Problema.

- Se ha corrido una prueba experimental con la finalidad de obtener las curvas de polarización y a través
del Método de la extrapolación Tafel determinar Ecorr e i corr, y a partir de este último valor obtener la velocidad
de corrosión de la aleación en mm/año, asi como el valor de las pendientes de Tafel anódica y catódica.
DENSID POLARIZACIÓN
-0.2
(Utilice los datos que se muestran a continuación ((1). Potential (V) Vs. E(1) Current (Amperios) )
0.1 1
que deberán convertirse a μAmp. Además determinar la constante K de la ecuación de Stern y Geary de la Polarización Lineal,
utilizando parte de los datos de acuerdo a l criterio señalado por la Ecuación de Buttler y Volmer.
corr= 0.9618 i
Sistema: una Probeta plana circular de de 1 cm de diámetro de acero AISI-SAE 1020 expuesta a Agua Potable a 20oC.
Ayuda: para la extrapolación Tafel, trace las pendientes de Tafel a partir de un sobrevoltaje (respecto del potencial de corrosión
y para la polarización lineal los datos inteferiores a un sobrevoltaje de 5 mV.
f(x) = 0.0123203768x - 0.3690578191
R² = 0.058128434
Datos de Polarizacion del SAE 1020 en Agua Potable obtenidos en el Potentiostato - Galvanostato Autolab 281
Potential applied (V)Time (s) WE(1).Current (A) Index WE(1).Potential (V) Aprobeta=
-0.3 Ecorr= -0.349Segs
Volts V Amperios Volts voltaje
-0.439301 128.502 -6.90E-06 1 0.438385 0.438385
-0.438232 129.57 -6.72E-06 2 0.437256 0.437256
-0.437164 130.638 -6.56E-06 3 0.436249 0.436249
-0.436096 131.706 -6.42E-06 4 -0.435059 0.435059
(V)
VOLTAJE (V)

-0.435028 132.774 -6.29E-06 5 -0.434113 0.434113

VOLTAJE

-0.43396 133.842 -6.16E-06 6 -0.433014 0.433014

VO LTA JE (V) en a g u a p o ta b le - so lu sió n 3M KCl

-0.432892 134.911 -6.04E-06 7 -0.431976 0.431976

-0.431824 135.979 -5.92E-06 8 -0.430878 0.430878
-0.430756 137.047 -5.81E-06 9 -0.42984 0.42984
-0.429688 138.115 -5.70E-06 10 -0.428772 0.428772
-0.4 -0.428619 139.183 -5.59E-06 11 -0.427704 POLARIZACIÓN
0.427704
-0.427551 140.251 -5.49E-06 12 -0.426666 1 0.426666
-0.426483 141.319 -5.39E-06 13 -0.425568 0.425568
Axis Title

-0.425415 f(x)142.387 -5.29E-06 14 -0.424469 0.5 0.424469

= 1.1254463538x + 0.7582937655
-0.424347 R² 143.455 -5.20E-06
= 0.0199576875 15 -0.423431 0.423431
0
-0.423279
-0.45
f(x) = 0.5750044596x
144.524
-0.4 -5.11E-06
-0.35
+ 0.6033692382
16
-0.3 -0.422394
-0.25 DENSIDAD 0.422394 log(i): A/cm^2
-0.2DE CORRIENTE
-0.422211 R² = 0.0219970173
145.592 -5.01E-06 17 -0.421295 0.421295
-0.5
-0.421143 146.66 -0.43-4.92E-06 18 -0.420258
-0.38 0.420258
-0.33
-0.420074 147.728 -4.83E-06 19 -0.419189 -1 0.419189
-0.419006 148.796 -4.75E-06 20 -0.418091 0.418091
-1.5
-0.417938 149.864 -4.66E-06 21 -0.417053 0.417053
-0.5 Axis Title
-0.41687 150.932 -4.57E-06 22 -0.415955 -2 0.415955
-0.415802 152 -4.49E-06 23 -0.414886 0.414886
-0.414734 153.069 -4.40E-06 24 -0.413818 0.413818
-0.413666 154.137 -4.32E-06 25 -0.412811 Chart Title
0.412811
-0.412598
0.5 155.205 -4.23E-06 26 -0.411713 0.411713
Axis Title

