Constantes críticas, de Cp/R = a + bT + cT2 + d/T2, de la ecuación de Antoine, ln(P sat) = A - B/(T + C), ental

ID NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) a(i) b(i) c(i)

1 CH4 190.6 4600.2 0.007 1.702 9.081E-03 -2.164E-06
2 H2 33.2 1313.0 -0.216 3.249 4.220E-04 0.000E+00
3 N2 126.2 3400.0 0.038 3.280 5.930E-04 0.000E+00
4 CO2 304.2 7383.0 0.224 5.457 1.045E-03 0.000E+00
5 n-C4 425.2 3796.0 0.200 1.935 3.692E-02 -1.140E-05
6 H2O 647.3 22090.0 0.348 3.470 1.450E-03 0.000E+00
7 NH3 405.5 11350.0 0.250 3.578 3.020E-03 0.000E+00
8 CH3OH 512.6 8097.0 0.564 2.211 1.222E-02 -3.450E-06
9 O2 154.6 5043.0 0.022 3.639 5.060E-04 0.000E+00
10 CH3CH2OH 516.0 6380.0 0.100 3.518 2.000E-02 -6.002E-06
s. Introducción a la Termodinámica en Ingeniería Química. McGraw-Hill. 7a edición
n(P sat) = A - B/(T + C), entalpía de formación y entropía absoluta a 298 K y 1 bar
d(i) A(i) B(i) C(i) Dh°f298 s°298
0.000E+00 -74850.0 186.16
8.300E+03 0.0 130.68
4.000E+03 0.0 191.61
-1.157E+05 -393520.0 213.80
0.000E+00 13.6608 2154.70 238.789 -126150.0 310.12
1.210E+04 16.3872 3885.70 230.170 -241820.0 188.83
-1.860E+04
0.000E+00 16.5785 3638.27 239.500 -200670.0 239.70
-2.270E+04 0.0 205.04
0.000E+00 16.8958 3795.17 230.918 -235310.0 282.59
 ECUACIONES DE ESTADO CÚB
T (° C) = 427.00 ESPECIFICACIONES DE LA MEZCLA:
R= 8.314 T (K) = 700.00 P (kPa) = 1000.00
DATOS DE LOS COMPONENTES:
ID NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) a(i)
7 NH3 405.5 11350.0 0.250 0.000 3.578
10 CH3CH2OH 516.0 6380.0 0.100 1.000 3.518
4 CO2 304.2 7383.0 0.224 0.000 5.457
1 CH4 190.6 4600.2 0.007 0.000 1.702
1 CH4 190.6 4600.2 0.007 0.000 1.702
1 CH4 190.6 4600.2 0.007 0.000 1.702
1 CH4 190.6 4600.2 0.007 0.000 1.702
1 CH4 190.6 4600.2 0.007 0.000 1.702
1 CH4 190.6 4600.2 0.007 0.000 1.702
1 CH4 190.6 4600.2 0.007 0.000 1.702
Sy(i) = 1.000 1
y= 0.000 1.000 0.000 0.000 0.000

VALOR DEL DISCRIMINANTE (D) = RK SRK Peng-R

6.72E-06 6.80E-06 5.36E-06
RESULTADOS
VALORES DE Z: RK SRK Peng-R
Z= 0.9787 0.9809 0.9766
PROPIEDADES RESIDUALES:
R
h = -401.253 -426.1052 -456.567 kJ/kmol
R
s = -0.396 -0.4494 -0.457 kJ/kmol-K
vR = -0.124 -0.1114 -0.136 m3/kmol
PROPIEDADES DEL GAS IDEAL REFERIDAS A 300 K Y 100 kPa (1 BAR):
(hGI - h0) = 3.970E+04 kJ/kmol 99.25 Cpm/R = 11.94
(sGI - s0) = 6.217E+01 kJ/kmol-K
vGI = 5.820 m3/kmol
PROPIEDADES TERMODINÁMICAS DE MEZCLAS
(h - h0) = 3.930E+04 3.927E+04 3.924E+04 kJ/kmol
(s - s0) = 6.178E+01 6.172E+01 6.172E+01 kJ/kmol-K
(f - f0) = (h - h0) - T0(s - s0) 2.077E+04 2.076E+04 2.073E+04 kJ/kmol
v= 5.696 5.708 5.684 m3/kmol
 ECUACIONES DE ESTADO CÚBICAS
ECIFICACIONES DE LA MEZCLA:
T0 (K) = 300.0 P0 (kPa) = 100.0 FASE (1 : VAPOR; 2 : LIQ) = 1

