Ing. Mg.

Ricardo Rodriguez Vilchez

Ing. Mg. Ricardo Rodriguez Vilchez

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•

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0,15 M 0,10 M 0,07 M 0,05 M 0,03 M 0,01 M 0M

?
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 



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 •
•

•
•

d = espaciado de la red
𝑛𝜆 = d sen 𝜃
𝜃 = ángulo de difracción

𝑛𝜆 = d (sen 𝜃 ± sen i)
• 𝜆 ≈ d

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 𝑣𝑖

< 𝑐(𝒗𝒊 <

𝒄)

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 𝑛𝑖

• 𝒏>1 𝑛=1 𝑛 = 1.33 𝑛 = 2.42 𝑛 = 1.5 −

1.9
Veloc. en el vacío c
𝑛 = =
Veloc en el medio i v

𝑐 𝑐 = 𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑 𝑑𝑒 𝑙𝑎 𝑙𝑢𝑧 𝑒𝑛 𝑒𝑙 𝑣𝑎𝑐í𝑜

𝑣 = ; donde
𝑛 𝑛 = í𝑛𝑑𝑖𝑐𝑒 𝑑𝑒 𝑟𝑒𝑓𝑟𝑎𝑐𝑐𝑖ó𝑛

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 𝑛1
𝑛2

•
sinθ . n = sinθ . n

𝑛
𝜃 𝜃 =

n , =

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•
•
•
•
•

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𝑖 𝑟

𝑅𝑒𝑓𝑙𝑒𝑐𝑡𝑎𝑛𝑐𝑖𝑎, 𝜌 = =

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 →

• 𝑛 <𝑛 , 𝜃 ≥ 𝜃 ⇒ 𝜃 = 90

sin 𝜃 =

•
→




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𝐴 = 𝜀𝑏𝑐

𝐴 0.162 0.539
𝜀= = = 5.4 ⇛ 𝐶 = = 0.0998 ≅ 1 𝑚𝑜𝑙/𝐿
𝑏𝑐 0.03 5.4

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 𝐶𝑜 𝑁𝑂 6𝐻 𝑂 − 2𝑥10 𝑀
Cx10-3M 0.6 0.8 1.0 1.2 1.8
A 0.1784 0.2291 0.2924 0.3233 0.4948

Aplicando: 𝐴 = 𝜀𝑏𝑐
.
𝜀 = = 297.3 1. Muestra A1=0.203
.
. 0.203 = 𝜀̅𝑏 𝐶
𝜀 = = 286.3 .
. 𝐶 = = 0.714𝑥10 𝑀
. .
𝜀 =
.
= 292.4 2. Muestra A2=0.279
𝜀 =
.
= 269.4 0.279 = 𝜀̅𝑏 𝐶
. .
. 𝐶 = = 0.98𝑥10 𝑀
.
𝜀 = = 274.8
.

5𝑥10 𝑀
5𝑥10 𝑀

𝐴 = 𝜀 𝑏𝐶 + 𝜀 𝑏𝐶
𝐴 = 𝜀 𝑏𝐶 + 𝜀 𝑏𝐶

. .
530: 𝜀 = = = 602 𝜀 = = = 92

. .
690: 𝜀 = = = 92 𝜀 = = = 1204

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 0.125 = 602𝑏 𝐶 + 92𝑏 𝐶
0.398 = 92𝑏 𝐶 + 1204𝑏 𝐶

0.125 92
0.398 1204 0.125 1204 − 0.398(92)
𝐶 = = = 0.158 𝑀
602 92 602 1204 − 92(92)
92 1204

602 0.125
602 0.398 − 92(0.125)
𝐶 = 92 0.398 = = 0.318 𝑀
602 92 602 1204 − 92(92)
92 1204

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