-0.41153
0.4 156.273 -4.15E-06 27 -0.410614 0.410614
-0.410461
0.3 157.341 -4.07E-06 28 -0.409576 0.409576
-0.409393
0.2 158.409 -4.00E-06 29 -0.408508 0.408508
-0.408325
0.1 159.477 -3.92E-06 30 -0.407471 0.407471
-0.407257
0 160.545 -3.84E-06 31 -0.406372 0.406372
-0.1 0 20 40 60 80 100 120 140 160 180 200
-0.2
-0.3 f(x) = 0.000622074x - 0.3837491154
-0.4 R² = 0.08928208
 0.3

Axi
0.2
0.1
0
-0.1
-0.4061890 20 40
161.613 60
-3.76E-0680 100 32120 140 160 180 200
-0.405273 0.405273
-0.2
-0.405121 162.682 -3.68E-06 33 -0.404266 0.404266
-0.3
-0.404053 f(x) =163.75
0.000622074x-3.61E-06
- 0.3837491154 34 -0.403168 0.403168
-0.4
-0.402985 R² = 0.08928208
164.818 -3.53E-06 35 -0.402161 0.402161
Axis Title
-0.5
-0.401917 165.886 -3.46E-06 36 -0.401062 0.401062
-0.400848 166.954 -3.38E-06 37 -0.400024 0.400024
-0.39978 168.022 -3.31E-06 38 -0.398956 0.398956
-0.398712 densidad de corriente
169.09 -3.24E-06 39
POLARIZACIÓN
-0.397858 0.397858
-0.397644
1.5
170.158 -3.16E-06 40 -0.396851DEL ACERO VCL-140
0.396851 (Acero b
-0.396576 171.226 -3.09E-06 41 -0.395721 0.395721
Axis Title