b(i) c(i) d(i) ln(y(i)) Dh°f298 s°298

3.020E-03 0.000E+00 -1.860E+04 0.0000 0 0.00
2.000E-02 -6.002E-06 0.000E+00 0.0000 -235310 282.59
1.045E-03 0.000E+00 -1.157E+05 0.0000 -393520 213.80
9.081E-03 -2.164E-06 0.000E+00 0.0000 -74850 186.16 Constantes del Cp/R =
2 -2
9.081E-03 -2.164E-06 0.000E+00 0.0000 -74850 186.16 am + bmT + cmT + dmT
9.081E-03 -2.164E-06 0.000E+00 0.0000 -74850 186.16 am =
9.081E-03 -2.164E-06 0.000E+00 0.0000 -74850 186.16 bm =
9.081E-03 -2.164E-06 0.000E+00 0.0000 -74850 186.16 cm =
9.081E-03 -2.164E-06 0.000E+00 0.0000 -74850 186.16 dm =
9.081E-03 -2.164E-06 0.000E+00 0.0000 -74850 186.16 S[yi*ln(yi)] =
0.0000
0.000 0.000 0.000 0.000 0.000

SI EL DISCRIMINANTE ES MAYOR QUE CERO HAY UNA RAIZ REAL Y UNA FASE HOMOGÉNEA
SI EL DISCRIMINANTE ES MENOR QUE CERO HAY TRES RAICES REALES Y FASES EN EQUILIBRIO
RESULTADOS

Ecuac RK Ecuac SRK

NOMBRE y(i) f(i) fugacidad(i) f(i) fugacidad(i)
NH3 0.000 1.0012 0.00 1.0058 0.00
CH3CH2OH 1.000 0.9790 978.96 0.9810 981.02
CO2 0.000 1.0066 0.00 1.0142 0.00
CH4 0.000 1.0157 0.00 1.0193 0.00
CH4 0.000 1.0157 0.00 1.0193 0.00
CH4 0.000 1.0157 0.00 1.0193 0.00
CH4 0.000 1.0157 0.00 1.0193 0.00
CH4 0.000 1.0157 0.00 1.0193 0.00
CH4 0.000 1.0157 0.00 1.0193 0.00
CH4 0.000 1.0157 0.00 1.0193 0.00
onstantes del Cp/R =
am + bmT + cmT2 + dmT-2
3.518
2.000E-02
-6.002E-06
0.000E+00
0.000

E HOMOGÉNEA
SES EN EQUILIBRIO

Ecuac Peng-R
f(i) fugacidad(i)
1.0045 0.00
0.9768 976.84
1.0128 0.00
1.0177 0.00
1.0177 0.00
1.0177 0.00
1.0177 0.00
1.0177 0.00
1.0177 0.00
1.0177 0.00
2,5 kmol/s de amoníaco líquido saturado a 32° C se expande a través de una válvula isentálpica, hasta 2,10 bar. Determin
destruida en el proceso; c) la fugacidad en cada corriente. En la tabla de abajo se presentan las propiedades residuales ob
se obtienen con la ecuación de Antoine para el amoníaco, log10(Psat) = A - B/(T + C)

Ecuación de Antoine para el amoníaco: líquido saturado

log10 (Psat)  =  A  -  [B / (T + C)]; Psat en bar, T en ° C T (° C) = 32 fsat (bar) =
A B C P (bar) = 12.10
4.4854 926.132 240.17 (h - h0) = -20536.34
Cp/R (const) = 4.27 (s - s0) = -87.449
T0 (K) = 300 n1 (kmol/s) = 25.00
P0 (bar) = 1

T (° C) 32 32 -17.71 -17.71
T (K) 305 305 255.29 255.29 Balance de materia:
P (bar) 12.10 12.10 2.1 2.1
Condición líq sat vap sat líq sat vap sat Balance de entergía:
hR (kJ/kmol) -20713.84 -714.35 -23010.84 -150.03
sR (kJ/kmol-K) -67.31 -1.54 -89.96 -0.368 ng/n1 = (h1 - hf)/(hg - hf) =
(h - h0) -20536.34 -24598.16 -1737.35
(s - s0) -87.449 -101.858 -7.878 Balance de entropía:
(f - f0) 5698.28 5959.23 626.13 Sgen =
fsat 0.930 0.979 0.974 Fdestruida =
fsat (bar) 11.25 2.06 2.05
Flujo (kmol/s) 2.50 2.06 0.44 Cálculo de la fugacidad:
(F - F0) (kW) 14245.70 12251.05 278.12

