Problema 9.

1_Treybal
Soluciones Metanol - Etanol.
a) Calcule los equllibrios vapor - líquido para este sistema a 1 y 5 atmósferas absolutas
Graficar los diagramas T vs x,y y x vs y*

log⁡〖𝑝 _𝑖^𝑜 (𝑚𝑚𝐻𝑔)=𝐴 −𝐵/(𝑇(𝑜𝐶)+𝐶) 〗

Ley de Antoine:

A B C
Metanol: 7.879 1473.11 230
Etanol 8.045 1554.3 222.65

a.1) 1 atmósfera Metanol log (760)=7.879-1473.11/(T+230)

Etanol log (760)=8.045-1554.3/(T+222.65)

T (oC) poA (mmHg) poB (mmHg) x y* a T vs x

64.73 760.03253798 432.993784 0.99990051 0.99994332 1.755296648
80
66 798.50387315 457.380893 0.88712612 0.93207059 78
1.7458181679
76
68 862.33865147 498.116562 0.71902129 0.81584191 1.7311985117
74
72
70 930.32209035 541.84803 0.56156123 0.6874116 1.7169428306
70
72 1002.6568331 588.745879 0.41374629 0.5458494 1.7030383876
68
66
74 1079.5516389 638.987206 0.27467672 0.39016803 1.6894730117
64
76 1161.2214051 692.755704 0.14354156 0.21932043 62
1.6762350681
60
78.32 1262.2324347 759.797587 0.00040286 0.00066909 1.66127460260 0.2 0.4

1.7099096535
a.2) 5 atmósfera Tb,Met = 112.64 oC
Tb, Et = 125.4 oC
130 T
T (oC) poA (mmHg) poB (mmHg) x y* a 125
112.643799.3235591 2566.32404 1.00054861 0.97974431 1.4804535615 120
114 3950.967783 2679.40747 0.8812736 0.89739268 1.4745677255
116
4182.6993359 2853.02532 0.7121856 0.76774696 1.4660575611 115

118
4425.1223945 3035.65429 0.5500995 0.62738598 1.4577161844 110
120
4678.5824319 3227.6351 0.39447669 0.47566796 1.4495388363
105
122
4943.4302306 3429.31561 0.24481924 0.31191928 1.4415209293 0 0.1 0.2 0.3
124 5220.021796 3641.05083 0.1006663 0.13543307 1.4336580404
125.45420.8166196 3795.44165 0.00280449 0.00391821 1.4282439635
1.4539696002
b) Para cada presión, calcule las volatilidades relativas y determine el valor promedio.
a 1 atmósfera: a promedio = 1.71
a 5 atmósferas: a promedio = 1.18
c) Utilizando la ecuación 9.2, con las volatilidades proemdio, compare los valores de y*
para cada valor x con los obtenidos a partir de las presiones de vapor

a 1 atmósfera: y' = 1.71x/(1+0.71x) a 5 atmósferas:

0.99994181
0.93074626
0.81398361
0.68654027
0.54686049
0.39304531
0.22275418
s absolutas

a = poA/poB

T = (1473.11/(7.879-2.8808))-230 T = 64.73 oC
T = (1554.3/(8.045-2.8808))-222.65 T = 78.32 oC

1
T vs x,y 0.9 x vs y x
80 0.8 1
78 0.7
0.8
76 0.6
74 0.5 0.6
72
70
0.4 0.4
0.3
68 0.2
66 0.2
64 0.1 0
62 0
60 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0 0.2 0.4 0.6 0.8 1

1
130 T vs x,y 0.9
x vs y
0.8
125
0.7
0.6
120
0.5
0.4
115
0.3
0.2
110 0.1
0
105 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

NOTA: PARA EVITAR CONFUSIONES, VAMOS A CALCULAR

a CONSIDERANDO LA RELACIÓN DE LAS PRESIONES DE VAPOR
COMO SE INDICA EN LA CELDA H7
lores de y*

y' = 1.18x/(1+0.18x)
1.00037829
0.91498733
0.78203862
0.63937126
0.48576149
0.31976033
0.13964045
 y
1
0.8
0.6
0.4
0.2
0

OS A CALCULAR
RESIONES DE VAPOR
p*(mmHg) 1 5 10 20 40
T© -36.7 -19.6 -11.5 -2.6 7.6
T© -26.7 -4.4 6.4 18.4 31.8
T© -3.8 20.2 32.1 45.1 59.8
 PA*= 1283.5 PB*=
Pj mj(P*/PT) ZFj y*j xw
A 1283.5 1.68881579 0.5 0.42659395 0.32965417
B 563.313 0.74120132 0.25 0.26727995 0.31023049
C 201.09 0.26459211 0.25 0.30626522 0.55765462
1.00013912 1.19753928
 60 100 200 400 760
15.4 26.1 42.2 60.6 80.1
40.3 51.9 69.5 89.5 110.6
68.8 81.3 100.2 121.7 144.4
563.313 PC*= 201.09
SUPONER W/D 0.333

P 760 mmHg