1
-0.395508 172.295 -3.02E-06 42 -0.394714 0.394714
-0.39444
0.5 173.363 -2.95E-06 43 -0.393585 0.393585
-0.393372f(x) = 0.000012007x
174.431 -2.88E-06
+ 0.4154640418 44 -0.392548 0.392548
0
-0.392303 R² = 2.2416135538883E-06
175.499 -2.81E-06 45 -0.391449 0.391449
0 20 40 60 80 100 120 140 160 180 200
-0.391235
-0.5 176.567 -2.74E-06 46 -0.390381 0.390381
-0.390167 177.635 -2.67E-06 47 -0.389343 0.389343
-1
-0.389099 178.703 -2.60E-06 48 -0.388275 0.388275
-0.388031
-1.5 179.771 -2.53E-06 49 -0.387177 0.387177
-0.386963 180.84 -2.46E-06
Axis Title 50 -0.386078 0.386078
-2
-0.385895 181.908 -2.39E-06 51 -0.38504 0.38504
-0.384827 182.976 -2.32E-06 52 -0.383972 0.383972
-0.383759 184.044 -2.26E-06 53 -0.382935 0.382935
-0.38269 185.112 -2.18E-06 54 -0.381897 0.381897
-0.381622 186.18 -2.12E-06 55 -0.380798 0.380798
-0.380554 187.248 -2.05E-06 56 -0.37973 0.37973
-0.379486 188.316 -1.99E-06 57 -0.378662 0.378662
-0.378418 189.384 -1.92E-06 58 -0.377625 0.377625
-0.37735 190.453 -1.85E-06 59 -0.376526 0.376526
-0.376282 191.521 -1.79E-06 60 -0.375397 0.375397
-0.375214 192.589 -1.73E-06 61 -0.37442 0.37442
-0.374146 193.657 -1.66E-06 62 -0.373383 0.373383
-0.373077 194.725 -1.60E-06 63 -0.372253 0.372253
-0.372009 195.793 -1.53E-06 64 -0.371246 0.371246
-0.370941 196.861 -1.47E-06 65 -0.370117 0.370117
-0.369873 197.929 -1.40E-06 66 -0.36911 0.36911
-0.368805 198.997 -1.34E-06 67 -0.368042 0.368042
-0.367737 200.066 -1.27E-06 68 -0.366974 0.366974
-0.366669 201.134 -1.22E-06 69 -0.365936 0.365936
-0.365601 202.202 -1.15E-06 70 -0.364899 0.364899
-0.364532 203.27 -1.09E-06 71 -0.3638 0.3638
-0.363464 204.338 -1.03E-06 72 -0.362701 0.362701
-0.362396 205.406 -9.63E-07 73 -0.361725 0.361725
-0.361328 206.474 -8.98E-07 74 -0.360596 0.360596
-0.36026 207.542 -8.36E-07 75 -0.359497 0.359497
-0.359192 208.61 -7.78E-07 76 -0.358398 0.358398
-0.358124 209.679 -7.13E-07 77 -0.357391 0.357391
-0.357056 210.747 -6.48E-07 78 -0.356262 0.356262
-0.355988 211.815 -5.90E-07 79 -0.355225 0.355225
-0.354919 212.883 -5.28E-07 80 -0.354126 0.354126
-0.353851 213.951 -4.67E-07 81 -0.353088 0.353088
-0.352783 215.019 -4.03E-07 82 -0.35199 0.35199
-0.351715 216.087 -3.46E-07 83 -0.350922 0.350922
-0.350647 217.155 -2.86E-07 84 -0.349854 0.349854
-0.349579 218.224 -2.22E-07 85 -0.348816 0.348816
-0.348511 219.292 -1.66E-07 86 -0.347809 0.347809
-0.347443 220.36 -1.06E-07 87 -0.346741 0.346741
-0.346375 221.428 -4.90E-08 88 -0.345734 0.345734
-0.345306 222.496 1.22E-08 89 -0.344604 0.344604
-0.344238 223.564 7.17E-08 90 -0.343506 0.343506
-0.34317 224.632 1.26E-07 91 -0.342407 0.342407
-0.342102 225.7 1.89E-07 92 -0.34137 0.34137
-0.341034 226.768 2.50E-07 93 -0.340363 0.340363
-0.339966 227.837 3.07E-07 94 -0.339233 0.339233
-0.338898 228.905 3.70E-07 95 -0.338257 0.338257
-0.33783 229.973 4.23E-07 96 -0.337189 0.337189
-0.336761 231.041 4.58E-07 97 -0.336151 0.336151
-0.335693 232.109 5.37E-07 98 -0.335114 0.335114
-0.334625 233.177 5.98E-07 99 -0.334076 0.334076
-0.333557 234.245 6.56E-07 100 -0.332977 0.332977
-0.332489 235.313 7.11E-07 101 -0.33194 0.33194
-0.331421 236.381 7.68E-07 102 -0.330841 0.330841
-0.330353 237.45 8.28E-07 103 -0.329773 0.329773
-0.329285 238.518 8.81E-07 104 -0.328796 0.328796
-0.328217 239.586 9.41E-07 105 -0.327698 0.327698
-0.327148 240.654 9.97E-07 106 -0.32666 0.32666
-0.32608 241.722 1.05E-06 107 -0.325562 0.325562
-0.325012 242.79 1.10E-06 108 -0.324493 0.324493
-0.323944 243.858 1.17E-06 109 -0.323395 0.323395
-0.322876 244.926 1.22E-06 110 -0.322388 0.322388
-0.321808 245.995 1.27E-06 111 -0.32135 0.32135
-0.32074 247.063 1.33E-06 112 -0.320221 0.320221
-0.319672 248.131 1.39E-06 113 -0.319183 0.319183
-0.318604 249.199 1.44E-06 114 -0.318176 0.318176