n1 = flujo molar del líquido saturado a 32° C

nf = flujo molar del líquido saturado a 2,1 bar
ng = flujo molar del vapor saturado a 2,1 bar
a, hasta 2,10 bar. Determine: a) el flujo molar de líquido saturado a 2,10 bar; b) la exergía
propiedades residuales obtenidas con una ecuación de estado. Las condiciones de saturación

vapor saturado
T (° C) = -17.71 fsat (bar) = 2.05
11.25 P (bar) = 2.1
(h - h0) = -1737.35
(s - s0) = -7.878
ng (kmol/s) = 0.44
líquido saturado
T (° C) = -17.71 fsat (bar) = 2.06
P (bar) = 2.1
(h - h0) = -24598.16
n1 = nf + ng (s - s0) = -101.858
nf (kmol/s) = 2.06
(hf - h0) < (h1 - h0) < (hg - h0)
n1*(h1 - h0) = nf*(hf - h0) + ng*(hg - h0)
0.178

Sgen = nf*(sf - s0) + ng*(sg - s0) - n1*(s1 - s0)

5.72 kW/K
1716.53 kW

fsat = fsat*Psat fsat = EXP(hR/(RT) - sR/R)

 ECUACIÓN DE REDLICH-KWON
CoefA = 0.42748 CoefB = 0.08664 ESPECIFICACIONES DE LA MEZCLA:
2
ac = (1/Tr) R= 8.314 T (K) = 700.00
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i)
NH3 405.5 11350.0 0.3 0.000 1.7263
CH3CH2OH 516.0 6380.0 0.1 1.000 1.3566
CO2 304.2 7383.0 0.2 0.000 2.3011
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 1058.7426 b= 0.0583 P1 = -1.00000

A= 0.0313 B= 0.0100 Q1 = 0.02115
R1 = -0.00031
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33099 Z= 0.979
X2 = 0.31440
DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):
THETA = 0 Z(1) = 0.9785 Zmax = 0.9785
Z(2) = 0.0107 Zmin = 0.0107
Z(3) = 0.0107
VALOR DE LA RAIZ DE Z: COEFICIENTE DE FUGACIDAD Y FUGACIDA
Z= 0.9787 Componente cphi
NH3 1.0012
PROPIEDADES RESIDUALES: CH3CH2OH 0.9790
hR = -401.253 kJ/kmol CO2 1.0066
sR = -0.396 kJ/kmol-K CH4 1.0157
R
v = -0.124 m3/kmol CH4 1.0157
v = ZRT/P = 5.696 m3/kmol CH4 1.0157
CH4 1.0157
hR = RT*[Z-1-A/B*(1-T/a*da/dT)*ln(1 + B/Z)] CH4 1.0157
R
s = R*[ln(Z-B)+A/B*(T/a*da/dT*ln(1 + B/Z)] CH4 1.0157
CH4 1.0157
 ECUACIÓN DE REDLICH-KWONG (RK)
ES DE LA MEZCLA:
P (kPa) = 1000.00
1
ac(i) alfa(i) a(i) b(i) a(i)0,5 AP(i) BP(i)
0.7611 428.0768 325.8128 0.0257 18.0503 1.109 0.4417
0.8586 1233.1462 1058.7426 0.0583 32.5383 2.000 1.0000
0.6592 370.3577 244.1473 0.0297 15.6252 0.960 0.5094
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123

0.000 0.000 0.000 0.000

M= -3.122E-01 T/a*da/dT = -0.50000

N= -6.734E-02
D= 6.720E-06

phi = 1.0030
Z= 0.979

NTE DE FUGACIDAD Y FUGACIDAD

y(i) fug(i) (kPa)
0.000 0.000
1.000 978.959
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
cphi(i)
1.0012
0.9790
1.0066
1.0157
1.0157
1.0157
1.0157
1.0157
1.0157
1.0157
 ECUACIÓN DE REDLICH-KWONG (
CoefA = 0.42748 CoefB = 0.08664 ESPECIFICACIONES DE LA MEZCLA:
2
ac = (1/Tr) R= 8.314 T (K) = 700.00
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i)
NH3 405.5 11350.0 0.3 0.000 1.7263
CH3CH2OH 516.0 6380.0 0.1 1.000 1.3566
CO2 304.2 7383.0 0.2 0.000 2.3011
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 1058.7426 b= 0.0583 P1 = -1.00000

