⴔ) yi xi Yi Norm Xi Norm

0.9283 1.2741 -0.00116889 0.0054 0.0043 0.005 0.005

φ liq Ki P-R f(Ⴔ) yi xi Yi Norm Xi Norm

0.9282 1.2739 -0.00116826 0.0054 0.0043 0.005 0.005

φ liq Ki P-R f(Ⴔ) yi xi Yi Norm Xi Norm

0.9281 1.2738 -0.00116803 0.0054 0.0043 0.005 0.005

0.626 148.418 92.910 0.02406 0.00024 N2 0

-5117.78 0 -7.48305 0.00000776606 2

f(Ⴔ) yi xi Yi Norm Xi Norm 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−

METODO NEWTON RAPSON Z vapor METODO NEWTON RAPSON

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

METODO NEWTON RAPSON Z vapor METODO NEWTON RAPSON

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

METODO NEWTON RAPSON Z vapor METODO NEWTON RAPSON

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

METODO NEWTON RAPSON Z vapor METODO NEWTON RAPSON

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

METODO NEWTON RAPSON Z vapor METODO NEWTON RAPSON

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

METODO NEWTON RAPSON Z vapor METODO NEWTON RAPSON

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍

-2.00E-02 3.60E-02 5.00E-02 8.00E-02 9.50E-02 9.00E-02 9.50E-02 0.1

CO2 CH4 C2H6 C3H8 i-C4H10 n-C4H10 i-C5H12 n-C5H12

=𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍− 〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

METODO NEWTON RAPSON Z liquido

METODO NEWTON RAPSON Z liquido

METODO NEWTON RAPSON Z liquido

METODO NEWTON RAPSON Z liquido

METODO NEWTON RAPSON Z liquido

〖𝑓 =𝑍 〗 ^3−(1−𝐵) 𝑍^2+(𝐴−2𝐵−3𝐵^2 )𝑍−

Primera Iteración sup

Dióxido de CO2 0.00500 328.919 0.05963 0.0050 0.0003

Ⴔ vap* = 0.0000 Ⴔ liq* =

Etano C2H6 0.027 0.130 421.4770 618.7163 0.3355

Ⴔ vap* = 0.0000 Ⴔ liq* =

Etano C2H6 0.043 0.130 431.9980 618.7163 0.2689

Ⴔ vap* = 0.0000 Ⴔ liq* =