1. Datos termodinámicos a 298.

15 K y 1 atm
4. ∆𝐻° (𝐾𝐽/𝑚𝑜𝑙) 5. ∆𝐺° (𝐾𝐽/𝑚𝑜𝑙)
2. Compuesto 3. Estado
Xilosa Sólido -1057.8 -750.5
Manosa Sólido -1263 -793.74
Celobiosa Sólido -2465 -1580.34
Sacarina Sólido -422.8 -317.38
Xilitol Sólido -1219.3 -700.2

8. Calor de combustión a 298.15 K y 1 atm

11. ∆𝑈° (𝐾𝐽/𝑔)

9. Compuesto 10. Estado
Ácido benzoico Solido 226.434
Alambre Solido 26.28

12. Datos termodinámicos en cambio de fase

〖 15. 𝑞 〗 _𝑓𝑢𝑠𝑖ó𝑛 (𝐾𝐽/𝑚𝑜𝑙) 〖 17. 𝑞 〗 _𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑐𝑖ó𝑛 (𝐾𝐽/𝑚𝑜𝑙)

16. 𝑇_𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑐𝑖ó𝑛 (𝐾)
13. Compuesto 〖 14. 𝑇 〗 _𝑓𝑢𝑠𝑖ó𝑛 (𝐾)

Xilosa 416.2 31.7 729.86

Manosa 443.48 19.93 844.48
Celobiosa 767.77 68.92 1289.46
Sacarina 500.74 29.89 545.83
Xilitol 365.7 37.4 433
Agua NA NA 373
Etanol NA NA 351.5
Ácido acético NA NA 391
8.15 K y 1 atm
6. 𝑆° (𝐽/𝑚𝑜𝑙𝐾) 7. 𝐶_𝑝 (𝐽/𝑚𝑜𝑙𝐾)

175.3 178.1
216.51 214.2
410.08 384
352.72 297.79
187.6 219.15

8.15 K y 1 atm

cambio de fase

〖(𝐾) 〖 18. 𝐶 〗 _𝑝𝑙í𝑞𝑢𝑖𝑑𝑜 (𝐽/𝑚𝑜𝑙𝐾)

17. 𝑞 〗 _𝑣𝑎𝑝𝑜𝑟𝑖𝑧𝑎𝑐𝑖ó𝑛 (𝐾𝐽/𝑚𝑜𝑙) 19. 𝐶_𝑝𝑔𝑎𝑠 (𝐽/𝑚𝑜𝑙𝐾)
𝑧𝑎𝑐𝑖ó𝑛

126.3 281 303.13

117.51 273 390.04
185.55 665 889.71
62.97 219 245.4
111.1 476.1 334.42
40.76 75.33 1.84
39.28 2.44 1.43
-484.3 2.06 1.06
 22. Punto triple 23. Punto crítico
21. Compuesto 𝑇(𝐾) 𝑃(𝑏𝑎𝑟) 𝑇(𝐾)
1-pentanol 195.96 4.3×10-9 580
1-hexanol 225.8 4.3×10-9 610.5
1-heptanol 240 4.3×10-9 633
2-metil-1-butanol 178.3 4.3×10-9 575.4
2-feniletanol 210 4.3×10 -9
684

30. Vino Cabernet Sauvignon

32. Temperatura (°C)

31. Presión (mmHg)
1-pentanol 1-hexanol 1-heptanol
1 13.6 24.4 42.4
5 34.7 47.2 64.3
10 44.9 58.2 74.7
20 55.8 70.3 85.8
40 68 83.7 99.8
60 75.5 92 108
100 85.8 102.8 119.8
200 102 119.6 136.6
400 119.8 138 155.6
760 137.8 157 175.8

33. Equilibrio Ternario

34. Fase orgánica (g) 35. Fase

Ácido Oleico Agua 1- propanol Ácido Oleico
9.67 0.15 1.76 0.02
8.35 0.40 1.26 0.02
7.38 0.59 2.03 0.02
6.12 0.87 3.01 0.02
5.14 1.17 3.69 0.02
3.49 1.91 4.60 0.04

