P-x-y and T-x-y Diagram Construction October 3, 2013

You may discuss this problem in pairs or in groups but each individual must complete his or her own work.
Assuming Raoults Law to be valid, prepare a P-x-y diagram for a temperature of 90C and a T-x-y diagram for a pressure of 90
(a) A mixture of benzene (component 1) and ethylbenzene (component 2).
(b) A mixture of 1-chlorobutane (component 1) and chlorobenzene (component 2).

Benzene
Values for Antoine's Equation
A

B
13.7819

Calculated Saturation Pressure

2726.81

sat

T/C

P /kPa
90 136.4967836

217.572

Ethylbenzene
Values for Antoine's Equation
A

B
13.9726

T/C

C
3259.93
xB
0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.45
0.5
0.55
0.6
0.65
0.7
0.75
0.8
0.85
0.9
0.95
1

Calculated Saturation Pressure

Psat/kPa
90 24.26032121

212.3
T/C
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90
90

PT

yB

24.260321
29.872144
35.483967
41.095791
46.707614
52.319437
57.93126
63.543083
69.154906
74.766729
80.378552
85.990376
91.602199
97.214022
102.82584
108.43767
114.04949
119.66131
125.27314
130.88496
136.49678

0
0.228468338
0.384671708
0.498214471
0.584473377
0.65222789
0.706855593
0.751834377
0.789513231
0.821535905
0.849087098
0.873042251
0.894062275
0.912655476
0.929219192
0.94406851
0.957456502
0.969588766
0.98063406
0.990732197
1

er own work.
-x-y diagram for a pressure of 90 kPa for each of the following systems.

140

120

Pressure(kPa)

100

80

60

40

20
0

P-x-y Diagram - Benzene(1)/Ethylbenzene(2) @ 90C

0.25

0.5

0.75
x,y

Sat. Liquid
Sat. Vapor

Benzene
Values for Antoine's Equation
A

B
13.7819

C
2726.81

Calculated Saturation Temperature

P/kPA

217.572

Tsat/C
90 76.19911

Ethylbenzene

Calculated Saturation Temperature

Tsat/C

Values for Antoine's Equation

P/kPA
A
B
C
13.9726 3259.93
212.3
90 131.8362

T
76.19911
78.94911
81.69911
84.44911
87.19911
89.94911
92.69911
95.44911
98.19911
100.9491
103.6991
106.4491
109.1991
111.9491
114.6991
117.4491
120.1991
122.9491
125.6991
128.4491
131.8362

sat
B/kPa

90
98.09082
106.74
115.9732
125.8166
136.2967
147.4405
159.2754
171.829
185.1293
199.2048
214.0839
229.7957
246.3691
263.8335
282.2185
301.5536
321.8688
343.1938
365.5588
394.5787

sat
EB/kPa

14.48308
16.11375
17.89228
19.82859
21.93302
24.21631
26.6896
29.3644
32.25266
35.3667
38.71925
42.3234
46.19266
50.34089
54.78235
59.53165
64.60379
70.01409
75.77825
81.9123
90

xB
1
0.901304
0.811588
0.729853
0.655224
0.586933
0.524306
0.466747
0.413733
0.364799
0.319535
0.277576
0.238598
0.202313
0.168464
0.136821
0.10718
0.079355
0.053182
0.028513
0

xEB
0
0.098696
0.188412
0.270147
0.344776
0.413067
0.475694
0.533253
0.586267
0.635201
0.680465
0.722424
0.761402
0.797687
0.831536
0.863179
0.89282
0.920645
0.946818
0.971487
1

yB
1
0.982329
0.962543
0.940482
0.915978
0.888856
0.858932
0.826015
0.789904
0.750389
0.707255
0.660273
0.609209
0.553819
0.49385
0.429039
0.359116
0.283799
0.202798
0.115814
0

yEB
0
0.017671
0.037457
0.059518
0.084022
0.111144
0.141068
0.173985
0.210096
0.249611
0.292745
0.339727
0.390791
0.446181
0.50615
0.570961
0.640884
0.716201
0.797202
0.884186
1