1.Calcule la presión ejercida por 985.

8g de butano en un recipiente de 250cm 3 de capacidad y 30° C, utilizando:

a) La ley del gas ideal
➢ 𝑃𝑣 = 𝑛𝑅𝑇
P =x

M=985.8g C4H10 ➢ P=nRt/v

V=250cm^3=250ml*L/1000ml=.25L
p
T=30°c

1𝑚𝑜𝑙C4H10
985.8𝑔C4H10 ∗ ( ) = 16.99𝑚𝑜𝑙C4H10
58𝑔C4H10
𝑎𝑡𝑚
16.99𝑚𝑜𝑙 ∗ 0.082𝑙 1 ∗ 303.15
𝑚𝑜𝑙
𝑝= 𝑘 = 1689.37𝐴𝑡𝑚
0.25𝑙

b) La ecuación de van der Waals

a=14.66L^2bar/mol^2

b=0.1226l/mol
𝑅𝑇 𝑎
➢ 𝑃= ̅ −𝑏
− ̅̅̅̅2
𝑉 𝑉

𝑣
➢ 𝑣𝑚 = 𝑛

.25𝑙 𝑙
➢ = 0.0147
16.99𝑚𝑜𝑙 𝑚𝑜𝑙

Carlos Alan Ramirez Valadez

 bar
0.083L ( mol )∗303.15K 𝐿2 𝑏𝑎𝑟
k 14.66
𝑚𝑜𝑙2
➢ 𝑃= L 𝐿 − 𝐿 2
= −68075.29514𝑏𝑎𝑟
0.0147mol−0.1226𝑚𝑜𝑙 (0.0147𝑚𝑜𝑙)

c) La ecuación de Redlich Kwong

d)

𝑅𝑇 𝛼
e) 𝑃 = 𝑉 −
𝑚 −𝑏 √𝑇𝑉𝑚 (𝑉𝑚 +𝑏)

0.42748𝑅 2 𝑇𝑐2.5
f) 𝛼 = 𝑃𝑐

0.08664𝑅𝑇𝑐
g) 𝑏 = 𝑃𝑐

2
𝑏𝑎𝑟 2
(0.42748) (0.083𝑙 ) (425.20𝐾 )2.5 𝑏𝑎𝑟
𝑚𝑜𝑙 𝑘 −1 2
𝑎= = 288.91𝑙
38𝑏𝑎𝑟 1 𝑚𝑜𝑙2 𝐾

𝑏𝑎𝑟
0.08664 (0.083𝑙 ) (425.20𝐿) 𝑙
𝑏= 𝑚𝑜𝑙 𝑘 −1 = 0.0804
38𝑏𝑎𝑟 𝑚𝑜𝑙

Carlos Alan Ramirez Valadez

 𝑏𝑎𝑟 𝑏𝑎𝑟
(0.083𝑙 )(303.15𝐾) 288.91𝑙 2
𝑚𝑜𝑙 𝑘−1 𝑚𝑜𝑙2 𝐾
𝑃= 𝑙 𝑙 − 𝑙 𝑙 𝑙 = −12252.57𝑏𝑎𝑟
(0.0147𝑚𝑜𝑙)−(0.0804𝑚𝑜𝑙) (√30.15𝐾)(0.0147 )(0.0147𝑚𝑜𝑙+0.0804𝑚𝑜𝑙)
𝑚𝑜𝑙

d) La ecuación viral, sabiendo que para el butano B=-179cm 3 /mol y

C=10400cm 6 /mol 2 a 30 o C y B=-157cm 3 /mol y C=9650cm 6 /mol 2 a 50 o C

𝑃𝑉𝑚 𝐵 𝑐 𝐷
➢ = (1 + 𝑉 + 𝑉 2 + 𝑉 3 … )
𝑅𝑇 𝑚 𝑚 𝑚
250𝑐𝑚3 14.71𝑐𝑚3
𝑉𝑚 = =
𝐵 𝑐 𝐷
16.99𝑚𝑜𝑙 𝑚𝑜𝑙
(1+𝑉 + + 3 … )𝑅𝑇
𝑚 𝑉2 𝑉
➢ 𝑃= 𝑚 𝑚
𝑉𝑚

𝑐𝑚3 cm6
−179 10400
(1 + ( 𝑚𝑜𝑙 ) + ( 𝑚𝑜𝑙2 )) (82𝑐𝑚3 𝐴𝑡𝑚 ) (303.15𝑘)
𝑐𝑚 3 2 𝑚𝑜𝑙𝐾 −1
14.71 𝑐𝑚3
𝑚𝑜𝑙 (14.71 )
𝑚𝑜𝑙
𝑃= = 62346.99𝐴𝑡𝑚
𝑐𝑚3
14.71
𝑚𝑜𝑙

