T(K) k(M^-2s^-1) 1/T

270 3.43E-10 0.0037037

370 3.77E-10 0.0027027
470 3.99E-10 0.00212766
570 4.13E-10 0.00175439
670 4.23E-10 0.00149254

´-Ea/R= -95.163
R= 8.314 J/mol*K

Ea= 791.185182 J/mol

Ea= 0.79118518 kJ/mol

Pendiente -95.1626707
Ln(k)
-21.45 Valor de k para 500K
0.001 0.0015 0.002 0.0025 0.003 0.0035 0.004
-21.5
Ln(k)= -21.6313253
-21.55 k= 4.03306E-10
-21.6
f(x) = − 95.162670692852 x − 21.4408476709641
R² = 0.999901294503683
-21.65

-21.7

-21.75

-21.8

-21.85
 Ln(k)
-21.7932907
-21.6987759
-21.6420597
-21.6075735
-21.5836489
 [A](M) [B](M)
0.0063 0.004
0.011 0.004
0.0063 0.005

Para y
-0.675447603
y=
-0.223143551

Para x
-0.552068582
x=
-0.557345639

Determinar el valor de K

k= 2.85E-07
4.03E-10
Velocidad de reacción para [A]=0005M y [B]=0

r= 6.99E-07
 r(M/s)
2.85E-07
4.95E-07
5.60E-07

3.02696448 y= 3.0

Orden G. 4.0

0.99053181 x= 1.0

Ec. De velocidad
r=7.07e02[A]*[B]^3

7.07E+02 K= 7.07E+02 1/s

acción para [A]=0005M y [B]=0.006M

0.005
0.006
 t(s) P total (kPa) P[SO2Cl2] (kPa)
0 11.07 11.07
10800 14.79 7.35
21600 17.26 4.88
32400 18.9 3.24
43200 19.99 2.15
54000 20.71 1.43

P[SO2Cl2] (kPa) Ln(P[

12 3

a)
10 2.5
LA REACCIÓN ES DE ORDEN 1 f(x) = − 0.000173121693122 x f(x) = − 3.791029
+ 9.69428571428571 + 2.4040445647
8 R² = 0.922113266961061 2
R² = 0.999999515
b) Valor de k
k= -4.00E-05 s-1 6 1.5

c) 4 1
Ln(P[SO2Cl2])= -4E-05t + 2.404
2 0.5
d) Tiempo de vida media
0 0
0 10000 20000 30000 40000 50000 60000 0 10000 20000
t(1/2)= -1.73E+04

e) Presión a las 11h

 Ln(P[SO2Cl2]) 1/P[SO2Cl2]
2.4042387467 0.09033424 LA REACCIÓN ES DE ORDEN 1
1.9947003132 0.13605442
1.5851452199 0.20491803
1.1755733298 0.30864198
0.7654678421 0.46511628
0.3576744443 0.6993007

Ln(P[SO2Cl2]) 1/P[SO2Cl2]
3 0.8

0.7
2.5
f(x) = − 3.79102931628571E-05 x 0.6 f(x) = 0.000012839729642 x
2 + 2.4040445647348 − 0.0532009587571
R² = 0.999999515418864 0.5 R² = 0.947365027807856

1.5 0.4

0.3
1
0.2
0.5
0.1

0 0
0 10000 20000 30000 40000 50000 60000 0 10000 20000 30000 40000 50000 60000