DATOS

P= 12 bar 𝑃𝑉=𝑍𝑅𝑇
V= cm3/mol
Z= 1
R= 83.14 cm3*bar/K*mol V= 2065.68258
T= 298.15 K
 Celsius a Kelvin
C= 25
K= 298.15
 Virial Truncada Datos
B= -140 cm^3/mol
𝑍=1+𝑃𝑉/𝑅𝑇=1+𝐵/𝑉 P= 21 bar
T= 328.15 K
R= 83.14 cm^3*bar/mol*K
Tc= 324.69
Pc= 83.4
Tr 1.01065632
Pr 0.25179856
F.O -155.899377
V= 0
V1= 125
Z= 0.92
𝑍=1+𝐵𝑃/𝑅𝑇=1+[(𝐵𝑃_𝑐)/(𝑅𝑇_𝑐 )]𝑃_𝑟/𝑇_𝑟
〖𝐵𝑃〗 _𝑐/
y

(𝑅𝑇_𝑐 )=𝐵^0+𝜔𝐵^1
R 83.14
𝐵^0= -0.33171928 T 328.15
𝐵^1= -0.02531912 Tc 324.6 Tr
𝜔= 0.125 P 21 Pr
Pc 83
Correlación -0.33488417 Coversor
K
B= -108.886755 C=

Z= 0.9161869
V= 1190.27472

Correlaciones de Pitzer
 (De la tabla B.19)
Datos
Vc 200 Vsat 109.520829

+𝜔𝐵^1 Tr
Zc
0.93
0.276 Z= 0.08430117

𝑉^𝑠𝑎𝑡=𝑉_𝑐× 〖 (𝑍 〗 _𝑐)^(1-Tr)^0.2857
1.01093654
0.25301205 R 83.14
T 328.15
P 21
328.15
55

Ecuación de Rackett
 Ec. Cúbica Peng Robinson

Datos Constantes Ecuaciones

T (°k) 600 α 0.75230626787 𝑎_1
Tc (°k) 430.8 R (cm3*bar/K*mol) 83.14 𝑏_1
P (bar) 300 w 0.245 A
Pc (bar) 78.84 k 0.736291752 B
V 𝑍^3−(1−𝐵) 𝑍^2+(𝐴−3𝐵^2−2𝑏)𝑍−(𝐴𝐵
Vc 𝑎_3
Peso molecular (g/mol) 0 𝑎_2
Valor experimental (bar) No aplica 𝑎_1
𝑎_0
p Ec.14
q Ec. 15
𝑅_1Ec. 16

Conversor de C a K
K 353.15 Z= 0.78577781754 V=
C 80 F.O. -3.1338848E-08

HR 1er término 1era parte deDERIVADA 2do término

-10686.2593 -7439933.09 -9345.506269 -112079.293

Hr -80339.8225 -49847.48
se divide /10

SR 1er término 2do término 3er término

-46.2663339 -93.4843997 1.86165678

SR -104.363788

se divide /10

Fugacidad
1er término 2do término 3er término
-0.21422218 -0.55648706 1.12237698

ln(f/P) -0.35525519
(f/P) 0.70099453
f= 210.29836

P bar Z ∅ F F vs P
600

500

400
 F vs P
10 0.9833 0.9833 9.8338 600
20 0.9669 0.9671 19.3438
500
40 0.9353 0.936 37.4435
60 0.9055 0.9066 54.4013 400
80 0.8779 0.879 70.32

Presión
300
100 0.8528 0.853 85.3
200 0.7776 0.7489 149.7834 200
300 0.7838 0.6836 205.0902
100
400 0.8358 0.6465 258.6249
500 0.907 0.6279 313.9745 0
0 50 100 150
F

CF vs P
600

500

400
Presión

300

200

100

0
0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1 1.05
C.F

CF vs P
 Resultado
5597108.29958413 𝐺_𝑖^𝑅=𝑅𝑇 ln⁡∅
35.344243957382 -17721.55
0.674780344812297
0.212558599695586
^2+(𝐴−3𝐵^2−2𝑏)𝑍−(𝐴𝐵−𝐵^2−𝐵^3 )=0
1
-0.787441400304414
0.11411967050748
-0.0886455631490188
-0.0925683157969786
-0.0948590848471632
0.00222018342037928

130.659136

3er término
1.86165678

4to término
1.86165678

F vs P
 F vs P

50 100 150 200 250 300 350

F
(𝑑𝐻/𝑑𝑃)𝑡=(1−𝛽𝑇)𝑉
(𝑑𝑆/𝑑𝑃)𝑝=-𝛽V

∆𝑆=−𝛽𝑉(𝑃_2 〖−𝑃〗 _1) ∆𝐻=(1−𝛽𝑇)𝑉(𝑃_2 〖−𝑃〗 _1)

DATOS -0.00266121 0.55174134
T 270 K Convertido Convertido
P1 381 Kpa -2.66121356 551.74134
P2 1200 Kpa
V 0.001551 m3/kg
β 0.002095 1/K
𝐻=(1−𝛽𝑇)𝑉(𝑃_2 〖−𝑃〗 _1)
Aumento del 1%
(𝑑𝑃)𝑣=𝑅/𝑇 𝑑𝑇 (𝑑𝑃)𝑡=−𝑅𝑇/𝑉^2 𝑑𝑉
DATOS
T 400 K 0.00287 -1.27555556
V 0.9 m3/kg
R 0.287 Kpa*m3/kg*K
𝑃)𝑡=−𝑅𝑇/𝑉^2 𝑑𝑉
Recipiente rígido 𝑑𝑉=(𝑑𝑉/𝑑𝑇)𝑝𝑑𝑇+(𝑑𝑉/𝑑𝑃)𝑡𝑑𝑃
DATOS 𝑓(𝑃,𝑉,𝑇)=0 𝑉(𝑇,𝑃)
T1 298.15 K
T2 323.15 K 𝛽𝑉(𝑇_2−𝑇_1 )−𝐾𝑉(𝑃_2−𝑃1)=0 𝛽=1/𝑉(𝑑𝑉/𝑑𝑇)𝑝𝐾=−1/𝑉(𝑑𝑉/𝑑𝑃)𝑡
P 1 bar
β 0.000362 k-1
K 0.0000442 bar-1 𝑃_2=(𝛽(𝑇_2−𝑇_(1)))/𝐾+𝑃_1
𝛽𝑉(𝑇_2−𝑇_1 )−𝐾𝑉(𝑃_2−𝑃1)=0=𝑑𝑉=𝛽V*dT-KV
V 0.001003 m3/kg

Conversor P2 205.751131
T en C 50
T en K 323.15

cm3/g a m3/kg
1.003
0.001003
=−1/𝑉(𝑑𝑉/𝑑𝑃)𝑡

𝑉(𝑃_2−𝑃1)=0=𝑑𝑉=𝛽V*dT-KV*dP