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RESOLUCIÓN:
3 ¯ −1 k )(748.15 k)
RT ( 83.14 cm mol
V= =
P 34 ¯¿ =1829.4468cm3 mol−1 ¿
v=?
z=?
%error =?
RT A (α )
V= +B−
P V (V + B)
T 748.15
Tr= = =1.1562
T c 647.1
1 2
[ 2
α SRK = 1+(0.480+1.574 ω−0.176 ω )(1−Tr ) 2
]
α SRK =¿ ¿
Hallar A y B:
0.42748∗R2 Tc 2
a= =0.42748∗¿ ¿
Pc
0.08664∗R∗Tc 0.08664∗83.14∗647.1
b= = =21.1345
Pc 220.55
RT aα (V −b)
V= +b−
P PV (V +b)
Reemplazar en la ecuación:
5610112.6073∗0.8548(1829.4468−21.1345)
V =1829.4468+ 21.1345−
34∗1829.4468 ( 1829.4468+ 21.1345 )
V 1=1770.5368
V 2=1767.9371
V 3=1767.8184
V 4 =1767.8130
V 5=1767.8128
V 6=19767.8127
cm 3
V 7=1767.8127
mol
PV 34∗1767.8127
Z= = =0.9663
RT 83.14∗748.15
100∗1−0.9663
%error= =3.37 %
1
B1∗Pr 0.1542
Z1 =
Tr
⟹ ( 0.0455 )(1.1562 )
=0.0061
3 ¯ −1 k )(748.15 K )
ZRT (0.9686)(83.14 cm mol
V= = =1772.0022cm3 /mol
P 34
100∗( 1−0.9686 )
%error= =3.14 %
1
cm3
V =98.408
g
cm3 g
V =98.408 ∗18.015
g mol
cm3
V =1772.8201
mol
3
PV (34)(1772.8201 cm /mol)
. Z= = =0.9690
RT ( 83.14)(748.15)
100∗( 1−0.9690 )
%error = =3.1 %
1
TABLA DE VALORES:
ECUACION V Z %ERROR
SOAVE REDLICH 1767.8127 0.9663 3.37%
KWONG
PITZER 1772.0022 0.9686 3.14%
TABLA DE VAPOR 1772.8201 0.9690 3.1%
⟨C p⟩H B C D
= A+ ∗T 0∗( τ +1 ) + ∗T 20∗( τ 2 + τ+1 )+
R 2 3 ( τ∗T 20 )
constantes molares para el cloro de la tabla C.1
A=4.442
B=0.089 ×10−3
C=0.0
D=−0.344∗105
T 573.15 K
τ= = =1 K
T 0 573.15 K
Reemplazando a la ecuación:
J J
⟨ C p ⟩ H =8.314 mol K ∗4.3883=36.4843 mol K
⟨ C p ⟩ H ( T −T 0 )
∆ H=
R
Q=3400 KJ =3400000 J =n ∆ H
Q 3400000 J J
∆ H= = =170000
n 20 mol mol
∆H
T= +T
⟨C p⟩H 0
J
170000
mol
T= +573.15 K
J
36.4843
mol K
T 1=5232.6885 K
T 5232.6885 K
τ= = =9.1297
T0 573.15 K
J J
⟨ C p ⟩ H =8.314 mol K ∗4.6889=38.9835 mol K
J
170000
mol
T= +573.15 K
J
38.9835
mol K
T 2=4933.9693
T 4933.9693
τ= = =8.6085
T 0 573.15 K
J J
⟨ C p ⟩ H =8.314 mol K ∗4.6749=38.8671 mol K
J
170000
mol
T= +573.15 K
J
38.8671
mol K
T 3=4947.0292
T 4947.0292
τ= = =8.6313
T 0 573.15 K
J J
⟨ C p ⟩ H =8.314 mol K ∗4.6755=38.8721 mol K
J
170000
mol
T= +573.15 K
J
38.8721
mol K
T 4=4946.4666
T 4946.4666
τ= = =8.6303
T 0 573.15 K
J J
⟨ C p ⟩ H =8.314 mol K ∗4.6755=38.8721 mol K
J
170000
mol
T= +573.15 K
J
38.8721
mol K
T 5=4946.4666
T 4946.4666
τ= = =8.6303
T 0 573.15 K
3. Gas acetileno a 550 K y 5 bar se somete a una expansión adiabática hasta 1 bar.
Determinar la Temperatura final del acetileno, suponiendo que el acetileno es
un gas ideal bajo estas condiciones.
⟨C p⟩H B C D
= A+ ∗T 0∗( τ +1 ) + ∗T 20∗( τ + τ 2+1 )+ 2
R 2 3 τT0
Propiedad adiabática
º
Q=0
s∗Q 0
∆ = =0
T T
∆ s ⟨C p⟩H T P
= ln −ln
R R T0 P0
⟨C p⟩H T P
ln =ln
R T0 P0
P0=5 ¯¿
P=1 ¯¿
T 0=550
T =0
⟨C p⟩H T 1
ln =ln =−1.6094
R T0 5
⟨C p⟩H T
ln =−1.6094
R T0
T −1.6094
ln =
T0 ⟨C p⟩H
R
T −1.6094
=exp ( )
T0 ⟨ C p ⟩H
R
−1.6094
T =T 0 exp ( )
⟨ C p ⟩H
R
Gas acetileno
A=6.132
B=1.952∗10−3
C=0.0
D=−1.299∗105
T 0=550 K
Resolución
T
τ=
T0
⟨C p⟩H
=6.7761
R
−1.6094
T =550 exp ( )
6.7761
T 1=433.7234
T 433.7234
τ= = =0.7885
T0 550
⟨C p⟩H
=6.5474
R
−1.6094
T =550 exp ( )
6.5474
T 2=430.1410
T 430.1410
τ= = =0.7820
T0 550
⟨C p⟩H
=6.5394
R
−1.6094
T =550 exp ( )
6.5394
T 3=430.0114
⟨C p⟩H
=6.5391
R
−1.6094
T =550 exp ( )
6.5391
T 4=430.0114
DATOS:
1.2 Kj
CP GC =
kgK
De tablas
4.18 Kj
CP H 2 O=
kgK
Balance de energía
Calentamiento de agua
Q H 2 O =ṁH 2 O CP H 2O ( T 2−T 1 )
Despejando T 4
T 4=¿236.45+273.15=509.60 K ¿
T 1=20+273.15=293.15 K
T 2=60+273.15=333.15 K
T 3=280+273.15=553.15 K
s gen=m1 ( s1 −s 2 ) m3 ( s4 −s3 )
s gen=m1 ∆ S 21 +m3 ∆ S 43
T2
−∆ S 21=m1 CP H 2 O ln
T1
T4
−∆ S 21=m3 CP CG ln
T3
25000 kg
∗1 h
h
∗4.18 kj
3600 s
S gen= ∗ln ¿
kgk
S gen=1.526 kj/s
S gen=1.526 kw