A= 0.0313 B= 0.0100 Q1 = 0.02115
R1 = -0.00031
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33099 Z= 0.979
X2 = 0.31440
DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):
THETA = 0 Z(1) = 0.9785 Zmax = 0.9785
Z(2) = 0.0107 Zmin = 0.0107
Z(3) = 0.0107
VALOR DE LA RAIZ DE Z: COEFICIENTE DE FUGACIDAD Y FUGACIDAD
Z= 0.9787 Componente cphi
NH3 1.0012
PROPIEDADES RESIDUALES: CH3CH2OH 0.9790
hR = -401.253 kJ/kmol CO2 1.0066
sR = -0.396 kJ/kmol-K CH4 1.0157
R
v = -0.124 m3/kmol CH4 1.0157
v = ZRT/P = 5.696 m3/kmol CH4 1.0157
CH4 1.0157
hR = RT*[Z-1-A/B*(1-T/a*da/dT)*ln(1 + B/Z)] CH4 1.0157
R
s = R*[ln(Z-B)+A/B*(T/a*da/dT*ln(1 + B/Z)] CH4 1.0157
CH4 1.0157
 ECUACIÓN DE REDLICH-KWONG (RK)
ES DE LA MEZCLA:
P (kPa) = 1000.00
1
ac(i) alfa(i) a(i) b(i) a(i)0,5 AP(i) BP(i)
0.7611 428.0768 325.8128 0.0257 18.0503 1.109 0.4417
0.8586 1233.1462 1058.7426 0.0583 32.5383 2.000 1.0000
0.6592 370.3577 244.1473 0.0297 15.6252 0.960 0.5094
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123

0.000 0.000 0.000 0.000

M= -3.122E-01 T/a*da/dT = -0.50000

N= -6.734E-02
D= 6.720E-06

phi = 1.0030
Z= 0.9785

NTE DE FUGACIDAD Y FUGACIDAD

y(i) fug(i) (kPa)
0.000 0.000
1.000 978.959
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
cphi(i)
1.0012
0.9790
1.0066
1.0157
1.0157
1.0157
1.0157
1.0157
1.0157
1.0157
 ECUACIÓN DE REDLICH-KWONG (
CoefA = 0.42748 CoefB = 0.08664 ESPECIFICACIONES DE LA MEZCLA:
2
ac = (1/Tr) R= 8.314 T (K) = 700.00
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i)
NH3 405.5 11350.0 0.3 0.000 1.7263
CH3CH2OH 516.0 6380.0 0.1 1.000 1.3566
CO2 304.2 7383.0 0.2 0.000 2.3011
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
CH4 190.6 4600.2 0.0 0.000 3.6726
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 1058.7426 b= 0.0583 P1 = -1.00000

A= 0.0313 B= 0.0100 Q1 = 0.02115
R1 = -0.00031
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33099 Z= 0.979
X2 = 0.31440
DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):
THETA = 0 Z(1) = 0.9785 Zmax = 0.9785
Z(2) = 0.0107 Zmin = 0.0107
Z(3) = 0.0107
VALOR DE LA RAIZ DE Z: COEFICIENTE DE FUGACIDAD Y FUGACIDAD
Z= 0.9787 Componente cphi
NH3 1.0012
PROPIEDADES RESIDUALES: CH3CH2OH 0.9790
hR = -401.253 kJ/kmol CO2 1.0066
sR = -0.396 kJ/kmol-K CH4 1.0157
R
v = -0.124 m3/kmol CH4 1.0157
v = ZRT/P = 5.696 m3/kmol CH4 1.0157
CH4 1.0157
hR = RT*[Z-1-A/B*(1-T/a*da/dT)*ln(1 + B/Z)] CH4 1.0157
R
s = R*[ln(Z-B)+A/B*(T/a*da/dT*ln(1 + B/Z)] CH4 1.0157
CH4 1.0157
 ECUACIÓN DE REDLICH-KWONG (RK)
ES DE LA MEZCLA:
P (kPa) = 1000.00
2
ac(i) alfa(i) a(i) b(i) a(i)0,5 AP(i) BP(i)
0.7611 428.0768 325.8128 0.0257 18.0503 1.109 0.4417
0.8586 1233.1462 1058.7426 0.0583 32.5383 2.000 1.0000
0.6592 370.3577 244.1473 0.0297 15.6252 0.960 0.5094
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123
0.5218 233.3507 121.7648 0.0298 11.0347 0.678 0.5123

