GRUPO 07

Cálculo de Equilibrio L - V de la Mezclas binaria

ACETATO DE ETILO - ETANOL

Componente Temperatura, fracción molar de A en, Presión total,

A B °C Liquido Vapor Kpa
78.3 0.000 0.000
76.6 0.050 0.102
75.5 0.100 0.187
73.9 0.200 0.305
72.8 0.300 0.389
72.1 0.400 0.457
71.8 0.500 0.516
Acetato de etilo Etanol 101.3
71.8 0.540 0.540
71.9 0.600 0.576
72.2 0.700 0.644
73 0.800 0.726
74.7 0.900 0.837
76 0.950 0.914
77.1 1.000 1.000

Antoine constant Temperatura aplicable a la

Especies
A B C región, °C 𝑙𝑜𝑔𝑃^𝑠𝑎𝑡=𝐴_1
Acetato de etilo 7.10179 1244.951 217.881 16 - 76
Etanol 8.1122 1592.864 226.184 20 - 93

Parámetros

Van Laar
Sistema
𝛼 𝛽
Acetato de etilo(1), etanol (2) 0.8552 0.7526

𝑙𝑛𝛾_𝐴^𝐿=𝛼/(1+(𝛼𝑋_𝐴)/(𝛽𝑋_𝐵 ))^2 𝑙𝑛𝛾_𝐵^𝐿=𝛽/(1+(𝛽𝑋_𝐵)/(𝛼𝑋_𝐴 ))^2

𝑙𝑜𝑔𝑃^𝑠𝑎𝑡=𝐴_1−𝐴_2/(𝑇+𝐴_3 )
 Sistema: AcetatoDeEtilo(A) Etanol(B)
Constantes de Antoine A1 7.10179 8.1122
presión en Torr y T en °C A2 1244.951 1592.864
A3 217.881 226.184

〖 log⁡𝑃 〗 ^𝑠𝑎𝑡=𝐴_1−𝐴_2/(𝑇+𝐴_3 )

1bar= 100 Kpa

1atm= 760 mm Hg
1atm= 14,696 psi
1atm= 1,01325 bar
1atm= 101,325 Kpa

Datos experimentales
EJE X EJE Y
XA YA T
0 0 78.3
0.05 0.102 76.6
0.1 0.187 75.5
0.2 0.305 73.9
0.3 0.389 72.8
0.4 0.457 72.1
0.5 0.516 71.8
0.54 0.54 71.8
0.6 0.576 71.9
0.7 0.644 72.2
0.8 0.726 73.3
0.9 0.837 74.7
0.95 0.914 76
1 1 77.1
DIAGRAMA T-x,y a Presión constante