39. composición de mezcla (g)

38. Experimento
Ácido Oleico Agua Etanol
1 5.01 4.49 0.50
2 4.10 4.50 1.41
3 3.50 4.50 2.00
4 3.08 4.33 2.60
5 2.50 4.49 3.01
 20. Ecuación
23. Punto crítico 24. Punto normal
𝑃(𝑏𝑎𝑟) 𝑇_𝑓𝑢𝑠𝑖ó𝑛 (𝐾) 𝑇_𝑒𝑏𝑢𝑙𝑙𝑖𝑐𝑖ó𝑛 (𝐾) A
39 194.95 411 4.32418
34.2 227 430 4.41271
30.6 238.25 448 3.9794
39.4 195 402 4.48266
39.2 246.15 494.65 5.36689

Temperatura (°C)
2-metil-1-butanol 2 - feniletanol
10.3 58.2
31.5 85.9
41.7 100
52.8 114.8
64.9 130.5
71.8 141.2
81.6 154
95.8 175
112.3 197.5
129 219.5

35. Fase acuosa (g)

Agua 1- propanol
9.12 0.86
8.49 1.49
8.13 1.86
7.81 2.18
7.60 2.38
7.01 2.95
 20. Ecuación de Antoine
〖 25. 𝑙𝑜𝑔 〗 _10 𝑃(𝑏𝑎𝑟)=𝐴−𝐵/(𝐶+𝑇(𝐾))

B C Rango (K)
1297.689 -110.669 347.91 - 429.13
1422.031 -107.706 325.4 - 430.5
1256.783 -133.487 336.8 - 449.6
1360.367 -99.937 298.12 - 403
2479.574 -30.51 331.4 - 495

36. Compuesto37. Densidad (g/mL)

Ácido Oleico 0.895
Agua 1
1- propanol 0.79
26. Entalpia de fusión (KJ/mol) 27. Entalpía de vaporización (KJ/mol)
10.5 44.36
15.48 44.5
18.35 45.77
9.271 44.747
14.61 55.1
28. Densidad del líquido (g/mL) 29. Densidad del sólido (g/mL)
0.812 1.0402
0.816 1.0105
0.82 1.0086
0.814 1.0402
1.02 1.194
 39. Curva de calibración del AA
Solución A C (ppm)
1 0.0884895 2.365
2 0.1979219 5.753
3 0.3123285 9.295
4 0.5084541 15.367
5 0.6999608 21.296
6 0.8850721 27.027
7 1.0467336 32.032

40. Temperatura de 20 °C (valores de absorbancia)

Experimento t (seg) Repollo Grosella negra Durazno Chile
1 0 1.0408 0.7806 0.6245 0.9368
2 1320 0.8743 0.6557 0.5246 0.7869
3 2640 0.7546 0.5660 0.4528 0.6791
4 6600 0.5267 0.3950 0.3160 0.4740
5 9900 0.4059 0.3044 0.2436 0.3653
6 13200 0.3487 0.2615 0.2092 0.3138
7 23100 0.2342 0.1756 0.1405 0.2108
8 29700 0.1874 0.1405 0.1124 0.1686
9 39600 0.1509 0.1132 0.0906 0.1358

42.
Repollo Grosella
Experimento 10^(−4) 𝑟_0 (𝑐°/𝑠)
10^(−4) [𝐴𝐴] 10^(−4) ["ADHA"] 10^(−4) ["ADAG"] 10^(−4) [𝐴𝐴]
10^(−4) ["ADH
1 0.88000 0.00022 0.00011 0.00011 0.00029
2 1.76000 0.00011 0.00022 0.00011 0.00014
3 2.64000 0.00011 0.00011 0.00033 0.00014
4 3.52000 0.00011 0.00011 0.00011 0.00014
ación del AA
Moles (M/L) Curva de calibración
1E-02 1.2

