Ejercicio 2

Datos:

𝑋 𝑒𝑡𝑖𝑙𝑏𝑒𝑛𝑐𝑒𝑛𝑜 = 0.6
𝑛 𝑡𝑜𝑙𝑢𝑒𝑛𝑜
𝑆= = 0.06
𝑛 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜
𝑡𝑜𝑛
𝑚 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜 = 1500
𝑑í𝑎
Determinar el flujo molar producido del estireno
𝑡𝑜𝑛 1000 𝑘𝑔 1 𝑑í𝑎 1 𝑘𝑚𝑜𝑙
𝑛 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜 𝑝𝑟𝑜𝑑𝑢𝑐𝑖𝑑𝑜𝑠 = 1500 ∗ ∗ ∗ = 600.97 𝑘𝑚𝑜𝑙/ℎ
𝑑í𝑎 1 𝑡𝑜𝑛 24 ℎ 104 𝑘𝑔
Mediante el dato de la selectividad de 0.06, se obtiene el número de moles producidos del tolueno
𝑛 𝑡𝑜𝑙𝑢𝑒𝑛𝑜
𝑆= = 0.06
𝑛 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜
𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
𝑛 𝑡𝑜𝑙𝑢𝑒𝑛𝑜 𝑝𝑟𝑜𝑑𝑢𝑐𝑖𝑑𝑜𝑠 = 0.06 ∗ 𝑛 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜 = 0.06 ∗ 600.97 = 36.06
ℎ ℎ

Con base al dato de conversión del etilbenceno, se puede determinar el número de moles que se
alimentan al reactor

𝑛 𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛𝑎 𝑛 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜 + 𝑛 𝑡𝑜𝑙𝑢𝑒𝑛𝑜

𝑋𝑒𝑡𝑖𝑙𝑏𝑒𝑛𝑐𝑒𝑛𝑜 = =
𝑛 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜 𝑛 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜𝑠 𝑒𝑡𝑖𝑙𝑏𝑒𝑛𝑐𝑒𝑛𝑜
𝑘𝑚𝑜𝑙
600.97 + 36.06 𝑘𝑚𝑜𝑙/ℎ
= ℎ = 0.6
𝑛 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜𝑠

𝑘𝑚𝑜𝑙
600.97 + 36.06 𝑘𝑚𝑜𝑙/ℎ
𝑛 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜 𝑒𝑡𝑖𝑙𝑏𝑒𝑛𝑐𝑒𝑛𝑜 = ℎ = 1061.72 𝑘𝑚𝑜𝑙/ℎ
0.6

Determinar la cantidad de etilbenceno que no reacciona:

𝑠
𝑛 𝑒𝑡𝑖𝑙𝑏𝑒𝑛𝑐𝑒𝑛𝑜 = 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜𝑠 − (𝑛 𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛𝑎𝑛 𝑡𝑜𝑙𝑢𝑒𝑛𝑜 + 𝑛 𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛𝑎𝑛 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜)
𝑟
𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
= 1061.72 − (600.97 + 36.06 ) = 424.69 𝑘𝑚𝑜𝑙/ℎ
ℎ ℎ
 1era reacción C6H5-CH2-CH3 C6H5-CH-CH2 H2
A 1061.72 0 0
R 600.97 600.97 600.97
S 460.75 600.97 600.97

600.97 ∗ 𝑐𝑜𝑒𝑓𝑖𝑐𝑖𝑒𝑛𝑡𝑒 𝑒𝑠𝑡𝑒𝑞𝑢𝑖𝑜𝑚é𝑡𝑟𝑖𝑐𝑜 𝐶6𝐻5 − 𝐶𝐻2 − 𝐶𝐻3

𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛𝑎C6H5 − CH2 − CH3 =
𝑐𝑜𝑒𝑓𝑖𝑐𝑖𝑒𝑛𝑡𝑒 𝑒𝑠𝑡𝑒𝑞𝑢𝑖𝑜𝑚é𝑡𝑟𝑖𝑐𝑜 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜
600.97 ∗ 1
= = 600.97
1