Ingrese la Presión, torr=mmHg, = 760 1 atm

TsA= 77.0628423 °C
TsB= 78.2981919 puro

i T °C PsA PsB xA yA diagonal

0 77.0628423 760 723.606186 1 1 1
0.01 77.0751958 760.30943 723.962787 0.99148669 0.99189037 0.99148669
0.02 77.0875493 760.618961 724.319536 0.98294847 0.983749 0.98294847
0.03 77.0999028 760.928591 724.676431 0.97438522 0.97557575 0.97438522
0.04 77.1122563 761.238322 725.033472 0.9657968 0.96737044 0.9657968
0.05 77.1246098 761.548153 725.390661 0.95718308 0.9591329 0.95718308
0.06 77.1369633 761.858083 725.747996 0.94854392 0.95086297 0.94854392
0.07 77.1493168 762.168114 726.105478 0.9398792 0.94256047 0.9398792
0.08 77.1616703 762.478246 726.463108 0.93118878 0.93422524 0.93118878
0.09 77.1740238 762.788477 726.820884 0.92247251 0.92585711 0.92247251
0.1 77.1863773 763.098809 727.178807 0.91373027 0.9174559 0.91373027
0.11 77.1987308 763.409241 727.536877 0.90496192 0.90902143 0.90496192
0.12 77.2110843 763.719773 727.895095 0.89616731 0.90055354 0.89616731
0.13 77.2234378 764.030405 728.253459 0.8873463 0.89205205 0.8873463
0.14 77.2357913 764.341138 728.611971 0.87849876 0.88351677 0.87849876
0.15 77.2481447 764.651971 728.970631 0.86962454 0.87494752 0.86962454
0.16 77.2604982 764.962905 729.329437 0.8607235 0.86634414 0.8607235
0.17 77.2728517 765.273939 729.688391 0.85179549 0.85770643 0.85179549
0.18 77.2852052 765.585073 730.047492 0.84284037 0.84903422 0.84284037
0.19 77.2975587 765.896308 730.406741 0.833858 0.84032732 0.833858
0.2 77.3099122 766.207643 730.766137 0.82484822 0.83158554 0.82484822
0.21 77.3222657 766.519079 731.125681 0.81581088 0.82280869 0.81581088
0.22 77.3346192 766.830615 731.485372 0.80674585 0.8139966 0.80674585
0.23 77.3469727 767.142252 731.845212 0.79765296 0.80514906 0.79765296
0.24 77.3593262 767.453989 732.205198 0.78853207 0.79626589 0.78853207
0.25 77.3716797 767.765827 732.565333 0.77938302 0.7873469 0.77938302
0.26 77.3840332 768.077765 732.925615 0.77020566 0.77839189 0.77020566
0.27 77.3963867 768.389804 733.286045 0.76099983 0.76940067 0.76099983
0.28 77.4087402 768.701944 733.646624 0.75176538 0.76037304 0.75176538
0.29 77.4210937 769.014184 734.00735 0.74250216 0.7513088 0.74250216
0.3 77.4334472 769.326526 734.368224 0.73320999 0.74220776 0.73320999
0.31 77.4458007 769.638967 734.729246 0.72388874 0.73306971 0.72388874
0.32 77.4581542 769.95151 735.090416 0.71453822 0.72389445 0.71453822
0.33 77.4705077 770.264153 735.451734 0.70515829 0.71468178 0.70515829
0.34 77.4828612 770.576897 735.813201 0.69574878 0.70543149 0.69574878
0.35 77.4952147 770.889742 736.174815 0.68630952 0.69614338 0.68630952
0.36 77.5075682 771.202688 736.536578 0.67684035 0.68681723 0.67684035
0.37 77.5199217 771.515734 736.898489 0.6673411 0.67745285 0.6673411
0.38 77.5322751 771.828882 737.260549 0.65781162 0.66805001 0.65781162
0.39 77.5446286 772.14213 737.622757 0.64825172 0.6586085 0.64825172
0.4 77.5569821 772.45548 737.985114 0.63866123 0.64912812 0.63866123
0.41 77.5693356 772.76893 738.347619 0.62903999 0.63960864 0.62903999
0.42 77.5816891 773.082481 738.710272 0.61938783 0.63004984 0.61938783
0.43 77.5940426 773.396133 739.073075 0.60970456 0.62045152 0.60970456
0.44 77.6063961 773.709886 739.436025 0.59999002 0.61081344 0.59999002
0.45 77.6187496 774.02374 739.799125 0.59024403 0.60113539 0.59024403
0.46 77.6311031 774.337696 740.162373 0.58046641 0.59141713 0.58046641
0.47 77.6434566 774.651752 740.52577 0.57065698 0.58165846 0.57065698
0.48 77.6558101 774.965909 740.889316 0.56081556 0.57185913 0.56081556
0.49 77.6681636 775.280168 741.253011 0.55094197 0.56201892 0.55094197