3E-02 1 f(x) = 5.688676 x + 0.0121

5E-02 0.8 R² = 1

9E-02 0.6
1E-01 0.4
2E-01 0.2
2E-01 0
0E+00 1E-01 2E-01

ia) 41. Temperatura de 50 °C (va

Perejil Experimento t (seg)
0.8535 1 0
0.7169 2 1320
0.6188 3 2640
0.4319 4 6600
0.3329 5 9900
0.2859 6 13200
0.1920 7 23100
0.1536 8 29700
0.1238 9 39600

42. Método de las velocidades iniciales a 20 °C

Grosella negra Durazno
10^(−4) ["ADHA"] 10^(−4) ["ADAG"] 10^(−4) [𝐴𝐴]
^(−4) [𝐴𝐴] 10^(−4) ["ADHA"] 10^(−4) ["ADAG"]
0.00014 0.00014 0.00024 0.00012 0.00012
0.00029 0.00014 0.00012 0.00024 0.00012
0.00014 0.00043 0.00012 0.00012 0.00036
0.00014 0.00014 0.00012 0.00012 0.00012
 2E-01

. Temperatura de 50 °C (valores de absorbancia)

Repollo Grosella negra Durazno Chile Perejil
0.7436 0.5234 0.3844 0.5251 0.4315
0.6247 0.4397 0.3229 0.4411 0.3625
0.5391 0.3795 0.2787 0.3807 0.3129
0.3763 0.2648 0.1945 0.2657 0.2184
0.2900 0.2041 0.1499 0.2048 0.1683
0.2491 0.1753 0.1288 0.1759 0.1446
0.1673 0.1178 0.0865 0.1182 0.0971
0.1339 0.0942 0.0692 0.0945 0.0777
0.1078 0.0759 0.0557 0.0761 0.0626

Chile Perejil
10^(−4) [𝐴𝐴] 10^(−4) ["ADHA"] 10^(−4) ["ADAG"]
10^(−4) [𝐴𝐴] 10^(−4) ["ADAG"]
10^(−4) ["ADHA"]
0.00035 0.00018 0.00018 0.00040 0.00020 0.00020
0.00018 0.00035 0.00018 0.00020 0.00040 0.00020
0.00018 0.00018 0.00053 0.00020 0.00020 0.00059
0.00018 0.00018 0.00018 0.00020 0.00020 0.00020
−4) ["ADAG"]
Experimento t (seg) Chile Concentración
1 0 0.5251 0.09018
2 1320 0.4411 0.07541
3 2640 0.3807 0.06480
4 6600 0.2657 0.04458
5 9900 0.2048 0.03387
6 13200 0.1759 0.02880
7 23100 0.1182 0.01864
8 29700 0.0945 0.01449
9 39600 0.0761 0.01126

t (seg) Concentración In C (M)

0 0.09018 -2.405
1320 0.07541 -1.322
2640 0.06480 -2.642
6600 0.04458 -6.603
9900 0.03387 -9.903
13200 0.02880 -13.203
23100 0.01864 -23.103
29700 0.01449 -29.704
39600 0.01126 -39.604

t (seg) Concentración In C (M) 1/C (M)

0 0.09018 -2.405 10.672846015
1320 0.07541 -1.322 12.503912474
2640 0.06480 -2.642 15.05425029
6600 0.04458 -6.603 22.279377316
9900 0.03387 -9.903 29.420513809
13200 0.02880 -13.203 34.650568697
23100 0.01864 -23.103 53.597355654
29700 0.01449 -29.704 68.98582791
39600 0.01126 -39.604 88.801792276

t (seg) Concentración In C (M) 1/C (M)

0 0.09018 -2.405 8.6836464308
 1320 0.07541 -1.322 11.938342126
2640 0.06480 -2.642 12.790751425
6600 0.04458 -6.603 15.827823628
9900 0.03387 -9.903 19.61849331
13200 0.02880 -13.203 21.52330906
23100 0.01864 -23.103 30.537640076
29700 0.01449 -29.704 39.315493409
39600 0.01126 -39.604 49.223042251