2da reacción C6H5-CH2-CH3 H2 C6H5-CH3 CH4

A 460.75 600.97 0 0
R 36.06 36.06 36.06 36.06
S 424.69 564.91 36.06 36.06

Calcular la alimentación de vapor de H2O

𝑘𝑚𝑜𝑙
𝑛 𝑎𝑙𝑖𝑚𝑒𝑛𝑡𝑎𝑑𝑜𝑠 𝐻2𝑂 = 𝑛 𝑒𝑡𝑖𝑙𝑏𝑒𝑛𝑐𝑒𝑛𝑜 ∗ 6 = (1061.72 ) ∗ 6 = 6370.32 𝑘𝑚𝑜𝑙/ℎ
ℎ

Balance para el etilbenceno:

𝐶𝑜𝑟𝑟𝑖𝑒𝑛𝑡𝑒 1 + 𝐶𝑜𝑟𝑟𝑖𝑒𝑛𝑡𝑒 7 = 𝐶𝑜𝑟𝑟𝑖𝑒𝑛𝑡𝑒 2

𝑘𝑚𝑜𝑙 𝑘𝑚𝑜𝑙
𝐶𝑜𝑟𝑟𝑖𝑒𝑛𝑡𝑒 1 𝑟𝑒𝑎𝑐𝑐𝑖𝑜𝑛𝑎𝑛𝑑𝑜 = 𝐶𝑜𝑟𝑟𝑖𝑒𝑛𝑡𝑒 2 − 𝐶𝑜𝑟𝑟𝑖𝑒𝑛𝑡𝑒 7 = 1061.72 − 424.69
ℎ ℎ
= 637.03 𝑘𝑚𝑜𝑙/ℎ
Balance molar para cada corriente

Componente Etilbenceno Estireno Hidrógeno Tolueno Metano Vapor H20

Corriente
1 637.03
2 1061.72
3 600.97 6370.32
4 424.69 600.97 564.91 36.06 36.06 6370.32
5 564.91 36.06 6370.32
6 36.06
7 424.69
8 600.97

Balance global de materia

1 5
PROCESO
8
3

6
 𝑚
𝑛=
𝑃𝑀
Entradas:
𝑘𝑚𝑜𝑙 𝑘𝑔
𝑚 𝑒𝑡𝑖𝑙𝑏𝑒𝑛𝑐𝑒𝑛𝑜 = 𝑛 ∗ 𝑃𝑀 = (637.03 ) ( 106 ) = 67525.18 𝑘𝑔/ℎ
ℎ ℎ
𝑘𝑚𝑜𝑙 𝑘𝑔
𝑚 𝑣𝑎𝑝𝑜𝑟 𝐻2𝑂 = 𝑛 ∗ 𝑃𝑀 = (6370.32 ) ( 18 ) = 114665.76 𝑘𝑔/ℎ
ℎ ℎ

∑ 67525.18 + 114665.76 = 182190.94 𝑘𝑔/ℎ

Salidas:
𝑘𝑚𝑜𝑙 𝑘𝑔
𝑚 𝐻2 = 𝑛 ∗ 𝑃𝑀 = (564.91 ) ( 2 ) = 1129.82 𝑘𝑔/ℎ
ℎ ℎ
𝑘𝑚𝑜𝑙 𝑘𝑔
𝑚 𝑣𝑎𝑝𝑜𝑟 𝐻2𝑂 = 𝑛 ∗ 𝑃𝑀 = (6370.32 ) ( 18 ) = 114665.76 𝑘𝑔/ℎ
ℎ ℎ
𝑘𝑚𝑜𝑙 𝑘𝑔
𝑚 𝑚𝑒𝑡𝑎𝑛𝑜 = 𝑛 ∗ 𝑃𝑀 = (36.06 ) ( 16 ) = 576.96 𝑘𝑔/ℎ
ℎ ℎ
𝑘𝑚𝑜𝑙 𝑘𝑔
𝑚 𝑒𝑠𝑡𝑖𝑟𝑒𝑛𝑜 = 𝑛 ∗ 𝑃𝑀 = (600.97 ) ( 104 ) = 62500.88 𝑘𝑔/ℎ
ℎ ℎ
𝑘𝑚𝑜𝑙 𝑘𝑔
𝑚 𝑡𝑜𝑙𝑢𝑒𝑛𝑜 = 𝑛 ∗ 𝑃𝑀 = (36.06 ) ( 92 ) = 3317.52 𝑘𝑔/ℎ
ℎ ℎ

∑ 1129.82 + 114665.76 + 576.96 + 62500.88 + 3317.52 = 182190.94 𝑘𝑔/ℎ

Tarea: 10,837.24 kg/h