Carlos Alan Ramirez Valadez

2.Una mezcla compuesta 587g de C 2 H 4 y 766.9g de CO 2 en un recipiente de 376cm 3 a una presión de 25atm.
Determine la temperatura a la que se encuentra:
a) Utilizando la ecuación del gas ideal
1𝑚𝑜𝑙
• P=25 Atm 776.9g CO2 ∗ = 17.4295 𝑚𝑜𝑙
44𝑔
• M=776.9g co2
• M=587g C2H4 1𝑚𝑜𝑙
587𝑔C2 𝐻4 ∗ = 20.9644𝑚𝑜𝑙
• T=x 28𝑔
• 376cm3
𝑛 𝑇 = (17.4295𝑚𝑜𝑙 + 20.9644𝑚𝑜𝑙) = 38.3938𝑚𝑜𝑙

➢ 𝑃𝑣 = 𝑛𝑅𝑇

𝑃𝑉 (25𝑎𝑡𝑚)(0.376𝐿)
𝑇= = = 2.9860𝑘
𝑛𝑅 (38.39𝑚𝑜𝑙)(𝑂. 082𝐿 𝑎𝑡𝑚 )
𝑚𝑜𝑙𝑘 −1

b) La ecuación de Van der Waals

Carlos Alan Ramirez Valadez

 L2 Bar
➢ aco2 = 3.640 17.4295𝑚𝑜𝑙
mol2 𝑌 co2 = = 0.4539
L 38.3938𝑚𝑜𝑙
➢ bco2 = 0.0426
mol
L2 Bar 20.9644𝑚𝑜𝑙
➢ 𝑎C2 𝐻4 = 4.612 𝑌 C2 𝐻4 = 17.4295 = 0.5461
mol2 38.3938𝑚𝑜𝑙
L
➢ bC2 𝐻4 = 0.0582
mol

𝑎 1
➢ 𝑇 = (𝑃 + 𝑉̅ 2 ) (𝑉̅ − 𝑏 ) (𝑅 )
2
L2 Bar L2 Bar L2 Bar
2 ➢ 𝑎𝑚 = (( 0.4539√3.640 2
) + (0.5461√4.612 2
)) = 4.1565 mol2
𝑗 mol mol
➢ 𝑎𝑚 = (∑𝑖 𝑌𝑖 √𝑎𝑖 )
L L 𝐿
𝑗
➢ 𝑏𝑚 = ∑𝑖 𝑌𝑖 𝑏1 ➢ 𝑏𝑚 = ((0.4539 ∗ 0.0426 mol ) + (0.5461 ∗ 0.0582 mol ) = 0.05111 𝑚𝑜𝑙

𝑣 .376𝐿 𝐿
➢ 𝑉𝑚 = 𝑛 = 38.3938𝑚𝑜𝑙 = 9.7932 ∗ 10−3 𝑚𝑜𝑙

L2 Bar
4.1565 𝐿 𝐿 1
mol2
𝑇= (25.3313𝑏𝑎𝑟 + 2 ) ((9.7932 ∗ 10−3 ) − (0.05111 )) ( )
−3 𝐿 𝑚𝑜𝑙 𝑚𝑜𝑙 𝑏𝑎𝑟
(9.7932 ∗ 10 ) 0.083 𝐿
𝑚𝑜𝑙 𝑚𝑜𝑙𝐾 −1

= −213630.57𝐾

Carlos Alan Ramirez Valadez

3.Cierto gas a 0 o C y 1atm de presión tiene un valor de z=1.00054.
a) Calcúlese el valor de la constante b de van der waals para este gas.
(𝑧−1)𝑅𝑇
➢ 𝑏= 𝑃

𝑎𝑡𝑚
(1.00054 − 1) (0.082 𝐿 ) (273.15) 𝐿
𝑏= 𝑚𝑜𝑙𝑘 −1 = 0.012095082
1𝑎𝑡𝑚 𝑚𝑜𝑙
c) Si la temperatura Boyle es de 107K calcúlese el valor de la constante a
d) 𝑇𝑏𝑜𝑦𝑙𝑒= 𝑎
𝑅𝑏