0.000 0.000 0.000 0.000

M= -3.122E-01 T/a*da/dT = -0.50000

N= -6.734E-02
D= 6.720E-06

phi = 1.0030
Z= 0.0107

NTE DE FUGACIDAD Y FUGACIDAD

y(i) fug(i) (kPa)
0.000 0.000
1.000 978.959
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
0.000 0.000
cphi(i)
1.0012
0.9790
1.0066
1.0157
1.0157
1.0157
1.0157
1.0157
1.0157
1.0157
 ECUACIÓN DE SOAVE-REDLICH-KWONG (
CoefA = 0.42748 CoefB = 0.08664 ESPECIFICACIONES DE LA MEZCLA:
2
fw = 0,48 + 1,57w - 0,176w R= 8.314 T (K) = 700
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i) fw(i)
NH3 405.5 11350.0 0.250 0.000 1.7263 0.8615
CH3CH2OH 516.0 6380.0 0.100 1.000 1.3566 0.6352
CO2 304.2 7383.0 0.224 0.000 2.3011 0.8228
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 988.5730 b= 0.0583 P1 = -1.00000

A= 0.0292 B= 1.0010E-02 Q1 = 0.01908
R1 = -0.00029
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33205 Z= 0.9809
X2 = 0.31547

DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):

THETA = 0 Z(1) = 0.9806 Zmax = 0.9806
Z(2) = 0.0097 Zmin = 0.0097
Z(3) = 0.0097
VALOR DE LA RAIZ DE Z: COEFICIENTE DE FUGACIDAD Y FUGACIDA
Z= 0.9809 Componente cphi
NH3 1.0058
PROPIEDADES RESIDUALES: CH3CH2OH 0.9810
hR = -426.105 kJ/kmol CO2 1.0142
sR = -0.449 kJ/kmol-K CH4 1.0193
vR = -0.111 m3/kmol CH4 1.0193
v = ZRT/P = 5.7084 m3/kmol CH4 1.0193
CH4 1.0193
hR = RT*[Z-1-A/B*(1-T/a*da/dT)*ln(1 + B/Z)] CH4 1.0193
R
s = R*[ln(Z-B)+A/B*(T/a*da/dT*ln(1 + B/Z)] CH4 1.0193
CH4 1.0193
N DE SOAVE-REDLICH-KWONG (SRK)
ES DE LA MEZCLA:
P (kPa) = 1000.00
1
ac(i) alfa(i) a(i) b(i) a(i)0,5 fw(i)*(alfa(i)*Tr(i))^0,5 AP(i)
0.5323 428.0768 227.8709 0.0257 15.0954 23.419 0.9602
0.8017 1233.1462 988.5730 0.0583 31.4416 25.982 2.0000
0.3302 370.3577 122.2935 0.0297 11.0586 24.022 0.7034
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345

0.000 0.000 0.000 0.000

M= -3.143E-01 T/a*da/dT = -0.82635

N= -6.801E-02
D= 6.801E-06

phi = 1.0030
Z= 0.9806

NTE DE FUGACIDAD Y FUGACIDAD

y(i) fug(i) (kPa)
0.000 0.00
1.000 981.02
0.000 0.00
0.000 0.00
0.000 0.00
0.000 0.00
0.000 0.00
0.000 0.00
0.000 0.00
0.000 0.00
BP(i) cphi(i) F(Psat)
0.4417 1.0058
1.0000 0.9810
0.5094 1.0142
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
 ECUACIÓN DE SOAVE-REDLICH-KWONG (SRK
CoefA = 0.42748 CoefB = 0.08664 ESPECIFICACIONES DE LA MEZCLA:
2
fw = 0,48 + 1,57w - 0,176w R= 8.314 T (K) = 700
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i) fw(i)
NH3 405.5 11350.0 0.250 0.000 1.7263 0.8615
CH3CH2OH 516.0 6380.0 0.100 1.000 1.3566 0.6352
CO2 304.2 7383.0 0.224 0.000 2.3011 0.8228
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 988.5730 b= 0.0583 P1 = -1.00000

A= 0.0292 B= 1.0010E-02 Q1 = 0.01908
R1 = -0.00029
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33205 Z= 0.981
X2 = 0.31547

DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):