0.5 77.6805171 775.594528 741.616855 0.54103602 0.5521376 0.54103602
0.51 77.6928706 775.908989 741.980848 0.53109754 0.54221494 0.53109754
0.52 77.7052241 776.223551 742.34499 0.52112633 0.5322507 0.52112633
0.53 77.7175776 776.538214 742.709281 0.51112222 0.52224465 0.51112222
0.54 77.7299311 776.852979 743.073721 0.501085 0.51219654 0.501085
0.55 77.7422846 777.167844 743.43831 0.49101449 0.50210615 0.49101449
0.56 77.7546381 777.482812 743.803048 0.4809105 0.49197322 0.4809105
0.57 77.7669916 777.79788 744.167936 0.47077283 0.48179752 0.47077283
0.58 77.7793451 778.11305 744.532973 0.4606013 0.47157879 0.4606013
0.59 77.7916986 778.428321 744.898159 0.4503957 0.4613168 0.4503957
0.6 77.8040521 778.743693 745.263495 0.44015584 0.4510113 0.44015584
0.61 77.8164055 779.059167 745.62898 0.42988152 0.44066203 0.42988152
0.62 77.828759 779.374743 745.994615 0.41957254 0.43026874 0.41957254
0.63 77.8411125 779.690419 746.3604 0.40922869 0.41983117 0.40922869
0.64 77.853466 780.006198 746.726334 0.39884978 0.40934908 0.39884978
0.65 77.8658195 780.322077 747.092417 0.3884356 0.3988222 0.3884356
0.66 77.878173 780.638059 747.45865 0.37798593 0.38825027 0.37798593
0.67 77.8905265 780.954141 747.825034 0.36750058 0.37763303 0.36750058
0.68 77.90288 781.270326 748.191566 0.35697934 0.36697021 0.35697934
0.69 77.9152335 781.586612 748.558249 0.34642198 0.35626156 0.34642198
0.7 77.927587 781.902999 748.925082 0.33582831 0.34550679 0.33582831
0.71 77.9399405 782.219488 749.292064 0.3251981 0.33470564 0.3251981
0.72 77.952294 782.536079 749.659197 0.31453113 0.32385784 0.31453113
0.73 77.9646475 782.852772 750.02648 0.3038272 0.31296311 0.3038272
0.74 77.977001 783.169566 750.393912 0.29308608 0.30202118 0.29308608
0.75 77.9893545 783.486462 750.761495 0.28230754 0.29103176 0.28230754
0.76 78.001708 783.80346 751.129228 0.27149137 0.27999457 0.27149137
0.77 78.0140615 784.120559 751.497111 0.26063734 0.26890934 0.26063734
0.78 78.026415 784.43776 751.865145 0.24974522 0.25777577 0.24974522
0.79 78.0387685 784.755064 752.233329 0.23881479 0.24659358 0.23881479
0.8 78.051122 785.072468 752.601663 0.22784581 0.23536247 0.22784581
0.81 78.0634755 785.389975 752.970148 0.21683806 0.22408215 0.21683806
0.82 78.075829 785.707584 753.338783 0.20579129 0.21275234 0.20579129
0.83 78.0881825 786.025295 753.707568 0.19470527 0.20137272 0.19470527
0.84 78.100536 786.343107 754.076504 0.18357977 0.18994301 0.18357977
0.85 78.1128894 786.661022 754.445591 0.17241454 0.1784629 0.17241454
0.86 78.1252429 786.979038 754.814829 0.16120935 0.16693208 0.16120935
0.87 78.1375964 787.297156 755.184217 0.14996394 0.15535025 0.14996394
0.88 78.1499499 787.615377 755.553756 0.13867808 0.14371709 0.13867808
0.89 78.1623034 787.933699 755.923446 0.12735152 0.1320323 0.12735152
0.9 78.1746569 788.252124 756.293286 0.115984 0.12029557 0.115984
0.91 78.1870104 788.570651 756.663278 0.10457527 0.10850657 0.10457527
0.92 78.1993639 788.88928 757.03342 0.09312509 0.09666498 0.09312509
0.93 78.2117174 789.208011 757.403714 0.08163319 0.08477049 0.08163319
0.94 78.2240709 789.526844 757.774158 0.07009932 0.07282276 0.07009932
0.95 78.2364244 789.845779 758.144754 0.05852322 0.06082147 0.05852322
0.96 78.2487779 790.164817 758.515501 0.04690463 0.0487663 0.04690463
0.97 78.2611314 790.483956 758.886399 0.03524328 0.0366569 0.03524328
0.98 78.2734849 790.803198 759.257448 0.0235389 0.02449294 0.0235389
0.99 78.2858384 791.122543 759.628648 0.01179123 0.01227409 0.01179123
1 78.2981919 791.441989 760 0.00 0.00 0
TEMPERATURA °C
DIAGRA
79.00