𝑏𝑎𝑟 𝐿 𝐿2 𝑏𝑎𝑟
𝑎 = (107𝑘) (0.083𝐿 ) (0.012095082 ) = 0.1074164232
𝑚𝑜𝑙𝑘 −1 𝑚𝑜𝑙 𝑚𝑜𝑙2

Carlos Alan Ramirez Valadez

4. Determine el volumen molar del n – hexano a 200K y 25 bar mediante:
a) La ecuación del gas ideal
𝑏𝑎𝑟
➢ 𝑉𝑚 = 𝑋 𝑅𝑡 (0.083 𝐿 )(200𝑘) 𝐿
𝑚𝑜𝑙𝑘−1
➢ 𝑃 = 25𝑏𝑎𝑟 ➢ 𝑃𝑣 = 𝑛𝑅𝑇 𝑉𝑚 = = = 0.664 𝑚𝑜𝑙
𝑃 25𝑏𝑎𝑟
➢ 𝑇 = 200𝑘

e) La ecuación de van der Waals

𝐿2 𝑏𝑎𝑟
f) 𝑎 = 24.71
𝑚𝑜𝑙2
𝐿
g) 𝑏 = .1735
𝑚𝑜𝑙
𝑅𝑇 𝑎 𝑎𝑏
h) 𝑉̅ 3 − (𝑏 + ) 𝑉̅ 2 + ( ) 𝑉̅ − = 0
𝑃 𝑃 𝑃

𝑏𝑎𝑟 𝐿2 𝑏𝑎𝑟 𝐿2 𝑏𝑎𝑟 𝐿

𝐿 (0.0834𝐿 −1 )(200𝐾) 24.71 (24.71 2 )(0.1735 𝑚𝑜𝑙)
𝑉̅ 3 − (𝑜. 1735 + 𝑚𝑜𝑙𝐾 ) 𝑉̅ 2 + ( 𝑚𝑜𝑙 2
) 𝑉̅ − 𝑚𝑜𝑙
=0
𝑚𝑜𝑙 25 𝑏𝑎𝑟 25 𝑏𝑎𝑟 25𝑏𝑎𝑟

𝐿 2 𝐿 3
i) 𝑉̅ 3 − (0.8407 𝑚𝑜𝑙 2 ) 𝑉̅ 2 + (0.9884 𝑚𝑜𝑙 3 ) 𝑉̅ − 0.1714874 = 0

𝑥1 = 0.19911047208
𝑥2 = 0.319197
𝑥3 = 0.319197

Carlos Alan Ramirez Valadez

 𝐿
𝑉𝑚= 0.19911047208
𝑚𝑜𝑙

c) Factor de compresibilidad (cartas de compresibilidad)

𝑇𝑟
➢ 𝑧= 𝑉 𝑟𝑒𝑎𝑙
𝑃𝑟 𝑧= =
𝑇 𝑉𝑖𝑑𝑒𝑎𝑙
➢ 𝑇𝑟 = 𝑍 = 0.26 + 1 = 1.26
𝑇𝐶
𝑃
➢ 𝑃𝑟 =
𝑃𝐶
𝐿
➢ 𝑇𝑐 = 507.40𝐾 𝑉 𝑟𝑒𝑎𝑙 0.19911 𝑚𝑜𝑙
➢ 𝑃𝑐 = 29.7 𝑏𝑎𝑟 𝑧 = 1+ = = 1.29
𝑉𝑖𝑑𝑒𝑎𝑙 𝐿
➢ 𝑃𝑉 = 𝑍𝑅𝑇 0.664
𝑚𝑜𝑙
𝑅𝑇
➢ 𝑧=
𝑃𝑉
𝑏𝑎𝑟
𝑍𝑅𝑇 (1.29) (0.0834 𝐿 𝑚𝑜𝑙𝑘 −1 ) (200𝑘) 𝐿
𝑉= = = 0.860688
𝑃 25𝑏𝑎𝑟 𝑚𝑜𝑙

d) Factor acéntrico. 200𝑘

𝑇𝑟 = = 0.3941
507.40𝐾
➢ 𝑧 = 𝑧0 +(𝑧1𝑤 ) 25 𝑏𝑎𝑟
𝑃𝑟 = = 0.8417
29.70𝑏𝑎𝑟
𝑧 = 1.35 + ((−.12)(0.30)) = 1.314

𝑏𝑎𝑟
𝑍𝑅𝑇 (1.314) (0.0834 𝐿 𝑚𝑜𝑙𝑘 −1 ) (200𝑘) 𝐿
𝑉= = = 0.872496
𝑃 25𝑏𝑎𝑟 𝑚𝑜𝑙

Carlos Alan Ramirez Valadez