concentracion concentracion alicuota material

corregida (ppm) a partir de (ppm) (mL) alicuota

504.42 500 0,1451g KMnO4
50.44 50.0 500 25.0 pipeta
10.09 10.0 500 10.0 pipeta
0.20 0.2 10 1.0 bureta
0.50 0.5 10 2.5 bureta
1.01 1.0 10 5.0 pipeta
2.02 2.0 10 10.0 pipeta
3.03 3.0 10 15.0 bureta
5.04 5.0 10 25.0 pipeta
8.07 8.0 10 40.0 pipeta
15.13 15.0 50 15.0 pipeta
20.18 20.0 50 20.0 pipeta
25.22 25.0 50 25.0 pipeta
30.26 30.0 50 30.0 pipeta

concentracion
absorbancia (530nm) repeticion
(ppm)
0.2 -0.001 1
0.5 0.009 2
1.0 0.024 3
2.0 0.061 4
3.0 0.104 5
5.0 0.190 6
8.0 0.332 7
10.0 0.391 8
15.0 0.613 9
20.0 0.847 10
25.0 1.078
30.0 1.198
50.0 1.880
 material vol concentracion concentracion
tolerancia V final (mL) final tolerancia (ppm) corregida
1000 balon aforado 500 504.42
0.06 250.0 balon aforado 0.30 50.0 50.44
0.04 500.0 balon aforado 0.50 10.0 10.09
0.10 50.0 balon aforado 0.12 0.2 0.20
0.10 50.0 balon aforado 0.12 0.5 0.50
0.03 50.0 balon aforado 0.12 1.0 1.01
0.04 50.0 balon aforado 0.12 2.0 2.02
0.05 50.0 balon aforado 0.12 3.0 3.03
0.06 50.0 balon aforado 0.12 5.0 5.04
0.06 50.0 balon aforado 0.12 8.0 8.07
0,04;0,03 50.0 balon aforado 0.12 15.0 15.13
0.06 50.0 balon aforado 0.12 20.0 20.18
0.06 50.0 balon aforado 0.12 25.0 25.22
0.04 50.0 balon aforado 0.12 30.0 30.26

absordancia
alicuota Conc inicial
(10ppm) Vol final
0.384 V1 C1 = V2
0.384
0.379 C2 = C1
0.372 V2
0.372
0.373 504.42
0.373 250.0
0.367
0.366 50.44200
0.366 0.1400558696

50,4 +/- 0,14 ppm

 Incertidumbre alicuota
( ) alicuota (mL) corregida
0.36
0.14 25.0 24.8
0.04 10.0 9.9
0.01 1.0 1.0
0.01 2.5 2.5
0.01 5.0 5.0
0.01 10.0 9.9
0.02 15.0 14.9
0.03 25.0 24.8
0.05 40.0 39.6
0.10 15.0 14.9
0.14 20.0 19.8
0.12 25.0 24.8
0.20 30.0 29.7

Conc objetivo

C2

V1
V2

25.0
250.0

0.0027765725

50,4 +/- 0,14 ppm

 celda %T A
Blanco 87.7 0.058 A=2-log%T
Muestra 87.4 0.068
Factor correccion 0.853

concentracion 10 ppm

l %T A Sin corregir A corregida

CURVA ESPECTRA
400 95.8 0.022 0.019 Análisis de Mn2+
410 98.2 0.009 0.008
0.400
420 97.9 0.011 0.009
0.350
430 98.6 0.007 0.006
0.300
440 94.8 0.027 0.023

Absorbancia
0.250
450 97.1 0.015 0.013 0.200
460 91.4 0.046 0.039 0.150
470 83.8 0.090 0.077 0.100
480 77.6 0.129 0.110 0.050
490 71.9 0.168 0.143 0.000

400
410
420
430
440
450
460

480
490
500
470
500 61.4 0.248 0.212
Longitud de On
510 54.1 0.313 0.267
520 47.3 0.381 0.325
l máx 530 46.4 0.391 0.334
540 47.8 0.376 0.321
550 48.7 0.366 0.312
560 63.3 0.233 0.199
570 65.6 0.215 0.183
580 82.8 0.096 0.082
590 92.3 0.041 0.035
600 95.4 0.024 0.020
 CURVA ESPECTRAL
Análisis de Mn2+ en medio ácido
420
430
440
450
460

480
490
500

520
530
540
550

570
580
590
600
470

510

560

Longitud de Onda
 ppm %T T ABS(0,4343/(TLOGT))
0.2 100.2 1.0023 433.30
0.5 97.9 0.9795 49.27
1.0 94.6 0.9462 19.12
2.0 86.9 0.8690 8.19
3.0 78.7 0.7870 5.31
5.0 64.6 0.6457 3.54
8.0 46.6 0.4656 2.81
10.0 40.6 0.4064 2.73
15.0 24.4 0.2438 2.91
20.0 14.2 0.1422 3.61
25.0 8.4 0.0836 4.82
30.0 6.3 0.0634 5.72
50.0 1.3 0.0132 17.52