78.00

77.00

76.00

75.00

74.00

73.00

72.00

71.00
0 0.1 0.2 0.3 0.4

1
Diagram
0.9

0.8

0.7

0.6
y

0.5
 0.8

0.7

0.6

y
0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4

x
 DIAGRAMA T-X,Y (P=101.325kPa cte)

T-x

T-y

T - X experim

T -y experime

0.3 0.4 0.5 0.6 0.7 0.8 0.9

X,Y

Diagrama composición X-Y

ideal raoult

diagonal

Datos exper
 ideal raoult

diagonal

Datos exper

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x
 T-x

T-y

T - X experimental

T -y experimental

0.8 0.9 1

ideal raoult - dalton

diagonal

Datos experimentales
 ideal raoult - dalton

diagonal

Datos experimentales

1
 Sistema: AcetatoDeEtilo(A) Etanol(B)
Constantes de Antoine A1 7.10179 8.1122
presión en torr,mmHg y T en °C A2 1244.951 1592.864
A3 217.881 226.184

〖 log⁡𝑃 〗 ^𝑠𝑎𝑡=𝐴_1−𝐴_2/(𝑇+𝐴_3 )
perry 7th ed.
alfa= 0.8552 A 12
beta= 0.7526 A 21

1bar= 100 Kpa

1atm= 760 mm Hg
1atm= 14,696 psi
1atm= 1,01325 bar
1atm= 101,325 Kpa

𝑙𝑛𝛾_𝐴^𝐿=𝛼/(1+(𝛼𝑋_𝐴)/(𝛽𝑋_𝐵 ))^2 𝑙𝑛𝛾_𝐵^𝐿=𝛽/(1+(𝛽𝑋_𝐵)/(𝛼𝑋_𝐴 ))^2

 DIAGRAMA T-x,y a Presión constante

Ingrese la Presión, torr=mmHg, = 760 1 atm

TsA= 77.0628423 puro
TsB= 78.2981919 puro

Intervalo T °C PsA PsB xAsupuesto 𝛾_𝐴 𝛾_B

0 78.2981919 791.441989 760 5.38E-07 2.35184224 1
0.05 77.9732823 783.074192 750.28329 9.11666E-03 2.31080199 1.00008057
0.1 77.6483727 774.776759 740.670426 0.018735906707 2.26882893 1.00033945
0.15 77.3234631 766.54927 731.160538 0.028945624485 2.22572143 1.00080815
0.2 76.9985535 758.391308 721.752762 0.03987723355 2.1811489 1.00152983
0.25 76.6736439 750.302456 712.446238 0.051500167495 2.13548025 1.00254486
0.3 76.3487343 742.282299 703.240112 0.063959245153 2.08841322 1.00391459
0.35 76.0238247 734.330423 694.133533 0.077395157121 2.03974436 1.00571637
0.4 75.6989151 726.446414 685.125657 0.091924414905 1.98943551 1.00804185
0.45 75.3740055 718.629862 676.215644 0.107738042239 1.93727727 1.01101605
0.5 75.0490959 710.880355 667.402658 0.125076274477 1.88302855 1.01480576
0.55 74.7241863 703.197484 658.68587 0.144242884101 1.82641955 1.019637
0.6 74.3992768 695.580842 650.064453 0.165632185006 1.76713819 1.02582343
0.65 74.0743672 688.030021 641.537588 0.189869490853 1.70456735 1.03384801
0.7 73.7494576 680.544616 633.104458 0.217751646973 1.63815223 1.04441771
0.75 73.424548 673.124223 624.764252 0.250609396969 1.56683898 1.05872691
0.8 73.0996384 665.768438 616.516165 0.290747381268 1.48887569 1.07896746
0.85 72.7747288 658.476859 608.359394 0.343073211123 1.40048804 1.11002878
0.9 72.4498192 651.249086 600.293143 0.423710719076 1.28897434 1.16874579
0.95 72.356789 649.191279 598.000121 0.463282644216 1.24352887 1.20265333
1 72.326789 648.528792 597.262242 0.481939675499 1.22396517 1.21986477
0.05 72.292789 647.778625 596.426901 0.551546449767 1.16041247 1.29139071
0.1 72.4262842 650.728007 599.712355 0.636653143763 1.10030885 1.39583136
0.15 72.5894263 654.346924 603.748009 0.682494310899 1.07482729 1.46063924
0.2 72.8525685 660.2179 610.305263 0.732103190114 1.05205183 1.53819509
0.25 73.1157106 666.130791 616.922017 0.768826151868 1.03815261 1.60095226
0.3 73.3788527 672.08581 623.598693 0.798568294853 1.02862247 1.65534098
0.35 73.6419948 678.083171 630.335718 0.823767988762 1.0217001 1.70405398
0.4 73.9051369 684.123086 637.133519 0.845718901648 1.01649956 1.74854506
0.45 74.168279 690.205771 643.992526 0.865204420406 1.01251054 1.78971015
0.5 74.4314212 696.331442 650.913171 0.882741525274 1.00941219 1.82815147
0.55 74.6945633 702.500312 657.895888 0.898692357978 1.00699005 1.86429883
0.6 74.9577054 708.712599 664.941112 0.913322047405 1.00509403 1.89847287
0.65 75.2208475 714.96852 672.049282 0.92683142475 1.00361536 1.93092109
0.7 75.4839896 721.26829 679.220838 0.939376800083 1.00247295 1.9618397
0.75 75.7471317 727.612129 686.456222 0.951082555491 1.0016049 1.99138777
0.8 76.0102738 734.000254 693.755878 0.962049507616 1.00096309 2.0196966
0.85 76.273416 740.432884 701.120253 0.972360656367 1.00050946 2.04687623
0.9 76.5365581 746.910239 708.549795 0.982085253291 1.0002135 2.07302015
0.95 76.7997002 753.432537 716.044955 0.991281752916 1.00005045 2.09820864
1 77.0628423 760 723.606186 1 #DIV/0! 2.12251138
 Componente Temperatur fracción molar de A en, Presión
A B a, °C Liquido Vapor total, Kpa
78.3 0.000 0.000
76.6 0.050 0.102
75.5 0.100 0.187
73.9 0.200 0.305
72.8 0.300 0.389
72.1 0.400 0.457
71.8 0.500 0.516
Acetato de etilo Etanol 101.3
71.8 0.540 0.540
71.9 0.600 0.576
72.2 0.700 0.644
73 0.800 0.726
74.7 0.900 0.837
76 0.950 0.914
77.1 1.000 1.000
constante