THETA = 0 Z(1) = 0.9806 Zmax = 0.9806
Z(2) = 0.0097 Zmin = 0.0097
Z(3) = 0.0097
VALOR DE LA RAIZ DE Z: COEFICIENTE DE FUGACIDAD Y FUGACIDAD
Z= 0.9809 Componente cphi y(i)
NH3 1.0058 0.000
PROPIEDADES RESIDUALES: CH3CH2OH 0.9810 1.000
hR = -426.105 kJ/kmol CO2 1.0142 0.000
sR = -0.449 kJ/kmol-K CH4 1.0193 0.000
vR = -0.111 m3/kmol CH4 1.0193 0.000
v = ZRT/P = 5.7084 m3/kmol CH4 1.0193 0.000
CH4 1.0193 0.000
hR = RT*[Z-1-A/B*(1-T/a*da/dT)*ln(1 + B/Z)] CH4 1.0193 0.000
R
s = R*[ln(Z-B)+A/B*(T/a*da/dT*ln(1 + B/Z)] CH4 1.0193 0.000
CH4 1.0193 0.000
N DE SOAVE-REDLICH-KWONG (SRK)
ES DE LA MEZCLA:
P (kPa) = 1000.00
1
ac(i) alfa(i) a(i) b(i) a(i)0,5 fw(i)*(alfa(i)*Tr(i))^0,5 AP(i)
0.5323 428.0768 227.8709 0.0257 15.0954 23.419 0.9602
0.8017 1233.1462 988.5730 0.0583 31.4416 25.982 2.0000
0.3302 370.3577 122.2935 0.0297 11.0586 24.022 0.7034
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345

0.000 0.000 0.000 0.000

M= -3.143E-01 T/a*da/dT = -0.82635

N= -6.801E-02
D= 6.801E-06

phi = 1.0030
Z= 0.9806

DAD Y FUGACIDAD
fug(i) (kPa)
0.00
981.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
BP(i) cphi(i) F(Psat)
0.4417 1.0058
1.0000 0.9810
0.5094 1.0142
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
 ECUACIÓN DE SOAVE-REDLICH-KWONG (SRK
CoefA = 0.42748 CoefB = 0.08664 ESPECIFICACIONES DE LA MEZCLA:
2
fw = 0,48 + 1,57w - 0,176w R= 8.314 T (K) = 700
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i) fw(i)
NH3 405.5 11350.0 0.250 0.000 1.7263 0.8615
CH3CH2OH 516.0 6380.0 0.100 1.000 1.3566 0.6352
CO2 304.2 7383.0 0.224 0.000 2.3011 0.8228
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
CH4 190.6 4600.2 0.007 0.000 3.6726 0.4910
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 988.5730 b= 0.0583 P1 = -1.00000

A= 0.0292 B= 1.0010E-02 Q1 = 0.01908
R1 = -0.00029
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33205 Z= 0.981
X2 = 0.31547

DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):

THETA = 0 Z(1) = 0.9806 Zmax = 0.9806
Z(2) = 0.0097 Zmin = 0.0097
Z(3) = 0.0097
VALOR DE LA RAIZ DE Z: COEFICIENTE DE FUGACIDAD Y FUGACIDAD
Z= 0.9809 Componente cphi y(i)
NH3 1.0058 0.000
PROPIEDADES RESIDUALES: CH3CH2OH 0.9810 1.000
hR = -426.105 kJ/kmol CO2 1.0142 0.000
sR = -0.449 kJ/kmol-K CH4 1.0193 0.000
vR = -0.111 m3/kmol CH4 1.0193 0.000
v = ZRT/P = 5.7084 m3/kmol CH4 1.0193 0.000
CH4 1.0193 0.000
hR = RT*[Z-1-A/B*(1-T/a*da/dT)*ln(1 + B/Z)] CH4 1.0193 0.000
R
s = R*[ln(Z-B)+A/B*(T/a*da/dT*ln(1 + B/Z)] CH4 1.0193 0.000
CH4 1.0193 0.000
N DE SOAVE-REDLICH-KWONG (SRK)
ES DE LA MEZCLA:
P (kPa) = 1000.00
2
ac(i) alfa(i) a(i) b(i) a(i)0,5 fw(i)*(alfa(i)*Tr(i))^0,5 AP(i)
0.5323 428.0768 227.8709 0.0257 15.0954 23.419 0.9602
0.8017 1233.1462 988.5730 0.0583 31.4416 25.982 2.0000
0.3302 370.3577 122.2935 0.0297 11.0586 24.022 0.7034
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345
0.3026 233.3507 70.6044 0.0298 8.4026 14.373 0.5345

