Tiempo (s) [Br2] (M) Log [Br2] (M)

0 0.012 -4.42284862919414
50 0.0101 -4.59521985513492
100 0.00846 -4.77240610536401
150 0.0071 -4.94766049493487
200 0.00596 -5.12268479790488
250 0.005 -5.29831736654804
300 0.0042 -5.47267075369282
350 0.00353 -5.64645740803693
400 0.00296 -5.82256601064617

Tiempo vs. Concentración

0.014
0.012
0.01
0.008
0.006
0.004
0.002
0
0 50 100 150 200 250 300 350 400 450
 Tiempo (s) Log [Br2] (M)
0 -4.42284862919414
50 -4.59521985513492
100 -4.77240610536401
150 -4.94766049493487
200 -5.12268479790488
250 -5.29831736654804
300 -5.47267075369282
350 -5.64645740803693
400 -5.82256601064617

In C vs. t
0
0 50 100 150 200 250 300 350 400 450
-1
-2
-3
-4
-5 f(x) = − 0.00350125611759498 x − 4.42206337886509
-6
-7

k= -0.0035 s-1
Conclusiones:La cinética de la reacción es de primer orden.
En este caso depende de Br2
V= -0.0035[Br2]
[Br2]= 0.012(e-0.0035t)
Redondear a 1 cifra Tiempo de vida media = 0.0693/k
Ej: 198
3.752484
3.74
3.7 o 3.8
 [A]/10^-3 mol dm^-3 Tiempo (s) Tiempo (s) Log[A]/10^-3 mol dm^-3
41.6 0 0 3.72810016726722
29.8 100 100 3.39450839351136
15.6 292 292 2.74727091425549
11.8 376 376 2.46809953147162
5.8 590 590 1.75785791755237

Tiempo (s) Log[A]/10^-3

700 4
600 3.5 f(x) = − 0.00334233303507804 x + 3.726945037138
3 R² = 0.999987053817112
500 2.5
f(x) = − 15.3735376939504 x + 593.214408557443
400 R² = 0.926750601926823 2
300 1.5
1
200
0.5
100 0
0 0 100 200 300 400
0 5 10 15 20 25 30 35 40 45
k= -0.0033 S-1
Tiempo de vida media:
210
 Log[A]/10^-3 mol dm^-3

334233303507804 x + 3.72694503713881
7053817112

200 300 400 500 600 700

V= -0.0033[A]
 Ejercicio discusión
N 5.00E+08
No 1.00E+06
t 4 hr
Encontrar µ
Formula
N=Noe^µt
Despejando td= In2/µ
N/No= e^µt td= 0.45h-1
In(N/No) = µt
µ= InN-InNo/t
µ td
1.55E+00 4.46E-01
 Tiempo (s) Concentración (M) Ln
390 550 6.30991828
780 400 5.99146455
1195 300 5.70378247
2000 200 5.29831737
3155 100 4.60517019

Orden de la reacción 1° orden

Constante de velocidad -0.0006 s^-1
K/2 =ln(1/2)/K 1155.24530093324 s^-1
V= -0.0006[(CH3)2O] [(CH3)2O]=550 e^-0.0006t

7) Relación entre el cambio en la concentración de reactivos o productos con el tiempo.

Constante de velocidad 1.43x10^-2 s^-1

Concentración inicial 0.567 M
[A]=[A0]e^-kt [A]=0.567 e^(1.43x10^-2)(t)
[A]=0.567 e^(1.43x10^-2)(150) [A]= 0.06637758
 Concentración (M)
600

500
f(x) = − 0.151206318921794 x + 537.414303658378
400 R² = 0.905626698657005

300

200

100

0
0 500 1000 1500 2000 2500 3000 3500

Ln
7

6 f(x) = − 0.000599783689882217 x
+ 6.48380524008822
5 R² = 0.995080726758194

0
0 500 1000 1500 2000 2500 3000 3500

Ln Linear (Ln)

[0.00463]=0.500 e^(1.43x10^-2)(t)
t= Ln(N/N0)/k
t= 327.41617