Química II

Formulario para el examen cap 4

AF Y BF
PH = Log 1/H+ HCl = 0,001 N = 10-3 PH = 3
POH = Log 1/OH- NaOH = 0,1 N = 10-1 N PH= 13
SAL AF + BF NaCl = 0,1 N PH = 7 neutro
AD Y BD
H+ = Ca α Ka = dato = Ca α2/ 1-α
OH- = Cbα Kb = dato = Cb α2/ 1-α
PORKY
H+ = √ KaCa = Ca α
OH- = √ KbCb = Cb α
HENDERSON
AD PH= (PKa + Log 1/Ca) 0,5
BD POH= (PKb + Log 1/Cb) 0,5

SALES AF + BF……………..NaCl PH = 7
AD + BF
AF + BD
AD + BD……………..CH3COONH4 = PH=7

AD + BF (TRADICIONAL)
CH3COONa = 0,1 N Ka = 1,75 x 10-5
Kh = Kw/Ka = Cs α2/1-α
H+ = Cs α
AF + BF (TRADICIONAL)
NH4Cl = 0,1 N Kb = 1,8 x 10-5
Kh = Kw/Kb = Cs α2/1-α
OH- = Csα PH =14 – POH
PORKY AD + BF
H+ = √ KhCs Kh = Kw/Ka
AF + BD
OH- = √ KhCs Kh = Kw/Kb
PH =14 – POH
HENDERSON – HASSELBALCH
AD + BF
POH = (PKw – Pka – Log Cs) 0,5
AF + BD
PH= (PKw – PKb - Log Cs) 0,5

AD + BD
PORKY H+ = √ Kw Ka/ Kb
HENDERSON PH= (PKw + PKa -PKb)
BUFFER – TAMPON – SOLUCIONES REGULADORAS
CH3COONa
CH3COOH Ka
NH4Cl
NH3 Kb
TRADICIONAL
Ka = (Ca +Cs) α2 = (1+x)x PH= Log 1/Ct α
1-α 1-x
PH = Log 1/x

Kb = (Cb +Cs) α2 = (1+x)x POH= Log 1/Ct α

1-α 1-x
POH = Log 1/x
HENDERSON
CH3COONa
CH3COOH……..Ka PH = PKa + Log Cs/Ca

NH4Cl
NH3 …………….Kb POH = PKb + Log Cs/Cb

VALORACIÓN
AF + BF……………H + = VaNa – VbNb
Vt
AD +BF……………OH- = VbNb – VaNa
Vt
AF + BD
AD + BD