0.000 0.000 0.000 0.000

M= -3.143E-01 T/a*da/dT = -0.82635

N= -6.801E-02
D= 6.801E-06

phi = 1.0030
Z= 0.0097

DAD Y FUGACIDAD
fug(i) (kPa)
0.00
981.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
BP(i) cphi(i) F(Psat)
0.4417 1.0058
1.0000 0.9810
0.5094 1.0142
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
0.5123 1.0193
 ECUACIÓN DE PENG-ROBINSON (PengR)
CoefA = 0.45724 CoefB = 0.0778 ESPECIFICACIONES DE LA MEZCLA:
2
fw = 0,37464 + 1,54226w - 0,26992w T (K) = 700
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i) fw(i)
NH3 405.5 11350.0 0.250 0.000 1.7263 0.7433
CH3CH2OH 516.0 6380.0 0.100 1.000 1.3566 0.5262
CO2 304.2 7383.0 0.224 0.000 2.3011 0.7066
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 1100.2584 b= 0.0523 P1 = -0.99101

A= 3.25.E-02 B= 8.99.E-03 Q1 = 0.01426
R1 = -0.00021
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33053 Z= 0.9766
X2 = 0.31576

DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):

THETA = 0 Z(1) = 0.9765 Zmax = 0.9765
Z(2) = 0.0073 Zmin = 0.0073
Z(3) = 0.0073
VALOR DE LA RAIZ DE Z COEFICIENTE DE FUGACIDAD Y
Z= 0.9766 Componente
NH3
PROPIEDADES RESIDUALES: CH3CH2OH
hR = -456.567 kJ/kmol CO2
sR = -0.457 kJ/kmol-K CH4
vR = -0.136 m3/kmol CH4
v = ZRT/P = 5.684 m3/kmol CH4
CH4
hR = RT*{Z-1-A/(2,82843B)*(1-T/a*da/dT)*ln[(Z + 2,4142B)/(Z - 0,4142B)]} CH4
R
s = R*{ln(Z-B)+A/(2,82843B)*(T/a*da/dT)*ln[(Z + 2,4142B)/(Z - 0,4142B)]} CH4
CH4
CIÓN DE PENG-ROBINSON (PengR)
ES DE LA MEZCLA: R= 8.314
P (kPa) = 1000.00
1
ac(i) alfa(i) a(i) b(i) a(i)0,5 fw(i)*(alfa(i)*Tr(i))^0,5 AP(i)
0.5878 457.8784 269.1448 0.0231 16.4056 20.898 0.9892
0.8342 1318.9945 1100.2584 0.0523 33.1701 22.257 2.0000
0.4029 396.1410 159.6067 0.0267 12.6336 21.333 0.7617
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161

0.000 0.000 0.000 0.000

M= -3.131E-01 T/a*da/dT = -0.67100

N= -6.759E-02
D= 5.359E-06

phi = 1.0024
Z= 0.9765

COEFICIENTE DE FUGACIDAD Y FUGACIDAD

cphi y(i) fug(i) (kPa)
1.0045 0.000 0.00
0.9768 1.000 976.84
1.0128 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
BP(i) cphi(i)
0.4417 1.0045
1.0000 0.9768
0.5094 1.0128
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
 ECUACIÓN DE PENG-ROBINSON (PengR)
CoefA = 0.45724 CoefB = 0.0778 ESPECIFICACIONES DE LA MEZCLA:
2
fw = 0,37464 + 1,54226w - 0,26992w T (K) = 700
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i) fw(i)
NH3 405.5 11350.0 0.250 0.000 1.7263 0.7433
CH3CH2OH 516.0 6380.0 0.100 1.000 1.3566 0.5262
CO2 304.2 7383.0 0.224 0.000 2.3011 0.7066
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 1100.2584 b= 0.0523 P1 = -0.99101

A= 0.032485 B= 0.00899 Q1 = 0.01426
R1 = -0.00021
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33053 Z= 0.9766
X2 = 0.31576

DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):

THETA = 0 Z(1) = 0.9765 Zmax = 0.9765
Z(2) = 0.0073 Zmin = 0.0073
Z(3) = 0.0073
VALOR DE LA RAIZ DE Z COEFICIENTE DE FUGACIDAD Y
Z= 0.9766 Componente
NH3
PROPIEDADES RESIDUALES: CH3CH2OH
hR = -456.567 kJ/kmol CO2
sR = -0.457 kJ/kmol-K CH4
vR = -0.136 m3/kmol CH4
v = ZRT/P = 5.684 m3/kmol CH4
CH4
hR = RT*{Z-1-A/(2,82843B)*(1-T/a*da/dT)*ln[(Z + 2,4142B)/(Z - 0,4142B)]} CH4
R
s = R*{ln(Z-B)+A/(2,82843B)*(T/a*da/dT)*ln[(Z + 2,4142B)/(Z - 0,4142B)]} CH4
CH4
CIÓN DE PENG-ROBINSON (PengR)
ES DE LA MEZCLA: R= 8.314
P (kPa) = 1000.00
2
ac(i) alfa(i) a(i) b(i) a(i)0,5 fw(i)*(alfa(i)*Tr(i))^0,5 AP(i)
0.5878 457.8784 269.1448 0.0231 16.4056 20.898 0.9892
0.8342 1318.9945 1100.2584 0.0523 33.1701 22.257 2.0000
0.4029 396.1410 159.6067 0.0267 12.6336 21.333 0.7617
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161