-0.317535 250.267 1.50E-06 115 -0.317108 0.317108
-0.316467 251.335 1.55E-06 116 -0.31604 0.31604
-0.315399 252.403 1.61E-06 117 -0.314941 0.314941
-0.314331 253.471 1.67E-06 118 -0.313904 0.313904
-0.313263 254.539 1.72E-06 119 -0.312836 0.312836
-0.312195 255.608 1.77E-06 120 -0.311707 0.311707
-0.311127 256.676 1.83E-06 121 -0.310608 0.310608
-0.310059 257.744 1.89E-06 122 -0.309601 0.309601
-0.30899 258.812 1.94E-06 123 -0.308563 0.308563
-0.307922 259.88 1.99E-06 124 -0.307465 0.307465
-0.306854 260.948 2.05E-06 125 -0.306366 0.306366
-0.305786 262.016 2.10E-06 126 -0.305389 0.305389
-0.304718 263.084 2.16E-06 127 -0.304321 0.304321
-0.30365 264.152 2.21E-06 128 -0.303284 0.303284
-0.302582 265.221 2.27E-06 129 -0.302246 0.302246
-0.301514 266.289 2.32E-06 130 -0.301147 0.301147
-0.300446 267.357 2.38E-06 131 -0.300049 0.300049
-0.299377 268.425 2.43E-06 132 -0.298981 0.298981
-0.298309 269.493 1.54E-06 133 -0.297852 0.297852
-0.297241 270.561 1.93E-06 134 -0.296783 0.296783
-0.296173 271.629 1.98E-06 135 -0.295746 0.295746
-0.295105 272.697 2.12E-06 136 -0.294739 0.294739
-0.294037 273.766 2.23E-06 137 -0.29364 0.29364
-0.292969 274.834 2.33E-06 138 -0.292572 0.292572
-0.291901 275.902 2.41E-06 139 -0.291565 0.291565
-0.290833 276.97 2.49E-06 140 -0.290497 0.290497
-0.289764 278.038 2.57E-06 141 -0.28949 0.28949
-0.288696 279.106 2.64E-06 142 -0.288391 0.288391
-0.287628 280.174 2.72E-06 143 -0.287354 0.287354
-0.28656 281.242 2.79E-06 144 -0.286255 0.286255
-0.285492 282.31 2.86E-06 145 -0.285187 0.285187
-0.284424 283.379 2.94E-06 146 -0.28418 0.28418
-0.283356 284.447 3.01E-06 147 -0.283112 0.283112
-0.282288 285.515 3.07E-06 148 -0.281677 0.281677
-0.281219 286.583 3.15E-06 149 -0.280579 0.280579
-0.280151 287.651 3.21E-06 150 -0.279572 0.279572
-0.279083 288.719 3.27E-06 151 -0.278442 0.278442
-0.278015 289.787 3.34E-06 152 -0.277374 0.277374
-0.276947 290.855 3.40E-06 153 -0.276337 0.276337
-0.275879 291.923 3.46E-06 154 -0.275238 0.275238
-0.274811 292.992 3.52E-06 155 -0.274231 0.274231
-0.273743 294.06 3.59E-06 156 -0.273132 0.273132
-0.272675 295.128 3.64E-06 157 -0.272034 0.272034
-0.271606 296.196 3.70E-06 158 -0.271027 0.271027
-0.270538 297.264 3.76E-06 159 -0.269958 0.269958
-0.26947 298.332 3.82E-06 160 -0.268921 0.268921
-0.268402 299.4 3.87E-06 161 -0.267822 0.267822
-0.267334 300.468 3.93E-06 162 -0.266815 0.266815
-0.266266 301.537 3.99E-06 163 -0.265717 0.265717
-0.265198 302.605 4.05E-06 164 -0.264648 0.264648
-0.26413 303.673 4.10E-06 165 -0.26358 0.26358
-0.263062 304.741 4.16E-06 166 -0.262482 0.262482
-0.261993 305.809 4.21E-06 167 -0.261414 0.261414
-0.260925 306.877 4.27E-06 168 -0.260376 0.260376
-0.259857 307.945 4.32E-06 169 -0.259277 0.259277
-0.258789 309.013 4.38E-06 170 -0.25824 0.25824
-0.257721 310.081 4.43E-06 171 -0.257172 0.257172
-0.256653 311.15 4.49E-06 172 -0.256104 0.256104
-0.255585 312.218 4.54E-06 173 -0.255035 0.255035
-0.254517 313.286 4.60E-06 174 -0.253967 0.253967
-0.253448 314.354 4.65E-06 175 -0.252899 0.252899
-0.25238 315.422 4.70E-06 176 -0.251831 0.251831
-0.251312 316.49 4.76E-06 177 -0.250732 0.250732
-0.250244 317.558 4.81E-06 178 -0.249725 0.249725
-0.249176 318.626 4.86E-06 179 -0.248688 0.248688
-0.248108 319.694 4.92E-06 180 -0.24762 0.24762
-0.24704 320.763 4.97E-06 181 -0.246552 0.246552
-0.245972 321.831 5.02E-06 182 -0.245575 0.245575
-0.244904 322.899 5.07E-06 183 -0.244507 0.244507
-0.243835 323.967 5.13E-06 184 -0.243378 0.243378
-0.242767 325.035 5.18E-06 185 -0.24231 0.24231
-0.241699 326.103 5.23E-06 186 -0.241272 0.241272
-0.240631 327.171 5.29E-06 187 -0.240234 0.240234
-0.239563 328.239 5.34E-06 188 -0.239105 0.239105
ación y a través
er la velocidad DENSIDAD DE CORRIENTE (A)