Se debe realizar con

las concentraciones
experimentales
 CURVA DE CRAWFORD
Análisis de Mn2+ en medio ácido
60.00

50.00
ABS(0,4343/(TLOGT))

40.00

30.00

20.00
[VALOR DE X] [VALOR DE X]
10.00
(20,0ppm) (3,0ppm)
0.00
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000 1.2000
Transmitancia (T)
1.2000
 ppm %T 100-%T A log [ppm] 100-%T
0.2 100.2 -0.2 -0.001 0.0 -0.2 CURVA DE RING
0.5 97.9 2.1 0.009 -0.30 2.1 Análisis de Mn2
1.0 94.6 5.4 0.024 0.00 5.4 120.0

2.0 86.9 13.1 0.061 0.31 13.1 100.0

3.0 78.7 21.3 0.104 0.48 21.3 80.0
5.0 64.6 35.4 0.19 0.70 35.4

100 - %T
60.0
8.1 46.6 53.4 0.332 0.91 53.4 40.0 f(x) = 5.41048452888 x − 7.91
10.1 40.6 59.4 0.391 1.00 59.4 20.0
R² = 0.937271669015651
15.1 24.4 75.6 0.613 1.18 75.6 0.0
20.2 14.2 85.8 0.847 1.30 85.8 0.0 -0.3 0.0 0.3 0.5 0
-20.0
25.2 8.4 91.6 1.078 1.40 91.6
30.3 6.3 93.7 1.198 1.48 93.7
50.4 1.3 98.7 1.880 1.70 98.7

Realizar la gráfica con las

CURVA DE RINGBOM
concentraciones
Análisis de Mn2+ en medio ácido
experimentales 105.0
95.0
85.0
75.0
65.0
55.0
100 -%T

Rango lineal
45.0
35.0
25.0
15.0
5.0
0.0

0.5

1.0

1.5
-0.5

2.0

-5.0
-15.0

Log(Concentración)
 CURVA DE RINGBOM
Análisis de Mn2+ en medio ácido
120.0
100.0
80.0
100 - %T

60.0
40.0 f(x) = 5.41048452888 x − 7.91222566331585
R² = 0.937271669015651
20.0
0.0
0.0 -0.3 0.0 0.3 0.5 0.7 0.9 1.0 1.2 1.3 1.4 1.5 1.7
-20.0

Log (ppm)

120.0

100.0
f(x) = 30.4051857345102 x + 47.6669377600353
R² = 0.932062260741807
80.0

60.0

f(x) 40.0
= 26.1479583772877 x + 5.77888054073783
R² = 0.797557394474451
20.0

0.0
-0.5 0.0 0.5 1.0 1.5 2.0

-20.0
ppm %T A A corregido
5.0 64.6 0.19 0.162 CURVA DE CALIBRACIO
Análisis de Mn2+ en me
8.1 46.6 0.332 0.283
10.1 40.6 0.391 0.334 1.000
15.1 24.4 0.613 0.523 0.900
0.800
0.700

Absorbancia
0.600
0.500 f(x) = 0.189366 x + 0.144157
0.400 R² = 1

0.300
0.200
0.100
0.000
10.1
Concentracion
 CURVA DE CALIBRACION A corregido
Análisis de Mn2+ en medio ácido
0.600

0.500 f(x) = 0.035316065779774 x − 0.012996700334682

R² = 0.996554507614202
0.400

0.300

0.189366 x + 0.144157
1 0.200

0.100

0.000
4.0 6.0 8.0 10.0 12.0 14.0

15.1
Concentracion
orregido

x − 0.012996700334682

10.0 12.0 14.0 16.0

 SEÑAL RUIDO

n absordancia PROM DESV EST limite de 0.021

(10ppm) P deteccion
1 0.384
2 0.384
3 0.379
Señal Ruido
4 0.372
5 0.372
0.374 0.006
6 0.373
7 0.373
8 0.367
9 0.366
10 0.366

PRECISION DEL INSTRUMENTO

absordancia DESV EST ERROR
n (10ppm) PROM P ALEATORIO
1 0.384
2 0.384
3 0.379
4 0.372
5 0.372
0.374 0.006 1.7
6 0.373
7 0.373
8 0.367
9 0.366
10 0.366

PRECISION DEL METODO

absordancia DESV EST ERROR
n PROM
(10ppm) P SISTEMATICO
1 0.376
2 0.385
3 0.381 0.3828 0.004 1.1
4 0.384
5 0.388
 limite 0.064
cuantificacion