0.000 0.000 0.000 0.000

M= -3.131E-01 T/a*da/dT = -0.67100

N= -6.759E-02
D= 5.359E-06

phi = 1.0024
Z= 0.0073

COEFICIENTE DE FUGACIDAD Y FUGACIDAD

cphi y(i) fug(i) (kPa)
1.0045 0.000 0.00
0.9768 1.000 976.84
1.0128 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
BP(i) cphi(i)
0.4417 1.0045
1.0000 0.9768
0.5094 1.0128
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
 ECUACIÓN DE PENG-ROBINSON (PengR)
CoefA = 0.45724 CoefB = 0.0778 ESPECIFICACIONES DE LA MEZCLA:
2
fw = 0,37464 + 1,54226w - 0,26992w T (K) = 700
DATOS DE LOS COMPONENTES: FASE 1: VAPOR; 2: LIQ) =
NOMBRE Tc(i) (K) Pc(i) (kPa) w(i) y(i) Tr(i) fw(i)
NH3 405.5 11350.0 0.250 0.000 1.7263 0.7433
CH3CH2OH 516.0 6380.0 0.100 1.000 1.3566 0.5262
CO2 304.2 7383.0 0.224 0.000 2.3011 0.7066
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
CH4 190.6 4600.2 0.007 0.000 3.6726 0.3854
Sumay = 1.000
y= 0.000 1.000 0.000 0.000 0.000 0.000

Cálculos: a= 1100.2584 b= 0.0523 P1 = -0.99101

A= 0.032485 B= 0.00899 Q1 = 0.01426
R1 = -0.00021
DISCRIMINANTE MAYOR QUE CERO (UNA RAIZ REAL, UNA FASE HOMOGÉNEA):
X1 = 0.33053 Z= 0.9766
X2 = 0.31576

DISCRIMINANTE MENOR QUE CERO (TRES RAICES REALES, FASES EN EQUILIBRIO):

THETA = 0 Z(1) = 0.9765 Zmax = 0.9765
Z(2) = 0.0073 Zmin = 0.0073
Z(3) = 0.0073
VALOR DE LA RAIZ DE Z COEFICIENTE DE FUGACIDAD Y
Z= 0.9766 Componente
NH3
PROPIEDADES RESIDUALES: CH3CH2OH
hR = -456.567 kJ/kmol CO2
sR = -0.457 kJ/kmol-K CH4
vR = -0.136 m3/kmol CH4
v = ZRT/P = 5.684 m3/kmol CH4
CH4
hR = RT*{Z-1-A/(2,82843B)*(1-T/a*da/dT)*ln[(Z + 2,4142B)/(Z - 0,4142B)]} CH4
R
s = R*{ln(Z-B)+A/(2,82843B)*(T/a*da/dT)*ln[(Z + 2,4142B)/(Z - 0,4142B)]} CH4
CH4
CIÓN DE PENG-ROBINSON (PengR)
ES DE LA MEZCLA: R= 8.314
P (kPa) = 1000.00
1
ac(i) alfa(i) a(i) b(i) a(i)0,5 fw(i)*(alfa(i)*Tr(i))^0,5 AP(i)
0.5878 457.8784 269.1448 0.0231 16.4056 20.898 0.9892
0.8342 1318.9945 1100.2584 0.0523 33.1701 22.257 2.0000
0.4029 396.1410 159.6067 0.0267 12.6336 21.333 0.7617
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161
0.4183 249.5960 104.4174 0.0268 10.2185 11.669 0.6161

0.000 0.000 0.000 0.000

M= -3.131E-01 T/a*da/dT = -0.67100

N= -6.759E-02
D= 5.359E-06

phi = 1.0024
Z= 0.9765

COEFICIENTE DE FUGACIDAD Y FUGACIDAD

cphi y(i) fug(i) (kPa)
1.0045 0.000 0.00
0.9768 1.000 976.84
1.0128 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
1.0177 0.000 0.00
BP(i) cphi(i)
0.4417 1.0045
1.0000 0.9768
0.5094 1.0128
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177
0.5123 1.0177