10
ry de la Polarización Lineal, Polarización Lineal,

icorr= 0.9618
a Potable a 20oC.
o del potencial de corrosión) de ± 50 mV

Galvanostato Autolab 281 N

0.78539816 cm2
densidad de corriente log(i) A/cm^2
8.78E+00 0.9435684556
8.56E+00 0.9324745219
8.36E+00 0.9221005243
8.18E+00 0.9125060248
8.00E+00 0.9033273285
7.84E+00 0.8943815384
7.69E+00 0.8859060706
7.54E+00 0.8772619021
7.39E+00 0.8688993371
7.26E+00 0.861069839
7.12E+00 0.8526224879
6.99E+00 0.8444911647
6.87E+00 0.8366970509
6.74E+00 0.8287596788
6.62E+00 0.8209301656
ORRIENTE log(i): A/cm^2 6.50E+00 0.8132154182
6.38E+00 0.8050979129
-4
-0.33 6.27E+00
-0.28 0.7969599535
-0.23
6.15E+00 0.7888590477
6.04E+00 0.781190266 -4.5
5.93E+00 0.7728727181
5.82E+00 0.764769296
5.71E+00 0.7567480889 -5
5.61E+00 0.7487564428
5.50E+00 0.7402168946
5.39E+00 0.731661998 -5.5
5.29E+00 0.723478011
5.19E+00 0.7149737818
-6
5.09E+00 0.7064334248
4.99E+00 0.6978226648
4.89E+00 0.6892786636 -6.5

-7
 -6

-6.5
4.79E+00 0.6804235623
4.69E+00 0.6711318832
4.59E+00 0.6621513691 -7
4.50E+00 0.6531692903
4.40E+00 0.6435366281
4.31E+00 0.6344303 -7.5

4.21E+00 0.6243692647
4.12E+00 0.6149709692
VCL-140 (Acero bonificado)
4.03E+00 0.6052810886 -8