Y-X
1.000
Curva de Burbuja Curva de Rocío 0.900
yA-modificado
xA calculado yA Error 0.800
0.0000000 0.00 0.0000005 0.700
0.00911668162887 0.02170639 -2.50968E-08

Y
0.018760829698638 0.04333507 -2.4922992E-05 0.600
0.028945624484707 0.06498008 0 0.500
0.039882722970567 0.08679408 -5.48942052E-06
0.051509970942612 0.10857428 -9.803448E-06 0.400
0.063974234707231 0.13045937 -1.49895539E-05 0.300
0.077397858406459 0.15253428 -2.70128516E-06
0.09192450482288 0.17480374 -8.99182941E-08 0.200
0.107738788614028 0.197357 -7.46374544E-07 0.100
0.125076280237995 0.22030013 -5.76120776E-09
0.1442429 0.24375788 -3.17391716E-09 0.000
0.000 0.100 0.200 0.300 0.400 0.500
0.165645864141059 0.27 -0.0000137
0.189872092174295 0.29299698 -2.60132E-06 X
0.217751936152701 0.31941751 -2.89179847E-07
0.250609415983253 0.34777899 -1.90144808E-08
0.290754210352001 0.37921356 -6.82908441E-06
0.343078684495798 0.41628728 -5.47337291E-06
0.423710759416727 0.46800151 -4.03407102E-08
0.463252879733729 0.49210864 2.976448236E-05 80
0.481933162074246 0.5033585 6.513424856E-06
0.551553662230176 0.54551601 -7.21246294E-06
0.636665251176977 0.59979578 -1.21074138E-05
0.682494151894631 0.63158556 1.590047624E-07 78
0.732102619576434 0.67 0.0000006
0.768826118212781 0.69957658 3.36550E-08
0.798567941557201 0.72640563 3.532953272E-07
76
0.82376778810063 0.750927 2.006615833E-07
0.845718800138799 0.77384483 1.015092219E-07
Temperatura (°C)

0.865204373781849 0.80 4.66242861E-08

0.882741505735504 0.81640286 1.953824469E-08 74
0.898692350539344 0.83650619 7.438751504E-09
0.913322044862788 0.85602647 2.542437594E-09
0.926831423985843 0.87506715 7.639894273E-10
0.939376799887622 0.89 1.952527029E-10 72
0.951082555450666 0.91201293 4.024214295E-11
0.962049507609756 0.93003246 0.0000000
0.972360656366867 0.94780869 5.79425E-13
0.982085253290677 0.9653765 2.409183963E-14 70
0.991281752915749 0.98 0
#DIV/0! #DIV/0! #DIV/0!
68
0.000 0.100 0.200 0.300 0.400 0
68
0.000 0.100 0.200 0.300 0.400 0
 Y-X

experimental
YA
XA

0.300 0.400 0.500 0.600 0.700 0.800 0.900 1.000

X

T - x;y

T-X-experimental
T-Y-experimental
T-X-modificada
T-Y-modificada

0.300 0.400 0.500 0.600 0.700 0.800 0.900 1.000

X-Y
0.300 0.400 0.500 0.600 0.700 0.800 0.900 1.000

X-Y