RESOLUCIN DE EXAMEN DE CINTICA QUMICA

[H2O2] 2[H2O]
t(s) vol vt(ml) n[O2](ml/L) v(l) [O2] (mol/L)
(mol/L) (mol/L)
0 0.0 25.0 0.00000000 0.025000 0.0000000000 0.4262 0.00000
0.418834
3 3.0 28.0 0.00010312 0.028000 0.0036828276
34 0.00737
0.409534
6 8.0 33.0 0.00027498 0.033000 0.0083328624
28 0.01667
0.403903
9 12.0 37.0 0.00041248 0.037000 0.0111480186
96 0.02230
0.399681
12 15.7 40.7 0.00053966 0.040700 0.0132593858
23 0.02652
0.396514
15 19.0 44.0 0.00065309 0.044000 0.0148429111
18 0.02969
0.393636
18 22.5 47.5 0.00077339 0.047500 0.0162819745
05 0.03256
0.392528
21 24.0 49.0 0.00082495 0.049000 0.0168357832
43 0.03367
0.391152
24 26.0 51.0 0.00089370 0.051000 0.0175235194
96 0.03505
0.390504
27 27.0 52.0 0.00092807 0.052000 0.0178475490
9 0.03570
0.390190
30 27.5 52.5 0.00094526 0.052500 0.0180049348
13 0.03601
0.389881
33 28.0 53.0 0.00096245 0.053000 0.0181593511
3 0.03632
0.389578
36 28.5 53.5 0.00097963 0.053500 0.0183108810
24 0.03662
0.389280
39 29.0 54.0 0.00099682 0.054000 0.0184596049
79 0.03692
0.389163
42 54.2 0.00100369 0.054200 0.0185183261
29.2 35 0.03704
 0.388988
45 29.5 54.5 0.00101401 0.054500 0.0186055999
8 0.03721
0.388702
48 30.0 55.0 0.00103119 0.055000 0.0187489404
12 0.03750
0.388420
51 30.5 55.5 0.00104838 0.055500 0.0188896982
6 0.03778
0.388254
54 30.8 55.8 0.00105869 0.055800 0.0189729421
12 0.03795
0.388254
57 30.8 55.8 0.00105869 0.055800 0.0189729421
12 0.03795

Nombre: Humberto Pacompia Quispe cdigo:2012302044

Dnde:
t (s) : Tiempo en segundos
Vol. O2 : Volumen de oxigeno formado REACCION
Vt (mL) : Volumen total en mililitros
n [O2]mol : Nmero de moles del oxigeno 2 H 2 O2 ( l ) catalalizador 2 H 2 O(l)+O2 ( g)

V (l) : Volumen en litros
[O2] (mol/L) : Concentracin molar o molaridad del oxigeno

a) Para hallar el vol.(ml) se us la siguiente formula

Vt=V0+V (ml)
Vt=50+3.0 = 53.00.
Formulas Para Hallar La Concentracin ([]) Molar
b) Calculo de nmero de moles.
DATOS
P: 0,846 atm.
R: 0,082 atm.l.mol-1.k.1
T: 300,15 K
V0 50 ml
[H2O2] 0,4262 mol
PV
n moles=
mL
RT 1000
L

(0,846 atm1)
n moles=
mL
0,846 atm .(300.15 k 1000)
L

=0.0001024 mol/l k

c) Calculo de concentracin molar O2.

 n moles
[ O2 ]= VolumenV ( L)

0,00010312mol .
[ O2 ]= 0,053000 l

= 0,0019456448 mol/l.

d) Clculos de la Molaridad Inicial del Perxido De Hidrogeno (H2O2)

Datos:
volumen H2O2 10 ml
peso molecular 34,0146 g/mol
densidad molar 1,45 g/ml

g
[ H 2 O2 ( l ) ]=1.45 ml H 2 O2 X 10 ml H 2 O2 =14.5 g

14.5 g H 2 O2
g
34.0146 H O
mol 2 2 mol H 2 O2
[ H 2 O2 ( l ) ]= 1l solucion =0.426 1l solucion
 0.4262 mol
e) Graficas de aparicin del oxgeno(O2)

Grafica De Aparicon Del La[o2]

0.0140000000

0.0120000000

0.0100000000

0.0080000000
[[O2] (mol/L)] 0.0060000000
[O2] vs t(s)

0.0040000000

0.0020000000

0.0000000000
0 10 20 30 40 50 60

tiempo (s)
f) Graficas de desaparicin de perxido de hidrogeno (H2O2)

Grafica desaparicion del [H2O2]

0.43
0.43
0.42
0.42
0.41
[H2O2] (mol/L)] 0.41 [H2O2] vs t(s)
0.4
0.4
0.39
0.39
0 10 20 30 40 50 60

tiempo (s)