3.94E+00 0.5949838324
3.85E+00 0.5849630771
3.76E+00 0.574617289
3.67E+00 0.5641095437
3.57E+00 0.5529652817
3.48E+00 0.5421071582
3.40E+00 0.5310715263
3.31E+00 0.5196445389
3.22E+00 0.5083292219
3.13E+00 0.4960640832
3.04E+00 0.4832771272
2.96E+00 0.4708452714
2.87E+00 0.4582800139
2.78E+00 0.4441905912
2.70E+00 0.4306945673
2.61E+00 0.4174111705
2.53E+00 0.4030402244
2.45E+00 0.3884555693
2.36E+00 0.3727199084
2.28E+00 0.3579499289
2.20E+00 0.342353314
2.11E+00 0.3243400735
2.03E+00 0.3082938914
1.95E+00 0.2906816836
1.87E+00 0.2712425274
1.79E+00 0.2519337382
1.71E+00 0.2321218569
1.62E+00 0.210117043
1.55E+00 0.1898901206
1.47E+00 0.1659175195
1.38E+00 0.1404239057
1.31E+00 0.1160574794
1.23E+00 0.088734792
1.14E+00 0.0581027803
1.06E+00 0.0268934772
9.91E-01 -0.0039997711
9.07E-01 -0.0422532052
8.26E-01 -0.0831805706
7.51E-01 -0.1245324065
6.72E-01 -0.172744762
5.94E-01 -0.2261321164
5.14E-01 -0.2893087733
4.40E-01 -0.3565400244
3.64E-01 -0.4387997805
2.83E-01 -0.5481093941
2.11E-01 -0.6747019467
1.35E-01 -0.8703374795
6.23E-02 -1.2053354108
1.56E-02 -1.8073971766
9.13E-02 -1.0394720061
1.61E-01 -0.794064941
2.40E-01 -0.6192696522
3.19E-01 -0.4965665728
3.91E-01 -0.4078128933
4.70E-01 -0.3274672112
5.39E-01 -0.2684631589
5.84E-01 -0.2338699059
6.83E-01 -0.165274138
7.62E-01 -0.1182834046
8.35E-01 -0.0781013099
9.05E-01 -0.0431836329
9.78E-01 -0.0096568503
1.05E+00 0.0230699901
1.12E+00 0.0497563602
1.20E+00 0.0787152205
1.27E+00 0.1036091973
1.34E+00 0.127907278
1.40E+00 0.1472059861
1.49E+00 0.172657753
1.56E+00 0.1918462529
1.62E+00 0.2103249185
1.70E+00 0.2302384597
1.77E+00 0.2474716414
1.83E+00 0.2629407312
1.91E+00 0.2805407814
1.98E+00 0.2963499542
2.04E+00 0.3106096857
2.12E+00 0.3265720815
2.19E+00 0.3400444918
2.26E+00 0.3539347235
2.33E+00 0.3666700593
2.40E+00 0.3803781135
2.47E+00 0.3922347581
2.54E+00 0.4046396286
2.60E+00 0.4157287106
2.68E+00 0.4274911747
2.75E+00 0.4391868989
2.81E+00 0.4491982278
2.89E+00 0.4602160194
2.95E+00 0.4702745367
3.02E+00 0.4807181686
3.10E+00 0.4907558137
1.96E+00 0.2918918672
2.45E+00 0.3898346521
2.53E+00 0.4023729759
2.70E+00 0.4315695313
2.84E+00 0.4534972787
2.96E+00 0.4714152571
3.07E+00 0.4871415524
3.17E+00 0.50125595
3.27E+00 0.514204004
3.36E+00 0.5269284016
3.46E+00 0.5391915268
3.55E+00 0.55083331
3.65E+00 0.5618482539
3.75E+00 0.5735365487
3.83E+00 0.5830291037
3.91E+00 0.5921871067
4.01E+00 0.6026343239
4.09E+00 0.6115585393
4.17E+00 0.620100205
4.25E+00 0.6286760893
4.33E+00 0.6362676717
4.41E+00 0.6443789132
4.48E+00 0.6512145951
4.56E+00 0.6594247177
4.64E+00 0.666354984
4.71E+00 0.673249152
4.78E+00 0.6796472648
4.86E+00 0.6864399495
4.92E+00 0.6923056287
5.01E+00 0.6996119798
5.08E+00 0.7056031907
5.15E+00 0.7119381438
5.22E+00 0.7173421603
5.29E+00 0.7238604008
5.36E+00 0.7294654967
5.44E+00 0.7353400278
5.51E+00 0.7407686848
5.58E+00 0.7463118407
5.64E+00 0.7513971665
5.72E+00 0.7576040649
5.78E+00 0.7621218686
5.86E+00 0.7675442532
5.92E+00 0.7724452528
5.99E+00 0.7771216175
6.06E+00 0.7823902315
6.12E+00 0.7869332865
6.19E+00 0.791675942
6.26E+00 0.7965555619
6.33E+00 0.8013809643
6.39E+00 0.8053620104
6.45E+00 0.8098298396
6.53E+00 0.8150274837
6.60E+00 0.8196538537
6.66E+00 0.8237239223
6.73E+00 0.8282590511
6.80E+00 0.832249634
 icorr= 0.9618 A
Ecorr= -0.349 V
densidad Fe= 7.8 g/cm^3
equiv. Gramo Fe= 27.925

VELOC. CORROSIÓN
(mm/año)= 0.0111909438