40. Temperatura de 20 °C (valores de

absorbancia)
t (seg) Chile Concentración In C (M)
0 0.9368 0.16254251481 -0.88
1320 0.7869 0.13619538864 -1.321
2640 0.6791 0.11725839171 -2.641
6600 0.4740 0.08119576276 -6.602
9900 0.3653 0.06209409629 -9.902
13200 0.3138 0.05303727167 -13.202
23100 0.2108 0.03492362243 -23.103
29700 0.1686 0.02751349319 -29.703
39600 0.1358 0.02175005934 -39.603

Orden cero Prime

45000 0
0 f(x)5000 10000 15000 2000
= − 0.00099207661416828
40000 -5 R² = 0.999612763371427
35000 -10
30000 -15
25000 f(x) = − 240199.56232027 x + 32595.726830287 -20
R² = 0.76768918066229
20000
-25
15000
-30
10000
-35
5000
-40
0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16 0.18 -45
 Orden cero
45000
40000
35000
30000
25000 f(x) = − 428489.079260414 x + 32195.2305560986
R² = 0.76768918066229
20000
15000
10000
5000
0
0.00000 0.02000 0.04000 0.06000 0.08000 0.10000

Primer orden
0
0 f(x)5000 10000 15000 20000 25000
= − 0.000978233850711418 30000 35000 40000 45000
x − 0.574760086590956
-5 R² = 0.997029956591785
-10
-15
-20
-25
-30
-35
-40
-45

Segundo Orden
100
90
80 f(x) = 0.00197685790254381 x + 9.64041524951942
R² = 0.998899080099993
70
60
50
40
30
20
10
0
0 5000 10000 15000 20000 25000 30000 35000 40000 45000

1/C2 (M)
11.146226 17.3672929 Tercer orden
100
90
80 f(x) = 0.0019630617835768 x + 10.082453424591
R² = 0.998648156343859
70
 Tercer orden
13.302224 23.8766843 100
90
15.471842 25.5815029 f(x) = 0.0019630617835768 x + 10.082453424591
80
22.462414 31.6556473 70
R² = 0.998648156343859

29.546979 39.2369866 60
34.74954 43.0466181 50
40
53.657013 61.0752802
30
69.032211 78.6309868 20
88.8372 98.4460845 10
0
0 5000 10000 15000 20000 25000 30000 35000 40000 45000

1/C (M) 1/C2 (M) Tercer orden

5.0158729 6.25192 50
6.5853902 7.41832 45
f(x) = 0.00100847992989387 x + 5.94485209090061
8.1495298 8.58953 40 R² = 0.999406857065737
35
12.164444 12.357 30
16.003601 16.1358 25
18.778919 18.8813 20
15
28.59063 28.6514 10
36.312136 36.3596 5
45.951635 45.9878 0
0 5000 10000 15000 20000 25000 30000 35000 40000 45000

Primer Orden Segundo orden

0 50
0 f(x)5000 10000 15000 20000 25000
= − 0.000992076614168287 30000 35000 40000 45000
x − 0.210646890882854
-5 R² = 0.999612763371427 45
f(x) = 0.00102968392536223 x + 5.30557810296452
40 R² = 0.999495164901662
-10
35
-15 30
25
-20
20
-25 15
-30 10
5
-35
0
-40 0 5000 10000 15000 20000 25000 30000 35000 40000

-45

0.0000012474
0000 45000

o orden

0557810296452

25000 30000 35000 40000 45000

 43. Valores de absorción de oxigeno a 90.15
CMC Quitosano Pectinas
P (torr) ʋ (cm3/g) P (torr) ʋ (cm3/g) P (torr) ʋ (cm3/g)
61.6 0.878 51 0.720 44 0.623
104.5 0.958 86 0.786 74 0.680
159.5 1.076 131 0.882 113 0.764
201.3 1.166 165 0.956 143 0.828
245.3 1.276 201 1.046 174 0.906
315.7 1.463 259 1.200 224 1.039
486.2 1.881 399 1.542 345 1.336
586.3 2.288 481 1.876 416 1.624
669.9 2.728 549 2.237 476 1.937

