Cinetica de reacciones Q

Universidad Santiago de Cali

Programa: Quimica
Fecha: 10/06/2020
Docente: Yesid Zambrano
Estudiante: William David Mera
Laboratorio de fisico quimica lll (cinetica)
a de reacciones Quimicas
1
Tipo orden 0
C (mol/m3) t(minutos) Orden 0

concentracion (mol/m3)
1000 0 1200
500 100 1000
800
333 200 600
f(x) = − 1.85 x + 826.6
R² = 0.813000984390381
250 300 400
200 400 200
0
0 50 100 150 200 250 300 350 400
tiempo (min)

Tipo orden 1
C (mol/m3) C (mol/m3) t(minutos) Orden 1
1000 6.90775528 0 8
500 6.2146081 100 6 f(x) = − 0.003912023005428 x + 6.73246143144463
333 5.80814249 200 R² = 0.947158541524116

Ln[c]
4
250 5.52146092 300
2
200 5.29831737 400
0
0 50 100 150 200 250 300 350 400
t(min)

Tipo orden 2
C (mol/m3) t(minutos) 1/C (mol/m3) Orden 2
1000 0 0.001 0.006
500 100 0.002 0.005
0.004 f(x) = 1E-05 x + 0.001000600600601
333 200 0.003003003 R² = 0.999999278558358
0.003
1/[c]

250 300 0.004 0.002

200 400 0.005 0.001
0
0 50 100 150 200 250 300 350 4
t(min)
en 0

00 250 300 350 400 450

mpo (min)

en 1

73246143144463

0 250 300 350 400 450

t(min)

en 2
m 1E-05 [A]0 500
t 300 minutos
600601
1/[A] 0.005 m3/mol

200 250 300 350 400 450 [A] [A] [A]

t(min)
mol/m3
2 Para orden 0
CC (mol/L) t(min) CA (mol/L) 𝐶𝐴=𝐶𝐴_0−(𝐶𝐶/2)
0 0 5.5
1.18 41 4.91
1.38 48 4.81
1.63 55 4.685 Orden 0
2.24 75 4.38
6
2.75 96 4.125
3.31 127 3.845 5
3.76 146 3.62 f(x)==0.866591166571236
R² − 0.006082953821553 x + 4.86519599192583
3.81 162 3.595 4
4.11 180 3.445
3
4.31 194 3.345
4.45 212 3.275 2
4.86 267 3.07
5.15 318 2.925 1
5.32 368 2.84
0
5.35 379 2.825 0 50 100 150 200 250 300 350 4
5.42 410 2.79

Para orden 1
t(min) LN (CONC.)
0 0
41 -0.11347415
48 -0.13405101 Orden 1
55 -0.16038218 0
0 50 100 150 200 250 300
75 -0.22769937
-0.1
96 -0.28768207 f(x)==0.918698451790352
R² − 0.001616041372638 x − 0.109089194297458
127 -0.35797449 -0.2
146 -0.41827407 -0.3
162 -0.4252041
-0.4
180 -0.46782419
194 -0.4972814 -0.5
212 -0.51843022
-0.6
267 -0.58307053
318 -0.63145361 -0.7

368 -0.66094404 -0.8

379 -0.66623973
410 -0.6787065

Para orden 2
t(min) 1/C0NC.
0 0.18181818

Orden 2.
0.4
f(x) = 0.000440926578328 x + 0.197740212506752
41 0.20366599
48 0.20790021 Orden 2.
55 0.21344717 0.4
75 0.2283105 f(x) = 0.000440926578328 x + 0.197740212506752
0.35
96 R² = 0.957793621140631
0.24242424
0.3
127 0.26007802
146 0.27624309 0.25
162 0.27816412 0.2
180 0.29027576
0.15
194 0.29895366
212 0.30534351 0.1
267 0.3257329 0.05
318 0.34188034
368 0
0.35211268 0 50 100 150 200 250 300
379 0.3539823
410 0.35842294
 Orden 0

6553 x + 4.86519599192583

200 250 300 350 400 450

Orden 1
150 200 250 300 350 400 450

0352
372638 x − 0.109089194297458

Orden 2.

