k1 0.

0075
k2 0.000000062
k3 4.7E-13
n = [H+]^3+k1.[H+]^2+k1.k2.[H+]+k1.k2.k3

HPO4 2-
PO4 3-
H2PO4 -
H3PO4

pH [H+] n [PO4 3-] [HPO4 2-] [H2PO4 -] [H3PO4 ]

0 1 1.0075 2.169231E-23 4.615385E-11 0.00074442 0.09925558
1 0.1 0.001075 2.033023E-20 4.325581E-09 0.00697674 0.09302325
2 0.01 0.00000175 1.248854E-17 2.657136E-07 0.04285703 0.05714271
3 0.001 8.500465E-09 2.571036E-15 5.470289E-06 0.08823047 0.01176406
4 0.0001 7.60465E-11 2.8739E-13 6.11468E-05 0.09862387 0.00131498
5 0.00001 7.5565E-13 2.892212E-11 0.000615364 0.0992523 0.00013234
6 0.000001 7.966E-15 2.743535E-09 0.005837308 0.09415014 1.2553E-05
7 0.0000001 1.215012E-16 1.798747E-07 0.038271221 0.06172778 8.2304E-07
8 0.00000001 5.40022E-18 4.047058E-06 0.08610761 0.01388832 1.8518E-08
9 0.000000001 4.727186E-19 4.623258E-05 0.098367199 0.00158657 2.1154E-10
10 1E-10 4.679355E-20 0.000467052 0.09937267 0.00016028 2.137E-12
11 1E-11 4.8693E-21 0.004488325 0.095496273 1.5403E-05 2.0537E-14
12 1E-12 6.835575E-22 0.031972438 0.068026464 1.0972E-06 1.4629E-16
13 1E-13 2.650501E-22 0.082456117 0.017543855 2.8297E-08 3.7729E-19
14 1E-14 2.232E-22 0.097916666 0.002083333 3.3602E-10 4.4803E-22

Diagrama de distribucion de especies del ácido fosfrico

0.12

0.1

0.08
PO3-
= [especie]/[analitca]

HPO4 2-
0.06 H2PO4 -
H3PO4

0.04

0.02

0
0 2 4 6 8 10 12 14 16
pH
0.02

0
0 2 4 6 8 10 12 14 16
pH