51. Valores de absorción de oxigeno a 200

CMC Quitosano Pectinas
P (torr) ʋ (cm3/g) P (torr) ʋ (cm3/g) P (torr) ʋ (cm3/g)
3192.00 121.20 2617.44 99.38 2266.32 86.05
6384.00 163.20 5234.40 133.82 4532.40 115.87
15230.40 183.60 12488.93 150.55 10813.58 130.36
23438.40 194.40 19219.49 159.41 16641.26 138.02
30552.00 198.00 25052.64 162.36 21691.92 140.58
35750.40 199.20 29315.33 163.34 25382.78 141.43
de oxigeno a 90.15 K
Goma arábiga Almidón
P (torr) ʋ (cm3/g) P (torr) ʋ (cm3/g)
75 1.062 85 1.211
126 1.159 144 1.322
193 1.302 220 1.485
244 1.411 278 1.609
297 1.544 339 1.761
382 1.770 436 2.019
588 2.276 671 2.596
709 2.768 809 3.157
811 3.301 924 3.765

de oxigeno a 200 K
Goma arábiga Almidón
P (torr) ʋ (cm /g)
3
P (torr) ʋ (cm3/g)
3862.32 146.65 4373.04 166.04
7724.40 197.47 8745.60 223.58
18428.78 222.16 20865.65 251.53
28360.46 235.22 32110.61 266.33
36967.92 239.58 41856.24 271.26
43257.98 241.03 48978.05 272.90
 43. Valores de absorción de oxigeno a 90.15 K
Almidón
P (torr) ʋ (cm3/g) P (Atm) 1/p (Atm) 1/ʋ (cm3/g) LN P (Atm)
85 1.211 0.1118 8.9457 0.8255 -2.191
144 1.322 0.1896 5.2733 0.7563 -1.6628
220 1.485 0.2894 3.4549 0.6736 -1.2399
278 1.609 0.3653 2.7375 0.6215 -1.007
339 1.761 0.4451 2.2465 0.5679 -0.8094
436 2.019 0.5729 1.7455 0.4953 -0.557
671 2.596 0.8823 1.1334 0.3852 -0.1252
809 3.157 1.0640 0.9399 0.3167 0.062
924 3.765 1.2157 0.8226 0.2656 0.1953

Isoterma de Langmuir) Isoterm

0.9000
f(x) = 0.0651398115051562 x + 0.347713836892146
0.8000 R² = 0.772172857000334

0.7000 f(x) = 0.470898849

R² = 0.9175012174
0.6000
0.5000
0.4000
0.3000
0.2000
0.1000
0.0000
0.0000 1.0000 2.0000 3.0000 4.0000 5.0000 6.0000 7.0000 8.0000 9.0000 10.0000 -2.5 -2
no a 90.15 K Isoterma de BET
4

LN ʋ (cm3/g) P/(V*(1-P)) 3

0.1914 0.1039 1.07595105 20.8882

0.2791 0.1770 1.07144525 10.8104
f(x) = − 2.3902658737802 x + 1.15910097635114
0.3954 0.2744 1.05489331 00.7106 R² = 0.183689214170761
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000
0.4756 0.3577 1.02128451 -10.6347
0.5658 0.4556 0.97703147 -20.5549
0.7026 0.6644 0.86228768 -30.4271
0.9539 2.8880 0.30550477 0.1177
-4
1.1496 -5.2685 -0.20194547 -0.0640
-5
1.3257 -1.4973 -0.81191061 -0.2157
-6

Isoterma de Freundlich Isoterma d

1.4

1.2
f(x) = 0.470898849392313 x + 1.05479367336585 f(x) = 1.00086730453958 x + 2.91
R² = 0.917501217499072 1 R² = 0.824563326058489

0.8

0.6

0.4

0.2

0 -2.5 -2 -1.5 -
-2.5 -2 -1.5 -1 -0.5 0 0.5
ma de BET

5910097635114
0.8000 1.0000 1.2000 1.4000

Isoterma de temkin
4

3.5

f(x) = 1.00086730453958 x + 2.91847418653309 3

R² = 0.824563326058489
2.5

1.5

0.5

0
-2 -1.5 -1 -0.5 0 0.5