78328 x + 0.197740212506752
 Orden 2.
(𝟏/𝑨)=(𝟏/𝑨_𝑰 )+𝑲𝒕
Ecuación=
78328 x + 0.197740212506752
0631

K= 0.0004

150 200 250 300 350 400 450

𝟏/𝑨)=(𝟏/𝑨_𝑰 )+𝑲𝒕
3 Orden 0
TIEMPO PRESION Orden 0
0 760 800
2 600 700
600 f(x) = − 37.4107142857143 x + 671.25
4 475 R² = 0.916772411344185
500
6 390
400
8 320 300
10 275 200
12 240 100
14 215 0
0 2 4 6 8 10 12 14 16

Orden 1
Orden 1
TIEMPO LN. PRESION
7.0000
0 6.6333
6.0000 f(x) = − 0.090819484273059 x + 6.56024622448452
2 6.3969 R² = 0.984685691934966
5.0000
4 6.1633
4.0000
6 5.9661
3.0000
8 5.7683
2.0000
10 5.6168 1.0000
12 5.4806 0.0000
14 5.3706 0 2 4 6 8 10 12 14 1

Orden 2
TIEMPO 1/PRESION Orden 2
0 0.0013 0.0050
0.0045
2 0.0017 0.0040 f(x) = 0.0002440584053 x + 0.00119546803241
R² = 0.996794239414819
4 0.0021 0.0035
0.0030
6 0.0026 0.0025
8 0.0031 0.0020
0.0015
10 0.0036 0.0010
12 0.0042 0.0005
0.0000
14 0.0047 0 2 4 6 8 10 12 14 1
 10 12 14 16

448452

10 12 14 16

(𝟏/𝑨)=(𝟏/𝑨_𝑰 )+𝑲𝒕
Ecuación=

41
K= 0.0002

10 12 14 16
4
tiempo(min) tiempo (s) N2 (cm3) x A0/A0-x Ec. Orden 1
0 0 0 0 1 0
6 360 19.3 19.3 1.49487179 0.40204045
9 540 26 26 1.80495356 0.59053486
12 720 32.6 32.6 2.26848249 0.8191111
14 840 36 36 2.61434978 0.96101541
18 1080 41.3 41.3 3.42941176 1.23238875
20 1200 43.3 43.3 3.88666667 1.35755189
22 1320 45 45 4.38345865 1.47783806
24 1440 46.5 46.5 4.94067797 1.59750256
26 1560 48.4 48.4 5.88888889 1.77306734
30 1800 50.3 50.3 7.2875 1.98616055
∞ ∞ 58.3 58.3

Volumen vs ti empo
60
f(x) = 0.026467049642315 x + 9.20616735313246
50 R² = 0.914650803144961
Volumen de N2

40

30

20

10

0
0 200 400 600 800 1000 1200 1400 1600 1800 2000
Tiempo (s)
 P 1 atm
T 323 K
𝑛=(𝑃.𝑉)/(𝑅.𝑇)
R 0.082 atm*L/mol*K
[A]0 10 g/mL

𝑋= 〖𝑉 ^𝑡 〗 _𝑁2− 〖𝑉 ^0 〗 _𝑁2
A0 58.3 g/mL 𝐾𝑡=ln⁡〖𝐴 _0/(𝐴_0−𝑋) 〗
tiempo vida 1/2 630.1338 s 𝐴_0= 〖𝑉 ^"∞ " 〗 _𝑁2− 〖𝑉 ^0 〗 _𝑁2

pendiente=K 0.0011 s-1

orden 1
2.5

2
f(x) = 0.001116416628441 x + 0.006629671935446
R² = 0.999169527845347
Ln(A0/A0-x)

1.5

0.5

0
0 200 400 600 800 1000 1200 1400 1600 1800 2000

Tiempo (s)
𝑉 ^0 〗 _𝑁2

− 〖𝑉 ^0 〗 _𝑁2
 5
Temperatura (K) k(cm3/mol*s) 1/T Ln[k]
592 522 0.00168919 6.25766759
603 755 0.00165837 6.62671775 6000
627 1700 0.0015949 7.43838353
651.5 4020 0.00153492 8.29903718 5000

656 5030 0.00152439 8.52317526 4000 f(x) = 68.3516778938258 x −

R² = 0.929618291486408
3000
ln⁡〖 (𝐾 〗 )=ln⁡〖 (𝐴)−𝐸_𝑎/𝑅 〗∗ 1/((𝑇))Ecuación de Arrhenius

k
linealizada 2000

−𝐸_𝑎/𝑅=𝑚 13622 1000

=
0
R= 8.314 J/k*mol 580 590 600 610 620 6

Ea= 113253.308 J/mol 𝐸_𝑎=m*R

 Sin linealizar Linealizado

00 9
8 f(x) = − 13622.4499019544 x + 29.2297383826509
00 R² = 0.99751930662523
7
00 f(x) = 68.3516778938258 x − 40375.9151937456 6
R² = 0.929618291486408
5

Ln[k]
00
4
00 3
2
00
1
0 0 1/
580 590 600 610 620 630 640 650 660 T(k) 0.0015 0.00155 0.0016 0.00165 0.0017
44 x + 29.2297383826509

1/T
016 0.00165 0.0017