𝑉𝑓=𝐾𝑓∗𝐶𝑎=𝑗1/𝑛𝐹

Vb=Kb∗C1=jb/N𝑓
V=Vb−Vf=(𝑗𝑏−𝑗𝑓)/𝑛𝑓=𝑗/𝑛𝑓

las constantes de velocidad estan aproximadas por la ecuacion artenius

𝐾𝑓=𝐴𝑓∗exp⁡(−∆𝑡 𝐺𝑎/(𝑅∗𝑇))
𝐾𝑓=𝐴𝑏∗exp(−∆𝑡 𝐺𝑎/(𝑅∗𝑇)) donde afy ab son constantes
evelin mayly quihui flores

A)

γ1 γ2
0.5 0.5

area 113.0976

rpta
B)

La reacción que se producira gracias al impulso

Si vemos que esa reacción no es lo suficientem
proporcionar la corriente de oxidación necesa
Es probable que la corriente sea proporcionad
agua para formar O2.
 La reaccion

(Fe(CN)6)3- + e- <-------> (Fe(CN)6)4-

io, ref 229 A.m-2

T 298 K
C Fe3- 0.001 M
C Fe4- 0.001 M

datos
Ckl(M) CFe3-(M) CFe4-(M) radio(cm) V(V vs CalomelE0(V) R(J/mol.K)
0.1 5 4 3 0.10 0.36 8.314

USAMOS LA ECUACION

𝐸=𝐸_0−(𝑅×𝑇)/(𝑛×𝐹)×ln⁡(𝐶_𝑃/𝐶_𝑅 )

E 0.36573283408861

usamos la ecuacion 3.20

SCE(V) ns= SCE-E i0(A.m-2) obtenido i(A.m-2)
0.342 -0.02373283 1024119.1336949 -980050.952485608

-110841411
-11084.1411 A
se producira gracias al impulso será la oxidación del ferrocianuro.
a reacción no es lo suficientemente rápida se devera
corriente de oxidación necesaria, adicional
la corriente sea proporcionada por la oxidación de
T(K) F(C/equiv) n(equiv/mol)
298.15 96485 1
sobrepotencial densidad actual(A.m-2) densidad de corriente calculada
-0.1 -4.20 -4.10254235248666
-0.09 -3.36 -3.3400506228766
-0.08 -2.40 -2.70619867351314
-0.07 -2.30 -2.17654185687825
-0.06 -1.80 -1.73064720767856
-0.05 -1.25 -1.35130516919732
-0.04 -1.00 -1.02386536173156
-0.03 -0.80 -0.735670755243733
-0.02 -0.50 -0.47556839195233
-0.01 -0.22 -0.233477744056601
0.01 0.24 0.233946865782475
0.02 0.45 0.477481410258588
0.03 0.80 0.740114172844938
0.04 1.00 1.03211911739034
0.05 1.45 1.36493557344019
0.06 1.80 1.75161640292577
0.07 2.10 2.20733995156455
0.08 2.80 2.75000586542174
0.09 3.50 3.4009381619083
0.1 4.10 4.18572317151509

Chart T
5

4
f(x) = 199.226266470194 x⁴ + 1888.9416244849 x³ + 2.1455561
R² = 0.999945890154131
3

0
-0.15 -0.1 -0.05 0
-1

-2

-3

-4

-5
-3

-4

-5
 error error^2 logi
-0.097 0.00949799305883377 1.62324929
-0.020 0.00039797764761160 1.52633928 CONSTANTES
0.306 0.09375762766120600 1.38021124 T 298.15 K
-0.123 0.01524191310307010 1.36172784 F/RT 38.9237762
-0.069 0.00480980980278092 1.25527251
0.101 0.01026273730609760 1.09691001 R 8.314
0.024 0.00056955549057840 1 T 298.15
-0.064 0.00413825173091176 0.90308999 F 96485
-0.024 0.00059690347179496 0.69897
0.013 0.00018164958485524 0.34242268 PARAMETROS
0.006 0.00003664043385537 0.38021124 io 0.58935674
-0.027 0.00075522790980085 0.65321251 αa 0.50869747
0.060 0.00358631229404601 0.90308999 αc 0.50354057
-0.032 0.00103163770193412 1
0.085 0.00723595666594968 1.161368
0.048 0.00234097246584181 1.25527251
-0.107 0.01152186520187960 1.32221929
0.050 0.00249941349222957 1.44715803
0.099 0.00981324776610669 1.54406804
-0.086 0.00734846213460491 1.61278386
0.14 0.18562415492398900

Chart Title
5 logi
1.8
4
0194 x⁴ + 1888.9416244849 x³ + 2.14555616095683 x² + 22.2964739245891 x + 0.000110237643687303
4131 1.6
3
1.4

2 1.2
1
1
0.8
0 0.6
-0.05 0 0.05 0.1 0.15
-1 0.4
0.2
-2
0
-0.15 -0.1 -0.05 0
-3

-4

-5
-3

-4

-5
 logi
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
0.1 -0.05 0 0.05 0.1 0.15
𝑖=1/(1/(𝑛𝐹𝐾𝑚𝐶𝑟,ℎ)+1/(𝑖0,𝑏 exp⁡(𝜎𝑎𝐹/𝑅𝑇)𝑛𝑠))

transferencia de masa

reaccion quimica

𝑖=1/(1/𝑛𝐹𝐾𝑚𝐶𝑘)=𝐧𝐅𝐊𝐦𝐂𝐤

la intencidad no va depender de n