POTENCIALES ESTNDAR DE REDUCCION A 25 C

Reaccin de electrodo
(V)
+
Li + e = Li
-3.05
K + + e- = K
-2.925
Sr2+ + 2e- = Sr
-2.888
Ca2+ + 2e- = Ca
-2.866
+
Na + e = Na
-2.714
Mg2+ + 2e- = Mg
-2.52
H2 + 2e- = 2H-2.25
3+
Al + 3e = Al
-1.66
Zn(CN)42- + 2 e- = Zn + 4CN-1.26
ZnO22- + 2H2O + 2e- = Zn + 4OH-1.216
Mn2+ + 2e- = Mn
-1.18
2+
Zn(NH3)4 + 2e = Zn + 4NH3
-1.03
Sn(OH)62- + 2e- = HSnO2- + H2O + 3OH-0.90
Fe(OH)2 + 2e- = Fe + 2OH-0.877
2H2O + 2e- = H2 + 2OH-0.828
Fe(OH)3 + 3e- = Fe + 3OH-0.77
Zn2+ + 2e- = Zn
-0.763
Ag2S + 2e- = 2Ag + S2-0.69
2+
Fe + 2e = Fe
-0.440
Bi2O3 + 3H2O + 6e- = 2Bi + 6OH-0.44
Cr3+ + e- = Cr2+
-0.41
2+
Cd + 2e = Cd
-0.403
PbSO4 +2e- = Pb + SO42-0.356
Ag(CN)2- + e- = Ag +2CN-0.31
Co2+ + 2e- = Co
-0.277
Ni2+ + 2e- = Ni
-0.25
AgI + e- = Ag + I-0.151
Sn2+ + 2e- = Sn
-0.136
2+
Pb + 2e = Pb
-0.126
Cu(NH3)42+ + 2e- = Cu + 4NH3
-0.12
Fe3+ + 3e- = Fe
-0.036
2H+ + 2e- = H2
0.000
AgBr + e- = Ag + Br0.095
HgO(r) + H2O +2e- = Hg + 2OH0.098
Sn4+ + 2e- = Sn2+
0.15
2+
+
Cu + e = Cu
0.153
AgCl + e- = Ag + Cl0.222
Hg2Cl2 + 2e- = 2Hg + 2Cl0.2676
Cu2+ + 2e- = Cu
0.337
34Fe(CN)6 + e = Fe(CN)6
0.36
Ag(NH3)2+ + e- = Ag + 2NH3
0.373
O2(g) + 2H2O + 4e- = 4OH0.401
2Ag2CrO4 + 2e = 2Ag + CrO4
0.446
H2SO4 + 2e- = 2H+ + SO420.6151
Fe3+ + e- = Fe2+
0.771
Ag+ + e- = Ag
0.799
2+
Hg + 2e = Hg
0.854
O2 + 4H+ + 4e- = 2H2O
1.229
Cr2O72- + 14H+ + 6e- = 2Cr3+ + 7H2O
1.33
Cl2(g) + 2e = 2Cl
1.36
Au (s) = Au 3+ + 3 e1.50
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O
1.51
4+
3+
Ce + e = Ce
1.61
PbO2 + SO42- + 4H+ + 2e- = PbSO4 + 2H2O
1.685
H2O2 + 2H+ + 2e- = 2 H2O
1.78
F2(g) + 2e- = 2F2.87

POTENCIALES ESTNDAR DE REDUCCION DE ALGUNAS

SEMIRREACCIONES BIOLOGICAS A 25 C y pH = 7.0

SISTEMA
O2 / H2O
Cu2+/ Cu+, hemocianina
Cit f3+/ Cit f2+
Cit a3+/ Cit a2+
Cit c3+/ Cit c2+
Crotonil CoA/Butiril CoA
Fe3+/ Fe2+, hemoglobina
F3+/ Fe2+, mioglobina
Fumarato/succinato
AM/AMH2+
Oxalacetato/malato
Piruvato/lactato
Acetaldehdo/etanol
FAD / FADH2
NAD+ / NADH
NADP+ / NADPH
CO2 / formato
H+ / H2
Fe3+ / Fe2+, ferredoxin
Acido actico/acetaldehdo
Acetato /piruvato

REACCION DE MEDIA CELDA

O2(g) + 4H+ + 4e- = 2H2O
Cu2+ + e- = Cu+
Fe3+ + e- = Fe2+
Fe3+ + e- = Fe2+
Fe3+ + e- = Fe2+
Crotonil CoA + 2H+ + 2e- = butiril CoA
Fe3+ + e- = Fe2+
Fe3+ + e- = Fe2+
OOCCH=CHCOO- + 2H+ + 2e- =
OOCCH2CH2COOMB + 2H+ + 2e- = MBH2
OOCCOCH2COO- + 2H+ + 2e- =
OOCCHOHCH2COOCH3COCOO- + 2H+ + 2e- = CH3CHOHCOOCH3CHO + 2H+ + 2e- = CH3CH2OH
FAD + 2H+ + 2e- = FADH2
NAD+ + 2H+ + 2e- = NADH + H+
NADP+ + 2H+ + 2e- = NADPH + H+
CO2 + H+ + 2e- = HCOO2H+ + 2e- = H2
Fe3+ + e- = Fe2+
CH3COOH + 2H+ + 2e- = CH3CHO + H2O
CH3COOH + CO2 + 2H+ + 2e- =
CH3COCOOH + H2O

(V)

0.816
0.540
0.365
0.29
0.254
0.19
0.17
0.046
0.031
0.011
-0.166
-0.185
-0.197
-0.219
-0.320
-0.324
-0.42
-0.421
-0.432
-0.581
-0.70